• Title/Summary/Keyword: Discharge water

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Perfluorinated Sulfonic Acid based Composite Membranes for Vanadium Redox Flow Battery (바나듐 레독스 흐름 전지를 위한 과불소화 술폰산 복합막)

  • Cho, Kook-Jin;Park, Jin-Soo
    • Journal of the Korean Electrochemical Society
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    • v.19 no.1
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    • pp.21-27
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    • 2016
  • Vanadium redox flow batteries (VRFBs) using the electrolytes containing various vanadium ions in sulfuric acid as supporting solution are one of the energy storage devices in alternatively charging and discharging operation modes. The positive electrolyte contains $V^{5+}/V^{4+}$ and the negative electrolyte $V^{2+}/V^{3+}$ depending on the operation mode. To prevent the mixing of two solutions, proton exchange membranes are mainly used in VRFBs. Nafion 117 could be the most promising candidate due to the strong oxidative property of $V^{5+}$ ion, but causes high crossover of electroactive species to result in a decrease in coulombic efficiency. In this study, the composite membranes using Nafion ionomer and porous polyethylene substrate were prepared to keep good chemical stability and to decrease the cost of membranes, and were compared to the properties and performance of the commercially available electrolyte membrane, Nafion 117. As a result, the water uptake and ionic conductivity of the composite membranes increased as the thickness of the composite membranes increased, but those of Nafion 117 slightly decreased. The permeability of vanadium ions for the composite membranes significantly decreased compared to that for Nafion 117. In a single cell test for the composite membranes, the voltage efficiency decreased and the coulombic efficiency increased, finally resulting in the similar energy efficiency. In conclusion, the less cost of the composite membranes by decreasing 6.4 wt.% of the amount of perfluorinated sulfonic acid polymer due to the introduction of porous substrate and lower vanadium ion permeability to decrease self-discharge were achieved than Nafion 117.

Analysis of Impact of Hydrologic Data on Neuro-Fuzzy Technique Result (수문자료가 Neuro-Fuzzy 기법 결과에 미치는 영향 분석)

  • Ji, Jungwon;Choi, Changwon;Yi, Jaeeung
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.4
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    • pp.1413-1424
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    • 2013
  • Recently, the frequency of severe storms increases in Korea. Severe storms occurring in a short time cause huge losses of both life and property. A considerable research has been performed for the flood control system development based on an accurate stream discharge prediction. A physical model is mainly used for flood forecasting and warning. Physical rainfall-runoff models used for the conventional flood forecasting process require extensive information and data, and include uncertainties which can possibly accumulate errors during modelling processes. ANFIS, a data driven model combining neural network and fuzzy technique, can decrease the amount of physical data required for the construction of a conventional physical models and easily construct and evaluate a flood forecasting model by utilizing only rainfall and water level data. A data driven model, however, has a disadvantage that it does not provide the mathematical and physical correlations between input and output data of the model. The characteristics of a data driven model according to functional options and input data such as the change of clustering radius and training data length used in the ANFIS model were analyzed in this study. In addition, the applicability of ANFIS was evaluated through comparison with the results of HEC-HMS which is widely used for rainfall-runoff model in Korea. The neuro-fuzzy technique was applied to a Cheongmicheon Basin in the South Han River using the observed precipitation and stream level data from 2007 to 2011.

Effect of Juvenile Fish Predation on the Zooplankton Community in the Large Regulated Nakdong River, South Korea (저수지화 성향을 띤 낙동강에서 치어 섭식이 동물플랑크톤 군집에 미치는 영향)

  • Chang, Kwang-Hyeon;Hwang, Soon-Jin;Jang, Min-Ho;Kim, Hyun-Woo;Jeong, Kwang-Seuk;Joo, Gea-Jae
    • Korean Journal of Ecology and Environment
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    • v.34 no.4 s.96
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    • pp.310-318
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    • 2001
  • In the large regulated Nakdong River, the Predation effect of juvenile fish on the zooplankton community was evaluated by gut and stomach analyses of fish in 1999. Juvenile fish of five species showed high density from May to early June when river discharge was low and water body became stagnant. During this period, large rotifers, Asplanchna spp. and Brachionus spp. declined and the decrease of cladoceran (Moina micrura and Bosminopsis deitersi) density was also obeserved. At this time, small rotifers including Polyarthra spp. reached maximum density. Gut analysis of fish demonstrated that small-sized juvenile fish (< 15 mm in total length)preferred large rotifers as well as cladocerans, while large sized fish (> 15 mm)selected only cladocerans. On the other hand, juvenile Micropterus salmoides of which size was larger than other juvenile fish consumed not only zooplankton but also other small juvenile fish. Based on these results, the decline of large rotifers and cladocerans during early summer in the river seems to be result of predation by juvenile fish. However, the period when juvenile fish maintained their high density was as short as one month and the decreased density of cladocera rapidly recovered as soon as juvenile fish became scarce. Such a short period of juvenile fish devel-opment in the river can be attributed to the consumption of juvenile fish by the young-of-the-year cohorts as well as adults of M. salmoides. The high trophic state of the river might permit the rapid recovery of the cladoceran community. The predation impact of juvenile fish in the Nakdong River seems to be affected by the existence of piscivore as well as high trophic status.

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Trace Metals of Suspended Particulate Matters in the Keum River (금강 부유물중 미량 금속의 함량과 이동)

  • 최만식;이창복
    • 한국해양학회지
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    • v.30 no.5
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    • pp.371-381
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    • 1995
  • To investigate the concentrations and transport patterns of particulate metals in river suspended matters, eighteen samples were collected from a fixed station located in the upper part of the Keum River through one year, and analysed for major elements (AI, Fe, P, Mn) and trace elements (Cr, Co, Ni, Cu, Zn, Cd, Pb, U). The contents of metals in suspended particulate matters (SPM) varied greatly with season and SPM load; maximum value in winter with low SPM level and minimum value in flood period and in spring Yangtze SPMs. The different trace metal level between rivers of Korea and China may be caused by the different geology of drainage basin(U) and by the different extent of anthropogenic input (Mn, Pb). Most of all particulate metals (>70%) except Mn, P and Cd were transported in the flood period with high water discharge and high suspended load. The magnitude of each transport phase (dissolved, non-detrital and detrital metals) was compared. The portions of labile metals (dissolved plus non-detrital metals) in the aquatic environment were in the range of 50%(Co) to 92%(Mn) of total metal transport and in the rank of Mn>Cd, U>Cu>Zn>Ni>Pb>Co.

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Contribution of Nutrient Flux through the Korea Strait to a Primary Production in the Warm Region of the East Sea (동해 난수역의 일차생산에 대한 대한해협 유입 영양염의 기여)

  • Lee, Tongsup;Rho, Taekeun
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.18 no.2
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    • pp.65-69
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    • 2013
  • In situ measurement of a primary production in East Sea, a marginal sea with a fair accessibility, is nonetheless an arduous task because of dynamic variability. In this study, we estimated the mean value of background (gross) primary production over the warm region of the East Sea based on a biogeochemical hypothesis. We propose an immiscible-shoaling hypothesis for the estimation of primary production, which assumes that primary production in the warm region occurred only by the nutrient supply through the Korea Strait. Annual primary production thus estimated is $209\;gC\;m^{-2}\;y^{-1}$, which is comparable to the satellite-based estimates of net primary production in the region. However, since this hypothesis assumes that primary production is based on only the new nutrients supplied to the system, primary production would increase by 40% if we release the assumption, and assume f = 0.6. This suggests that nutrient influx through the Korea Strait alone is more than enough to support primary production previously reported. Primary production may increase as much as two times if we considered other external perturbations excluded intentionally to estimate the background level of primary production, such as coastal upwelling, submerged ground water discharge, aeolian input, ocean dumping, and mixing by typhoons as well as the contribution of cyanobacteria that has not been quantified in the region. This implies the primary production in the warm region of the East Sea would be comparable to that of the Peru upwelling region with f = 0.6.

Five human cases of Diphyllobothrium latum infection through eating raw flesh of redlip mullet, Liza haenatocheila (가숭어 (Liza haemotocheila)가 감염원으로 추정되는 광절열두조충 집단감염)

  • 정평림;최운준
    • Parasites, Hosts and Diseases
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    • v.35 no.4
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    • pp.283-290
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    • 1997
  • A total of 32 human diphyllobothriasis cases have been reported so far in Korea, exclud- ing 21 egg-positive cases from stool examinations. Authors experienced five more human cases of DiphHllobothrium latum infection, especially infected due to eating raw flesh of redlip mullet, Lizc hoematocheiln. Five cases were neighbors residing in the Puchon area, Kyonggi-do, who ate raw mullets (L. hQematocheila) in a party in February 1996. The mul- lets were purchased at the Noryangjin fisheries market in Seoul. All of cases (2 males and 3 females) were 35 to 43 years old and healthy with the body weight range of 56-62 kg. They complained about gastrointestinal trouble and abdominal discomfort, but were in normal ranges of their hematology and urinalysis data. None revealed any sign of anemia The patients experienced natural discharge of a chain of segments before, and showed diphyllobothriid eggs in their stool specimens when they visited our laboratory. They were administered with praziquantel (15 mg/kg of body weight) and 30 g of magnesium sulfate as a purgative. Two whole worms with the scolices (310-340 cm in length; 8-13 mm in width) were expelled each from two out of five cases after anthelmintic treatment, and the others expelled the parts of strobilae without scolex. The worms were identified as D. Ictum, based on the following biological characters. external morphologies, coiling of uterus, the number of uterine loops, position of genital opening, morphologies of cirrus, cirrus sac and seminal vesicle on the histological sections, position of vagina and uterine pore , and microscopical and SEM morphologies of the eggs.

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A Study on Introduction to Performance based Design of Sprinkler Installation on Risk Level for Individual Occupancy in Korea (공간용도별 위험등급기반의 스프링클러헤드 성능 설계기법의 국내적용 연구)

  • Lee, Young-Jae;Park, Hyung-Joo
    • Fire Science and Engineering
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    • v.26 no.2
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    • pp.1-10
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    • 2012
  • While a performance based sprinkler design method has been widely used in UK and USA according to fire hazards of occupancies, Korean fire safety industry could not yet accept it due to nonstandardization on risk level of various occupancy. Even only two or three spray pattern sprinkler was produced in Korea fire safety industry, therefore, various spray pattern sprinklers have not yet introduced to major occupancies. Spray pattern sprinklers with one of two K value have been used in all occupancies in Korea Market. UK and USA's Fire industry should produced the spray sprinklers with various K-factors and protection area due to performance based sprinkler design requirement. Therefore the fire load density for main occupancies has been investigated in order to compare with installation standard in advanced countries. Eventually a lot of variations in orifice and K factors of standard heads were set up including special heads needed for high hazard areas such as large drop type, enlarged orifice type and early suppression fast response.

A preliminary study of the hydraulic-geometrical relations of bed slope in some selected alluvial rivers (우리 나라 沖積河川 河床傾斜의 水理機何 特性에 관한 연구)

  • ;;;Woo, Hyoseop;Yu, Kwonkyu;Park, Jongkwan
    • Journal of the Korean Geographical Society
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    • v.29 no.3
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    • pp.253-265
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    • 1994
  • The hydraulic-geometrica1 relations between the riverbed slope and water discharge and other hydraulic variables in some selected alluvial rivels in Korea have been investigated. The rivers from which the data relevant to this study were collected are mainly the first tributaries, considered to be mostly in the equilibrium state, of the 10 major rivers in Korea. The investigating methods adopted in this study are similar to the one suggested by Leopold and Maddock and the one suggested by Garde. All of 18 rivers their drainage areas of which range between 100-2,000 $\textrm{km}^2$ were considered and the changes in riverbed slope, drainage area, bed material size along the downstream river distance were measured. It is found in this study that the change in the riverbed slope, S, along the downstream can be expressed in terms of the coefficient, $\beta$, expressing the change in the drainage area along the downstream and the drainage area, A, by an empirical relation as 0.0063 0.0063 S = $S_{ 0}$ $A_{0}$$^{-------- +0.51}$A-$^{-------- -0.51}$. $\beta$ $\beta$ According to this relation, the riverbed slope of the river reaches investigated in this study appear to be proportional to the -0.6th power of the drainage area. This result is consistent with the previous ones obtained by Hack.k.

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Experimental Investigation of Effects of Sediment Concentration and Bed Slope on Debris Flow Deposition in Culvert (횡단 배수로에서 토석류 퇴적에 대한 유사농도와 바닥경사 영향 실험연구)

  • Kim, Youngil;Paik, Joongcheol
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.5B
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    • pp.467-474
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    • 2011
  • Debris flow is one of the most hazardous natural processes in mountainous regions. The degradation of discharge capacity of drainage facilities due to debris flows may result in damages of properties and casualty as well as road. Understanding and accurate reproducing flow behaviour of debris flows at various conditions, such as sediment volume concentration and approaching channel and culvert slopes, are prerequisite to develop advanced design criteria for drainage facilities to prevent such damages. We carried out a series of laboratory experiments of debris flows in a rectangular channel of constant width with an abrupt change of bottom slope. The experimental flume consists of an approaching channel part with the bed slope ranging $15^{\circ}$ to $30^{\circ}$ and the test channel with slope ranging from $0^{\circ}$ to $12^{\circ}$ which mimics a typical drainage culvert. The experiments have been conducted for 22 test cases with various flow conditions of channel slopes and sediment volume concentration of debris flows to investigate those effects on the behaviour of debris flows. The results show that, according to sediment volume concentration, the depth of debris flow is approximately 50% to 150% larger than that of fresh water flow at the same flow rate. Experimental results quantitatively present that flow behaviour and deposit history of debris flows in the culvert depend on the slopes of the approaching and drainage channels and sediment volume concentration. Based on the experimental results, furthermore, a logistic model is developed to find the optimized culvert slope which prevents the debris flow from depositing in the culvert.

Development of Flood Control Effect Index by Using Fuzzy Set Theory (Fuzzy 집합 이론을 이용한 홍수조절효과 정량화 지표 개발)

  • Kim, Juuk;Choi, Changwon;Yi, Jaeeung
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.5B
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    • pp.415-429
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    • 2011
  • Quantitative evaluation indexes for flood control effect of a multi-purpose reservoir used widely in Korea are the discharge control rate, reservoir release rate, reservoir storage rate, and flood control storage utilization rate. Because these indexes usually use and compare inflow, release, and storage data directly, the uncertainties included in these data are not considered in evaluation process, and the downstream flood control effects are not assessed properly. Also, since the acceptable partial failure in a design of water resources system is not considered, the development of a new flood control effect evaluation index is required. Fuzzy set theory is therefore applied to the development of the index in order to consider the data uncertainty, the downstream flood control effect, and the acceptable partial failure. In this study, the flood control effect of a multi-purpose reservoir is evaluated using the flood control effect index developed by applying fuzzy set theory. The Chungju reservoir basin was selected as a study basin and the storm events of July, 2006 are used to study the applicability of the developed index. The related factors for flood control effect are fuzzified, the acceptable failure region is divided from the system state to evaluate the flood control effect using developed flood control effect index. The flood control effect index were calculated by applying to the study basin and storm events. The results show that the developed index can represent the flood control effect of a reservoir more realistically and objectively than the existing index.