• 제목/요약/키워드: Diffusion study

검색결과 5,166건 처리시간 0.031초

촉진염화물 확산계수의 시간의존성을 고려한 고성능 콘크리트의 염화물 침투 해석기법 (Analysis Technique for Chloride Penetration in High Performance Concrete Behavior Considering Time-Dependent Accelerated Chloride Diffusivity)

  • 권성준;박선규
    • 콘크리트학회논문집
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    • 제25권2호
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    • pp.145-153
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    • 2013
  • 촉진 염화물 확산계수는 최근들어 염화물 거동 평가를 위하여 많이 사용되고 있다. 촉진 염화물 확산계수는 겉보기 확산계수와 마찬가지로 재령에 따라 감소하는데, 이 연구에서는 공극률을 이용하여 촉진확산계수의 감소를 구현하였다. DUCOM 프로그램을 이용하여 15 배합에 대한 공극률을 도출하였으며, 이를 회귀분석하여 재령 270일 동안 감소하는 염화물 확산계수를 모델링하였다. 또한 자유염화물과 구속염화물간의 관계인 비선형 구속능을 고려하여, 고성능 콘크리트내의 염화물 거동을 평가하였다. 기존의 실험자료인 180일간 염화물에 침지되어 있는 시편을 이용하여, 이 연구에서 제안한 기법의 검증을 수행하였다. 제안된 기법은 다양한 물-시멘트비 및 혼화재(고로슬래그 미분말 및 플라이애쉬)를 가진 고성능 콘크리트의 염화물 거동을 적절하게 평가하였다. 또한 혼화재료를 사용한 콘크리트의 경우, 확산계수의 시간의존성이 뚜렷하므로 염화물 거동 해석시 재령에 따른 염화물 확산계수의 감소를 반드시 구현해야 함을 알 수 있었다.

Study on the Optical Properties of Light Diffusion Film with Plate Type Hollow Silica

  • Lee, Ji-Seon;Moon, Seong-Cheol;Noh, Kyeong-Jae;Lee, Seong-Eui
    • 한국세라믹학회지
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    • 제54권5호
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    • pp.429-437
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    • 2017
  • Micro hollow plate type silica with low refraction properties was synthesized and its hollow structure was applied as an optical structure to develop a light diffusion material that simultaneously satisfies the requirements of good light diffusibility, high transmissibility, and high luminance. The developed light diffusion material was applied to a light diffusion film and the film's optical properties were assessed. Hollow silica was synthesized by precipitation method using $Mg(OH)_2$ core particles, sodium silicate, and ammonium sulfate as the silica precursors. The concentration of the silica precursor was adjusted to control hollow silica shell thickness. The total light transmittance of the light diffusion film composed of the hollow silica was 94.55%, which was 4.57% higher than that of the PC film; new film's haze was 71.20%, which was 70.9% higher. Furthermore, the luminance increased by 5.34% compared to that of the light source. The reason for the results is not only that the micro plate type hollow silica, which has a low refractive property, played a role in reducing the difference in refractive index between the medium boundaries, but also that there was a light-concentrating effect due to the changing of light paths to the front direction inside the hollow structure. Optical simulation verified the enhanced optical properties when hollow silica was applied to the light diffusion film.

나노크기 실리카를 사용한 반도체용 액상 에폭시 수지 성형재료의 흡습성질 (Moisture Absorption Properties of Liquid Type Epoxy Encapsulant with Nano-size Silica for Semiconductor Packaging Materials)

  • 김환건
    • 반도체디스플레이기술학회지
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    • 제9권2호
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    • pp.33-39
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    • 2010
  • The moisture absorption properties such as diffusion coefficient and moisture content ratio of liquid type epoxy resin systems with the filler were investigated. Bisphenol A type and Bisphenol F type epoxy resin, Kayahard MCD as hardener and 2-methylimidazole as catalyst were used in these epoxy resin systems. The nano-sized spherical type fused silica as filler were used in order to study the moisture absorption properties of these liquid type epoxy encapsulant according to the change of filler size. The temperature of glass transition (Tg) of these epoxy resin systems was measured using Dynamic Scanning Calorimeter (DSC), and the moisture absorption properties of these epoxy resin systems according to the change of time were observed at $85^{\circ}C$ and 85% relative humidity condition using a thermo-hygrostat. The diffusion coefficients in these systems were calculated in terms of modified Crank equation based on Ficks' law. An increase of Tg and diffusion coefficient with filler size in these systems can be observed, which are attributed to the increase of free volume with Tg. The change of maximum moisture absorption ratio according to the filler size and filler content cannot be observed; however, the diffusion coefficients of these systems decreased with filler content. The diffusion via free volume is dominant in the epoxy resin systems with low nano-sized filler content; however, the diffusion with the interaction of absorption according the increase of the filler surface area is dominant in the liquid type epoxy encapsulant with high nano-sized filler content.

균열 아크릴 시편의 기체 확산계수와 균열폭의 관계 (Relationship between Crack Width and Gas Diffusion Coefficient of Cracked Acrylic Specimens)

  • 이도근;임민혁;신경준
    • 한국건설순환자원학회논문집
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    • 제6권4호
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    • pp.245-251
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    • 2018
  • 최근 구조물의 유지관리의 중요성이 부각되면서 자기치유 콘크리트 기술 분야의 연구가 활발히 이루어지고 있다. 이에 반해서 자기치유 성능을 평가하기 위한 척도는 부족한 실정이다. 균열폭을 측정하기 위한 방법으로 시각적인 방법이 1차적으로 사용되고 있으나 시편 내부의 균열폭을 관찰하기가 어려우며, 비균질한 균열특성으로 인해 표면에 대한 국부적인 측정만 할 수 있는 단점이 있다. 균열에 대한 간접적인 평가 방법으로 투수실험이 널리 활용되고 있지만 물의 점성으로 인한 문제가 있으며, 또한 실험 중 시편내부 물질의 용출될 가능성이 존재한다. 본 연구에서는 기체확산 특성을 활용한 균열폭 평가 방법을 제안하고자 하였다. 아크릴로 이상화된 직선균열을 제작하여 균열폭, 두께에 따른 시편의 확산계수를 분석하였다. 실험결과를 통하여 균열폭과 확산계수는 선형관계에 있음을 보였고, 두께와 확산계수는 역수의 관계에 있음을 증명하였다.

Effect of Participant Activity of SNS Based Online Event on the Diffusion

  • Hong, Jae-Won;Kwak, Jun-Sik
    • 한국컴퓨터정보학회논문지
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    • 제26권2호
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    • pp.221-227
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    • 2021
  • 본 연구에서는 SNS를 통한 온라인 이벤트 확산에 영향을 미치는 요인을 소비자들의 발자취를 통해 탐색하고자 하였다. 이를 위해 시중 'C' 맥주 브랜드가 시행한 온라인 이벤트의 로그 데이터를 수집하여 분석하였다. 로그 데이터의 분석단위는 시간대별로 설정하였으며 분석방법은 기술적 분석과 회귀분석을 이용하였다. 연구결과는 다음과 같다. 첫째, SNS 기반 온라인 이벤트의 뷰(view) 확산에 영향을 미치는 요인은 좋아요, 친구 사용 쿠폰, 친구 규모 등으로 나타났다. 특히 친구 규모가 확산에 가장 큰 영향을 미쳤는데 이는 온라인 이벤트에서 소셜 허브의 중요성을 다시금 시사하고 있다. 둘째, 유입자 수 확산에 영향을 미치는 요인도 좋아요, 친구 사용 쿠폰, 친구 규모 등으로 나타났다. 셋째, 댓글은 참여 빈도가 적어 뷰와 유입자의 확산에 영향을 미치지 않는 것으로 나타났다. 본 연구는 실제 데이터를 기반으로 온라인 소비자들의 행동을 탐색하고 나아가 기업의 온라인 이벤트 효과를 제고할 수 있는 방안을 제시하고자 하였다는 데 의의가 있다.

초소형 PCD 공구 제작을 위한 확산접합부의 형상에 따른 인장강도 특성 (Tensile Strength Properties of the Diffusion Bonding Copula Shape for Micro PCD Tool Fabrication)

  • 정바위;김욱수;정우섭;박정우
    • 한국기계가공학회지
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    • 제14권2호
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    • pp.25-30
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    • 2015
  • This study involved the fabrication of precision machine tools using a polycrystalline diamond tip [sintered PCD and cemented carbide (WC-Co) tip] and WC-Co shanks via diffusion bonding with a paste-type nickel alloy filler metal. Diffusion bonding is a process whereby two materials are pressed together at high temperature and high pressure for a sufficient period of time to allow significant atomic diffusion to occur. For smooth progress, a filler metal of nickel alloy was used at the interface. Optical microscopy images were used to observe the copula of the bonded layer. It was confirmed that cracks occurred near the junction in all cases. The tensile strength of the bond was measured using a universal testing machine (UTM) with WC-Co proportional test specimens.

저탄소 녹색성장을 위한 스마트그리드의 확산전략: 근거이론 접근법 (Strategies of Diffusing Smart Grids for Low-carbon Green Growth: Grounded Theory Approach)

  • 주재훈;김련화
    • 한국정보시스템학회지:정보시스템연구
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    • 제22권1호
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    • pp.225-248
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    • 2013
  • Korean government has been implementing a smart grid testbed in Jeju Island for the low-carbon green growth. As smart grids are in the early stage of their diffusion, strategic guidelines and related measures are needed to spread them successfully. In general, the successful diffusion of new technologies or new products are mostly determined in its early stages. With the introduction of smart grids, the electricity market paradigm will be transformed into user-oriented from provider-oriented. Thus, a study on the diffusion of smart grids from the perspective of users is necessary. This paper examines factors affecting the adoption and diffusion of smart grids from users' perspectives and provide strategic guidelines for diffusing the smart grid. Researchers conducted in-depth interviews with 41 people who have been already using smart grids in the Jeju testbed. Semi-structured interviews were used to collect data. The interviews were recorded on a digital voice recorder memory and subsequently transcribed verbatim. A total of 133 pages of transcripts were obtained from about 10 hours interviews. 97 concepts, 47 sub-categories and 19 categories were identified through open coding of grounded theory. We suggested a paradigm model for diffusing smart grids and total of seven propositions as strategic guidelines.

비정질 및 단결정 실리콘에서 10~50 keV 에너지로 주입된 안티몬 이온의 분포와 열적인 거동에 따른 연구 (A Study on Implanted and Annealed Antimony Profiles in Amorphous and Single Crystalline Silicon Using 10~50 keV Energy Bombardment)

  • 정원채
    • 한국전기전자재료학회논문지
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    • 제28권11호
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    • pp.683-689
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    • 2015
  • For the formation of $N^+$ doping, the antimony ions are mainly used for the fabrication of a BJT (bipolar junction transistor), CMOS (complementary metal oxide semiconductor), FET (field effect transistor) and BiCMOS (bipolar and complementary metal oxide semiconductor) process integration. Antimony is a heavy element and has relatively a low diffusion coefficient in silicon. Therefore, antimony is preferred as a candidate of ultra shallow junction for n type doping instead of arsenic implantation. Three-dimensional (3D) profiles of antimony are also compared one another from different tilt angles and incident energies under same dimensional conditions. The diffusion effect of antimony showed ORD (oxygen retarded diffusion) after thermal oxidation process. The interfacial effect of a $SiO_2/Si$ is influenced antimony diffusion and showed segregation effects during the oxidation process. The surface sputtering effect of antimony must be considered due to its heavy mass in the case of low energy and high dose conditions. The range of antimony implanted in amorphous and crystalline silicon are compared each other and its data and profiles also showed and explained after thermal annealing under inert $N_2$ gas and dry oxidation.