• Title/Summary/Keyword: Diffusion study

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THE NUMERICAL SIMULATION OF HYDROGEN JET DIFFUSION FOR HYDROGEN LEAKAGE IN THE ENCLOSED GEOMETRY (밀폐공간에서 수소 누설로 인한 수소 제트 확산에 대한 수치해석)

  • Ahn, Hyuk-Jin;Lee, Sang-Hyuk;Hur, Nahm-Keon;Lee, Moon-Kyu;Yong, Gee-Joong
    • 한국전산유체공학회:학술대회논문집
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    • 2009.04a
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    • pp.176-182
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    • 2009
  • In the present study, a numerical simulation for the diffusion of hydrogen jet in a enclosure was performed to aid the leakage test of the hydrogen for the safety of the hydrogen vehicle. The temporal and spatial distributions of the hydrogen concentration in the test chamber are predicted from the present numerical analyses. Flammable region of 4-74% and explosive region of 18-59% hydrogen by volume was identified from the present results. Factors influencing the diffusion of the hydrogen jet were examined to evaluate the effectiveness of forced ventilation for relieving the accumulation of the leaked hydrogen gas in the chamber, which include location of open windows, size of leakage nozzle, and leakage rate among others. The distribution of the concentration of the leaked hydrogen for various cases can be used as a database in various applications for the hydrogen safety.

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Simultaneous Formation of NiSi Contact and Cu Plug/Ti Barrier (NiSi 접촉과 Cu 플러그/Ti 확산방지층의 동시 형성 연구)

  • Bae, Kyoo-Sik
    • Korean Journal of Materials Research
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    • v.20 no.6
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    • pp.338-343
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    • 2010
  • As an alternative to the W plug used in MOSFETs, a Cu plug with a NiSi contact using Ta / TaN as a diffusion barrier is currently being considered. Conventionally, Ni was first deposited and then NiSi was formed, followed by the barrier and Cu deposition. In this study, Ti was employed as a barrier material and simultaneous formation of the NiSi contact and Cu plug / Ti barrier was attempted. Cu(100 nm) / Ti / Ni(20 nm) with varying Ti thicknesses were deposited on a Si substrate and annealed at $4000^{\circ}C$ for 30 min. For comparison, Cu/Ti/NiSi thin films were also formed by the conventional method. Optical Microscopy (OM), Scanning Probe Microscopy (SPM), X-Ray Diffractometry (XRD), and Auger Electron Microscopy (AES) analysis were performed to characterize the inter-diffusion properties. For a Ti interlayer thicker than 50 nm, the NiSi formation was incomplete, although Cu diffusion was inhibited by the Ti barrier. For a Ti thickness of 20 nm and less, an almost stoichiometric NiSi contact along with the Cu plug and Ti barrier layers was formed. The results were comparable to that formed by the conventional method and showed that this alternative process has potential as a formation process for the Cu plug/Ti barrier/NiSi contact system.

Analysis and Measurement of Effective Refractive Indices with Ion-exchanged Slab Waveguide (이온교환 평판도파로의 실효굴절율 측정 및 해석)

  • 천석표;박정일;박태성;정홍배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.73-76
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    • 1995
  • In this study, the slab waveguide was fabricated using potassium-nitride(KNO$_3$) or silver-nitride (AgNO$_3$) molten sources by ion-exchange process. The effective refractive indices of waveguide were measured by Prism-Coupling method. and The characteristics of waveguide(mode dispersion, effective diffusion depth. surface refractive index, diffusion coefficient, and refractive index profile etc,) were investigated by WKB method, In the case of potassium ion-exchange, the computer calculation showed that the refractive index profile of waveguide followed Gaussian function, the surface refractive index increased with ion-exchange time and the effective diffusion depth increased a little as ion-exchange time increased, while the surface refractive index of silver ion-exchanged waveguide decreased with ion-exchange time because of the ion depletion on the surface of waveguide, and the effective diffusion depth seriously with ion-exchange tim. Double ion-exchanged waveguide was fabricated by performing silver ion-exchange after potassium ion-exchange. Double ion-exchanged waveguide had a tight mode binding force since the surface refractive index was larger than single step ion-exchanged waveguide.

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A model for columnar-dendritic solidification of binary alloys accounting for dendrite tip undercooling (선단과냉을 고려한 이원합금의 주상 수지상응고 모델)

  • Yu, Ho-Seon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.5
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    • pp.698-707
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    • 1998
  • A simplified model for predicting microsegregation during columnar-dendritic solidification of binary alloys is developed, in which back diffusion, dendrite arm coarsening and dendrite tip undercooling are simultaneously incorporated. The inclusion of tip undercooling is accomplished by modifying the initial conditions of the existing solute diffusion model, in such forms that tip undercooling depresses the beginning of solidification below the liquidus temperature, and that the secondary arm spacing evolves in accordance with the minimum undercooling theory. Sample calculations for the well-known benchmark system show that the present predictions not only consist with the extablished limiting cases, but also agree favorably with the available experimental data within a reasonable tolerance. In particular, a typical decreasing trend in the eutectic fraction at high cooling rates is successfully resolved. Comparison of the individual and combined effects of characteristic parameters in reference with the limiting cases reveals the interactions among parameters. Every parameter plays the role of reducing the eutectic fraction, and the degree of influence depends primarily on the cooling rate. Coarsening enhances the effect of tip undercooling, while suppressing that of back diffusion. A vigorous back diffusion seems to restrain the apperance of the undercooling effect. Overall, each contribution of the three parameters to microsegregation is estimated to be of the same order, which suffices to justify the present study.

THERMAL DIFFUSION AND RADIATION EFFECTS ON UNSTEADY MHD FREE CONVECTION HEAT AND MASS TRANSFER FLOW PAST A LINEARLY ACCELERATED VERTICAL POROUS PLATE WITH VARIABLE TEMPERATURE AND MASS DIFFUSION

  • Venkateswarlu, M.;Ramana Reddy, G.V.;Lakshmi, D.V.
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.18 no.3
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    • pp.257-268
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    • 2014
  • The objective of the present study is to investigate thermal diffusion and radiation effects on unsteady MHD flow past a linearly accelerated vertical porous plate with variable temperature and also with variable mass diffusion in presence of heat source or sink under the influence of applied transverse magnetic field. The fluid considered here is a gray, absorbing/emitting radiation but a non-scattering medium. At time t > 0, the plate is linearly accelerated with a velocity $u=u_0t$ in its own plane. And at the same time, plate temperature and concentration levels near the plate raised linearly with time t. The dimensionless governing equations involved in the present analysis are solved using the closed analytical method. The velocity, temperature, concentration, skin-friction, the rate or heat transfer and the rate of mass transfer are studied through graphs in terms of different physical parameters like magnetic field parameter (M), radiation parameter (R), Schmidt parameter (Sc), Soret number (So), Heat source parameter (S), Prandtl number (Pr), thermal Grashof number (Gr), mass Grashof number (Gm) and time (t).

Modulated LII technique for the Measurement of Flow Velocity in Laminar Flames (층류화염 유동속도 측정을 위한 modulated LII 기법)

  • Lee, Won-Nam;Lee, Jung-Soo;Nam, Youn-Woo
    • Journal of the Korean Society of Combustion
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    • v.11 no.3
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    • pp.36-43
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    • 2006
  • The modulated LII technique has been suggested for the measurement of axial velocity profiles of laminar diffusion flames. The theoretical background is explained based on the blackbody radiation and LII signal. Experimentally, soot particles in ethylene diffusion flames are heated by a modulated Ar-ion laser beam. LII signals and their phase angles are measured using a lock-in amplifier at the different flame heights and the axial flow velocities are obtained from the measured phase angle delay informations. The measured velocities are similar to those from LDV measurements under the same operating conditions. The effects of laser power, LII signal wavelength, and modulation frequencies are not sensitive to the velocity measurement. However, the choice of an optical chopper blade type could affect the measurement result. The use of a 6/5 chopper blade showed the better result that is. possibly due to the square shape of modulated laser beam. This study successfully demonstrated that axial flow velocities of laminar diffusion flames can be measured by a new technique utilizing LII signal, which does not need particle seeding unlikely to LDV or PIV techniques.

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The Effect of Mn Addition on Nitrogenation Behavior and Magnetic Properties of Sm-Fe Alloy Powder Produced by Reduction-diffusion Method (환원-확산법에 의해 제조된 Sm-Fe 합금분말의 질화거동 및 자기특성에 미치는 Mn첨가 효과)

  • Seo, Young-Taek;Baek, Youn-Kyoung;Lee, Jung-Goo;Choi, Chul-Jin
    • Journal of Powder Materials
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    • v.20 no.1
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    • pp.13-18
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    • 2013
  • In the present study, we systematically investigated the effect of Mn addition on nitrogenation behavior and magnetic properties of Sm-Fe powders produced by reduction-diffusion process. Alloy powders with only $Sm_2(Fe,Mn)_{17}$ single phase were successfully produced by the reduction-diffusion process. The coercivity of $Sm_2(Fe,Mn)_{17}$ powder rapidly increased during nitrogenation and reached the maximum of 637 Oe after 16 hours. After further nitrogenation, it decreased. In contrast, the coercivity of $Sm_2Fe_{17}$ powder gradually increased during nitrogenation for 24 hours. The coercivity of $Sm_2(Fe,Mn)_{17}$ powder was higher than that of $Sm_2Fe_{17}$ powder at the same condition of nitrogenation. It was considered that the Mn addition facilitates the nitrogenation of $Sm_2Fe_{17}$ powder and enhances the coercivity.

Analytical Model of Salt Budget in the Upper Indian River Lagoon, Florida USA

  • Kim, Young-Taeg
    • Ocean and Polar Research
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    • v.26 no.1
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    • pp.33-42
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    • 2004
  • Effect of freshwater discharge on the long-term salt balance in the Northern and Central Indian River Lagoon (IRL) is successfully simulated by a new analytical solution to a water balance-based one-dimensional salt conservation equation. Sensitivity tests show that the salinity levels drop abruptly even during the dry season (November to May) due to the high surface runoff discharge caused by tropical storms, depressions, and passage of cold fronts. Increasing surface runoff and direct precipitation has risen by ten times, lowering the salinity level down to 12psu in the Northern Central zone, and to 17 psu in the Northern zone. However, the salinity level in the Southern Central zone has decreased to 25 psu. High sensitivity of the Northern Central zone to freshwater discharge can be partially explained by a rapid urbanization in this zone. During the dry season, less sensitivity of the Southern Central zone to the increased surface runoff is attributed to the proximity of the zone to the Sebastian Inlet and a strong diffusion condition possibly resulting from the seawater intrusion to the surficial aquifer at the Vero Beach. During the wet season, however, the whole study area is highly sensitive to freshwater discharge due to the weak diffusion conditions. High sensitivity of the IRL to the given diffusion conditions guarantees that the fresh-water release occurs during strong wind conditions, achieving both flood control in the drainage basin and a proper salinity regime in the IRL.

A Study of Hygroscopic Moisture Diffusion Analysis in Multimaterial System (이종 소재 접합체의 흡습 질량 확산 해석)

  • Kim, Yong-Yun
    • Journal of the Microelectronics and Packaging Society
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    • v.18 no.2
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    • pp.11-15
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    • 2011
  • Heat transfer equation is first reviewed and then governing equation of moisture diffusion. Analogy scheme is applied to analysis the moisture absorption problem of polymers. It make possible to numerically analyze the diffusion problem for single medium by using commercial finite element code if it is under the isothermal loading condition. It is extended to special multimaterial system by introducing pressure ratio function, whose moisture characteristics of materials are proportional to temperature only. The weight changes of silicon-nonconductive-polymer joint model due to moisture absorption is measured and been very close to the numerical results as for single media with boundary condition with zero concentration, but yields numerical errors as for multisystem media.

A Study on the Mass Flow Effects to the Performance of PEMFC (고분자 전해질형 연료전지내의 질량유동이 성능에 미치는 영향)

  • Park, Chang-Kwon;Jo, In-Su;Oh, Byeong-Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.4
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    • pp.422-431
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    • 2007
  • Polymer electrolyte membrane fuel cell(PEMFC) is very interesting power source due to high power density, simple construction and operation at low temperature. But it has problems such as high cost, improvement of performance and effect of temperature. These problems can be approached to be solved by using mathematical models which are useful tools for analysis and optimization of fuel cell performance and for heat and water management. In this paper, the present work is to develop an electrochemical model to examine the electrochemical process inside PEM fuel cell. A complete set of considerations of mass, momentum, species and charge is developed and solved numerically with proper account of electrochemical kinetics. When depth of gas channel becomes thinner, diffusion of reactant makes well into gas diffusion layer(GDL) and the performance increases. Although at low current region there is little voltage difference between experimental data of PEM fuel cell and numerical data. When the porosity size of gas diffusion layer for PEM fuel cell is bigger, oxygen diffusion occurs well and oxygen mass fraction appears high in catalyst layer.