• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.175.1-175.1
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• 2011

A rotating activated bacillus contactor (RABC) process with a series of aerobic reactors was tested in pilot scale to treat digested liquid from an anaerobic digester treating swine wastewater and sewage sludge. The influent (digested liquid) for the RABC process showed C/N ratios less than 2 as a typical feature of effluent from anaerobic digesters. The pilot process, which consists of three 3 RABC reactors, four aerobic tanks and a sedimentation tank, was operated for 210 days with a hydraulic retention time of 20 days without pH and temperature control. Since the Bacillus-enriched aerobic reactors shows high efficiencies of nitrogen removal at low DO levels less than 1.0 mg/L, they were operated at reduced aeration intensities. With relatively low concentrations of organics in comparison with nitrogen concentrations, the RABC process tested in this study showed stable and high nitrogen and organics removal efficiencies over 80%. The nitrogen removal process tested in this study was proven to be an effective and operation-cost saving (lower aeration) method to remove nitrogen without adding external carbon sources to meet the optimum C/N ratio.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.4
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• pp.397-403
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• 2012

Galactose, an isomer of glucose with an opposite hydroxyl group at the 4-carbon, is a major fermentable sugar in various promising feedstock for hydrogen production including red algal biomass. In this study, hydrogen production characteristics of galactose-glucose mixture were investigated using batch fermentation experiments with heat-treated digester sludge as inoclua. Galactose showed a hydogen yield compatible with glucose. However, more complicated metabolic steps for galactose utilization caused a slower hydrogen production rate. The existence of glucose aggravated the hydrogen production rate, which would result from the regulation of galactose-utilizing enzymes by glucose. Hydrogen produciton rate at galactose to glucose ratio of 8:2 or 6:4 was 67% of the production rate for galactose and 33% for glucose, which could need approximately 1.5 and 3 times longer hydraulic retention time than galacgtose only condition and glucose only condition, respectively, in continuous fermentation. Hydrogen production rate, Hydrogen yield, and organic acid production at galactose to glucose ratio of 8:2 or 6:4 were 0.14 mL H2/mL/hr, 0.78 mol $H_2$/mol sugar, and 11.89 g COD/L, respectively. Galactose-rich biomass could be usable for hydogen fermenation, however, the fermentation time should be allowed enough.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.06b
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• pp.317-321
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• 2006

The investigation of the formation of organic sulfur compounds (i.e., odor species), mainly methyl mercaptan and demethyl suifide, during kraft pulping has been conducted, in which both hardwood and softwood species were used. It was discovered that there is an organic sulfur compounds formation phase transition point with respect to delignification extent. The transition point occurs at a kappa number of approximately 35 and 20 for softwoods and hardwoods, respectively. The results also showed that both low sulfidity and anthraquinone (AQ) addition are helpful to control the formation of theses organic sulfur compounds during kraft pulping. Whereas Hexenuronic acid (HexA) has contribution to Kappa number, the extended delignification not only lead to low pulp yield, but also be adverse to odor control. A significant in-digester odor reduction can be achieved if the pulping is to be terminated before phase transition point and combined with AQ addition.

• Journal of Korean Society on Water Environment
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• v.27 no.6
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• pp.769-775
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• 2011

An experimental study of biofilm nitritation system for high-strength ammonium wastewater has been carried out to examine the temperature effect on different organic and solid concentration. Operating temperature varied from $35^{\circ}C$ to $15^{\circ}C$. The influent N concentration of identical three reactors was adjusted to about $300mg\;NH_4-N/L$. A control unit fed with a synthetic wastewater, while the others were fed with reject water which is consisted of the supernatant of both digester and thickener. The results indicated that nitrite accumulation was stable in temperature range of $35^{\circ}C$ to $25^{\circ}C$. However, nitritation was significantly reduced at below $20^{\circ}C$. Free ammonia (FA) and free nitrous acid (FNA) were major inhibitors to the nitrite oxidizer for nitrite accumulation in lower temperature. From the estimation of temperature coefficient (${\Theta}$) of biofilm and suspended nitritation system, biofilm nitritation system could absorb the negative temperature effect compared with suspended nitritation system.

• Journal of Environmental Science International
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• v.30 no.12
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• pp.1093-1100
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• 2021

The present study investigated the effect of ammonia load on microbial communities in mesophilic anaerobic digestion of propionic acid. A laboratory-scale continuous anaerobic digester treating propionic acid as a sole organic substrate was operated under non-inhibitory condition and inhibitory conditions with ammonia (1.5 g and 3.5 g ammonia-N/L, respectively), and bacterial and archaeal communities in the steady states of each ammonia condition were analyzed using high-throughput sequencing. Thirteen bacterial families were detected as abundant bacterial groups in mesophilic anaerobic digestion of propionic acid. Increase in ammonia concentration resulted in significant shifts in microbial community structures. Syntorophobacter, Pelotomaculum, and Thermovigra were determined as the dominant groups of (potential) propionate oxidizing bacteria in the non-inhibitory condition, whereas Cryptanaerobacter and Aminobacterium were the dominant groups of (potential) propionate oxidizing bacteria in the ammonia-inhibitory condition. Methanoculleus and Methanosaeta were the dominant methanogens. Acetate-oxidation coupled with hydrogenotrophic methanogenesis might be enhanced with increases in the relative abundances of Methanoculleus and Tepidanaerobacter acetatoxydans under the ammonia-inhibitory condition. The results of the present study could be a valuable reference for microbial management of anaerobic digestion systems that are exposed to ammonia inhibition and propionic acid accumulation.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.2
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• pp.53-63
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• 2018

The hydrolysis of organic solid waste, such as sludge, is the rate-limiting step of the anaerobic digestion. The longer rate-limiting step lead to decrease of treatment efficiency and increase hydraulic retention time and anaerobic digester. Therefore, the pre-treatment has been applied for accelerating the hydrolysis step. This study was investigated the effects of pre-treatment of waste activated sludge using ultrasonic and alkaline integrated treatment simultaneously. The results showed the cumulative methane production and the methane production rate increased while the lag phase decreased. Therefore ultrasonic and alkaline integrated pre-treatment of waste activated sludge resulted in acceleration of hydrolysis step in anaerobic digestion.

• KSBB Journal
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• v.11 no.2
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• pp.211-217
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• 1996

Batch experiments were conducted to investigate the effect of electron donor on reductive dechlorination of 2,4,5-trichlorophenol by a methanogenic consortium. The methanogenic consortium was obtained from the anaerobic digester of a municipal wastewater treatment plant. The batch reactor containing methanogenic consortium was spiked with 2,4,6-trichlorophenol at 10 mg/$\ell$. Acetate, ethanol, glucose of methanol, each was added as an electron donor for methanogenic consortium. During the course of the experiments liquid samples were taken from the batch reactor to measure dechlorination rate and find the dechlorination pathway of 2,4,6-trichlorophenol. After incubation 2,4,6-trichlorophenol was first dechlorinated to 2,4-dichlorophenol and then to 4-chlorophenol. Phenol was not detected in the batch reactor the highest rate of dechlorination of 2,4,6-trichlorophenol was observed when ethanol was used as an electron donor.

• Journal of Korean Society on Water Environment
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• v.26 no.5
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• pp.754-760
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• 2010

This study was carried out not only to evaluate optimal operating condition to increase biogas production, but also to estimate feasibility of renewable energy from anaerobic digester of sewage sludge. Semi- continuous Fed and Mixed Reactors (SCFMRs) were operated in various condition to quantify the reactor variables. The result of SCFMR operation showed that the biogas productivity and total volatile solids (TVS) removal of total solids (TS) 4% reactor at hydraulic retention time (HRT) 20 days with Organic Loading Rate (OLR) of $1.45kg/m^3-d$ were $0.39m^3/m^3-d$ and 26.7%, respectively which was two times higher than that of TS 2.5% reactor. Consequently the daily biogas production of $20,000m^3$ would be possible from the total volume of $52,000m^3$ of anaerobic digesters of the municipal wastewater treatment plant in D city. In feasibility study for the Biogas utilization, combined heat and power system (CHP) and CNG gasification were examined. In case of CHP, the withdrawal period of capital cost for gas-engine (GE) and micro gas-turbine (MGT) were 7.7 years and 9.1 years respectively. biogas utilization as Clean Natural Gas (CNG) shows lower capital cost and higher profit than that of CHP system. CNG gasificaion after biogas purification is likely the best alternative for Biogas utilization which have more economic potential than CHP system. The withdrawal period of capital cost appeared to be 2.3 years.

• Journal of the Korea Organic Resources Recycling Association
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• v.18 no.1
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• pp.73-80
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• 2010

Two nitrite oxidizing bacteria, NOB1 and NOB2, were isolated from anaerobic digester liquer of food wastewater and analyzed for their growth characteristics and the ability to oxidize nitrite under different temperature, pH, and DO( dissolved oxygen) concentrations. Both of the isolated strains have shown the best growth at pH 7.0 and at $35^{\circ}C$, and also shown higher growth rate with the increasing dissolved oxygen concentrations. As the factors to restrict the growth of these strains, parameters such as pH and DO were found to be effective ones, by increasing (up to 9.0) or decreasing pH (up to 5.0), or lowing DO below 1.0 ppm. Especially, the ability to oxidize nitrite in both strains was about 50% lower in below 1.0 ppm of DO than above of 1.0 ppm. NOB2 was found to be two times greater in both the growth rate and the nitrite-oxidizing ability than NOB1.

• Journal of the Korea Organic Resources Recycling Association
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• v.23 no.4
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• pp.11-20
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• 2015

In the present work, a basic study on the in-situ biogenic methane generation from low grade coal bed was conducted. Lignite from Indonesia was used as a sample feedstock. A series of BMP (Biochemical Methane Potential) tests were carried out under the different experimental conditions. Although nutrients and anaerobic digester sludge were added to the coal, the produced amount of methane was limited. Both temperature control and particle size reduction showed little effect on the increase of methane potential. When rice straw was added to lignite as an external carbon source, methane yield of 94.4~110.4 mL/g VS was obtained after 60 days of BMP test. The calorific value of lignite after BMP test decreased (4.5~12.1 %) as increasing the content of rice straw (12.5~50 wt % of lignite), implying that anaerobic digestion of rice straw led to partial degradation of lignite. Therefore, rice straw could be used as an external carbon source for the start-up of in-situ biogas generation from low grade coal bed.