• 제목/요약/키워드: Dispersion Agents

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자연환기상태 실내공간에서의 화학작용제 확산 모델링 연구 (A Study on the Chemical Warfare Agents Dispersion Modelling in a Naturally Ventilated Indoor System)

  • 계영식;정우영;김용준
    • 한국군사과학기술학회지
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    • 제11권4호
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    • pp.133-140
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    • 2008
  • The purpose of this study is to provide response methods to minimize the damage from chemical terrorism in a naturally ventilated indoor system using several types of dispersion simulations. Three chemical warfare agents such as sarin(GB), phosgene and chlorine gas which have high potential to be used in terror or to be involved with accidents were selected in this simulation. Fire dynamic simulation based on Large Eddy Simulation which is effective because of less computational effort and detailed expression of the dispersion flow was adopted to describe the dispersion behavior of these agents. When the vent speed is 0.005m/s, the heights of 0.1 agent mass fraction are 0.9m for sarin, 1.0m for phosgene and 1.1m for chlorine gas, and the maximum mass fraction are 0.27 for all three agents. However, when the vent speed is increased to 0.05m/s, the heights of 0.1 agent mass fraction become 1.6m for all three agents and maximum mass fraction inside the room increase to 0.70 for sarin, 0.58 for phosgene and 0.53 for chlorine gas. It is shown that molecular weight of the agents has an important role for dispersion, and it is important to install ventilation system with height less than 1.6m to minimize the damage from chemical toxicity.

우리나라 토양(土壤)에 있어서 수종(數種) 분산제(分散劑)의 분산능(分散能)에 관(關)하여 (The Dispersion Capacity of Some Chemical Dispersing Agents in Korean Soils)

  • 임정남;조인상;조성진
    • 한국토양비료학회지
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    • 제13권2호
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    • pp.65-70
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    • 1980
  • 우리나라 토양(土壤)의 입도분석(粒度分析)에 적합(適合)한 분산제(分散劑)를 선정(選定)하기 위하여 대표토양(代表土壤) 18점(点)에 대(對)한 표토(表土) 및 심토(深土)의 입도분석(粒度分析) 결과(結果)는 다음과 같다. 1. 토양입자(土壤粒子)가 작을수록 분산제별(分散劑別) 분산능력(分散能力)의 차이(差異)가 커지는 경향(傾向)으로 점토입자(粘土粒子)(<0.002mm)의 분석치(分析値)에 있어서 분산제(分散劑)에 따라 차이(差異)가 컸었다. 2. 분산율(分散率)은 Sodium Pyrophosphate가 가장 높고 다음으로 Sodium Hexametaphophate, Ammonium Hydroxide, Sodium Hydroxide, Sodium Oxalate 순(順)이었다. 3. Sodium Hexametaphosphate는 Volcanic Ash Soil만을 제외(除外)하고 우리나라 모두 토양(土壤)의 입도분석(粒度分析)에 있어서 분산제(分散劑)로써 사용(使用)할 수 있을 것으로 본다. 4. Volcanic Ash Soil의 분산율(分散率)은 분산제(分散劑)를 사용(使用)하지 않은 경우보다 오히려 감소(減少)되는 경향(傾向)이 있으므로 이의 분산방법(分散方法)의 선정(選定)에는 특별(特別)한 주의(注意)가 요망(要望)된다.

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PU/MWNT 발포필름의 발포 특성연구 (The Characteristic of PU/MWNT Foaming Film)

  • 박준형;박미라;최라희;김승진
    • 한국염색가공학회지
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    • 제24권1호
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    • pp.79-90
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    • 2012
  • This study surveys the characteristics of the PU/MWNT foaming film according to foaming conditions. For this purpose, firstly, 16 kinds of PU/MWNT forming films were prepared with 4 kinds of dispersion solutions (IPA/MWNT, DMF/MWNT, MEK/MWNT, and Toluene/MWNT) and 4 kinds of blowing agents (organic I, organic II, capsule, and inorganic). The electrical resistivity of these PU/MWNT foaming films according to the dispersion solutions and blowing agents were analysed and discussed with surface profile and cell morphology of measured by SEM. And secondly, 24 kinds of PU/MWNT foaming films were also prepared with 2 kinds of IPA dispersion solution contents and 3 kinds of blowing agents with variation of the blowing temperatures and film thickness. The physical properties of the PU/MWNT foaming films such as electrical resistivity (surface and volume) and triboelectricity with cell morphology were measured and discused through the quantities of IPA, blowing agent added and also physical conditions(temperature, thickness so on) for establishing optimum foaming conditions with good electrostatic dissipation.

Effects of Coupling and Dispersion Agents on the Properties of Styrene-Butadiene Rubber/Butadiene Rubber Compounds Reinforced with Different Silica Contents

  • Yang, Jae-Kyoung;Park, Wonhyeong;Ryu, Changseok;Kim, Sun Jung;Kim, Doil;Kim, Jong-Ho;Seo, Gon
    • Elastomers and Composites
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    • 제53권3호
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    • pp.109-123
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    • 2018
  • The effect of the silica content on the state and properties of silica-filled styrene-butadiene rubber/butadiene rubber (SBR/BR) compounds containing coupling and dispersion agents was evaluated by varying the content of silica from 50 to 120 phr. Bis-[(triethoxysilyl)propyl] tetrasulfide (TESPT) and zinc 2-ethylhexanoate (ZEH) were used as the coupling and dispersion agents, respectively. The maximum silica content in the pristine material was 80 phr, which increased to 120 phr upon the addition of TESPT and ZEH. The incorporation of TESPT considerably improved most of the rubber properties due to its coupling action and the suppression of silica flocculation, while further addition of ZEH resulted in additional improvements. The properties of the rubber compounds with different silica contents can be fully explained either by an enhancement of the rubber-silica interactions or by their deterioration due to an excessive amount of silica aggregates.

지방산으로 개질된 글리세라이드가 실리카 충진 배합고무의 가황과 기계적 물성에 미치는 영향 (The Effect of Glyceride Modified by Fatty Acid on Mechanical Properties of Silica filled Rubber Compounds)

  • 김동욱;김창환;정호균;강용구
    • Elastomers and Composites
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    • 제48권2호
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    • pp.114-124
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    • 2013
  • 글리세라이드의 지방산 사슬길이 및 구조적 차이에 따른 영향을 평가하기 위하여 팜오일에서 추출된 글리세롤과 palmitic acid, stearic acid등 사슬길이가 $C_{12}{\sim}C_{18}$인 지방산을 이용하여, mono, di, tri등 다양한 글리세라이드 구조를 가진 신규 분산제를 합성하였고, 이를 실리카 충진배합물에 적용하여 기존의 금속염 분산제와 비교평가 하였다. 실험결과, 글리세라이드 분산제는 기존의 금속염 지방산 분산제 대비 혼합고무 내 윤활효과가 낮아서 혼합고무의 점도는 높으나, 실리카 분산이 크게 향상됨을 확인하였다. 이는 기계적 물성과 마모성능, Payne effect로 확인되었다. 또한 글리세라이드의 지방산 사슬길이가 길수록, 글리세롤에 중합된 지방산 수가 적을수록(tri- < di-< mono-glyceride)혼합고무 내 실리카 분산특성은 향상되었다.

Epoxy-Organoclay Nanocomposites의 Dispersion Agent 영향 (Effect of Dispersion Agents for Epoxy-Organoclay Nanocomposites)

  • 박재준;조대령;이현동;방병윤
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.296-297
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    • 2008
  • 층상실리케이트 나노입자가 충진된 에폭시수지를 분산정도 향상을 위해 즉, 층상실리케이트 층간간경의 삽입과 박를 향상시키기 위해 분산제를 첨가하였고, 초음파 적용으로 분산시켰다. 그 결과 분산제 종류에따라 분산정도인 X-RD 특성이 서로다른 결과를 얻었다. 절연성능을 평가하기위해 단시간 절연파괴강도와 장시간 절연파괴특성인 트리시스템을 이용하여 절연파괴시간 및 측정하였다. 이와같은 결과에대한 통계적인 분석으로 Weibull plots를 이용하였고 그 결과 분산제가 첨가된 나노콤포지트의 기울기 파라미터인 $\beta$값의 결과로부터 나노콤포지트 우수성을 확인 할수있었다.

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Lignin 화합물의 Concrete 분산성에 대한 연구 (The Effect of Lignin Compound on Dispersibility of Concrete)

  • 문정연;한기성
    • 한국세라믹학회지
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    • 제13권3호
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    • pp.37-42
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    • 1976
  • Although the water mixed into the concrete plays the role of hydration and acquiring the necessary workability, the more portion of water acts to obtain the substantial workability rather than to complete the hydration. However, the excess amount of water causes the poor quality of concrete, therefore it is useful to add the minimum amount of water as required as to acquire the proper workability. There have been the considerable numbers of investigations in which the dispersion phenomena of strong eletrolytic high polymer compounds such as lignosulfate and some of surface activation agents were studied to utilize as the dispersion agent of concrete. In the present study, Na-lignate, dispersion properties of which has not been studied yet, were investigated with the purpose of utilizing as a dispersion agent of concrete. The microscopic observations showed a great improvement in the dispersion of cement particles, also the fluidity and compressive strength of concrete were remarkably increased with the addition of Na-lignate: The addition of Na-lignate by 0.02% showed the increase of 1.76 times and 1.27 times of slump value and flow value respectively, and the compressive strength was increased by 1.07 times.

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Effect of surface treatment of graphene nanoplatelets for improvement of thermal and electrical properties of epoxy composites

  • Kim, Minjae;Kim, Yeongseon;Baeck, Sung Hyeon;Shim, Sang Eun
    • Carbon letters
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    • 제16권1호
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    • pp.34-40
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    • 2015
  • In this study, in order to improve the thermal and electrical properties of epoxy/graphene nanoplatelets (GNPs), surface modifications of GNPs are conducted using silane coupling agents. Three silane coupling agents, i.e. 2-(3,4-epoxycyclohexyl)-ethyltrimethoxysilane (ETMOS), 3-glycidoxypropyltriethoxysilane (GPTS), and 3-glycidoxypropyltrimethoxysilane (GPTMS), were used. Among theses, GPTMS exhibits the best modification performance for fabricating GNP-incorporated epoxy composites. The effect of the silanization is evaluated using transmission electron microscopy (TEM), scanning electron microscopy, thermogravimetric analysis, and energy dispersive X-ray spectroscopy. The electrical and thermal conductivities are characterized. The epoxy/silanized GNPs exhibits higher thermal and electrical properties than the epoxy/raw GNPs due to the improved dispersion state of the GNPs in the epoxy matrix. The TEM microphotographs and Turbiscan data demonstrate that the silane molecules grafted onto the GNP surface improve the GNP dispersion in the epoxy.

Development of a radiological emergency evacuation model using agent-based modeling

  • Hwang, Yujeong;Heo, Gyunyoung
    • Nuclear Engineering and Technology
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    • 제53권7호
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    • pp.2195-2206
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    • 2021
  • In order to mitigate the damage caused by accidents in nuclear power plants (NPPs), evacuation strategies are usually managed on the basis of off-site effects such as the diffusion of radioactive materials and evacuee traffic simulations. However, the interactive behavior between evacuees and the accident environment has a significant effect on the consequential gap. Agent-based modeling (ABM) is a method that can control and observe such interactions by establishing agents (i.e., the evacuees) and patches (i.e., the accident environments). In this paper, a radiological emergency evacuation model is constructed to realistically check the effectiveness of an evacuation strategy using NetLogo, an ABM toolbox. Geographic layers such as radiation sources, roads, buildings, and shelters were downloaded from an official geographic information system (GIS) of Korea, and were modified into respective patches. The dispersion model adopted from the puff equation was also modified to fit the patches on the geographic layer. The evacuees were defined as vehicle agents and a traffic model was implemented by combining the shortest path search (determined by an A * algorithm) and a traffic flow model incorporated in the Nagel-Schreckenberg cellular automata model. To evaluate the radiological harm to the evacuees due to the spread of radioactive materials, a simple exposure model was established to calculate the overlap fraction between the agents and the dispersion patches. This paper aims to demonstrate that the potential of ABM can handle disaster evacuation strategies more realistically than previous approaches.

계면활성제 종류에 따른 Mullti-walled carbon nanotube의 유기용매 분산 효과 (The effect of surfactants on the dispersion of Multi-walled carbon nanotube in organic solvent)

  • 이봉석;김원중;김태영;서광석
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.203-204
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    • 2008
  • Using various surfactants, multi-walled carbon nanotube (MWNT) was dispersed in organic solvent, isopropylalcohol(IPA). To refine the MWNT and give the functional group, MWNT was treated with sulfuric acid/nitric acid(v/v=3/1). The cationic, nonionic and anionic surfactants were used as MWNT dispersion agents in the organic solvent. Dispersion effect of various surfactants was observed by optical microscope and HR-TEM. Surface resistivities of MWNT dispersions were measured after coating on PET film. MWNT was dispersed well by poly vinyl pyrrolidone(PVP), nonionic surfactant.

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