• Bulletin of the Korean Chemical Society
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• 제26권2호
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• pp.312-314
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• 2005

• 패션비즈니스
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• 제10권6호
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• pp.16-27
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• 2006

The purpose of this study was to examine the effects of chemical finishes on performance characteristics of microfiber blend fabrics. A 60% polyester microfiber /40% cotton blend woven fabric was finished by ten chemicals: three silicone softeners, one fluorochemical, and their mixtures. Performance characteristics examined were fabric hand attributes. Fabric hand was evaluated by instrumental measures using Kawabata KES-F system instruments. Silicone-only finishes did not change the bending properties significantly from those of the control fabric. The fluorochemical-only finish made the fabric stiffer and crisper. When the two chemicals were mixed they tended to offset this adversary effect. Most of the chemical finishes made the surface finer and smoother. Fluorochemical-only finish improved fabric strength. Likewise, dimethylpolysiloxane silicone improved fabric strength. Amino-functional hydrophilic and diamino-functional silicone softeners, on the other hand, reduced fabric strength. However, when mixed with the fluorochemical, the adversary effect was diminished.

• 한국의류산업학회지
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• 제3권5호
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• pp.486-491
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• 2001

The purpose of this study was to examine the effects of chemical finishes on performance characteristics of microfiber blend fabrics. A 60% polyester microfiber/40% cotton blend woven fabric was finished by ten chemicals: three silicone softeners, one fluorochemical, and their mixtures. Performance characteristics examined were abrasion resistance, and oil/water repellency. Chemical finishes containing dimethylpolysiloxane silicone performed better in fabric abrasion resistance than other chemicals. The correlation between abrasion wear and instrumental measures of fabric hand indicated that the breaking strength loss by abrasion related negatively to the coefficient of friction. This implied that the finished fabrics with lower surface frictional coefficient (slipperier) had higher breaking strength loss by abrasion. The microfiber structure of polyester did not appear to help in oil/water repellency due to the larger surface areas of the microfibers. The fluorochemical finished fabric had the most significant improvement on oil/water repellency. The silicone-only finishes, however, did not improve oil/water repellency. When mixed with the fluorochemical, silicone finishes showed improved oil/water repellency.

• KSBB Journal
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• 제30권4호
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• pp.141-147
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• 2015

The convenient determination of methylsulfonylmethane (MSM) for a commercially available dietary supplement was developed using gas chromatography (GC)-flame ionization detector (FID). Chromatography was performed on a capillary column ($0.32mm\;I.D{\times}30m$, $0.25{\mu}m$) coated with dimethylpolysiloxane using diethylene glycol methyl ether as an internal standard. The performance characteristics of GC were evaluated in terms of selectivity, linearity, precision, accuracy, recovery, limit of detection (LOD) and limit of quantification (LOQ). The calibration curve was highly linear (the coefficient of determination: 0.9979) within the concentration range of $10.0{\sim}800.0{\mu}g/mL$ for MSM. The recoveries for three fortified concentrations were 96.7~97.1%, 96.6~97.3% and 96.8~97.2%, respectively. The LOD and LOQ of the method were $0.29{\mu}g/mL$ and $0.97{\mu}g/mL$, respectively. All obtained results were acceptable according to the guidelines of the Association of Official Analytical Chemists for dietary supplements. Thus, the validated analytical method using the GC-FID system is suitable for the determination of MSM in dietary supplement formulations for quality control.

• 한국산업보건학회지
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• 제26권1호
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• pp.20-29
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• 2016

Objectives: The purpose of this study is to simplify and standardize analytical method of polar solvents(methanol, isopropanol, n-butanol, acetone, methylene chloride and MIBK) in the working environmental by GC. Because NIOSH methods are various and complicated. Methods: The method is using the same stationary phase(5% phenyl 95% dimethylpolysiloxane), absorbent(silica gel) and desorption solvent(DMSO) for above 6 solvents. For the 6 solvents desorption efficiency, calibration curve, and limit of detection were studied Results: As the results, 6 solvents{2 groups ; first group(methanol/isopropanol/butanol) and second group(acetone/methylene chloride/MIBK)} could be separated and quantified within 10 minutes. Desorption efficiency from silica gell of 6 solvents using dimethylsulfoxide(DMSO) was methanol 86.2%, isopropanol 103.2%, n-butanol 101.8%, acetone 98.2%, methylene chloride 103.9% and MIBK 106.2% in the range of 0.2, 0.5, 2.0 times of TWA, consequently, satisfied NIOSH estimation level(beyond 75%). Correlation coefficient(r)in the range of 0.2~2.0 times of TWA, was above 0.999 for 6 solvent. LOD(mg/DMSO ml) using calibration curve in the range of 0.2~2 times of TWA was methanol 0.11, isopropyl alcohol 0.20, n-butanol 0.03, acetone 0.50, methylene chloride 0.05, MIBK 0.04 respectably. Conclusions: This method can be used at the sampling and analytical method for polar solvents by GC. Also, will be able to be applied with NIOSH methods.

• Bulletin of the Korean Chemical Society
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• 제30권1호
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• pp.35-42
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• 2009

Headspace micro solid phase extraction using mulberry paper bag (HS-MPB-$\mu$-SPE) has been developed and validated for the analysis of volatile flavor compounds from five spice by gas chromatography-mass spectrometry (GC/MS). HS-MPB-$\mu$-SPE was performed with adsorbent particles enclosed inside a mulberry paper bag. Four different kinds of adsorbents such as Tenax TA, Porapack Q, dimethylpolysiloxane and polyethylene glycol were tested. The extraction solvents compared were petroleum ether, methylene chloride, and chloroform. Better results were obtained when Tenax TA and petroleum ether were used. The limit of detection (LOD) and the limit of quantitation (LOQ) were in the range of 1.3 ng/mL and 4.3 ng/mL, respectively, for o-cymene as a model compound of monoterpene. Proposed method showed good reproducibility (3.3%, RSD) and good recoveries (94.0%). The HS-MPB- μ-SPE is very simple to use, inexpensive, rapid, requires small sample amounts and solvent consumption. Because the solvent for extraction is reduced to only a very small volume (0.6 mL), there is minimal waste or exposure to toxic organic solvent and no further concentration step. This method allows successful characterization of the headspace in contact with the five spice sample. Strong trans-anethole from star anise or fennel is a characteristic flavor of five spice powders. HS-MPB-$\mu$-SPE combined with GC/MS can be a promising technique for the broad spectrum measurement of volatile aroma compounds from solid spices.

• 한국화재소방학회논문지
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• 제23권4호
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• pp.137-144
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• 2009

본 논문은 광전식연기감지기 현장점검기기의 문제점에 관한 연구로서 현재 소방점검 시 광전식연기감지기의 성능확인을 위해 사용되는 A Type(향), B Type(디메틸실리콘오일), C Type(탄화수소혼합물)의 점검기기들을 실험대상으로 선정하고, 현장점검기기의 문제점을 도출하고자 신뢰성확인실험 및 성능확인실험, 연기시료에 따른 감지기 성능변화 실험을 실시하였다. 실험결과 소방점검 시 현장점검기기를 이용한 감도실험은 연기농도조건 및 풍속조건, 연기시료의 문제점을 확인할 수 있었으며, 결과적으로 현재 소방점검시 사용되는 광전식연기감지기 현장점검기기의 신뢰성에 문제가 있는 것을 확인할 수 있었다.