• Textile Coloration and Finishing
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• v.22 no.2
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• pp.94-100
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• 2010

Colored compounds adsorption from the textile dyeing effluents on activated carbons produced from various indigenous vegetable sources by zinc chloride activation is studied. The most important parameters in chemical activation were found to be the chemical ratio of $ZnCl_2$ to feed (3:1), carbonization temperature (460-470 $^{\circ}C$) and time of activation (75 min). The absorbance at 511 nm (red effluent) and 615 nm (blue effluent) are used for estimation of color. It is established that at optimum temperature ($50^{\circ}C$), time of contact (30-40 min) and adsorbent loading (2 g/L), activated carbons developed from rain tree (Samanea saman) saw dust and blackberry (Randia formosa) tree saw dust showed great capability to remove color materials from the effluents. It is observed that adsorption of reactive dyes by all types of activated carbons is more than that of disperse dyes. It is explained that because of its acidic nature the activated carbon can adsorb better reactive dye particles containing large number of nitrogen sites and $-SO_3Na$ group in their structure. The use of activated carbons from the indigenous biomass would be economical, because saw dusts are readily available waste worldwide.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.9
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• pp.532-540
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• 2019

PET microfibers with various diameters (0.5, 0.2, 0.06, and 0.01 dpf) were dyed with a dispersed dye (C.I. Disperse Blue 56) at various temperatures. The dyeing process was conducted under infinite dyebath conditions at constant temperatures. The effects of the dyeing temperature and diameter on the partition coefficient, affinity, and diffusion coefficient of disperse dyes were studied. The curve of isotherms was fitted well to Nernst-type model in a large range of initial dye concentrations. At the same temperature, the partition coefficient and affinity decreased with increasing sample diameter due to the increase in surface area. At all deniers, the partition coefficient and affinity decreased with increasing temperature because the dyeing process is an exothermic reaction. In addition, the decrease in radius of the sample gives rise to a decrease in the heat of dyeing. The fine diameter of the sample resulted in an increased surface area but decreased space between the microfibers. Consequently, decreasing the diameter of the microfibers leads to a decrease in the diffusion coefficient. At the same diameter, the diffusion coefficient increased with increasing temperature because of rapid dye movement and the large free volume of the sample inside. In addition, thermal dependence of the diffusion coefficient increased when the diameter of the sample increased.

• Journal of Fashion Business
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• v.10 no.4
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• pp.151-162
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• 2006

This study investigated into the effects of the colors of warp and weft on the overall colors of fabrics, along with the visual changes of colors by the measuring angle of both warp and weft, by means of cross-dyeing of cotton/PET union fabrics. First, the reflectance of polyester is higher than that of cotton over the whole wavelength. Second, the dyeing of polyester uses the disperse dyes and that of cotton uses fiber-reactive dyes, the differences in the features of dyes and the reflectance of fabrics cause the same colors to be perceived different by the angle of observation. Third, the dyeing of cotton and PET fabrics individually with the same color revealed that the dyeing of cotton and PET fabrics in one bath resulted in a small difference in colors between the two fabrics than the separate dyeing in two bathes. In the case of one bath, the dyeing of PET fabrics followed by that of cotton fabrics resulted in a small difference in color than the dyeing in the reversed order. Fourth, when cotton/PET union fabrics were dyed in ten colors, the difference in colors between the two fabrics was small; and due to the difference in the density of warp and weft of union fabrics, some difference was detected in comparison with the results of separate dyeing of cotton and PET fabrics in one bath. The latter did not produce the changes in color which was recognizable with the naked eyes. Fifth, when cotton/PET union fabrics were dyed in ten colors, any color change was not observed by the measuring angle, and the inclination in the direction of warp or weft resulted in the tendency of color-deepening. In the measurement of the latter, the inclination in the direction of weft resulted in the higher color-deepening than that in the direction of warp, due to the influence of weft.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2008.04a
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• pp.55-57
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• 2008

본 연구에서는 신규원사인 Rayonmimetics(RMM) 섬유를 상품화 된 분산염료를 가지고 염색하여 PET 섬유와 비교하였다. RMM 섬유의 염착률은 기존 PET 섬유와 비슷하였으나, critical adsorption range는 10$^{\circ}C$ 정도 낮았다. Colorimetric properties를 비교해 보면, a${\ast}$값과 b${\ast}$값에서 color에 따른 경향성을 보이며, PET 섬유와 대비하여 duller 해졌다. 견뢰도는 PET 섬유와 비슷한 견뢰도를 보였다.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2008.04a
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• pp.19-21
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• 2008

The quinolone antibiotics Ciprofloxacin shows broad antimicrobial spectrum, heat stability, limited water solubility, and similar structure and size to disperse dyes. The object of this study is to develop the infection-resistant medical extile material by applying Ciprofloxacin to a series of polyester materials such as PET, PDO, PLA, and PGA. All the Ciprofloxacin compound polyester materials demonstrated the superior antimicrobial activity to the organisms S. aureus and E. coli.

• Textile Coloration and Finishing
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• v.13 no.3
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• pp.197-202
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• 2001

The mechanical properties and dyeability of Poly(trimethylene terephthalate)(PTT) were investigated and compared to PET. Glass transition temperature of PTT was lower than that of PET, because amorphous region of PTT is mote flexible. n has smaller molecular and specific stress and larger strain than those of PET, due to the difference of molecular structure. Dyeing transition temperature of PTT was lower by $20^\circ{C}$ than that of PET. Because PTT has flexible chain and zigzag structure, dyeing Fate of PTT is faster than PET and dyeing of PTT is begun at lower temperature. As the hydrophobicity of disperse dyes increased, the ratio of equilibrium dye uptake on PTT to that on PET was increased.

• Textile Coloration and Finishing
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• v.10 no.5
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• pp.48-55
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• 1998

Polyester fabric is widely used in textile material though it has some problems such as low colour value, high refractive ratio(1.62) and etc. In order to give Z-black colour of polyester fabric, this study has selected several disperse dyes by measuring of absorbance, dyed in their optimum conditions and treated with 4 kinds of low refractive compounds such as silicone, fluorine, urethane and silicone-fluorine mixed compounds. The bathochromic effect of treated PET fabric evaluated as lightness(L) change by uv-visible spectrophotometer. This study also investigated that the effect of used bathochromic agents on the washing and lightfastness of treated PET fabric.

• Textile Coloration and Finishing
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• v.31 no.4
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• pp.258-267
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• 2019

Synthetic suede without PFCs(perfluorinated compounds) are followed by subsequent high temperature treatment. But migration fastness of synthetic suede may be reduced due to sublimation of disperse dyes that results from the high temperature treatment. Therefore, in this study, chitosan treatment was used to improve the migration fastness before polyurethane dipping process. Polyester fiber was treated with sodium hydroxide aqueous solution before chitosan processing. This samples treated with a chitosan concentration upto 0.5% were dyed and coated with PUD(polyurethane dispersion). The migration fastness was most improved at 0.35% application. This is presumably due to the fact that the chitosan may increase the dye-binding capability through intermolecular hydrogen bonding.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2008.10a
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• pp.25-26
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• 2008

일반적인 분산염료, Phthalimide계 중간체로 사용한 분삼염료, Diester계 커플러만 이용한 분산염료와 비교한 Diester계 치환기를 이용한 분산 염료들은 R/C조건과 EtOAc와 증류수로 층분리하여 증류수층의 UV-Vis absorbance은 떨어지고 용해성은 증가한다. 그리고 Thiopene ring만 가진 염료와 비교한 염료들은 같은 파장에서의 UV-Vis absorbance은 떨어져 용해도는 증가하고 Thiopene ring과 Azo group의 분해에 의한 화합물 때문에 단파장에서의 UV-Vis absorbance가 크게 증가하여 염색 폐수의 색도를 감소시킬 수 있다.

• Textile Coloration and Finishing
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• v.13 no.1
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• pp.9-17
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• 2001

The purpose of this study is to present basic data for the enzymatic modification of acetate fabrics. The weight loss and rate of weight loss of acetate fabrics increased with increasing NaOH concentration and treating time. Acetyl value decreased as the weight loss became higher. The weight loss of alkaline-treated acetate fabrics were directly proportional to the concentration and treating time of cellulase. The optimum temperature and pH in cellulase treatment were $55^\circ{C}$ and pH 3.5. The surface shape revealed that density of fiber decreased by alkaline-treatment. With the treating time of cellulase, fibrillation occurred. In case of higher weight loss in alkaline treatment, fibril is removed after 180 min. The tensile strength decreased by alkaline and cellulase treatment. Especially, in case of higher weight loss of alkaline treatment, tensile strength decreased suddenly. Alkaline treatment increased the drapability of acetates, while cellulase treatment increased it initially but decreased gradually with treatment time. The dyeability after alkaline treatment was improved for reactive dye, but deteriorated for disperse dye. The cellulase treatment of acetate lowered the dyeability for both types of dyes.