• Title/Summary/Keyword: Diffusion study

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Effects of Lewis Number and Preferential Diffusion in Syngas Flame Diluted with He and Ar (He와 Ar으로 희석된 합성가스 화염에서 루이스 수와 선호확산효과)

  • Kim, Tae Hyung;Park, Jeong;Kwon, Oh Boong;Park, Jong Ho
    • Journal of the Korean Society of Combustion
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    • v.19 no.4
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    • pp.28-34
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    • 2014
  • Numerical study is conducted to grasp flame characteristics in $H_2/CO$ syngas counterflow diffusion flames diluted with He and Ar. An effective fuel Lewis number, applicable to premixed burning regime and even to moderately-stretched diffusion flames, is suggested through the comparison among fuel Lewis number, effective Lewis number, and effective fuel Lewis number. Flame characteristics with and without the suppression of the diffusivities of H, $H_2$, and He are compared in order to clarify the important role of preferential diffusion effects through them. It is found that the scarcity of H and He in reaction zone increases flame temperature whereas that of $H_2$ deteriorates flame temperature. Impact of preferential diffusion of H, $H_2$, and He in flame characteristics is also addressed to reaction pathways for the purpose of displaying chemical effects.

The Temperature Dependence of the Diffusion Bonding Between Tungsten Carbides for Micro WC-PCD Tool Fabrication (초소형 초경 PCD Tool 제작을 위한 초경합금간 확산접합의 온도 의존성 연구)

  • Jeong, B.W.;Park, J.W.
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.22 no.5
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    • pp.812-817
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    • 2013
  • This study demonstrates the diffusion bonding process between a tungsten carbide shank (K30) and tungsten carbide (DX5) for micro WC-PCD tool fabrication. A type of nickel alloy was used as the filler met alto improve the bond ability between K30 and DX5. The bonding pressure, time, and surrounding conditions were kept constant. In particular, the normal pressure was controlled precisely under buckling analysis. Diffusion bonding was performed at various operation temperatures (1170-1770 K) by using a specially designed jig. The microstructure on the localized bonded surface was analyzed using scanning electron microscopy and optical microscopy. In the case of diffusion bonding of WCat 1370-1770K, the filler metal melted completely and diffused between the two base metals, and they were bonded more tightly on both sides than at temperatures below 1370 K. Our results demonstrated the importance of sensitive temperature dependence of diffusion bonding.

Practical and Provable Security against Differential and Linear Cryptanalysis for Substitution-Permutation Networks

  • Kang, Ju-Sung;Hong, Seok-Hie;Lee, Sang-Jin;Yi, Ok-Yeon;Park, Choon-Sik;Lim, Jong-In
    • ETRI Journal
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    • v.23 no.4
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    • pp.158-167
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    • 2001
  • We examine the diffusion layers of some block ciphers referred to as substitution-permutation networks. We investigate the practical and provable security of these diffusion layers against differential and linear cryptanalysis. First, in terms of practical security, we show that the minimum number of differentially active S-boxes and that of linearly active S-boxes are generally not identical and propose some special conditions in which those are identical. We also study the optimal diffusion effect for some diffusion layers according to their constraints. Second, we obtain the results that the consecutive two rounds of SPN structure provide provable security against differential and linear cryptanalysis, i.e., we prove that the probability of each differential (resp. linear hull) of the consecutive two rounds of SPN structure with a maximal diffusion layer is bounded by $p^n(resp.q^n)$ and that of each differential (resp. linear hull) of the SDS function with a semi-maximal diffusion layer is bounded by $p^{n-1}(resp. q^{n-1})$, where p and q are maximum differential and linear probabilities of the substitution layer, respectively.

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Effect of Tempering Condition on Hydrogen Diffusion Behavior of Martensitic High-Strength Steel (템퍼링 조건이 마르텐사이트계 고강도강의 수소확산거동에 미치는 영향)

  • Park, Jin-seong;Hwang, Eun Hye;Lee, Man Jae;Kim, Sung Jin
    • Corrosion Science and Technology
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    • v.17 no.5
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    • pp.242-248
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    • 2018
  • Martensitic high-strength steels revealed superior mechanical properties of high tensile strength exceeding 1000 Mpa, and have been applied in a variety of industries. When the steels are exposed to corrosive environments, however, they are susceptible to hydrogen embrittlement (HE), resulting in catastrophic cracking failure. To improve resistance to HE, it is crucial to obtain significant insight into the exact physical nature associated with hydrogen diffusion behavior in the steel. For martensitic steels, tempering condition should be adjusted carefully to improve toughness. The tempering process involves microstructural modifications, that provide changes in hydrogen diffusion/trapping behavior in the steels. From this perspective, this study examined the relationship between tempering condition and hydrogen diffusion behavior in the steels. Results based on glycerin measurements and hydrogen permeation evaluations indicated that hydrogen diffusion/trapping behavior was strongly affected by the characteristics of precipitates, as well as by metallurgical defects such as dislocation. Tempering condition should be adjusted properly by considering required mechanical properties and resistance to HE.

High-Temperature Tensile Strengths of Alloy 617 Diffusion Weldment (Alloy 617 확산용접재의 고온 인장강도)

  • Sah, Injin;Hwang, Jong-Bae;Kim, Eung-Seon
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.14 no.1
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    • pp.15-23
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    • 2018
  • A compact heat exchanger is one of critical components in a very high temperature gas-cooled reactor (VHTR). Alloy 617 (Ni-Cr-Co-Mo) is considered as one of leading candidates for this application due to its excellent thermal stability and strengths in anticipated operating conditions. On the basis of current ASME code requirements, sixty sheets of this alloy are prepared for diffusion welding, which is the key technology to have a reliable compact heat exchanger. Optical microscopic analysis show that there are no cracks, incomplete bond, and porosity at/near the interface of diffusion weldment, but Cr-rich carbides and Al-rich oxides are identified through high resolution electron microscopic analysis. In high-temperature tensile testing, superior yield strengths of the diffusion weldment compared to the code requirement are obtained up to 1223 K ($950^{\circ}C$). However, both tensile strength and ductility drop rapidly at higher temperature due to the insufficient grain boundary migration across the interface of diffusion weldment. Best fit curves for minimum yield strength and average tensile strength are drawn from the experimental tensile results of this study.

A new approach for calculation of the neutron noise of power reactor based on Telegrapher's theory: Theoretical and comparison study between Telegrapher's and diffusion noise

  • Bahrami, Mona;Vosoughi, Naser
    • Nuclear Engineering and Technology
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    • v.52 no.4
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    • pp.681-688
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    • 2020
  • The telegrapher's theory was used to develop a new formulation for the neutron noise equation. Telegrapher's equation is supposed to demonstrate a more realistic approximation for neutron transport phenomena, especially in comparison to the diffusion theory. The physics behind such equation implies that the signal propagation speed is finite, instead of the infinite as in the case of ordinary diffusion. This paper presents the theory and results of the development of a new method for calculation of the neutron noise using the telegrapher's equation as its basis. In order to investigate the differences and strengths of the new method against the diffusion based neutron noise, a comparison was done between the behaviors of two methods. The neutron noise based on SN transport considered as a precision measuring point. The Green's function technique was used to calculate the neutron noise based on telegrapher's and diffusion methods as well as the transport. The amplitude and phase of Green's function associated with the properties of the medium and frequency of the noise source were obtained and their behavior was compared to the results of the transport. It was observed, the differences in some cases might be considerable. The effective speed of propagation for the noise perturbations were evaluated accordingly, resulting in considerable deviations in some cases.

Design of diffusers in consideration of scattering and diffusion characteristics (확산 지향성을 고려한 확산체의 설계)

  • Kim, Yong-Hee;Kim, Jae-Ho;Kim, Jeong-Jun;Jeon, Jin-Yong
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2008.04a
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    • pp.21-24
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    • 2008
  • This study proposes a optimized shape of diffuser profile through investigating the scattering and diffusion characteristics of diffusers. The scattering coefficient according to ISO 17497-1 evaluates uniformity of reverberant sound field of late reflections, while the diffusion coefficient according to AES-4id-2001 evaluates polar response of early reflections. Thus both scattering and diffusion characteristics should contribute to design shape of diffusers to maximize physical performance. To find out design method, the previous results on hemisphere diffusers are reviewed. The frequency characteristics of scattering coefficients depended on the structural height of the diffusers, while amount of scattering coefficients depended on the surface coverage density of the diffusers. However absorptive properties also increased with augment of surface coverage density, thus optimum coverage density should be considered. For the directional diffuser, three types of 2D-diffusers are proposed; semicylinder of h=5mm, semi-truncated cone of h=5-25mm and semicylinder of h=25mm. As results, diffusers with the maximum height of 25mm show the highest scattering coefficients, while diffuser of h=5mm shows high scattering coefficients only at the high-frequency bands. Diffusion coefficient will be investigated for diffusive properties of the early reflection.

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Inward Diffusion of Tb Ions and the Magnetic Properties of the Nd-Fe-B Magnets (열처리 조건에 따른 Tb이온의 확산 및 Nd-Fe-B 자석의 자기적 특성)

  • Oh, Seong-Uk;Kim, Dong-Whan;Gong, Gun-Seung;Heo, Young-Woo;Kim, Jeong-Joo;Lee, Joon-Hyung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.1
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    • pp.27-31
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    • 2017
  • In this study, the effect of Tb inward diffusion on the magnetic properties of the Nd-Fe-B sintered magnets was studied. After sintering of the magnets, $TbF_3$ slurries were dip-coated on the surface of the samples, then heat-treatment was followed for $TbF_3$ diffusion. The element distribution in the magnets and the diffusion profiles of Tb ions were analyzed by an EPMA (electron probe micro-analyzer). Prolonged heat treatment resulted in a deeper diffusion length of Tb ions. Coercivity of the $1^{st}$ heat-treated sample showed 21.86 kOe, while that of the $1^{st}$, $2^{nd}$ heat-treated and annealed sample revealed 34 kOe.

Effect of Lateral Diffusion on Hydrogen Permeation Measurement in Thick Steel Specimens

  • Traidia, A.;El-Sherik, A.M.;Attar, H.;Enezi, A.
    • Corrosion Science and Technology
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    • v.16 no.4
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    • pp.201-208
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    • 2017
  • A finite element analysis is proposed to study the effect of specimen dimensions on lateral diffusion of hydrogen during hydrogen permeation flux measurements. The error of measurement on thick specimens because of 1D diffusion approximation may be as much as 70%. A critical condition for accurate measurements is to designate the area of hydrogen monitoring/exit surface smaller than the area of hydrogen charging/entry surface. For thin to medium thickness specimens (ratio of thickness to specimen radius of 5:10 and below), the charging surface should be maximized and the monitoring surface should be minimized. In case of relatively thick specimens (ratio of thickness to specimen radius above of 5:10), use of a hydrogen-diffusion barrier on the specimen boundaries is recommended. It would completely eliminate lateral losses of hydrogen, but cannot eliminate the deviation towards 2D diffusion near the side edges. In such a case, the charging surface should be maximized and the monitoring surface should be as closer in dimension as the charging surface. A regression analysis was carried out and an analytical relationship between the maximum measurement error and the specimen dimensions is proposed.

Radiation Heat Flux and Combustion Characteristics of Inverse Diffusion Flame Burner Using Synthesis Gas, Part 1 : Air-Fuel Combustion (합성가스를 이용한 역확산버너의 연소 및 복사열전달 특성, Part 1 : 공기-연료 연소)

  • Lee, Pil-Hyong;Park, Chang-Soo;Lee, Jae-Young;Park, Bong-Il;Hwang, Sang-Soon;Lee, Sung-Ho;Anh, Yong-Soo
    • Journal of the Korean Society of Combustion
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    • v.14 no.4
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    • pp.33-40
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    • 2009
  • Waste Thermal Pyrolysis Melting process was proposed and has been studied in order to prevent air pollution by dioxin and fly ash generated from combustion process for disposal of waste. In this study, applicability as the fuel of diffusion burner of synthesis gas formed from Waste Thermal Pyrolysis process was addressed. Results showed that there is no big difference in the flame shape between MNDF and SNDF, and lift off was detected in MIDF but flame is more stable in SIDF which contains hydrogen with high combustion velocity as flow rate in first nozzle is increased. And radiation heat flux in inverse diffusion flame of synthesis gas was found to be more by 1.5 times than that in inverse diffusion flame of methane because of higher mole fraction of $CO_2$ with high emissivity in product gas.

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