• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.362-365
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• 1999

The electrochemical properties of flyash obtained from combustion of fuel in fossil power plants and their performance as anode material of secondary battery have been investigated Various flysh pellets molded at various molding pressure have been used as anode lithium secondary battery. The best Performance was achieved when flyash pellet molded at pressure of 400kgf/$\textrm{cm}^2$ is utilized, that is, charge capacity of 300kgf/$\textrm{cm}^2$ and Coulombic efficiency of larger than 95% have been achieved. In addition, this battery exhibited good cycling performance. Considering these results, we predicted that utilization of the flyash as anode material and polyaniline conducting polymer as cathode material in a secondary will show capacity of 300mAh/g and Coulombic efficiency of higher than 95%.

• 한국재료학회지
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• 제16권6호
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• pp.346-350
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• 2006

Al-doped ZnO (AZO) thin films were grown on type of glass#1737 substrates by DC magnetron sputtering. The structural, electrical and optical properties of the films were investigated as a function of various plasma discharge power. The obtained films were polycrystalline with a hexagonal wurtzite structure and preferentially oriented in the (002) crystallographic direction. The lowest resistivity was $6.0{\times}10^{-4}{\Omega}cm$ with the carrier concentration of $2.69{\times}10^{20}cm^{-3}$ and Hall mobility of 20.43 $cm^2/Vs$. The average transmittance in the visible range was above 90%.

• 한국세라믹학회지
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• 제21권2호
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• pp.121-126
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• 1984

The dielectric properties of $BaTiO_3$ containing 0~0.3mol% and ZnO respectively as additives were investigated as a function of temperature from $25^{\circ}C$ to 14$0^{\circ}C$ and frequency from 24 KHz to 15MHz. The density of sintered $BaTiO_3$ was increased with addition of increasing to 0.15mol% amounts of $Sb_2O_3$ and the dielectric constant was also increased. This is due to space charge polarization with Ba vacancies. Above 0.15mol% $Sb_2O_3$ the density was decreased and the dielectric constant was also decreased due to occuring the discharge through voids. The density of sintered $BaTiO_3$ was decreased with addition of increasing to 0.15mol% amounts of ZnO and the dielectric constant was decreased due to occuring the discharge through voids. Above 0.15mol% ZnO the density was increased and the dielectric constant was also increased.

• Bulletin of the Korean Chemical Society
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• 제18권1호
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• pp.61-65
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• 1997

The electrochemical properties of LixCoyNi1-yO2 compounds (y=0.1, 0.3, 0.5, 0.7, 1.0) prepared by citrate sol-gel method have been investigated. The LixCoyNi1-yO2 compounds were annealed at 850 ℃ for 20 h after preheating at 650 ℃ for 6 h, in air. The x-ray diffraction (XRD) patterns for LixCoyNi1-yO2 have shown that these compounds have a well developed layered structure (R&bar{3} m). From the scanning electron microscopy of LixCoyNi1-yO2, particle size was estimated less than 5 μm. The Li//LixCoyNi1-yO2 electrochemical cell consists of Li metal anode and 1 M LiClO4-propylene carbonate (PC) solution as the electrolyte. The differences in intercalation rate of the LixCoyNi1-yO2 in the first charge/discharge cycle were less than 0.05 e-. The first discharge capacities of LixCoO2 and LixCo0.3Ni0.7O2 were ∼130 mAh/g and ∼160 mAh/g, respectively.

• Bulletin of the Korean Chemical Society
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• 제22권12호
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• pp.1328-1332
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• 2001

The structure and electrochemical properties of the LixCoyNi1-yO2 (y=0.1, 0.3, 0.5, 0.7, 1.0) system synthesized by solid state reaction with various starting materials have been investigated to optimize the characteristics and synthetic conditions of the LixCoyNi1-yO2. The first discharge capacities of LixCoyNi1-yO2 are 60 mAh/g-180 mAh/g with synthetic conditions. Among them, the LixNi0.7Co0.3O2, which was prepared with LiOH, NiO, and Co3O4 at $850^{\circ}C$, had the best electrochemical properties. The first discharge capacity of the compound was 180 mAh/g.

• 한국초전도ㆍ저온공학회논문지
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• 제11권2호
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• pp.29-32
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• 2009

The conduction cooling HTS SMES magnet is operated in cryogenic temperature. The insulation design at cryogenic temperature is an important element that should be established to accomplish miniaturization that is a big advantage of HTS SMES. However, the behaviors of insulators for cryogenic conditions in air or vacuum are virtually unknown. Therefore, we need active research and development of insulation concerning application of the conduction cooling HTS SMES. Specially, this paper was studied about high vacuum and cryogenic temperature breakdown and flashover discharge characteristics between cryocooler and magnet-coil. The breakdown and surface flashover discharge characteristics were experimented at cryogenic temperature and vacuum. Also, we were experimented about mechanical properties of 4-point bending test. From the results, we confirmed that about research between cryocooler and magnet-coil established basic data in the insulation design.

• 지질공학
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• 제4권2호
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• pp.153-168
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• 1994

지하수 개발을 위한 한국 농어촌진흥공사 충남지사의 축적 자료로부터 충청남도 지역의 지하수 개발 현황을 각 군별 지역에 따라 지질특성과 비교, 검토하였다. 조사관정 212개의 관측자료로부터는 집수면적과 양수량의 관계를 살펴보고, 개발판정 344개 관측자료로부터는 시추공 심도와 양수량 관계, 케이싱 심도와 양수량 관계, 암석종류와 양수량 관계, 그리고 선구조 분포와의 관계들을 검토하였다. 집수면적과 양수량의 관계는 일정한 관련성을 보이지 않으며, 이는 충적층보다 암반층 지하수가 많을 때는 지표의 집수면적의 영향이 작음을 의미한다. 시추공 심도와 양수량의 관계는 충적층 지하수의 경우에는 충적층이 깊을수록 지하수량이 많으나, 암반층 지하수의 경우에는 선형적으로 약간씩 증가하는 경향이 있으며, 풍화대 심도는 케이싱 심도로 추정할 수 있다. 암석 종류의 영향은 별 차이가 없으나 결정질 암석인 화강암과 편마암이 퇴적암과 편암에서보다 평균 양수량이 약간 많은 것으로 나타났으며, 이는 파쇄대 효과가 크다는 것을 의미한다. 암석종류, 케이싱 심도등이 비슷하면서도 양수량의 차이가 큰 홍성군과 부여군에서는 선구조 분포를 비교하였으며, 선구조의 교차점 밀도나 길이 밀도가 높은 홍성군의 양수량이 더 크게 나타났다. 따라서 심층 지하수 개발 방향은 집수면적이나 암석종류에 착안하기 보다는 선구조, 파쇄대 등을 파악하기 위하여 미지형 분석을 수행하고, 물리탐사 자료를 참고하여 추진함이 바람직하다고 판단된다.

• 한국세라믹학회지
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• 제40권6호
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• pp.507-512
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• 2003

The LiN $i_{l-y}$ $Co_{y}$ $O_2$ samples were synthesized at 80$0^{\circ}C$ and 85$0^{\circ}C$, by the solid-state reaction method, from the various starting materials LiOH, L $i_2$C $O_3$, NiO, NiC $O_3$, $Co_3$ $O_4$, CoC $O_3$, and their electrochemical properties are investigated. The LiN $i_{l-y}$ $Co_{y}$ $O_2$ pre-pared from L $i_2$C $O_3$, NiO, and $Co_3$ $O_4$ exhibited the $\alpha$-NaFe $O_2$ structure of the rhombohedral system (space group; R3m). As the Co content increased, the lattice parameters a and c decreased. The reason is that the radius of Co ion is smaller than that of Ni ion. The increase in da shows that two-dimensional structure develops better as the Co content increases. The LiN $i_{0.7}$ $Co_{03}$. $O_2$［HOO(800,0.3)] synthesized at 80$0^{\circ}C$from LiOH, NiO, and $Co_3$ $O_4$ exhibited the largest first discharge capacity 162 mAh/g. The size of particles increases roughly as the valve of y increases. The samples with the larger particles have the larger first discharge capacities. The cycling performances of the samples with the first discharge capacity larger than 150 mAh/g were investigated. The LiN $i_{0.9}$ $Co_{0.1}$ $O_2$［COO(850,0.1)］ synthesized at 85$0^{\circ}C$ from L $i_2$C $O_3$, NiO, and $Co_3$ $O_4$ showed an excellent cycling performance. The sample with the larger first discharge capacity will be under the more severe lattice destruction, due to the expansion and contraction of the lattice during intercalation and deintercalation, than the sample with the smaller first discharge capacity. As the first discharge capacity increases, the capacity fading rate thus increases.increases.s.s.s.

• 한국지반신소재학회논문집
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• 제6권2호
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• pp.1-8
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• 2007

최근 경제가 성장함에 따라 산업지역과 거주지의 요구가 증가하고 있다. 그러나 양질의 지반상태 지역을 구하기가 어렵다. 경제적이고 균형적인 지역 발전을 위하여 내륙지역 뿐만 아니라 연약지반에도 새로운 프로젝트가 수행되고 있다. 연약지반은 복잡한 공학적 특성과 강도가 낮고 대상 지역의 심도가 깊은 많은 변수를 가지고 있기 때문에 연약지반의 공학적 특성을 정확하게 분석하고 안정적인 계측과 경제적인 설계와 관리방법을 찾는 것이 필요하다. 연직배수공법은 프리로딩과 통수능력을 가진 여러 종류의 배수재를 사용하여 연약지반과 퇴적지반의 압밀촉진을 위하여 많이 사용되고 있다. 현장조건에서 통수능력은 지반상태, 구속압력, 장기간의 배수재 막힘과 꺽임과 같은 다양한 원인으로 변한다. 그러므로 많은 연구자들이 공학적인 소요통수능의 사용을 추천하였다. 본 논문에서는 4가지 코어형태의 연직배수재의 대형통수능력 시험을 수행하고 압밀영향요소에 따른 소요통수능을 산정하였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2007년도 제32회 학술대회 초록집
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• pp.182-182
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• 2007