• Korean Journal of Materials Research
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• v.9 no.7
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• pp.701-706
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• 1999

The crystal structure and magnetic properties of magnetic oxide system (F $e_2$ $O_3$)$_{5}$(A $l_2$ $O_3$)$_{4-x}$(G $a_2$ $O_3$)$_{x}$)SiO has been studied using X-ray diffraction and Mossbauer spectroscopy The changes of magnetic structure by the Ga ion substitution and the temperature variation have been investigated using Mossbauer spectroscopy, and the results are compared with those of the SQUIB measurements. Results of X-ray diffraction indicated that the crystal structures of the system change from a cubic spinel type to an orthorhombic via the intermediate region. This magnetic oxide system seems to be new kind of spinel type ferrites containing high concentration of cation vacancies. Various and complicated Mossbauer spectra were observed in the samples (x>0.2) at temperatures lower than room temperature. This result could be explained by freezing of the superparamagnetic dusters. On cooling and substitution, magnetic states of the system show various and multicritical properties. Unexpected dip in magnetization curves below 50K was observed in SQUID measurements. It was interpreted as an effect of spin canting including spin freezing or collective spin behavior.ior.r.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2017.05a
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• pp.166-166
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• 2017

금속 재료 중 철강은 기계적 특성이 우수하고 대량생산이 가능하여 선박, 건축, 자동차 등 다양한 분야에 기초재료로써 널리 사용되고 있다. 그러나 스테인리스강 등과 같은 일부 특수한 용도의 강을 제외하고는 부식환경에 취약한 특성을 가지기 때문에 내식성을 향상을 위한 표면처리에 관한 연구가 활발히 진행되고 있다. 가장 일반적으로 습식법(wet process)을 통해 표면상에 아연(Zn)을 도금해 사용하며, 아연이 자체적으로 포함한 희생양극(sacrificial anode) 및 차폐(barrier) 효과가 철강의 부식을 방지하게 된다. 하지만 산업의 고도화에 따라 더욱 가혹해진 노출환경으로 인해 고내식 강재에 대한 수요가 점차 증가하고 있으며, 아연코팅 층의 두께를 증가하여 내식성을 확보하는 방안은 미래 환경 및 자원적인 측면에서 근본적인 해결책으로 제시하기 어려움이 있다. 한편, 건식 프로세스(wet process)로 대별되는 PVD(physical vacuum deposition)에 의해 내식성을 향상시키고자 하는 연구들이 다양하게 진행되고 있다. 이것은 표면에 고순도 양질의 금속 막을 형성시킴으로써 외부환경과의 반응을 효과적으로 제어가 가능하며, 형성된 막은 그 물질의 고유 특성뿐만 아니라 제작 조건에 따른 표면의 기하학적 혹은 결정학적 구조에 의해 크게 영향을 받게 된다. 본 연구에서는 실용금속 중 이온화 경향이 가장 크고 산소와 반응하여 투과성이 작은 산화 피막 형성이 유리한 마그네슘(Mg)을 활용해 표면의 전기화학적 특성을 향상시켰다. 또한 금속 증착 중 진공도조절을 위해 도입되는 불활성 가스로 아르곤(Ar) 및 질소($N_2$)를 사용하여 표면에 형성한 막의 모폴로지 및 결정배향성이 내식성에 미치는 상관관계를 해석하고자 하였다. 실험방법으로 PVD법 중 비교적 간편하고 기초적인 지침을 제시하기 적합할 것으로 고려된 진공증착(vacuum evaporation)법을 이용해 아르곤 및 질소 분위기에서 진공도를 조절하며 용융아연도금상 Mg막을 형성하였다. 제작조건별 막의 기초 특성을 분석하기위해 SEM, EDS, XRD를 이용하였고, 결정배향성(crystal orientation) 분석을 위해 면간격(d-value)과 상대강도(relative intensity)를 확인하였다. 또한 내식성 평가로 염수분무(salt sprat test) 및 양극분극(anode polarization)을 각각 실시하였다. 실험결과에 따르면, Ar 및 $N_2$ 모두에서 가스압이 증가할수록 코팅층의 증착량은 적어지고 입상정(granular structure)의 모폴로지 형성 및 면간격과 상대강도가 증가하는 것이 확인되었다. 또한 쳄버 내 동일 진공도에서, $N_2$ 도입 시 Mg막은 더욱 치밀하고 미세한 입상정의 모폴로지로 형성되며 면간격과 상대강도는 더욱 증가한 것으로 나타났다. 내식성 평가에서 저진공 $N_2$ 조건에서 형성시킨 막이 가장 우수한 내식성이 나타났는데, 이는 상대적으로 불안정하고 반응하기 유리한 입계면적을 많이 포함한 입상정 모폴로지 및 표면에너지가 높은면의 면점유율 증가로 인해 외부환경과의 신속한 반응은 물론 안정적인 피막형성이 용이하였기 때문일 것으로 사료된다. 이상으로 Ar 및 $N_2$ 가스압 조건에 따른 고내식 Mg 막의 유효성을 확인하였고 향후 내식성을 향상시키는 방법으로 응용 가능할 것으로 생각된다.

• Economic and Environmental Geology
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• v.41 no.6
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• pp.763-771
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• 2008

Uncertainties are pervasive in engineering geological problems. Therefore, the presence of uncertainties and their significance in analysis and design of slopes have been recognized. Since the uncertainties cannot be taken into account by the conventional deterministic approaches in slope stability analysis, the probabilistic analysis has been considered as the primary tool for representing uncertainties in mathematical models. However, some uncertainties are caused by incomplete information due to lack of information, and those uncertainties cannot be handled appropriately by the probabilistic approach. For those uncertainties, the theory of fuzzy sets is more appropriate. Therefore, in this study, fuzzy reliability analysis has been proposed in order to deal with the uncertainties which cannot be quantified in the probabilistic analysis due to the limited information. For the practical example, a slope is selected in this study and both the probabilistic analysis and the fuzzy reliability analysis have been carried out for planar failure. In the fuzzy reliability analysis, the dip angle and internal friction angle of discontinuity are considered as triangular fuzzy numbers since the random properties of the variables cannot be obtained completely under the conditions of limited information. In the study, the fuzzy reliability index and the probabilities of failure are evaluated from fuzzy arithmetic and compared to those from the probabilistic approach using Monte Carlo simulation and point estimate method. The analysis results show that the fuzzy reliability analysis is more appropriate for the condition that the uncertainties arise due to incomplete information.

• The Journal of Engineering Geology
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• v.3 no.1
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• pp.21-37
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• 1993

In order to investigate the correlation of sedimentary rock properties. specific gravity, porosity, water content, sonic wave velodty, and point4oad strength index of core samples of limestones, sandstones and shales were measured. The relationships between density and velocity show $V_p=16300d-38719.3,{\;}V_s1896.4d-29225.1$ of regression equation for sandstones and $Vp=4085d-10264.8,{\;}V_s=3519d-7841.3$ for shales and <$Vp=4085d^2-20747d+303,{\;}V_s=3899d^2-21442d+318$ for limestones. Seismic wave velocity of shales which have high density is lower than that of sandstones, and this seems to be an effect of bedding in shale. P-wave velocity and S-wave velocity of limestones, sandstones and shales show the linear relationships as a whole. The regression equations are respectively calculated V_s=0.26V_p+1041.6m/sec,{\;}V_s=0.43V_p+424.2m/sec,{\;}and{\;}Vs=0.51V_p+261.9m/sec$ and the correlation coefficients of the velocity show r= 0.86 in sandstones, r= 0.75 in limestones and r=0.86 in shales. According to the point4oad strength test for limestones, point4ord strength anisotropy was not so dear even though the specimens show generally the banded structure. Variations of dip angle of bedding whihin the range $30^{\circ}-60^{\circ}$ does not have much influence upon the diametral strength index and axial strength index. From the result of point load test, P-wave velocity increases with point4ord strength index but the regression equations are $V_p=98.5lI{s_d}+4082.1m/sec,{\;}V_p=106.41{s_a}+3954m/sec$ and their correlation coefficient is low.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.9 no.1
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• pp.87-98
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• 1999

The objectives of this study were to evaluate exposures to airborne methylene chloride and postshift carboxyhemoglobin (COHb) in blood of workers engaged in processes using blowing or cleaning agents, and to investigate correlation between methylene chloride concentrations and the blood COHb levels of workers. The geometric mean (GM) of workers' exposures (8 hour-time weighted averages, TWA) to airborne methylene chloride during cleaning molds using rags wetted with the solvent in the manufacture of flexible polyurethane foam (GM = 61.4 ppm), during operating the dip tank for cleaning molds in the manufacture of lens (GM = 61.0 ppm), and during cleaning the blowing nozzles by spraying the solvent in the manufacture of shoes (GM = 117.2 ppm) were exceeded the American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value ($TLV^{(R)}$)-Time Weighted Average (TWA) (50 ppm). The COHb levels were significantly different among groups (p<0.05). The average COHh levels in blood of non-smoking workers were 2.0% in. low-level (<50 ppm) exposure group, and 3.9 % in high-level (>50ppm) exposure group. The average COHb levels in smoking workers were 3.1% in low-level exposure group, and 4.8% in high-level exposure group. The blood COHb levels of no-exposed workers to methylene chloride were 1.8% in non-smoking group, and 2.8% in smoking group. It was found that the COHb level dependeds on the methylene chloride concentration and smoking habit, and was highly correlated with methylene chloride concentration in air. The correlation coefficient was 0.81 among non-smoking workers. The estimated COHb level (3.6%) and 95% upper confidence limit (4.0%) corresponding to TLV-TWA of methylene chloride exceeded the current ACGIH Biological Exposure Index (COHb 3.5%) for carbon monoxide. The estimated COHb level (5.4%) at 100 ppm exceeded the standard (5%) recommended by National Institute for Occupational Safety and Health (NIOSH) for preventing adverse cardiovascular effect. The estimated COHb value and 95% upper confidence limit at 25 ppm of the Occupational Safety and Health. Adminstration (OSHA) Permissible Exposure Limit-TWA (PEL-TWA) were 2.6% and 3.0%, respectively. It is suggested that COHb in blood be kept below 3.0% to comply with OSHA PEL-TWA.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.29 no.5A
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• pp.566-573
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• 2004

A variable optical attenuator with a bending-sensitive fiber (BSF) that can be used in optical networks is developed. The proposed BSF consists of inner core, outer core, center dip and cladding. The proposed BSF is also very sensitive to mechanical perturbation, such as bending and pressure, making the light propagating in the BSF easily controlled and attenuated. The fabricated fiber-type variable optical attenuator using the proposed BSF (VOAFB) consisted of the BSF in a rectangular rubber ring with a fixed bend radius (BR) in a steady state. The variable optical attenuator using the proposed BSF (VOAFB) was able to attenuate the optical power by more than about -38㏈ with the gradient -88.4［㏈$.$$cm^{-1}$ /］ at (1540∼1560nm) based m adjusting the mechanical pressure applied to the upper surface of the rectangular rubber ring with the bent BSF. According to the experimental results when using the proposed VOAFB, the optical power was easily controlled by adjusting mechanical pressure and produced an insertion loss of 0.68㏈, polarization loss of 0.5㏈, and return loss of less than -60㏈.

• Research in Plant Disease
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• v.17 no.1
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• pp.13-18
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• 2011

This study was conducted to establish the efficient screening method for resistant cabbage to Fusarium wilt caused by Fusarium oxysporum f. sp. conglutinans. The resistance degrees of nine commercial cabbage cultivars to the disease were evaluated. Among them, five cultivars (YR-honam, Ogane, Greenhot, Redmat, and Ccoccoma) showing different resistance to the fungus were selected. Then development of Fusarium wilt of the cultivars according to several conditions including root wounding, dipping period of roots in spore suspension, inoculum concentration, and incubation temperature to develop the disease was investigated. Highly resistant cultivars such as 'YR-honam' and 'Ogane' hardly showed change of resistance to the disease by root wounding, dipping period, and inoculum concentration, while disease severity of Fusarium wilt on the cultivars was changed with incubation temperatures ($20^{\circ}C$, $25^{\circ}C$ and $30^{\circ}C$). When the cabbage cultivars were incubated at $25^{\circ}C$, they represented the most difference of resistance and susceptibility to Fusarium wilt. From above results, we suggest that an efficient screening method for resistant cabbage to F. oxysporum f. sp. conglutinans is to dip the non-cut roots of 14-day-old seedlings in spore suspension of $1{\times}10^7$ conidia/ml for 0.5 hr and to transplant the seedlings to plastic pots with a fertilized soil, and then to cultivate the plants in a growth chamber at $25^{\circ}C$ for 3 weeks to develop Fusarium wilt.

• Korean Journal of Applied Biomechanics
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• v.19 no.4
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• pp.739-748
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• 2009

The purpose of this study was to compare successful and failed trials of the dean and jerk exercise performed by an 2008 Beijing Olympic gold medalist. One successful and one failed trial of an Olympic gold medalist (2008 Beijing Olympic 77 kg event) were investigated for this study. A three-dimensional motion analysis was performed, using three digital camcorders (SF: 6Hz). The events were recorded during the 89th Korean National Athletic Games. After analyzing the jerk motion, the following results were found. The successful trial revealed a shorter performance time at Phase 1 and a longer one at Phase 3 and Phase 4 as compared to the failed trial. The vertical displacement of the knee in failed trial was lower than that m the successful one. The differences in the vertical velocity of barbell and knee between the trials were seen at Phase 3 and Phase 4. A faster COM inferior velocity was seen in the successful trial at Phase 3. A more flexed knee angle was seen in the failed trial as compared to the successful trial at E3.

• Journal of Plant Biotechnology
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• v.31 no.2
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• pp.133-138
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• 2004

Growth of M.9 (Malus domestica Bark. cv) and M.26 (Malus domestica Bark. cv) of dwarf apple rootstock, cultured on MS agar medium in a vessel with ventilating stopper (VS) and then in vivo rooting and acclimatization under combined-treatment by some materials with IBA, were investigated. Concentration of $CO_2$ and ethylene in the vessel with VS was lower then in the vessel with non-VS. Change of temperature and humidity in the vessel with VS was repeated by light condition. Stomatal pares of tissue in the vessel with VS were immediately closed after plantlets were exposed to room humidity but those in the vessel with non-VS were opened after 20 minutes exposure to room humidity. Leaf area and chloroplast index of tissue in the vessel with VS was higher then in the vessel with non-VS. In vivo rooting ratio and acclimatization ratio of M.9 and M.26 was highest in 300mg/L IBA＋3％ sucrose dip-treatment among other combined- treatments.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2011.10a
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• pp.39-41
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• 2011

The recycling rate of recovered paper in Korea is the highest in the world, 92%, but remanufacturing yield is low due to the extremely poor quality of the paper. The poor quality, in turn, influences to the reject amount in deinking process. To increase the yield of old newspaper recycling process, hydrophobic degree of inorganic pigments of deinking stock must be reduced. To determine the hydrophobicity, Pitch Potential Deposit Tester (PDT) was newly designed and applied with respect to the SB latex property of various quality used in Korea; its hydrophobic degree according to Tg, gel content, charge and particle size of latex and optimum designing condition of SB latex. And below are the conclusions: 1. The reason of excessive reject from old newspaper deinking process for total amount of printed ink is loss of inorganic pigments. When lipase, a biochemical catalyst, was applied with the purpose of preventing inorganic pigments loss about more than 70% of total reject weight and promoting hydration of pulp for deinking, deinking process yield of pre flotation secondary stage increased remarkably without any changes of deinking efficiency. 2. Lipase improved deinking stock by cutting ester linkage on surface of hydrophobic materials to promote its hydration. From this, it reached the conclusion that hydration degree of stock exercises significant effect on flotation deinking process yield. 3. Inorganic alkali promotes hydration of deinking stock. But there have been needs for more fundamental measures other than inorganic alkali of promoting hydration for yield improvement. For this, this study intended to find out reasons of chemical properties change on surface of hydrophobic material by change of pH. 4. Pitch Deposit Test (PDT) was performed for understanding principle of why surface of coating flake from OMG is hydrophobic and why it becomes hydrophilic when pH of stock is alkaline. As a result of this test, it is determined that swelling property by change of pH of latex film, which were used as coating adhesive is the reason for hydrophobic change. 5. Hydrophilicity of coating flake increased with hydrophilic pigments. And as more of SB Latex adhesive was used and higher of calcium hardness of stock became, its hydrophilicity decreased. SB Latex adhesive film is reformed by mechanical friction. For having hydrophilicity under neutral pH, strong bruising action such as kneading is required. 6. Because swelling of adhesive film decreases as Tg of SB latex gets lower and mean diameter gets smaller, it shows hydrophobicity under neutral pH. This lowers hydrophilicity of coating flake, which leads to easy elimination with flotation reject on DIP process. Therefore, for improving future flotation yield, it is necessary to develop to use eco-friendly clean SB latex by raising Tg and increasing mean diameter for recycling, and as a result, to reduce excessive loss of coating flake as a reject from deinking process.