• 제목/요약/키워드: Dilution Gas

검색결과 266건 처리시간 0.02초

Characterization of the Aroma of Salt-fermented Anchovy Sauce Using Solid Phase Microextraction-Gas Chromatography-Olfactometry Based on Sample Dilution Analysis

  • Kim, Hyung-Joo;Baek, Hyung-Hee
    • Food Science and Biotechnology
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    • 제14권2호
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    • pp.238-241
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    • 2005
  • Aroma-active compounds were evaluated from salt-fermented anchovy sauce by solid phase microextraction-gas chromatography-olfactometry (SPME-GC-O) based on sample dilution analysis (SDA). SPME extract from carboxen/polydimethylsiloxane (CAR/PDMS) fiber was the most similar to the original odor of salt-fermented anchovy sauce used for this experiment, followed by divinylbenzene/CAR/PDMS (DVB/CAR/PDMS) fiber. Because salt-fermented anchovy sauce contains 23% NaCl, NaCl concentration of diluent was considered when salt-fermented anchovy sauce was serially diluted. Linear relationship between GC response and sample concentration was observed when diluted with 23% NaCl solution, whereas not observed when diluted with deodorized distilled water. Eleven and 16 aroma-active compounds were detected by SPME-GC-O based on SDA using CAR/PDMS and DVB/CAR/PDMS fibers, respectively. Butanoic acid and 3-methyl butanoic acid showed the highest ${\log}_2SD$ factors for CAR/PDMS and DVB/CAR/PDMS fibers. Dimethyl trisulfide, methional, trimethyl amine, 1-penten-3-ol, and acetic acid were also detected as potent aroma-active compounds.

인버스 가스 크로마토 그래피를 이용한 소수화된 MCC의 표면 특성 분석 (Surface Characterization of Hydrophobically Modified MCC Using Inverse Gas Chromatography)

  • 이학래;이용민;박일;이진희;조중연;한신호
    • 펄프종이기술
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    • 제34권3호
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    • pp.9-16
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    • 2002
  • The adsorption characteristics and surface energetics of hydrophobically modified MCC have been investigated by the inverse gas chromatography technique at infinite dilution. The thermodynamic parameters of adsorption, ΔG, ΔH and ΔS, for n-alkanes were determined at infinite dilution. Heats of adsoption of the n-alkanes increased as the level of hydrophobic modification increased. The hydrophobically modified MCC also showed greater entropy of adsorption indicating restricted mobility of the adsorbed n-alkanes. The acid/base characteristics of the MCC were evaluated using polar probes. As the hydrophobicity of MCC increased, the basisity of the MCC decreased.

공정 파라미터에 따른 금속분말(SUS316L, IN718) 레이저 적층 표면 및 단면 특성 분석 (A Study on Surface and Cross-section Properties Depending on the Process Parameters of Laser Depositions with Metal Powders (SUS316L and IN718))

  • 황준호;신성선;이종훈;김성욱;김현덕
    • Journal of Welding and Joining
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    • 제35권3호
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    • pp.28-34
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    • 2017
  • The authors derived the criteria on the process parameters of laser depositions with metal powers(SUS316L & IN718) by evaluating the surface and cross-section properties of the deposition layers. The surface characteristics of the deposition layer are investigated through optical microscopy by controlling the process parameters of laser output, powder feeding rate and gas feeding rate. The cross-section characteristics were also analyzed after polishing and chemical etching process. As the gas feeding rate increased, the amount of powder loss increased and the difference in the dilution ratio and heat affected zone depending on laser outputs was observed. In addition, the powder feeding rate used in the experiment did not interfere with the energy absorption of the base material.

무한희석법(無限稀釋法)을 이용한 질산화(窒酸化) 미생물(微生物) 반포화계수(半飽和係數) 결정(決定)에 관한 실험적(實驗的) 연구(硏究) (Experimental detemination of Half-Saturation Coefficient for Nitrifying Bacteria by Infinite Dilution Method)

  • 이병희
    • 상하수도학회지
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    • 제12권1호
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    • pp.62-69
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    • 1998
  • To remove nitrogen from wastewater, ammonia nitrogen has to be oxidized to nitrate nitrogen before denitrification reaction which converts nitrate nitrogen to nitrogen gas. In order to understand nitrification, several mathematical models had been proposed and Monod type model has been accepted internationally. Since Monod type model consists of maximum substrate utilization rate, substrate concentration and half-saturation coefficient, these values have to be addressed before using Monod type model. Several experimental procedures to determine half-saturation coefficient have been developed, however, Infinite dilution method was known to be time saving procedure. In this study, the mathematical equations and experimantal procedures for Infinite dilution method are presented and this method is used to determine half-Saturation coefficient for nitrifying bacteria. As results, Infinite dilution method is proved that this coefficient can be determined within 8 hours and the values of half-saturation coefficient has a range of 0.728 and $0.455gNH_4{^+}-N/m^3$ and the average has $0.580gNH_4{^+}-N/m^3$ through 5 sets of experiments.

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Design of Metal Cored Wire for Erosion Resistant Overlay Welding

  • Kim, Jun-Ki;Kim, In-Ju;Kim, Ki-Nam;Kim, Ji-Hui;Kim, Seon-Jin
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2009년 추계학술발표대회
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    • pp.202-204
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    • 2009
  • Erosion is a common failure mode of materials frequently encountered in plant and power industry. Although the erosion resistance of Fe-base alloy has been inferior to the other expensive materials, it is expected that the strain-induced martensitic transformation can impart high erosion resistance to Fe-base alloy. The key technology to develop Fe-base metal cored welding wire for erosion resistant overlay welding may include the strain-induced metallurgy for hardening rate control and the welding flux metallurgy for dilution control. Sophisticated studies showed that the strain-induced martensitic transformation behavior was related to the critical strain energy which was dependent on the alloy composition. Dilution and bead shape of overlay weld were proved to be affected by metal transfer mode during gas tungsten arc welding and elements in welding fluxes. It was considered that the highly erosion resistant Fe-base overlay weld could be achieved by precise control of alloy composition to have proper level of critical strain energy for energy absorption and welding flux formulation to have small amount of deoxidizing metallic elements for dilution.

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저 발열량 가스 연료의 화염거동 및 NOx 발생 특성에 관한 실험적 연구 (Experimental Study on the Flame Behavior and the NOx Emission Characteristics of Low Calorific Value Gas Fuel)

  • 김용철;이찬
    • 한국에너지공학회:학술대회논문집
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    • 한국에너지공학회 1999년도 춘계 학술발표회 논문집
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    • pp.89-93
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    • 1999
  • Experimental studies are conducted to investigate the flame stability and the thermal/fuel NOx formation characteristics of the low calorific value(LCV) gas fuel. Synthetic LCV fuel gas is produced through mixing carbon monoxide, hydrogen, nitrogen and ammonia on the basis that the thermal input of the syngas fuel into a burner is identical to that of natural gas, and then the syngas mixture is fed to and burnt with air on flat flame burner. Flame behaviors are observed to identify flame instability due to blow-off or flash-back when burning the LCV fuel gas at various equivalence ratio conditions. Measurements of NOx in combustion gas are made for comparing thermal and fuel NOx emissions from the LCV syngas combustion with those of the natural gas one, and for analyzing ammonia to NOx conversion mechanism. In addition, the nitrogen dilution of the LCV syngas is preliminarily attempted as a NOx reduction technique.

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초저온 냉각 트랩을 결합한 비활성기체 동위원소 희석 질량분석 시스템의 제작 (Development of a Noble Gas Isotope Dilution Mass Spectrometric System Combined with a Cryogenic Cold Trap)

  • 홍봉재;신동엽;박기홍;함도식
    • 한국해양학회지:바다
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    • 제27권3호
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    • pp.144-157
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    • 2022
  • 비활성기체는 화학적, 생물학적 반응을 하지 않는 보존적인 특성을 가지고 있어 해양에서 수온과 염분 변화, 기체 주입, 해수의 혼합과 빙하 융해수의 분포와 같은 물리적인 변화의 추적자로 활용되고 있다. Ne, Ar과 Kr을 정밀하게 분석하기 위해 사중극자 질량 분석기, 고진공 전처리 라인, 초저온 냉각 트랩과 동위원소 표준기체로 구성된 분석 시스템을 제작했다. 고진공 라인은 시료의 용존 기체를 추출하여 동위원소 표준기체와 혼합하는 시료추출부, 합금 물질을 이용하여 반응성 기체를 제거하고 초저온 냉각 트랩으로 비활성기체를 기화점에 따라 분별 증류하는 기체 준비부, 비활성기체를 원소별로 측정하는 기체 측정부로 구성하였다. 기체준비부에 결합한 초저온 냉각 트랩은 질량분석기 내 Ar와 CO2의 부분압을 현저히 낮추어 Ne 동위원소 분석의 오차를 감소시켰다. 동위원소 표준기체는 22Ne, 36Ar과 86Kr를 혼합하여 제작하였고, 혼합 표준 기체의 원소별 양은 대기를 반복 측정하여 역동위원소 희석법으로 결정했다. 대기 평형수 반복 분석의 상대 오차는 Ne, Ar과 Kr에 대해 각각 0.7%, 0.7%, 0.4%이었다. 반복 측정한 대기 평형수의 농도와 포화 농도의 차이로 확인한 분석시스템의 정확도는 Ne, Ar, Kr에 대해 각각 0.5%, 1.0%, 1.7%이었다.

저압 EGR을 적용한 디젤엔진의 희석비에 따른 연소 특성 비교 (Comparison of Combustion Characteristics On the Basis of the Dilution Ratio in Diesel Engines with LPL EGR)

  • 임기훈;박준혁;최영;이선엽;김영민
    • 대한기계학회논문집B
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    • 제35권5호
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    • pp.525-531
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    • 2011
  • 디젤엔진에서 배기가스 재순환(EGR; Exhaust Gas Recirculation)은 선택적 환원 촉매나 $NO_x$ 흡장 촉 매에 비해 $NO_x$ 배출 저감을 위한 가장 효과적인 기술이다. 점점 더 강화되어 가는 $NO_x$ 배출 규제를 만족시키기 위해서는 많은 양의 EGR 가스 공급이 필요하다. 저압 EGR은 일정한 과급 압력에서 가변형상 터보차져의 제어와 거의 독립적이기 때문에 EGR 공급 측면에서 보면 저압 EGR이 기존의 고압 EGR에 비해서 더 많은 장점을 갖는다. 본 연구에서는 저압 EGR이 연소 특성에 미치는 영향을 고압 EGR을 적용했을 때와 비교하였다. 각 EGR 루프에 대해 혼합기의 희석 정도에 따른 영향을 분석하기 위해 독립변수로써 희석비를 사용하였다. 저압 EGR을 적용하였을 때, 고압 EGR을 적용했을 때와 동등한 $NO_x$ 배출량을 유지하면서 연료 소비율과 매연 배출은 고압 EGR의 경우보다 좀 더 낮은 결과를 보였다.

Gas 이송용 Utility Materials의 전해연마 특성에 관한 연구 (A Study on the Characteristics of Electro-Polishing and Utility Materials for Gas Transitting)

  • 안세원;이종형;박무수
    • 한국기계가공학회지
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    • 제3권3호
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    • pp.52-57
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    • 2004
  • Many kinds of gases, such as erosion gas, dilution gas, and toxic gas have been used in manufacturing process of LCD at semiconductor. In order to increase accumulation rate of manufacturing process, high degree of purity in these gases and minimized metalllic dust are required. All wetted stainless steel surface must be 316L electro-polished with $0254{\mu}m$ in average. Based on the AES analysis, Cr/Fe 11 and $Cr_2O_3$ thickness $25{\AA}$ are measured Molybdenum and silicon contaminants which is characteristic of stainless steel and oxygen were found on the surface.

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