• 제목/요약/키워드: Direct Synthesis

검색결과 591건 처리시간 0.037초

합성가스로부터 디메틸에테르 직접 합성 (Direct Synthesis of Dimethyl Ether from Synthesis Gas)

  • 함현식;김송형;강영구;신기석;안성환
    • 한국가스학회지
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    • 제13권4호
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    • pp.8-14
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    • 2009
  • 하이브리드 촉매를 이용하여 합성가스로부터 디메틸에테르(DME)를 1단계 공정으로 합성하였다. 하이브리드 촉매는 메탄올 합성반응을 위하여 Cu-ZnO-$Al_2O_3$, 메탄올 탈수반응을 위하여 aluminum phosphate 혹은 $H_3PO_4$-modified $\gamma$-alumina로 구성되었다. 제조한 촉매들은 XRD, BET, SEM, FT-IR, $NH_3$-TPD를 이용하여 특성분석을 하였다. XRD 분석을 통해 aluminum phosphate가 잘 합성되었음을 알 수 있었다. BET 분석을 통해 aluminum phosphate의 비표면적이 P/Al의 비에 따라서 달라짐을 확인할 수 있었다. 반응실험 결과 메탄올 탈수 촉매로 사용된 aluminum phosphate의 P/Al의 비가 1.2인 하이브리드 촉매에서 55%의 CO 전환율과 70%의 DME 선택도를 보여 주었다. $\gamma$-alumina를 인산으로 처리한 경우 촉매활성 감소를 막을 수 있었다. 하지만 85%의 진한인산으로 처리한 경우에는 촉매 활성 및 DME 선택도가 낮아짐을 확인할 수 있었다.

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폐과일껍질을 이용한 친환경 NiO 나노분말 합성 및 향균특성 연구 (Enviroment-Friendly Synthesis of Nanocrystalline Nickel Oxide and Its Antibacterial Properties)

  • ;송재숙;홍순익
    • 한국재료학회지
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    • 제28권1호
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    • pp.24-31
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    • 2018
  • This study reports an environment-friendly synthetic strategy to process nickel oxide nanocrystals. A mesoporous nickel oxide nanostructure was synthesized using an environmentally benign biomimetic method. We used a natural rambutan peel waste resource as a raw material to ligate nickel ions to form nickel-ellagate complexes. The direct decomposition of the obtained complexes at $700^{\circ}C$, $900^{\circ}C$ and $1100^{\circ}C$ in a static air atmosphere resulted in mesoporous nickel oxide nanostructures. The formation of columnar mesoporous NiO with a concentric stacked doughnuts architecture was purely dependent on the suitable direct decomposition temperature at $1100^{\circ}C$ when the synthesis was carried out. The prepared NiO nanocrystals were coated on cotton fabric and their antibacterial activity was also analyzed. The NiO nanoparticle-treated cotton fabric exhibited good antibacterial and wash durability performance.

음성/영상의 인식 및 합성 기능을 갖는 가상캐릭터 구현 (Cyber Character Implementation with Recognition and Synthesis of Speech/lmage)

  • 최광표;이두성;홍광석
    • 전자공학회논문지CI
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    • 제37권5호
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    • pp.54-63
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    • 2000
  • 본 논문에서는 음성인식, 음성합성, Motion Tracking, 3D Animation이 가능한 가상캐릭터를 구현하였다. 음성인식으로는 K-means 128 Level VQ와 MFCC의 특징패턴을 바탕으로 Discrete-HMM 알고리즘을 이용하였다. 음성합성에는 반음절 단위의 TD-PSOLA를 이용하였으며, Motion Tracking에서는 계산량을 줄이기 위해 Fast Optical Flow Like Method를 제안하고, 3D Animation 시스템은 Vertex Interpolation방법으로 Animation을 하고 Direct3D를 이용하여 Rendering을 하였다. 최종적으로 위에 나열된 시스템들을 통합하여 사용자를 계속적으로 주시하면서 사용자와 함께 구구단 게임을 할 수 있는 가상캐릭터를 구현하였다.

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Synthesis of direct-patternable ZnO film incorporating Pt Nanoparticles

  • Choi, Yong-June;Park, Hyeong-Ho;Reddy, A.Sivasankar;Park, Hyung-Ho
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.369-369
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    • 2007
  • ZnO film has been investigated during several decades because it has excellent optical property like a transmittance among the range of visible light for using transparent conducting oxide (TCO) films. But ZnO film has not enough conductivity for applying to TCO devices. Therefore we synthesized platinum nanoparticles and they incorporated into ZnO due to improve the electrical property of ZnO film by sol-gel synthesis method. Also, we fabricated photosensitive ZnO thin film containing Pt nanoparticles by sol-gel process and spin-coating for using photochemical solution deposition. Photosensitive ZnO film could carry out the direct-pattern which allow the etching process to be convenient. The optical and electrical properties of ZnO film with or without various atomic percent of Pt nanoparticles annealed at various temperatures were investigated by using UV-Vis spectroscopy and 4-point probe method, respectively. We characterized the ZnO thin film containing Pt nanoparticles using X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy.

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Direct synthesis of Neu5Ac from GlcNAc using NALasc and GlcNAc 2-epimerase

  • 이정규;이정오;이선구;김병기
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2001년도 추계학술발표대회
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    • pp.210-214
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    • 2001
  • GlcNAc 2-epimerase gene from human was cloned. However GIcNAc 2-epimerase was expressed in E. coli as inclusion body formation. Several approaches were tried such as expression in low temperature and low concentration of IPTG. With these treatments production of active form of human GIcNAc 2-epimerase ι ,vas enhanced. For the direct synthesis of NeuAc from GlcNAc and pyruvate, NALase and GlcNAc 2-epimerase were characterized in terms of temperature effect on activity. equilibrium and stability, inhibition by pyruvate etc. For cheap and ease preparation of both the NALase and GlcNAc 2-epimerase, pEN24ma vector was made. which express both the NALasc and GIcNAc 2-epimerase simultaneously. In addition, E. coli BL21(DE3) harboring two plasmids was also made. Of the two systems, the latter was better for the expression of both enzymes.

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