• Title/Summary/Keyword: Dispersion characteristic

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Electrorhelological Properties of Monodispersed Submicron-sized Hollow Polyaniline Adipate Suspension

  • Sung, Bo-Hyun;Choi, Ung-Su
    • KSTLE International Journal
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    • v.6 no.1
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    • pp.28-32
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    • 2005
  • The electrorheoloRical (ER) fluids are composed of a colloidal dispersion of polarizable particles in insulating oil, and it's the rheological property changes by the applied electric field. These changed are reversible and occur fast within a fewmilliseconds. The ER properties of the ER fluid such as increment of viscosity and yield stress come from the particle chain structure induced by electric fleld. When formulating the ER fluid for a speciflc application, some requirement must besatisfled, which are high yield stress under electric field, rapid response, and dispersion stability. While this characteristic makes valuable ER fluids in valious industrial applications, their lung term and quiescent application has been limited because ofproblems with particle sedimentation. In an effort to overcome sedimentation problem of ER fluids, the anhydrous ER materials of monodispersed hollow polyaniline (PANI) and adipate derivative respectively with submicron-sized suspension providing wide operating temperature range and other advantage were synthesized in a four-step procedure. The ER fluidswere characterized by FT-lR, TGA, DLS, SEM, and TEM. Stability of the suspensions was examined by an UV spectroscopy.The rheological and electrical properties of the suspension were investigated Couette-type rheometer with a high voltagegenerator, current density, and conductivity. And the behavior of ER suspensions was observed by a video camera attached toan optical microscope under 3kV/mm. The suspensions showed good ER properties, durability, and particle dispersion.

Electrical Enhancement of Polyurethane Composites Filled with Multiwalled Carbon Nanotubes by Controlling their Dispersion and Damage

  • Kim, Yoon-Jin;Jang, Yong-Kyun;Kim, Woo-Nyon;Park, Min;Kim, Jun-Kyung;Yoon, Ho-Gyu
    • Carbon letters
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    • v.11 no.2
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    • pp.96-101
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    • 2010
  • Dispersion of the functionalized multiwalled nanotubes (MWNT) in the polyurethane (PU) matrix and DC conductivity of the MWNT/PU composites are investigated with the oxidation conditions, the kind of surfactants and their content. First, the most optimal surfactant type and its critical micelle concentration in the MWNT suspension are determined as a cationic surfactant, benzalkonium chloride (BKC) of 0.6 wt.% to the MWNT content from DEA and FESEM results. All the MWNT oxidized under several conditions are negatively charged and functionalized with carboxylic group, whereas the degree of damage is different from oxidation conditions. In addition, each MWNT/PU composite derived from several oxidation conditions shows different DC conductivity at a characteristic MWNT content. It is found that in order to enhance DC conductivity of the polymeric composites containing the oxidized MWNT the better dispersion of MWNT should be obtained by effective functionalities and surfactant adsorption with preserving the intrinsic geometry of pristine MWNT.

Numerical Simulation for Recirculation of Air Mass in the Coastal Region Using Lagrangian Particle Dispersion Model (라그랑지안 입자확산모델을 이용한 광양만 권역에서의 공기괴 재순환현상 수치모의)

  • Lee, Hwa-Woon;Lee, Hyun-Mi;Lee, Soon-Hwan;Choi, Hyun-Jung
    • Journal of Environmental Science International
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    • v.19 no.2
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    • pp.157-170
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    • 2010
  • Air mass recirculation is a common characteristic in the coastal area as a result of the land-sea breeze circulation. This study simulates the recirculation of air mass over the Gwangyang Bay using WRF-FLEXPART and offers a basic information about the effective domain size that can reflect recirculation. For this purpose, WRF is set up four nested domains and three cases are selected. Subsequently FLEXPART is operated on the basis of WRF output. During the clear summer days with weak wind speed, particles that emitted from Yeosu national industrial complex and Gwangyang iron works flow into emission sources because of the land-sea breeze. When land-sea breeze is strengthen, the recirculation phenomena appears clearly. However particles aren't recirculated under weak synoptic condition. Also plume trajectory is analyzed and as a consequence, the smallest domain area have to be multiplied by 1.3 to understand recirculated dispersion pattern of particles.

Temporal and Spatial Spreading Characteristic of Drift Soil due to the Reclamation in the Pusan Port (해양 매립 및 준설토 투기에 따른 부유사 확산의 시.공간적 특성에 관한 연구)

  • 김용원;김종인;윤한삼;홍도웅
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2000.10a
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    • pp.196-203
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    • 2000
  • In this study, the evaluation method of diffusion characteristics of Suspended Soli&SS) and the generation limit(source and thick) are investigated, which is significantly affecting on marine examined by construction works such as dredging and reclamation. Dispersion characteristics of SS is examined by hydraulic tests and numerical works in consideration with the Pusan Port. Hydraulic model test was performed in 2-D wave flume to find the limit wave conditon of re-suspension of solid as well as the time dependent characteristics of settlement The results obtainded in the study are as follows; 1) The quantituative evaluation af SS is the basic parameter of marine environmental impact assessment in related with the port development The SS increases as the water content of sea bed solid increases and the density decreases. 2) The sea bed solid in Sinsundai area, Pusan Port has the water content range of 83~157% 3) The ratio of suspension velocity against settlement velocity is about 0.25 and SS concentration converges as the wave heigh. 4) The SS increases 2 time when time step increases 3 time(10 sec to 30 sec) in numerical simulation It means that the effect of the time step should be checked in detail to stable. The diffusion The diffusion coefficient are Affiected senstively in the dispersion process while sea ved friction coefficinet have not strong relation in the simulated area

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Urea Diffusional Characteristics of Film from Dispersion Based on Poly(ethylene-co-acrylic acid) (Poly(ethylene-co-acrylic acid)의 분산입자 제조와 그 필름의 요소 투과특성)

  • Yu, Dong-Guk;An, Jeong-Ho
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.90-97
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    • 2001
  • Dispersions are prepared from poly(ethylene-co-acrylic acid) (PEAA) ionomer with two different counter-ions, ammonium and sodium. The diffusional characteristic of urea aqueous solution are measured for the films prepared from the above mentioned dispersions. It is attempted to find the relationship between diffusional behavior and various chemical and physical characteristics of films. DSC is employed to characterize glass transition temperature and degree of crystallinity and the structural features of crystal phase and ionic clusters are examined by WAXD and FTIR. The diffusional characteristics of ionomer is found to be dependent on various parameters such as the size of initial dispersion as well as the kind of counter ion and the degree of neutralization.

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Analysis of Impulse Dispersion for IR-UWB Antenna Using Time-Frequency Analysis (시간-주파수 분석을 이용한 IR-UWB 안테나 임펄스 분산 특성 분석)

  • Koh, Young-Mok;Ra, Keuk-Hwan
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.21 no.12
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    • pp.1371-1379
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    • 2010
  • This paper presents an analysis of impulse dispersion for impulse radio ultra-wide band(IR-UWB) antenna. A set of antenna structure configurations are highlighted with verification based on the STFT(Short Time Fourier Transform) in 3.1~5.1 GHz: first, a taper-slotted antenna allowing the optimal impulse transmission, and second, 4 types of the omni-directional IR-UWB antenna using different feed structures(microstrip line, and CPW(Coplanar Waveguide)). The proposed STFT allows the analysis of the IR-UWB antenna's dispersion characteristic.

A study on properties and synthesis of polyurethane compound formed hard segments by polyether polyol for lamb skin coat (Lamb skin 코팅용 polyether polyol을 이용한 hard segment를 형성하는 polyurethane compound의 합성 및 물성에 관한 연구)

  • Lee, Joo-Youb;Nam, Sang-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.2
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    • pp.296-304
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    • 2014
  • For this research, prepared polyurethane dispersion of hard segment type and polyethylene emulsion wax. Use these resin, this article has been analyzed about mechanical properties variation by increasing amount of polyethylene emulsion wax on Lam skin leather and dried film. According to measure data for solvent resistance, PUD had good property. As known in the results, increase of polyethylene wax constant did not influence to big variation of hybrid resin properties. As test of tensile strength, PUD had good tensile characteristic($1.235kg_f/mm^2$) and PUD-EW4 had lowest tensile characteristic($1.022kg_f/mm^2$). As same as tensile characteristic, abrasion test determined PUD(52.225 mg.loss) had highest properties. In elongation case, PUD showed 698 % modulus which was best properties in this experiment.

BEHAVIOR OF LIQUID LPG SPRAY INJECTING FROM A SINGLE HOLE NOZZLE

  • PARK K.
    • International Journal of Automotive Technology
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    • v.6 no.3
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    • pp.215-219
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    • 2005
  • Liquefied petroleum gas (LPG) has been used as motor fuel due to its low emissions and low cost. A liquid direct injection system into a cylinder was suggested as a next generation system to maximize a fuel economy as well as a power. This study addresses the analysis of the LPG spray injecting from single hole injector. Two different test conditions are given, which are a fully developed spray case with various injection pressures and a developing spray case with ambient pressure variation. The LPG spray photographs are compared with the sprays of gasoline and diesel fuel at the same conditions, and the spray angles and penetration lengths are also compared, and then the spray behavior is analyzed. The LPG spray photos show that the dispersion characteristic depends very sensitively on the ambient pressure soon after injection. The spray angle is very wide in a low ambient pressure condition until the saturated pressure, but the angle is quickly reduced at the condition over the pressure. However, the down stream of the LPG spray shows much wider dispersion and less penetration than those of gasoline and diesel sprays regardless ambient pressure condition.

Synthesis of Porous Carbon Particles for the Absorption of Mercury (액상수은 제어를 위한 다공성 탄소입자 제조에 관한 연구)

  • Lee, Jung-Min;Kang, Shin-Jae;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.305-305
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    • 2009
  • The carbon nano-structured materials could be applied to the fields of advanced fillers, templates, electrode materials, sensor, storage, and absorption materials. The polyacrylonitrile (PAN) based carbon nano-particles provide the remarkable properties of high specific surface area, large pore volume, chemical inertness, and good mechanical stability. In this study, well-defined carbon nano-particles were obtained through pyrolysis of polyacrylonitrile based particles. The precursor nano-particles were prepared by modified aqueous dispersion polymerization using hydrophilic poly(vinyl alcohol) in a water/ N,N-dimethylformamide mixture media. Synthesized precursor nanoparticles have relatively monodisperse particles ranging 80 ~ 250nm. Stable spherical particles are obtained without coagulum or secondary particles in our system. The characteristic of the carbon nanoparticles were investigated in terms of surface area, morphology, and size distribution.

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On the attenuation of the axisymmetric longitudinal waves propagating in the bi-layered hollow cylinder made of viscoelastic materials

  • Kocal, Tarik;Akbarov, Surkay D.
    • Structural Engineering and Mechanics
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    • v.61 no.1
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    • pp.143-160
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    • 2017
  • The paper studies the attenuation of the axisymmetric longitudinal waves propagating in the bi-layered hollow cylinder made of linear viscoelastic materials. Investigations are made by utilizing the exact equations of motion of the theory of viscoelasticity. The dispersion equation is obtained for an arbitrary type of hereditary operator of the materials of the constituents and a solution algorithm is developed for obtaining numerical results on the attenuation of the waves under consideration. Specific numerical results are presented and discussed for the case where the viscoelasticity of the materials is described through fractional-exponential operators by Rabotnov. In particular, how the rheological parameters influence the attenuation of the axisymmetric longitudinal waves propagating in the cylinder under consideration, is established.