• Title/Summary/Keyword: Diffusion study

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Effect of Heat Treatment Conditions on Corrosion and Hydrogen Diffusion Behaviors of Ultra-Strong Steel Used for Automotive Applications

  • Park, Jin-seong;Seong, Hwan Goo;Kim, Sung Jin
    • Corrosion Science and Technology
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    • v.18 no.6
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    • pp.267-276
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    • 2019
  • The purpose of this study was to examine the influence of conditions for quenching and/or tempering on the corrosion and hydrogen diffusion behavior of ultra-strong automotive steel in terms of the localized plastic strain related to the dislocation density, and the precipitation of iron carbide. In this study, a range of analytical and experimental methods were deployed, such as field emission-scanning electron microscopy, electron back scatter diffraction, electrochemical permeation technique, slow-strain rate test (SSRT), and electrochemical polarization test. The results showed that the hydrogen diffusion parameters involving the diffusion kinetics and hydrogen solubility, obtained from the permeation experiment, could not be directly indicative of the resistance to hydrogen embrittlement (HE) occurring under the condition with low hydrogen concentration. The SSRT results showed that the partitioning process, leading to decrease in localized plastic strain and dislocation density in the sample, results in a high resistance to HE-induced by aqueous corrosion. Conversely, coarse iron carbide, precipitated during heat treatment, weakened the long-term corrosion resistance. This can also be a controlling factor for the development of ultra-strong steel with superior corrosion and HE resistance.

The Interpratation of Dyeing Behavior of the Easily Dyeable Polyester Yarn under Atmospheric Pressure by Thermodynamic Parameters (열역학적 파라미터에 의한 상압가염형 폴리에스테르 섬유의 염색거동 해석)

  • 김태경;윤석한;신상엽;임용진;조규민
    • Textile Coloration and Finishing
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    • v.14 no.1
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    • pp.51-57
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    • 2002
  • In the prior study, the mechanical properties and the dyeability of the easily dyeable polyester grim(EDY) were investigated. In this study, to interpret the dyeing behavior of EDY with C. I. Disperse Violet 1, the thermodynamic parameters of dyeing, such as the standard affinity, the heat of dyeing(the enthalpy change), the entropy change, the diffusion coefficient, and the activation energy of diffusion, were obtained from adsorption isotherms and dyeing rate at various temperatures and compared to these of regular polyester (REG-PET). The heat of dyeing(the enthalpy change) and the entropy change for EDY showed smaller negative values than those for REG-PET. This means that the dye molecules in the EDY are combined more loosely than in the REG-PET and that is due to the flexibility of polymer chains of EDY. The diffusion coefficients of C. I. Disperse Violet 1 into the EDY were larger than those for REG-PET, and the activation energy of diffusion on EDY was smaller than that on REG-PET.

A mathematical model of blood flow and convective diffusion processes in constricted bifurcated arteries

  • Chakravarty S.;Sen S.
    • Korea-Australia Rheology Journal
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    • v.18 no.2
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    • pp.51-65
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    • 2006
  • Of concern in the present theoretical investigation is the study of blood flow and convection-dominated diffusion processes in a model bifurcated artery under stenotic conditions. The geometry of the bifurcated arterial segment having constrictions in both the parent and its daughter arterial lumen frequently appearing in the diseased arteries causing malfunction of the cardiovascular system, is constructed mathematically with the introduction of suitable curvatures at the lateral junction and the flow divider. The streaming blood contained in the bifurcated artery is treated to be Newtonian. The flow dynamical analysis applies the two-dimensional unsteady incompressible nonlinear Wavier-Stokes equations for Newtonian fluid while the mass transport phenomenon is governed by the convection diffusion equation. The motion of the arterial wall and its effect on local fluid mechanics is, however, not ruled out from the present model. The main objective of this study is to demonstrate the effects of constricted flow characteristics and the wall motion on the wall shear stress, the concentration profile and on the mass transfer. The ultimate numerical solutions of the coupled flow and diffusion processes following a radial coordinate transformation are based on an appropriate finite difference technique which attain appreciable stability in both the flow phenomena and the convection-dominated diffusion processes.

The Diffusion Behavier Analysis Caused by High Pressure Natural Gas Leak in Enclosure with and without Ventilation System (I) (밀폐공간 및 강제환기공간에의 천연가스 고압분출 시 농도 확산분포 거동해석 (I))

  • Ha, Tae-Woong;Ha, Jong-Man;Kim, Eun-Ja
    • Journal of the Korean Institute of Gas
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    • v.16 no.4
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    • pp.23-31
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    • 2012
  • The basic understanding of gas diffusion and technology to predict the diffusion phenomena are needed to prepare against a disaster of leakage of natural gas and to design better consistent and reliable gas supply system in enclosure. The experimental results of British Gas Technology Co. are used in present study as a reference of theoretical study using CFD. The present results of 2D CFD analysis for mass flow rate of nozzle release show good agreement with experimental results within 2.6 % error. 3D CFD analysis for the characteristics of natural gas diffusion in enclosure with various ventilation patterns also gives reasonable agreement with experimental results.

The Effect of Turbulence Intensity on the NOx Formation of Hydrogen Coaxial Jet Turbulent Diffusion Flames (난류강도가 수소 동축분류 난류 확산화염의 NOx 생성에 미치는 영향)

  • Han, Ji-Ung;Jeong, Yeong-Sik;Lee, Chang-Eon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.2
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    • pp.147-155
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    • 2001
  • Experimental investigations were conducted for two hydrogen-nitrogen coaxial jet diffusion flames. A flame was a conventional coaxial jet diffusion flame and the other was a coaxial jet diffusion flame of which ambient air-jet turbulence was intensified. In this study, firstly two kinds of NOx measuring system were campared by using different convertors, secondly the NOx formation characteristics were investigated in order to examine the effect of turbulence intensity. In this study it is known that stainless convertor has some problem in the converting process from NO$_2$to NO in fuel rich region but molybdenum convertor can detect the amount of NOx correctly. The increase of turbulence intensity reduces the thermal NOx less than a half in our experiment and this effect is conspicuous near the nozzle. The conversion rate from NO to NO$_2$and the portion of NO$_2$among NOx are increased with turbulence intensity. These NOx measurements will help to understand the influences of turbulence intensity on NOx formation.

Analysis on the Diffusion and the Intention to Use among Technology Adopter Categories (수용자 집단별 혁신제품 확산 및 지속사용의도에 대한 영향)

  • Han, Sangyun;Bae, Sung Joo;Park, Se-Bum;Ma, Eunjung;Han, Hena
    • Journal of Information Technology Services
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    • v.13 no.3
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    • pp.25-50
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    • 2014
  • The purpose of this study is to examine factors affecting the diffusion and the intention to use, and how these factors differ among adopter categories. A survey was done to analyze the diffusion of smart-phone, the most popular and innovative product nowdays. We collected 197 survey questionnaires from smart-phone user and analyzed the data using SPSS 18.0 and Smart PLS 2.0. PLS (Partial Least Square) analysis was implemented before multiple group-innovator, early adopter, eraly majority- analysis which is categoriezed by Innovation Diffusion Model of Rogers (1995). The results show that firstly, in innovator group (n=63), the functional and the safety value have significantly positive effect on user satisfaction. In addition, we found that user satisfaction and the brand loyalty are significatly associated with the intention of use. Secondly, in early adopter group (n = 67), the design value has significantly positive effect on user satisfaction and it has significantly positive effect on brand loyalty. Finally, in early majority group (n = 67), the design value has significantly positive effect on the user satisfaction and it has stronger effect on the intention of use and brand loyalty. We conclude this paper with the implication of this study to both academia, business practice, and policy making.

대기압의 변화에 따른 휘발성 오염물질의 토양에서 대기로의 거동

  • Choi Ji-Won;Smith James A.;Hwang Gyeong-Yeop
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.114-116
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    • 2005
  • Natural attenuation has been actively studied and often selected as final clean-up process in remediation of contaminated ground-water and soil for the last decade. Accordingly, understanding of natural processes affecting the fate and transport of contaminants in the subsurface becomes important for a success of implementation of the natural remediation strategy, Contaminant advection and diffusion processes in the unsaturated zone are naturally related to environmental changes in the atmosphere. The atmospheric pressure changes affecting the transport of contaminants in the subsurface are investigated in this study. Moisture content, trichloroethylene (TCE) concentration, temperature, and pressure variations in the subsurface were measured for the July, August, November, and December 2001 at Picatinny Arsenal, New Jersey. These data were used for a one-phase flow and one-component transport model in simulating the soil-gas flow and accordingly the TCE transport in the subsurface in accordance with the atmosphere pressure variations at the surface. The soil-gas velocities during the sampling periods varied with a magnitude of $10^{-6}\;to\;10^{-7}\;m\;s^{-1}$ at land surface. The TCE advection fluxes at land surface were several orders of magnitude smaller than the TCE diffusion fluxes. A sensitivy analysis indicated that advection fluxes were more sensitive to changes in geo-environmental conditions compared to diffusion fluxes. Of all the parameters investigated in this study, moisture content has the most significant effect on TCE advection and diffusion fluxes.

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