• Title/Summary/Keyword: Dispersion behavior

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Effects of Surfactants on Dispersion Behavior of Vectran® in Water - Evaluation of Fibers Dispersion Behavior in Water with Quadrat Analysis - (Vectran®의 수중 분산 거동에 미치는 계면활성제의 영향(I) - 쿼드라트법을 결합한 수중 분산 거동 평가 -)

  • Kang, Yoo-Jung;Lee, Do-Hyun;Song, Sun-Hye;Bae, Jin-Seok
    • Textile Coloration and Finishing
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    • v.26 no.4
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    • pp.339-346
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    • 2014
  • To give a positive effect on dispersion behavior of high performance fibers $Vectran^{(R)}$ in water with reference to wet-laid nonwoven technology, 9 kinds of sulfonate type anionic surfactants were chosen to study. After dispersion experiment, the number and the area occupied by fibers in each sample were counted and figured to calculate the index of dispersion in conjunction with quadrat analysis. Similar tendency was observed in the results of two experiments. The sample without addition of any surfactant resulted in the most aggregated dispersion behavior. As the length of alkyl group attached to sulfonate increases, the sample shows more dispersed behavior. The sample with the surfactant having the aryl group and the longer alkyl group shows the most dispersed behavior and it can be seen with the naked eye as well.

Turbulent Dispersion Behavior of a Jet Issued into Thermally Stratified Cross Flows(I) (열적으로 성층화된 횡단류에 분출된 제트의 난류확산 거동(I))

  • Kim, Kyung Chun;Kim, Sang Ki
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.2
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    • pp.218-225
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    • 1999
  • Flow visualization study has been conducted to simulate the turbulent dispersion behavior of a crossflow jet physically under the conditions of various thermal stratification in a wind tunnel. A smoke jet with the constant ratio of the jet to freestream velocity is injected normally to the cross flow of the thermally stratified wind tunnel(TSWT) for flow visualization. The typical natures of the smoke dispersion under different thermal stratifications such as neutral, weakly stable, strongly stable, weakly unstable, strongly unstable and inversion layer are successfully reproduced in the TSWT. The Instantaneous velocity and temperature fluctuations are measured by using a cold and hot-wire combination probe. The time averaged dispersion behaviors, the centerline trajectories, the spreading angles and the virtual origins of the cross jet are deduced from the edge detected images with respect to the stability parameter. All the general characteristics of the turbulent dispersion behavior reveal that the definitely different dispersion mechanisms are inherent in both stable and unstable conditions. It is conjectured that the turbulent statistics obtained in the various stability conditions quantitatively demonstrate the vertical scalar flux plays a key role in the turbulent dispersion behavior.

Effects of Surfactants on Dispersion Behavior of Vectran® in Water(II) -Study on the Manufacture and Properties of Wet-laid Nonwoven Fabrics- (Vectran®의 수중 분산 거동에 미치는 계면활성제의 영향(II) - 습식부직포의 제조와 그 물성연구 -)

  • Kang, Yoo-Jung;Song, Sun-Hye
    • Textile Coloration and Finishing
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    • v.27 no.4
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    • pp.327-333
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    • 2015
  • This paper aims to manufacture nonwoven fabrics by wet-laid technology using Vectran$^{(R)}$ one of the highly favoured high-performace fiber. In previous study, a novel evaluation on fiber dispersion was studied to select optimum surfactant by the need for the control of fiber dispersion in water with reference to wet-laid nonwoven technology. 3 Types of sulfonate anionic surfactants were chosen and added in a stage of agitation to improve dispersion behavior of fibers in water. It was observed that the state of fiber dispersion in water affected various properties of nonwovens, including appearance, physical properties, and mechanical properties. Nonwoven added SDBS was uniform in web structure, thickness and weight. Its average pore was small in size and consisted of fine pores and the value of porosity was high. Further, the difference of tensile value between 2 directions was the least. Consequentially, as the dispersion behavior of fiber increases, nonwoven shows more balanced and uniform physical properties in all directions.

Modeling of rheological behavior of nanocomposites by Brownian dynamics simulation

  • Song Young Seok;Youn Jae Ryoun
    • Korea-Australia Rheology Journal
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    • v.16 no.4
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    • pp.201-212
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    • 2004
  • Properties of polymer based nanocomposites depend on dispersion state of embedded fillers. In order to examine the effect of dispersion state on rheological properties, a new bi-mode FENE dumbbell model was proposed. The FENE dumbbell model includes two separate ensemble sets of dumbbells with different fric­tion coefficients, which simulate behavior of well dispersed and aggregated carbon nanotubes (CNTs). A new parameter indicating dispersion state of the CNT was proposed to account for degree of dispersion quantitatively as well as qualitatively. Rheological material functions in elongational, steady shear, and oscillatory shear flows were obtained numerically. The CNT/epoxy nanocomposites with different dis­persion state were prepared depending on whether a solvent is used for the dispersion of CNTs or not. Dis­persion state of the CNT in the epoxy nanocomposites was morphologically characterized by the field emission scanning electronic microscope and the transmission electron microscope images. It was found that the numerical prediction was in a good agreement with experimental results especially for steady state shear flow.

Measurement of Zero Dispersion Wavelength in an Optical Fiber Using the Oscillatory Behavior of Four-Wave Mixing Efficiency

  • Kim, Dong-Hwan;Kim, Sang-Hyuck;Jo, Jae-Cheol;Choi, Sang-Sam
    • Journal of the Optical Society of Korea
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    • v.5 no.1
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    • pp.20-24
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    • 2001
  • Non-destructive measurement of zero-dispersion wavelength variation in a dispersion shifted fiber by four-wave mixing technique is carried out. The oscillatory behavior of the four-wave mixing efficiency is utilized for the measurement of the linear dispersion slope and zero-dispersion wavelength. A simple formula useful for engineering estimation of the characteristics of fiber four-wave mixing efficiency is presented.

Dispersion Behavior of Transparent Dielectric Glass Frits in the Multi-Solvent and Ammonium-Type Dispersant System (다성분 용매와 암모늄계 분산제가 적용된 투명 유전체 프릿트 슬립의 분산거동)

  • Kim, Joo-Won;Chun, Young-Hwan;Hwang, Jong-Hee;Lee, Sang-Jin
    • Journal of the Korean Ceramic Society
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    • v.43 no.10 s.293
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    • pp.635-639
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    • 2006
  • Dispersion behavior of the slurries consisted of Pb or Bi-based glass frits, which are used for the fabrication of green sheet as PDP front panel transparent dielectric, was examined in non-aqueous solvent system. Measurements of sedimentation height and viscosity were conducted to determine proper dispersion condition in the various solvent and dispersant system. Azotropic compound and ethyl acetate were used as the solvent and ammonium-type dispersant was applied to the slurries. All slurries were dispersed well in azotropic solvent system involving 20$\sim$50 vol% ethyl acetate at 2$\sim$3 wt% dispersant content. Especially, dispersion behavior was notably improved in the addition of ethyl acetate in the Bi-based frit slurry.

Biopharmaceutical Evaluation of a Solid Dispersion System Containing Sibutramine Freebase

  • Lee, Min-Suk;Chang, Hee-Chul;Kim, Taewan;Park, Jung-Hwa;Lee, Bong-Sang;Kim, Sung-Hee;Kim, Do-Hwan;Kim, Bo-Gyun;Oh, Seong-Tae;Kang, Myung-Joo;Park, Jong-Hyeok;Lee, Jaehwi;Choi, Young-Wook
    • Bulletin of the Korean Chemical Society
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    • v.29 no.4
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    • pp.749-754
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    • 2008
  • To increase the solubility of sibutramine freebase, the solid dispersion was prepared using a fluid-bed granulator. The solid dispersion containing sibutramine freebase was characterized by differential scanning calorimetry (DSC) and powder X-ray diffraction (XRD). After filling the sibutramine solid dispersion in the gelatin hard capsule, we performed in vitro dissolution test, the stability test under accelerated conditions and pharmacokinetic study in beagle dogs. The DSC and XRD data showed that sibutramine solid dispersion would be amorphous state. The dissolution rate of sibutramine solid dispersion was significantly increased about 70% than sibutramine freebase. The stability of sibutramine solid dispersion capsules was equivalent or above to commercial product of sibutramine. In beagle dogs, the sibutramine solid dispersion showed equivalent pharmacokinetic behavior with commercial product of sibutramine hydrochloride. In conclusion, the solid dispersion system provided a possible way to overcome the low solubility of sibutramine freebase, and the sibutramine solid dispersion can be a bioequivalent with the commercial product in humans.

A Study on the Kinetic Energy and Dispersion Behavior of High-velocity Impact-induced Debris Using SPH Technique (SPH 기법을 이용한 고속충돌 파편의 운동에너지와 분산거동 연구)

  • Sakong, Jae;Woo, Sung-Choong;Kim, Tae-Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.5
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    • pp.457-467
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    • 2016
  • In this study, we investigate the dispersion behavior of debris and debris cloud generated by high-velocity impacts using the smoothed particle hydrodynamics (SPH) technique. The projectile and target plate were made of aluminum, and we confirm the validity of the SPH technique by comparing the measured major and minor axis lengths of the debris cloud in the reference with the predicted values obtained through the SPH analysis. We perform high-velocity impact and fracture analysis based on the verified SPH technique within the velocity ranges of 1.5~4 km/s, and we evaluate the dispersion behavior of debris induced by the impact in terms of its kinetic energy. The maximum dispersion radius of the debris on the witness plates located behind the target plate was increased with increasing impact velocity. We derive an empirical equation that is capable of predicting the dispersion radius, and we found that 95% of the total kinetic energy of the debris was concentrated within 50% of the maximum dispersion radius.

Numerical Evaluation of charged Liquid Particle′s Behavior in Fluid Flow and Electric Field and The Electric Effect on the Particle Dispersion (유동과 전기장 내에서의 액체입자의 거동과 전기장이 입자의 산란에 미치는 영향에 관한 수치적 연구)

  • Kim, Hyeong-Min
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.4
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    • pp.570-577
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    • 2002
  • Charged liquid particle's behavior in electric and flow field was simulated to define the effect of electric field on the contact area and its dispersion. For the simulation of flow and electric field finite volume method was applied. To find out the particle's moving path in that field lagrangian equation of motion was solved by Runge-Kutta methods. We assumed that the particle was charged 10% of Rayleigh limit while the particle passing through the electrode and the particle does not have an effect on the electric field. In case of 30[Kv] of voltage charging the particles injected from the central 60% of the nozzle injection area adhere to the grounded moving plate and no dispersion occurred. Increasing the charged voltage to 40[Kv], it brought about the same phenomena as that of 30[Kv] charging except the dispersion. Voltage increasing from 30[Kv] to 40 [Kv] caused higher Coulomb force acts on the particle and it made the particle dispersion.

The rheological behavior of collagen dispersion/poly(vinyl alcohol) blends

  • Lai, Guoli;Du, Zongliang;Li, Guoying
    • Korea-Australia Rheology Journal
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    • v.19 no.2
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    • pp.81-88
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    • 2007
  • Blends of collagen dispersion (COL) with poly(vinyl alcohol) (PVA) in different weight ratios were investigated by oscillatory rheometry, Fourier transform-infrared spectroscopy and scanning electron microscopy. It was found that even with 80% of PVA, the COL/PVA blends behaved more like collagen dispersion than pure PVA solution in the dynamic thermal and frequency processing, for instance, a dominant elastic appearance (G'>G"), a similar shear thinning behavior and the thermal denaturation below $40^{\circ}C$. However, influence on the blend behaviour by PVA was noticeable, for instance, an increase of dynamic denaturation temperature, the decreasing intensity of amide I, II and III bands as well as the diminishing irregular pores on the surface of blends. The interaction between collagen and PVA could be observed, especially at the regions with low content or high content of PVA.