• Title/Summary/Keyword: Disperse dyes

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Dyeing Performance of Disperse Dyes Based on 2-aminothiazole for Cellulose Triacetate and Nylon Fibers

  • Maradiya, Hari-Raghav;Patel, Vithal-Soma
    • Fibers and Polymers
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    • v.3 no.1
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    • pp.43-48
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    • 2002
  • A series of monoazo disperse dyes based on 2-amino-4-phenylthiazole was prepared using various N,N-dialkvlaniline derivatives as the coupling component. The dyes were characterized by IR spectral studies, visible absorption spectroscopy and elemental analysis. The dyeing performance of these dyes was assessed on cellulose triacetate and nylon fibers. These dyes were found to give a wide range of colour shades varying from bright red to royal blue with very good depth, brightness and levelness on fibers. The dyed fibers showed good to very good light fastness and very good to excellent fastness to washing, perspiration, rubbing and sublimation. The dyebath exhaustion and fixation on the fibers were found to be very good.

Coloration of Poly(lactic acid) with Disperse Dyes. 1. Comparison to Poly(ethylene terephthalate) of Dyeability, Shade and Fastness

  • Choi Jae-Hong;Seo Woon-Young
    • Fibers and Polymers
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    • v.7 no.3
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    • pp.270-275
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    • 2006
  • The dyeability of poly(lactic acid) [PLA] with a range of commercial disperse dye was examined and compared to that of poly(ethylene terephthalate) [PET] in addition to the colour and fastness of the resultant dyeings. A screening exercise in which twenty dyes of differing energy types and chemical classes were applied to PLA revealed a substantial variation between the dyes in terms of dye uptake (12-88 % at 4 % o.w.f.). Nine dyes exhausted above 70 % and were selected for further study, which involved comparison of shade and fastness of PLA dyeings with those of the corresponding PET dyeings. Differences in shade depended on hue while wet fastness of each of the PLA dyeings was either the same or 0.5-1.0 point lower than its PET counterpart. In all but one case, dye photostability in PLA was found to be very similar to that in PET. Dye build-up profiles on PLA were also investigated and from these results mixtures of compatible dyes identified.

반응성, 분산, 산성염료 종류에 따른 폐수처리 시 거동 비교

  • Song, Mun-Hwan;Son, Seung-Hwan;Choe, Eun-Gyeong
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.04a
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    • pp.172-174
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    • 2008
  • The study has attempted to compare the behavior of reactive, disperse and acid dyes when wastewater from these three kinds of typical dyestuffs were treated by chemical coagulation and NF membrane in pilot scale. Disperse dyeing wastewater showed the tendency of easier removal in TOC and COD and especially in color. This is probably due to low water-solubility of disperse dyes compared with reactive and acid dyes and is a positive result in terms of water reuse. Bio-kinetic constants, ${\mu}$max, $K_s$ of reactive, disperse and acid dyes were obtained, implying that their biodegradability are not significantly different.

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The Disperse Dyeing of Polyester/Cotton Blend Using a Hetero-bifunctional Bridge Compound (I) (이반응형 브리지 화합물을 이용한 폴리에스테르/면 복합소재의 단일분산염료염색 (I))

  • Kim Tae-Kyeong;Yoon Seok-Han;Kim Mi-Kyung
    • Textile Coloration and Finishing
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    • v.18 no.3 s.88
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    • pp.1-9
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    • 2006
  • In order to dye polyester/cotton blend fabric by one-bath dyeing process with single disperse dye, a novel hetero-bifunctional bridge compound(DBDCBS) was synthesized and utilized. The DBDCBS was designed to contain two different reactive groups such as ${\alpha},{\beta}$-dibromopropionylamido and dichloro-s-triazinyl groups. The ${\alpha},{\beta}$-dibromopropionylamido group shows considerable reactivity towards amines or amino groups at acidic condition and high temperature. In contrast, the dichloro-s-triazinyl group has reactivity towards hydroxyl groups at alkaline condition and room temperature. In order to examine whether as a bridge the compound could combine dyes containing amino groups with cellulosic substrates, disperse dyes containing amino group were tried to dye the cotton fibers pretreated with the DBDCBS compound. By the results, polyester/cotton blends were dyed by one-bath dyeing process with single disperse dye,1,4-diaminoanthraquinone.

The Dyeing Behavior of PET Bulky Yarn with Disperse Dyes (분산염료에 의한 폴리에스터 Bulky Yarn의 염색거동)

  • Lee, Bum Hoon
    • Textile Coloration and Finishing
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    • v.30 no.2
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    • pp.70-76
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    • 2018
  • The dyeing behaviors of poly(ethylene terephthalate)(PET) bulky yarns, DTY(draw textured yarn) and SSY(latent crimped yarn), were investigated with different energy type disperse dyes compared with those of SDY(spin draw yarn). The maximum exhaustions of E-type disperse Red 60, Blue 56 and Yellow 54 on SSY were 99%, 94% and 93%, respectively. The maximum exhaustions of S-type disperse Red 179, Blue 79 and Orange 30 on SSY were 96%, 97% and 97%, respectively. The K/S values of SSY were significantly higher than those of DTY and SDY in all energy type of disperse dyes. The knit fabric composed of SSY became bulky at the end of high temperature dyeing process because of their thermal shrinkage property due to melt viscosity difference.

Relation between Chemical Structure of Yellow Disperse Dyes and Their Lightfastness

  • Kim, Sung-Dong;Park, Eun-Jin
    • Fibers and Polymers
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    • v.2 no.3
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    • pp.159-163
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    • 2001
  • Five yellow disperse dyes were synthesized and their dyeing, fastness and photodegradation behaviors were investigated. It was found that dyes derived from phenylindole and N-alkylaminobenzene showed dye uptake directly proportional to the dye concentration, but the build-up of dyes derived from carbazole and pyridone were not good. The wavelength at maximum absorption. molar extinction coefficient. and the tendency to the photodegradation were strongly dependent on the electron donating ability of the coupling component. The dye, whose coupling component was phenylindole, possessed the excellent dyeing properties and the high degree of lightfastness. UVA had an effect on the inhibition of the photodegradation especially for the easily photodegradabte dyes.

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Synthesis of Temporarily Solubilized Reactive Disperse Dyes and Their Application to the Polyester/Cotton Blend Fabric

  • Lee, Jung-Jin;Han, Nam-Keun;Lee, Won-Jae;Park, Jae-Hong;Kim, Jae-Pil
    • Fibers and Polymers
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    • v.3 no.3
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    • pp.85-90
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    • 2002
  • Five temporarily solubilized reactive disperse dyes were synthesized and characterized. They were applied to polyester/cotton blend fabric using one-bath dyeing method without dispersing agent. The dye that has azonaphthalene chro-mophore seemed to not only be exhausted on polyester but also react with cotton. But other dyes were selectively dyed on polyester and showed limited uptake on cotton. Good levelling as well as moderate to good colour fastness was obtained with the dyes on P/C blend fabric.

Dyeing Properties and Improvement of Washfastness of Ultrafine Polyester (해도형 극세사 폴리에스테르의 염색성 및 세탁견뢰도 향상에 관한 연구)

  • 김성동;이권선;이병선;안창희;김규식
    • Textile Coloration and Finishing
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    • v.15 no.1
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    • pp.48-55
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    • 2003
  • As the polyester fiber becomes thinner, thermomigration that is the most important factor deteriorating the washfastness, is more dominant. For improving the washfastness of ultrafine polyester dyed with disperse dye, it is necessary either to decrease the amount of thermomigrated dyes on the fiber surface, or to use a disperse dye containing diester group in the coupling component. This paper is concerned to investigate the relation between the chemical structure of three disperse dyes and their dyeing properties and washfastness. The disperse dye whose molecular size is big, can dye ultrafine polyester with good build-up, and its washfastness is reasonably good. Other disperse dye which has diester group, shows the same dyeing properties as the standard disperse dye, and its washfastness is better than that of the standard disperse dye.

Effects of Thermomigration on the Washfastness of Disperse Dyes Having Different Molecular Size

  • Kim, Sung-Dong;Kim, Min-Jung;Lee, Byung-Sun;Lee, Kwon-Sun
    • Fibers and Polymers
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    • v.5 no.1
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    • pp.39-43
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    • 2004
  • Effects of chemical structure of disperse dyes applied to conventional and microdenier polyesters on the dyeing property and washfastness were studied. It was found that washfastness of dyed polyester fabric is closely related to the degree of thermomigration of disperse dye during heatsetting. The bulky disperse dye, which was synthesized by substituting two acetoxy groups of C.I. Disperse Red 82 with two benzoxy groups, showed almost the same amount of absorbed dye by the microdenier polyester as C.I. Disperse Red 82, but the degree of thermomigration was low and subsequent washfastness was excellent. The high grade of washfastness of the bulky disperse dye might be caused by the increased dye-fiber interaction and the reduced mobility.

DYEING BEHAVIOR OF NEW DISPERSE-REACTIVE DYES

  • Kim, Tae-Kyung;Oh, Sea-Wha;Shin, Seung-Rim
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2002.04a
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    • pp.9-12
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    • 2002
  • The Dyestuff is fixed to the fiber to color it in a unique way depending on the chemistry between them. Whenever there arose problems in coloring fibers, the chemistry of dyestuff could be adjusted to solve them. That manner new concept dye classes, e.g., reactive dyes, disperse dyes, cationic dyes, have arrived along with the introduction of new fibers. The attempt has made to introduce the new reactive dye to solve this problem.

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