• 제목/요약/키워드: Direct Diffusion

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Characterization of Wavelength Effect on Photovoltaic Property of Poly-Si Solar Cell Using Photoconductive Atomic Force Microscopy (PC-AFM)

  • Heo, Jinhee
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.3
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    • pp.160-163
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    • 2013
  • We investigated the effect of light intensity and wavelength of a solar cell device by using photoconductive atomic force microscopy (PC-AFM). The $POCl_3$ diffusion doping process was used to produce a p-n junction solar cell device based on a Poly-Si wafer and the electrical properties of prepared solar cells were measured using a solar cell simulator system. The measured open circuit voltage ($V_{oc}$) is 0.59 V and the short circuit current ($I_{sc}$) is 48.5 mA. Also, the values of the fill factors and efficiencies of the devices are 0.7% and approximately 13.6%, respectively. In addition, PC-AFM, a recent notable method for nano-scale characterization of photovoltaic elements, was used for direct measurements of photoelectric characteristics in local instead of large areas. The effects of changes in the intensity and wavelength of light shining on the element on the photoelectric characteristics were observed. Results obtained through PC-AFM were compared with the electric/optical characteristics data obtained through a solar simulator. The voltage ($V_{PC-AFM}$) at which the current was 0 A in the I-V characteristic curves increased sharply up to 1.8 $mW/cm^2$, peaking and slowly falling as light intensity increased. Here, $V_{PC-AFM}$ at 1.8 $mW/cm^2$ was 0.29 V, which corresponds to 59% of the average $V_{oc}$ value, as measured with the solar simulator. Also, while light wavelength was increased from 300 nm to 1,100 nm, the external quantum efficiency (EQE) and results from PC-AFM showed similar trends at the macro scale, but returned different results in several sections, indicating the need for detailed analysis and improvement in the future.

Transdermal Delivery of Triamcinolone acetonide Gel by Ultrasound (초음파 조사에 의한 트리암시놀론 아세토니드 겔의 피부투과)

  • Song, Kyung-Suk;Kim, Young-Il;Yang, Jae-Heon
    • Journal of Pharmaceutical Investigation
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    • v.32 no.2
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    • pp.87-93
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    • 2002
  • This study is to enhance drug penetration via skin and investigate anti-inflammation effect following adoption of ultrasound. For this goal gel containing triamcinolone was prepared and the skin penetration rate and the change effects of blood plasma ingredients and serum enzyme were investigated. Using Franz type diffusion cell and the skin of hairless mouse, the permeation enhancing effect of ultrasound was tested. After the injury by direct trauma, the blood test was performed by measuring WBC, lymphocyte, and neutrophyl, and by analyzing CPK and LDH. The ultrasound transducer whose technical specification is geometric area(GA) $1.4\;cm^2$, effective radiation area(ERA) $0.8\;cm^2$, and beam non-uniformity ratio(BNR) 6.0 max was used. The influence of frequency having an effect on skin permeation rate was higher in the case of using 1MHz and continuous treatment. The temperature of receptor phase was not influenced in skin permeation by phonophoresis. Skin permeation increase attended by intensity of ultrasound, the permeation of triamcinolone was accelerated at $2.5\;w/cm^2\;than\;1.0\;w/cm^2$. Following muscle injury phonophoretic group the number of WBC, neutrophil and lympholyte were decreased significantly as compared with both control group and ultrasound group. The result of variation of serum CPK and LDH activity conformed to the phonophoretic effect as same pattern with the variation of WBC, neutrophil and lymphocyte.

Dissecting Aneurysm of Vertebral Artery Manifestating as Contralateral Abducens Nerve Palsy

  • Jeon, Jin Sue;Lee, Sang Hyung;Son, Young-Je;Chung, Young Seob
    • Journal of Korean Neurosurgical Society
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    • v.53 no.3
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    • pp.194-196
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    • 2013
  • Isolated abducens nerve paresis related to ruptured vertebral artery (VA) aneurysm is rare. It usually occurs bilaterally or ipsilaterally to the pathologic lesions. We report the case of a contralateral sixth nerve palsy following ruptured dissecting VA aneurysm. A 38-year-old man was admitted for the evaluation of a 6-day history of headache. Abnormalities were not seen on initial computed tomography (CT). On admission, the patient was alert and no signs reflecting neurologic deficits were noted. Time of flight magnetic resonance angiography revealed a fusiform dilatation of the right VA involving origin of the posterior inferior cerebellar artery. The patient suddenly suffered from severe headache with diplopia the day before the scheduled cerebral angiography. Neurologic examination disclosed nuchal rigidity and isolated left abducens nerve palsy. Emergent CT scan showed high density in the basal and prepontine cistern compatible with ruptured aneurismal hemorrhage. Right vertebral angiography illustrated a right VA dissecting aneurysm with prominent displaced vertebrobasilar artery to inferiorly on left side. Double-stent placement was conducted for the treatment of ruptured dissecting VA aneurysm. No diffusion restriction signals were observed in follow-up magnetic resonance imaging of the brain stem. Eleven weeks later, full recovery of left sixth nerve palsy was documented photographically. In conclusion, isolated contralateral abducens nerve palsy associated with ruptured VA aneurysm may develop due to direct nerve compression by displaced verterobasilar artery triggered by primary thick clot in the prepontine cistern.

Vortex dynamics in YBa$_2Cu_3O_7$ single crystals measured by micro Hall-probe array (Micro Hall probe array를 이용한 YBa$_2Cu_3O_7$ 단결정 내부의 자속 운동 측정)

  • Shim, Seong-Yeop;Hwang, Hyeon-Guk;Lee, Chang-Woo;Lee, Tae-Won;Kim, Dong-Ho
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.189-195
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    • 1999
  • We have studied the vortex dynamics in YBa$_2Cu_3O_7$ single crystals with columnar defects using micro Hall-probe array. The Hall-probe array technique allowed a simultaneous measurement of the time and spatial dependence of the vortex density so that more detailed information on flux dynamics could be obtained. We found that field profiles inside sample were similar to the Bean's critical state model from the magnetic hysteresis measurement. Normalized relaxation rates were maximum near the center and decreased toward the edge if applied field H$_{app}$ is greater than the penetration field H. But applied magnetic field H$_{app}$ is less than H, relaxation rates were minimum near the center and increased toward edge. We found that glassy exponent ${\mu}$ has the value of ${\sim}$ 1 whose corresponding vortex motion is half-loop excitation. However, single vortex creep, ${\mu}$ ${\sim}$ 1/7, was also found at 30 K and H$_{app}$ ${\cong}$ H'. Calculation of activation energy, U, was possible from direct analysis of the local relaxation data using the basic diffusion equation. From these results, we found that U increases logarithmically with time and U around center was lower than that at the edge.

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Molecular and Genomic Approaches on Nickel Toxicity and Carcinogenicity

  • Seo, Young-Rok;Kim, Byung-Joo;Ryu, Jae-Chun
    • Molecular & Cellular Toxicology
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    • v.1 no.2
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    • pp.73-77
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    • 2005
  • Nickel is the one of potent environmental, the occupational pollutants and the classified human carcinogens. It is a serious hazard to human health, when the metal exposure. To prevent human diseases from the heavy metals, it is seemingly important that understanding of how nickel exerts their toxicity and carcinogenic effect at a molecular and a genomic level. The process of nickel absorption has been demonstrated as phagocytosis, iron channel and diffusion. Uptaked nickel has been suggested to induce carcinogenesis via two pathways, a direct DNA damaging pathway and an indirect DNA damaging pathway. The former was originated from the ability of metal to generate Reactive Oxygen Species (ROS) and the reactive intermediates to interact with DNA directly. Ni-generated ROS or Nickel itself, interacts with DNAs and histones to cause DNA damage and chromosomal abnormality. The latter was originated from an indirect DNA damage via inhibition of DNA repair, or condensation and methylation of DNA. Cells have ability to protect from the genotoxic stresses by changing gene expression. Microarray analysis of the cells treated with nickel or nickel compounds, show the specific altered gene expression profile. For example, HIF-I (Hypoxia-Inducible Factor I) and p53 were well known as transcription factors, which are upregulated in response to stress and activated by both soluble and insoluble nickel compounds. The induction of these important transcription factors exert potent selective pressure and leading to cell transformation. Genes of metallothionein and family of heat shock proteins which have been known to play role in protection and damage control, were also induced by nickel treatment. These gene expressions may give us a clue to understand of the carcinogenesis mechanism of nickel. Further discussions on molecular and genomic, are need in order to understand the specific mechanism of nickel toxicity and carcinogenicity.

Improvement in Reduction Performance of LNT-Catalyst System with Micro-Reformer in Diesel Engine (연료 개질장치의 적용에 따른 디젤 LNT 환원성능 개선 특성)

  • Park, Cheol-Woong;Kim, Chang-Gi;Kim, Kwan-Tae;Lee, Dae-Hoon;Song, Young-Hoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.7
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    • pp.689-696
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    • 2010
  • The Because of its high thermal efficiency, the direct injection (DI) diesel engine has emerged as a promising potential candidate in the field of transportation. However, the amount of nitrogen oxides ($NO_x$) increases in the local high-temperature regions and that of particulate matter (PM) increases in the diffusion flame region during diesel combustion. In the de-$NO_x$ system the Lean $NO_x$ Trap (LNT) catalyst is used, which absorbs $NO_x$ under lean exhaust gas conditions and releases it in rich conditions. This technology can provide a high $NO_x$-conversion efficiency, but the right amount of reducing agent should be supplied to the catalytic converter at the right time. In this research, the emission characteristics of a diesel engine equipped with a micro-reformer that acts as a reductants-supplying equipment were investigated using an LNT system, and the effects of the exhaust-gas temperature were also studied.

A Study on the Characteristics of Ignition and Combustion, in a Diesel Spray Using Multi-Component Mixed Fuels (다성분 혼합연료를 이용한 디젤분무의 착화연소특성에 관한 연구)

  • Yoon, Jun-Kyu;Lim, Jong-Han
    • Journal of Energy Engineering
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    • v.16 no.3
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    • pp.120-127
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    • 2007
  • The purpose of this study is experimentally to analyze that the fuel mass fractions of multi-component mixed fuels have an effect on the characteristics of spray ignition and combustion under the ambient conditions of diesel combustion fields. The characteristics of ignition and combustion were investigated by chemiluminescence images and direct photography. The experiments were conducted in the RCEM(rapid compression expansion machine) with optical access. Multi-component fuels mixed with i-octane, n-dodecane and n-hexadecane are injected in RCEM by the electronic control of common rail injector. Experimental conditions set up 42, 72 and 112 MPa in injection pressure, 700, 800 and 900 K in ambient gas temperature. The results show that the ignition delay was dependent on high cetane number. In case of low ambient temperature, the more low boiling point fuels were mixed, the lower luminance regime had a remarkable effect and also shortened diffusion combustion by increasing heat release rate.

Characteristics of Suspended Solids Movement in the Sand Recalmation of Breakwater (방파제 모래치환공사시 부유토사의 거동 특성)

  • Maeng, Jun-Ho;Lee, Ji-Wang;Kim, Byung-Jun;Ko, Jung-Yong;Yang, Gwon-Yeol
    • Journal of Environmental Impact Assessment
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    • v.9 no.2
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    • pp.127-142
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    • 2000
  • This research was performed for analyzing the transport of suspended solids during the harbor construction. In behalf of the research, we have analyzes the characteristics of suspended solids movement in sand reclamation of breakwater according to age of tide and tidal period at the construction spot of Pusan new harbor. In the process of sand reclamation, soil was dumped by a dumping device which direct soil from the barge to the bottom of the sea. According to the results from this research, suspended solid concentration was very high in the range of 5m from the dumping point right after the dumping. However these suspended solids settled very quickly and the solids concentration was very beyond 10m from the dumping point. It is deduced that the movement of solids dumped from barge has the tendencies as following; 1) Most of the dumped solids precipitated quickly after the dumping 2) The rest of the suspended solids are diffused slowly toward the bottom of the water being figured smoothing curve 3) The diffusion movement of suspended solids tend to proceed toward the shore line in a parallel motion with tidal current at the sea-bottom That is to say, most of the suspended solids precipitated very quickly even though highly concentrated solids produced at the bottom of the solids which did not precipitated spread with the tidal current horizontally along the bottom of the sea.

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Exploration of growth mechanism for layer controllable graphene on copper

  • Song, Woo-Seok;Kim, Yoo-Seok;Kim, Soo-Youn;Kim, Sung-Hwan;Jung, Dae-Sung;Jun, Woo-Sung;Jeon, Cheol-Ho;Park, Chong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.490-490
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    • 2011
  • Graphene, hexagonal network of carbon atoms forming a one-atom thick planar sheet, has been emerged as a fascinating material for future nanoelectronics. Huge attention has been captured by its extraordinary electronic properties, such as bipolar conductance, half integer quantum Hall effect at room temperature, ballistic transport over ${\sim}0.4{\mu}m$ length and extremely high carrier mobility at room temperature. Several approaches have been developed to produce graphene, such as micromechanical cleavage of highly ordered pyrolytic graphite using adhesive tape, chemical reduction of exfoliated graphite oxide, epitaxial growth of graphene on SiC and single crystalline metal substrate, and chemical vapor deposition (CVD) synthesis. In particular, direct synthesis of graphene using metal catalytic substrate in CVD process provides a new way to large-scale production of graphene film for realization of graphene-based electronics. In this method, metal catalytic substrates including Ni and Cu have been used for CVD synthesis of graphene. There are two proposed mechanism of graphene synthesis: carbon diffusion and precipitation for graphene synthesized on Ni, and surface adsorption for graphene synthesized on Cu, namely, self-limiting growth mechanism, which can be divided by difference of carbon solubility of the metals. Here we present that large area, uniform, and layer controllable graphene synthesized on Cu catalytic substrate is achieved by acetylene-assisted CVD. The number of graphene layer can be simply controlled by adjusting acetylene injection time, verified by Raman spectroscopy. Structural features and full details of mechanism for the growth of layer controllable graphene on Cu were systematically explored by transmission electron microscopy, atomic force microscopy, and secondary ion mass spectroscopy.

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Spread of CTX-M Extended-spectrum β-lactamase Producing Escherichia coli in the Community in Chungcheong Area, Korea

  • Sung, Ji Youn;Oh, Ji-Eun;Kim, Eun Sun;Son, Ja Min;Kim, Hye Yeon;Lim, Da Young
    • Korean Journal of Clinical Laboratory Science
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    • v.45 no.2
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    • pp.43-47
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    • 2013
  • This study was designed to evaluate the prevalence of ESBL genes and monitor antimicrobial resistance pattern in Escherichia coli, isolated from a hospital and a community. We tested 200 E. coli strains isolated in the hospitals and community in Chungcheong area from January to March 2012. Antimicrobial susceptibilities were tested by using the disk diffusion method. A search for ESBL genes was conducted by PCR amplification, and the genotypes were determined by direct nucleotide sequence analysis of the amplified products. An Epidemiologic study was performed by repetitive extragenic palindromic sequence-based PCR (REP-PCR). The percentage of ESBL-producing isolates was 17% for hospital associated E. coli and 11% for community associated E. coli. The ESBL gene sequencing results showed that the most common ESBL in E. coli was CTX-M-14 (19/28), followed by CTX-M-15 (9/28). The REP-PCR study also showed the genetic diversity, but there was no difference between the hospital and community associated E. coli. In this study, the most common types of class A ESBLs identified were CTX-M in the hospital and the community in Chungcheong area. ESBL-producing E. coli isolates showed diverse clonality.

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