• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1997년도 춘계학술대회 논문집
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• pp.389-394
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• 1997

Consider a tetrhedron is composed of six dihedral angles .phi.(i=1,2..., 6), and a vertex of a tetrahedron is also three dihedral angles. It will assume that a vertex A, for an example, is composed of there angles definded such as .alpha..betha. and .gamma. !. then there is a corresponding angle can be given as .phi1.,.phi2.,.phi3.. Here, in order to differentiate between a conventional triangle and dihedral angle, if a dihedral angle degined in this paper is symbolized as .phi..LAMBDA.,the value of cos.theta.of .phi./sab a/, in a trigonometric function rule,can be defined to tecos.phi..LAMBD/sab A/., and it is defined as a tetradedral cosine .phi. or simply called a tecos.phi.. Moreover, in a simillar method, the dihedral angle of tetrahedron .phi..LAMBDA. is given as : value of sin .theta. can defind a tetra-sin.phi..LAMBDA., and value of tan .theta. of .phi..LAMBDA. is a tetra-tan .phi..LAMBDA. By induction it can derive that a tetrahedral geometry on the basis of suggesting a geometric tetrahedron

• 한국항공우주학회지
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• 제39권9호
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• pp.866-870
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• 2011

본 논문에서는 스팬방향으로 곡면 상반각과 방구멍을 갖는 전통 방패연에 작용하는 공기력을 풍동실험을 통해 측정하였다. 방구멍이 없는 평판 연의 경우 ${\alpha}=35^{\circ}$에서 $C_{Lmax}$=1.2이고 실속 현상이 뚜렷하게 나타났다. 반면에 방구멍을 가진 전통 방패연에서는 ${\alpha}=30^{\circ}$에서 $C_{Lmax}$=1.05를 가지지만 명백한 실속현상은 나타나지 않았으며 반경이 커짐에 따라 실속각 이후의 양력 및 항력 곡선이 완만하게 변하였다. 곡선 상반각이 커질수록 항력 곡선에 비해 양력 곡선이 차이가 커졌으며 방구멍 반경이 작을수록 상반각의 효과는 크게 나타나고 방구멍 반경이 클수록 상반각의 효과가 거의 일정하게 나타났다.

• 한국유체기계학회 논문집
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• 제18권5호
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• pp.5-12
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• 2015

This paper presents a numerical investigation of the effect of the dihedral stator on the loss in a transonic axial compressor. Four stator geometries with different stacking line variables are tested in the flow simulations over the whole operating range. It is found that a large shroud loss at the rotor outlet and the subsequent shroud corner separation in the stator passage occur at low mass flow rate. The hub dihedral stator and bowed blade generate unexpected hub-corner-separation, thereby causing a large total pressure loss over the entire operating range. However, the corresponding blockage forces the high momentum flow near the hub to divert toward the upper part of the passage suppressing the negative axial velocity region. The dihedral stator increases deflection angle and secondary vorticity near the endwall where the dihedral is applied. As a result, the endwall loss which is related to the endwall relative velocity decreases.

• Bulletin of the Korean Chemical Society
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• 제27권1호
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• pp.39-43
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• 2006

The relaxed torsional potential of a liquid crystalline polymer containing an ester functional group in a mesogenic unit (hereafter 12-4 oligomer) has been calculated with the ab initio self-consistent-field using 6-31G$^*$ basis set. GIAO^{13}C NMR chemical shifts also have been calculated at the B3LYP/6-31G$^*$ level of theory for each conformational structure obtained from torsional potential calculation. The results show that the phenyl ring-ester linkages are coplanar with the dihedral angle of about 0$^{\circ}$ and the ring-ring linkages in the biphenyl groups are tilted with the dihedral angle of around 43-44$^{\circ}$ in the lowest energy conformer. The biphenyl ring has a comparatively lower energy barrier of internal rotation potential in the ring-ring than that of phenyl ring-ester. The ^{13}C chemical shifts of carbonyl carbons were found to move to upfield due to $\pi$ -conjugation with phenyl ring and slightly affected about 0.5 ppm by dihedral angle of the ring-ring linkage.

• 한국결정학회지
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• 제16권1호
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• pp.1-5
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• 2005

The structure of the title compound has been determined by single-crystal X-ray diffraction work. The crystals are orthorhombic, space group $Pna2_1$ with a=11.095(3), b=21.834(7), c=12.574(4) $\AA$, and R1=0.0667. The average carbon bond length in aromaticity In the molecule is 1.386(1) $\AA$ and the average single bond length linking the central benEene ring and peripheral phenyl rings is 1.491(3) $\AA$. The average dihedral angle between the central benzene ring and each of six peripheral phenyl rings is $67.1(1)^{\circ}$ and the average dihedral angle between neighboring two phenyl rings is $55.0(1)^{\circ}$. Thus the molecule adopts a quasi-propeller configuration with approximate six-fold rotation symmetry.

• 한국세라믹학회지
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• 제30권11호
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• pp.881-890
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• 1993

MAS system has narrow sintering temp. range due to the liquid phae sintering and thereby densify rapidly. And especially, its poor mechanical properties limitedthe industrial application. In this study, the improvement of mechanical properties and densification is suggested by the consideration of the toughening mechanisms and isolated pore generation mechanism which is derived by the liquid phase sintering theory in 3Y-TZP added composites. After Pressureless sintering up to 140$0^{\circ}C$ for 5hr, the dihedral angle and contact angle are analyzed by the observation of microstructure. As a result of microstructure analysis, the sintering stage of the specimen sintered for 5hr is analyzed as solid-skeleton stage. And the isolated pore generation mechanisms are considered as (1) The swelling of the liquid phase is predominent due to the facts that dihedral angle is larger than 60$^{\circ}$, contact angle is large and that liquid volume fraction is smaller than 10%. (2) The porous characteristics of the MAS system is also suggested as: the SiO2-rich liquid film is firstly formed at the srface and therefore this reduces the contiguity of the pore, which induces the isolated pore. The strength and fracture toughness increased with the addition of 3Y-TZP and the main fracture toughness improvement mechanisms are analyzed as the crack deflection.

• 공업화학
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• 제20권3호
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• pp.335-338
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• 2009

유기발광다이오드의 청색 발광 물질로 많은 관심을 받고 있는 디스티릴아릴렌 화합물들의 합성 과정에서 핵심적인 중간체인 브로모트리페닐에틸렌 화합물들은 브로모벤조페논과 벤질포스포네이트의 반응을 통하여 얻어진다. 이 반응은 분리하기 어려운 (Z)-와 (E)-기하이성질체가 60 : 40의 비율로 생성한다. 본 연구에서는 2-프로탄올을 이용한 재결정법을 통하여 (Z)-이성질체를 간단하게 분리하였다. X-ray를 이용하여 (Z)-이성질체의 결정 구조를 살펴본 결과, tert-부틸페닐 고리와 브로모페닐 고리 간의 dihedral angle은 $56.5(4)^{\circ}$이며 브로모페닐 고리와 페닐 고리 간의 dihedral angle은 $74.1(4)^{\circ}$였다.

• 대한화학회지
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• 제24권1호
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• pp.15-19
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• 1980

Glycinato 및 glycine ester 리간드의 전자구조와 반응성을 조사하기 위하여 CNDO/2와 EHT 분자궤도함수법을 적용하였다. 두자리 배위자로 작용하는 glycinato 리간드의 구조는 탄소에서 질소쪽으로 가는 결합이 ${\Delta}O_4C_3C_2$ 와 ${\Delta}O_3C_2N_1$ 평면에서 $105^{\circ}9'$의 dihedral angle을 가지는 Gly-I 구조가 Gly Ⅱ 구조보다 안정함을 알았으며, glycine ester 리간드에 대한 에너지 성분 분석 결과로서 alkyl가 치환에 따른 전자효과를 볼 수 있었다. CNDO/2 MO 계산으로 얻은 전자밀도 $q_N$값으로부터 리간드의 안정도 순위는 Glycinato>Gly-Et-Ester>Gly-i-Pr-ester>Gly-Me-ester 순으로 나타났다.

• Journal of Photoscience
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• 제4권1호
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• pp.7-10
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• 1997

The structures of 8-membered azalactone isomers produced from photocyclization of 2-(N,N-dibenzylamino)ethyl benzoylacetate were determined by the X-ray structure analysis to clarify the stereochemical behavior of a 1,8-biradical. The remarkable stereoselectivity in cyclization of the 1,8-biradical to form cis- and trans-isomers of the azalactone was not observed. The ring conformations were boat-chair like and dihedral angles between C$_5$- and C$_6$- phenyl groups were ca 45$\circ$ in the both isomers. The 1,8-biradicals in the transition state for the cyclization would have nearly same boat-chair like conformation and twisted configuration with the dihedral angle of ca 45$\circ$ as the corresponding isomer, and this is responsible for luck of stereoselectivity in long-chain biradical cyclization.

• International Journal of Aerospace System Engineering
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• 제10권1호
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• pp.1-13
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• 2023

The present study was attempted to investigate flow interference effects and the aerodynamic characteristics of the front and rear wings of a joined-wing aircraft by changing the configuration variables. The study was performed using a computational fluid dynamics(CFD) tool to demonstrate forward flight and analyze aerodynamic characteristics. A total of 9 configurations were analyzed with variations on the position, height, dihedral angle, incidence angle, twist angle, sweepback angle, and wing area ratio of the front and rear wings while the fuselage was fixed. The quantities of aerodynamic coefficients were confirmed in accordance with joined-wing configurations. The closer the front and rear wings were located, the greater the flow interference effects tended. Interestingly, the rear wing did not any configuration change, the lift coefficient of the rear wing was decreased when adjusted to increase the incidence angle of the front wing. The phenomenon was appeared due to an effective angle of attack alteration of the rear wing resulting from the flow interference by the front wing configurations.