• Proceedings of the Korean Fiber Society Conference
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• 2003.10b
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• pp.225-226
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• 2003

일시적 수용성 반응성 분산염료는 염료합성시에 분산제를 사용하지 않기 때문에 원가절감 및 밀링공정 생략에 의한 생산성 증대효과가 있다[1-2l. 또한 혼방섬유를 단일염료로 일욕에서 염색할 수 있기 때문에 공정단축의 효과, 염색공정시에도 분산제를 사용하지 않아도 되므로 조제절감 및 염색폐수의 환경문제 개선 둥의 장점이 있다. 3원색(yellow, red, blue)의 일시적 수용성 반응성 분산염료를 이용하여, Acetate/Nylon(A/N), Acetate/polyester(A/P), Polyester/Nylon(P/N) 혼방섬유를 일욕에서 염색하였으며, 염색성, 견뢰도 및 염색폐수의 환경성을 평가하였다. (중략)

• Nuclear Engineering and Technology
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• v.4 no.2
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• pp.90-101
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• 1972

Radiation grafting of acrylic acid to Polyester fabric has been studied by an impregnation method to render its surface more hydrophilic. Impregnated fabric was irradiated under nitrogen with gamma-ray from Co-60. The homopolymer formed usually could be extracted with water at 10$0^{\circ}C$. Graft-fabric exhibited a good acceptability to acid, basic or disperse dyes in conventional aqueous dye bath at moderate temperature.

• Textile Coloration and Finishing
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• v.34 no.3
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• pp.146-156
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• 2022

In this study, the dyeing properties of double knit fabric composed of PET/PTT bi-component fiber and quick dry fiber were examined with disperse dyes. In addition, the shrinkage characteristics were investigated during the dyeing process. The K/S values and shrinkage rate of PET/PTT bi-component fiber were higher than those of PET/co-PET bi-component fiber and quick dry fiber. In the dye bath, dye migration of exhausted on PET/PTT bi-component fiber to quick dry fiber was found at high dyeing temperature. It was not found that there was a significant difference in K/S value on dyeing temperature between 115℃ and 130℃. But the slight color difference of two sides of a double knit fabric was found.

• Journal of the Korean Society of Clothing and Textiles
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• v.30 no.2 s.150
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• pp.275-285
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• 2006

The purpose of this study was to examine the change of dyeing ability by K/S values, when dyed in different twisting processes and by one bath system and two bath system, to find possible ways of minimizing the color difference between cotton and polyester in composite yarn. The two types of composite yarn, which had one setting process(CP1) and two setting processes(CP2) were dyed with reactive/disperse dyes in both one bath dyeing system and two bath system. The dyeing ability according to the two different twisting processes was measured, and the values of the CP1 were higher compare to the values of CP2 in both one and two bath dyeing systems. This is because CP1 applied only one setting could shrink dyeing process at 130$^{circ}C$. This shrinkage increased the number of twists in the unit length and increased the yarn density, and this is the reason that the K/S values were measured higher than those of CP2. In wet shrinkage test, in opposition to CP2 only had 0.76$\%$ of the shrinkage rate, CP1 had 3.00$\%$ of the shrinkage rate. Also, the dyeing ability according to the two different dyeing methods was measured, and the values of CP1 and CP2 were both higher when dyed in two bath system. On the other hand, the color differences between cotton and polyester in composite yarns, were smaller for CP2 than that for CP1 and were also smaller in two bath dyeing system than in one bath dyeing system. Therefore, the ways of minimizing color difference between cotton and polyester in composite yarn are to apply enough setting in order to minimize shrinkage in dyeing process and to choose two bath dyeing system.

• Textile Coloration and Finishing
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• v.8 no.6
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• pp.9-26
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• 1996

이 연구의 목적은 에틸렌이민 유도체를 갖는 아조계 분산 염료의 나일론 6.6 섬유에의 응용과 최적화된 폴리에스테르 및 나이론 극세사 섬유 염색 조건의 확립이다. 세가지 아지리디닐 모노 아조 염료와 이들 염료의 가수분해 된 형태 그리고 디메틸아닐린계 아조 염료의 폴리에스테르 및 나일론 6.6 극세사 섬유에 대한 염색 및 견뢰도 성질이 조사되었다. 염색 조건 중 pH의 변화에 따른 섬유상의 염착량 변화 조사에서 뚜렷한 경향을 얻을 수 없었으며, 이는 극세사 섬유의 물리적 성질이 두드러지게 착용한 이유라 여겨진다. 염색된 폴리에스테르 극세사 섬유상에서, 아지리디닐 염료는 이들의 가수 분해된 형태 그리고 디메틸아닐린계 아조 염료의 비교하여 개선된 견뢰도 성질을 나타내었다. 아지리디닐 아조 염료의 나일론 극세사 섬유 염색 시 pH 증가에 따라 세탁 및 광견뢰도가 개선되었고, pH8의 염색 조건에서 최적 견뢰도 개선을 나타내었다. 아지리디닐 아조 염료가 이들 염료의 가수분해 된 형태 그리고 디메틸아닐린계 아조 염료와 비교하여 폴리에스테르 및 나일론 섬유상에서 보다 개선된 견뢰도 성질을 나타내었고 이는 섬유와 염료간의 공유 결합으로 기인한 것으로 여겨진다.

• Textile Coloration and Finishing
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• v.11 no.5
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• pp.22-29
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• 1999

The increase in color depth of polyester fiber dyed with black disperse dyes was investigated with respect to the kinds of resins and alkali treatment. The color depth of the dyed polyester fiber increased continuously according to the concentration of resins coated onto the fabrics. The alkali treatment to polyester fiber before dyeing also enhanced the color depth. It was thought that the polyester fiber was hydrolyzed by alkali resulting micropores on the sample. And the following treatment with a resin, Jet Black T-101, to the polyester fiber increased the color depth much higher. The successive process of alkali treatment, dyeing and Jet Black T-101 treatment could give the best color depth to polyester fiber. Although the alkali treatment reduced the tensile strength of polyester fiber, the color depth of polyester fiber enhanced sufficiently within the range of practically acceptable weight loss and strength. To analyze the micropore on the polyester fiber formed by alkali treatment, nitrogen porosimeter was used. As the weight loss of polyester fiber treated with alkali increased, the BET(Brunauer-Emmett-Teller) surface area, total pore volume, and average pore size of the sample increased.

• Textile Coloration and Finishing
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• v.11 no.2
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• pp.27-37
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• 1999

Polypropylene(PP) films were treated with plasma glow discharge to produce peroxy radicals on the surfaces. The peroxy radicals formed on the PP film surfaces were subsequently used for the graft polymerization of acrylic acid and acrylamide in an aqueous solution by heating, respectively. Introduction of acrylic acid and acrylamide on the PP film could be confirmed by the observation of carbonyl and primary amine absorptions based on carboxylic acid and amide, respectively. And introduction of functional group could be confirmed by weight analysis and ESCA. The water contact angle(90$^{\circ}$) of PP film was constant, irrespective of elapsed time, while plasma-treated and functional monomer-grafted PP films were slowly increased with elapsed time, showing the rearrangement of surface polar groups in air condition. The water contact angle$(90^\circ)$ of PP film was decreased by the plasma treatment$(56^\circ)$ and further decreased by the grafting of acrylic acid$(34^\circ)$ and acrylamide$(37^\circ)$, indicating increased hydrophilicity of the modified surfaces. The water contact angle of plasma-treated PP film increased a little as time elapsing. The half-life periods of surface voltage on acrylic acid-(31sec) and acrylamide-grafted PP(42sec) were significantly decreased when compared to those on PP(950sec) and plasma-treated PP film(241sec). In the experiments using acid, basic and disperse dyes, absorbance and $\Delta{E}$ values of functional monomer-grafted PP films were significantly increased than that of oxygen plasma-treated one.

• Fibers and Polymers
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• v.5 no.4
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• pp.321-326
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• 2004

[ $TiO_2$ ] contents in yarns can influence color yield so that dyeing quality of industrial polyethylene terephthalate (PET) yarns can be improved through the adjustment of $TiO_2$ contents. To evaluate the dyeing performance of color yield, the chips which included the different $TiO_2$ contents of 330,550, and 1,100 ppm respectively were used to produce the yarns of different $TiO_2$ content by a spin-draft machine. The physical and structural properties of the yarns were measured to investigate effect of the $TiO_2$ contents on them. Dye uptake and dyeing rate were also evaluated using a colorimeter to compare the yarns having different TiOz contents. The experimental results showed that there were no appreciable variation in physical and structural properties among the yarn samples and no difference were observed among the dyed fabric samples with regard to dyeing uptake and dyeing rate. However, the color yield of dyed fabrics increased as $TiO_2$ contents decreased in the yarns especially when the fabric samples were dyed to pale shade. The physical reasoning could be proposed on why the yarns having low $TiO_2$ contents appeared to have higher color yield after dyeing.

• Textile Coloration and Finishing
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• v.8 no.5
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• pp.25-48
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• 1996

이 연구의 목적은 에틸렌이민 유도체를 갖는 아조계 분산 염료의 폴리에스테르 섬유에의 응용과 최적화된 폴리에스테르 염색 조건의 확립이다. 이들 아지리디닐 염료는 구조가 유사하며 말단에 하이드록시기를 갖는 염료(아지리디닐 염료의 가수분해 형태)와 비교하여 최대 흡수 파장의 천색적으로 천이 됨을 알 수 있었다. 세가지 아지리디닐 모노 아조 염료와 이들 염료의 가수분해 된 형태 그리고 디메틸아니린계 아조 염료의 폴리에스테르 섬유에 대한 염색 및 견뢰도 성질이 조사되었다. 아지리디닐 아조 염료는 산성 조건에서보다 염기성 조건하에서 보다 안정하였고, 뛰어난 build-up이 높은 pH조건에서 얻어졌으며, 폴리에스테르 염색 시 130$^{\circ}C$, pH 10의 조건에서 최적화된 색상 강도를 얻었다. 아지리디닐 염료는 이 염료의 가수분해 형태와 디메틸아닐린 염료와 비교하여 개선된 세탁 견뢰도를나타내었고 이는 용매 추출을 이용하여 확인 하였다. 아지리디닐 아조 염료는 역시 광 련뢰도에서도 또한 상용화된 분산 염료에 비교하여 높은 결과를 나타내었다.

• Textile Coloration and Finishing
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• v.8 no.5
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• pp.49-67
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• 1996

이 연구의 목적은 에틸렌이민 유도체를 갖는 아조계 분산 염료의 나일론 6.6 섬유에의 응용과 최적화된 나일론 염색 조건의 확립이다. 두 쌍의 염료 A-1/A-2와 D-1/D-2의 최대흡수파장(&{\lambda}_{max}&)을 비교할 경우, 아세톤 최대흡수파장(λ$_{max}$)의 차이가 없거나 적어졌다. 세가지 아지리디닐 모노 아조 염료와 이들 염료의 가수분해 된 형태 그리고 디메닐아닐린계 아조 염료의 나일론 6.6 섬유에 대한 염색 및 견뢰도 성질이 조사되었다. 아지리디닐 염료의 나일론 섬유상의 최대 염착은 pH 5에서 얻어졌으며, 염색된 나일론 섬유에서의 용매추출의 경우 최소 염료 추출은 pH 8.0-10.0 에서 얻어졌다. 아지리디닐 염료 염색된 나일론 섬유상의 세탁 견뢰도와 광 견뢰도는 염색 시 pH의 증가에 따라 증가하였으나, pH 8에서의 견뢰도 성질이 pH 10에서와 비교하여 보다 개선되었다. 세가지 아지리디닐 염료가 이들 염료의 가수분해 된 형태 그리고 디메틸아닐린계 아조 염료와 비교해서 나일론 6.6 섬유상에서 보다 개선된 견뢰도를 나타내었고 이는 염료와 섬유간의 공유 결합으로 기인한 것으로 여겨진다.