• Title/Summary/Keyword: Diffusion mixing

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Simulation of Mixing Behavior for Dredging Plume using Puff Model (퍼프모형을 이용한 준설플륨의 혼합거동 모의)

  • Kim, Young-Do;Park, Jae-Hyeon;Lee, Man-Soo
    • Journal of Korea Water Resources Association
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    • v.42 no.10
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    • pp.891-896
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    • 2009
  • The puff models have been developed to simulate the advection-diffusion processes of dredging suspended solids, either alone or in combination with Eulerian models. Computational efficiency and accuracy are of prime importance in designing these hybrid approaches to simulate a pollutant discharge, and we characterize two relatively simple Lagrangian techniques in this regard: forward Gaussian puff tracking (FGPT), and backward Gaussian puff tracking (BGPT). FGPT and BGPT offer dramatic savings in computational expense, but their applicability is limited by accuracy concerns in the presence of spatially variable flow or diffusivity fields or complex no-flux or open boundary conditions. For long simulations, particle and/or puff methods can transition to an Eulerian model if appropriate, since the relative computational expense of Lagrangian methods increases with time for continuous sources. Although we focus on simple Lagrangian models that are not suitable to all environmental applications, many of the implementation and computational efficiency concerns outlined herein would also be relevant to using higher order particle and puff methods to extend the near field.

A Study on Synthesis of Carbon Nanomaterial as a Material for Eco-ship (친환경 선박용 재료인 탄소나노물질의 합성에 관한 연구)

  • Choi, Jae-Hyuk;Kim, Jae-Hyun;Shin, Woo-Jung;Choi, Jung-Sik;Ryu, Kyoung-Boo;Lee, Sang-Min;Park, Seol-Hyun;Lee, Joo-Hee;Lim, Tae-Woo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.5
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    • pp.468-474
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    • 2012
  • In this study, experimental studies were performed for the carbon nanomaterial(CNM) which is catching on as a material for eco-ship. The opposed-flow methane flame was used as a heat source for synthesis of CNM. Ferrocene was used as a catalyst for the synthesis of CNM. These major parameters were $H_2$ mixing rate and sampling positions that synthesize CNMs in opposed-flow diffusion flames. The propensities of CNMs were experimentally determined using SEM and TEM images. The experimental result showed that the amount of CNTs was increased with increasing $H_2$ concentration. It can also be found that the optimal temperature in opposed-flow methane flame for synthesis of CNT was about 1500 K.

The Enhancement Effect of the Electrochemical Deposition in the Recovering Process of Cu from CuSO4 Solution (황산구리 용액으로부터의 구리회수공정에서 초음파에 의한 전착반응의 증대효과)

  • Yoon, Yong-Soo;Hong, In-Kwon;Lee, Jae-Dong;Jeong, Il-Hyun
    • Applied Chemistry for Engineering
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    • v.5 no.2
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    • pp.199-208
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    • 1994
  • In this study, the ultrasound which provides the properties of mixing, and surface cleaning effect, the increase of the effective reaction surface area and the enhancement of the effective collision frequency, was used to enhance the recovering efficiency of Cu from the Cu-ion containning waste water. The ultrasonic reactor used in this study was designed and constructed for improving the disadvantage of the existing ultrasonic reactor. From the experimental result and its analysis, we obtained following conclusions. 1. The ultrasound increased the rate of electrochemical deposition to 582.2% in maximum at the condition of $0.1M-CuSO_4$, and 2.1 V-overpotential. 2. The enhancement effect of ultrasound induced by the reduction of diffusion layer thickness was 277.8% in maximum and induced by the other effect except for the reduction effect of the diffusion layer thickness was 253.6% in maximum at $0.1M-CuSO_4$ and 2.1V overpotential. 3. This study gave the possibility of the scale-up of ultrasonic reactor and in particular, ultrasonic reactor would be effective in the treatment of waste water containning a low concentration of Cu ion.

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Adsorption Characteristics of Methyl Orange on Ginkgo Shell-Based Activated Carbon (은행 껍질 기반 활성탄의 메틸오렌지 흡착 특성)

  • Lee, Jeong Moon;Lee, Eun Ji;Shim, Wang Geun
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.636-645
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    • 2022
  • In this study, we investigated the adsorption characteristics of methyl orange (MO), an anionic dye, on ginkgo shell-based activated carbon (AC). For this purpose, ACs (GS-1, GS-2, and GS-4) with different textural properties were prepared using ginkgo shells and potassium hydroxide (KOH), a representative chemical activating agent. The correlation between the textural characteristics of AC prepared and the mixing ratio of KOH was investigated using nitrogen adsorption/desorption isotherms. The MO adsorption equilibrium experiment on the prepared ACs was conducted under different pH (pH 3~11) and temperature (298~318 K) conditions, and the results were investigated by Langmuir, Freundlich, Sips and temperature-dependent Sips equations. The feasibility of the MO adsorption treatment process of the prepared AC was also investigated using the dimensionless Langmuir separation factor. The heterogeneous adsorption properties of MO for the prepared AC examined using the adsorption energy distribution function (AED) were closely related to the system temperature and textural characteristics of AC. The kinetic results of the batch adsorption performed at different temperatures can be satisfactorily explained by the homogeneous surface diffusion model (HSDM), which takes into account the external mass transfer, intraparticle diffusion, and active site adsorption. The relationship between the activation energy value obtained by the Arrhenius plot and the adsorption energy distribution function value was also investigated. In addition, the adsorption process mechanism of MO on the prepared AC was evaluated using Biot number.

Properties of Fresh State and Characteristics of Shrinkage in Concrete Containing Low Fineness GGBFS (저분말도 고로슬래그 미분말을 혼입한 콘크리트의 굳지 않은 상태의 특성 및 수축 특성)

  • Kim, Tae-Hoon;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.1-7
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    • 2020
  • GGBFS(Ground Granulated Blast Furnace Slag) is one of the most actively used mineral admixtures with excellent long-aged strength and chloride diffusion resistance. Unlike Standard covering GGBFS in Japan and the U.K., the domestic standard for GGBFS does not contain low fineness of GGBFS under 4000 grade. In this paper, several basic tests are carried out for the concrete with 3,000 grade GGBFS concrete and ternary blended concrete for reducing hydration heat by mixing 4,000 grade GGBFS and fly ash, such as fresh concrete properties, compressive strength, and shrinkage properties. The air content and slump between the ternary blended concrete and the concrete with low-fineness GGBFS showed the similar level, and the results of difference in setting time from them were less than 20 minutes, showing no significant difference. In the evaluation of compressive strength and shrinkage characteristics, the ternary blended concrete showed lower long-aged strength and higher shrinkage than the low-fineness GGBFS concrete.

Improvement of Seawater Corrosion Resistance of Concrete Reinforcing Steel Using by Conductive Photocatalyst (전도성 광촉매를 이용한 콘크리트 철근의 염해 내구성 향상에 관한 연구)

  • Bae, Geun-Guk;Bae, Geun-Woo;Ahn, Yong-Sik
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.2
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    • pp.152-159
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    • 2017
  • In marine environment, the durability of concrete and reinforcing steel is known to be deteriorate by the permeation of chloride ion into concrete. In this study the conductive photocatalyst was used to improve the seawater corrosion resistance of the concrete and steel. Mortar and concrete samples were prepared by mixing with various amounts of conductive active carbon and photocatalytic powder($TiO_2$). The compressive strength of concrete was decreased with the increase of the amount of conductive carbon powders. The samples containing conductive carbon and photocatalytic powders showed the superior seawater corrosion resistance compared with the ordinary sample, which was verified by XRF analysis showing the concentration of chloride ion($Cl^-$) of mortars and concretes. The inhibitive effect of photocatalyst against chloride attack was discussed with the diffusion coefficient of chloride ion into mortar and concrete.

The Architectural Characteristics and the Confucian Order of Jeong-Gak (정각(旌閣)의 건축적(建築的) 특성(特性)과 예적(禮的) 질서(秩序) -전북지방을 중심으로-)

  • Hong, Seung-Jae;Ahn, Seon-Ho
    • Journal of architectural history
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    • v.9 no.3 s.24
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    • pp.37-49
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    • 2000
  • Jeong-Gak is one of the Confucian architecture in Cho-Sun Dynasty. This study is founded on the architectural characteristics and the Confucian order of Jeong-Gak. The Cho-Sun Dynasty had put in operation positive Jeong-Pyo Policy for diffusion Confusion ethics and educate the people. Prize methods of Jeong-Pyo Policy are Jeong-Ryeo, Jeong-moon, remit corvee, present a post and present goods. Jeong-Moon and Jeong-Ryeo is red gate. Vocabularies of Jeong-Moon and Jeong-Ryeo have used mixing but I think that both meaning is different essentially each other. The red gate that elected in front of gate or gateway is Jeong-Moon and another red gate that elected an entrance a village is Jeong-Ryeo. Jeong-Moon and Jeong-Ryeo have no roof, so they are many problem for maintenance and management. Accordingly Jeong-Gak come out from the reign of King Jung-Jong because shelter of Jeong-Moon and Jeong-Ryeo. The function of the Jeong-Gak is shelter of the Jeong-Moon and Jeong-Ryeo, encouragement of Sam-Gang(三綱) ethics, and ostentation of a family. Besides it has a monumental characteristic. It has been distributed the whole country land that Jeong-Gak is closely related with the community of same family (rural community) the latter period of the Cho-Sun Dynasty. The architectural particularity of the Jeong-Gak is brilliance of building materials as compared with different Confucian architecture and appearance of various architectural type. It is that a type of Jeong-Gak appeared Jeong-Ryeo-Gak type, a lofty gate type, and Stone Jeong-Ryeo type. And there are keeping a rule that is to say Confucian order clearly.

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Effects of Two-dimensional Heat and Mass Transports on Condensational Growth of Soot Particles in a Tubular Coater (원형관 코팅장치에서 연소 입자의 응축성장에 미치는 2차원 열 및 물질전달의 영향)

  • Park, Sung Hoon
    • Particle and aerosol research
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    • v.9 no.3
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    • pp.163-171
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    • 2013
  • Soot particles emitted from combustion processes are often coated by non-absorbing organic materials, which enhance the global warming effect of soot particles. It is of importance to study the condensation characteristics of soot particles experimentally and theoretically to reduce the uncertainty of the climate impact of soot particles. In this study, the condensational growth of soot particles in a tubular coater was modeled by a one-dimensional (1D) plug flow model and a two-dimensional (2D) laminar flow model. The effects of 2D heat and mass transports on the predicted particle growth were investigated. The temperature and coating material vapor concentration distributions in radial direction, which the 1D model could not accounted for, affected substantially the particle growth in the coater. Under the simulated conditions, the differences between the temperatures and vapor concentrations near the wall and at the tube center were large. The neglect of these variations by the 1D model resulted in a large error in modeling the mass transfer and aerosol dynamics occurring in the coater. The 1D model predicted the average temperature and vapor concentration quite accurately but overestimated the average diameter of the growing particles considerably. At the outermost grid, at which condensation begins earliest due to the lowest temperature and saturation vapor concentration, condensing vapor was exhausted rapidly because of the competition between condensations on the wall and on the particle surface, decreasing the growth rate. At the center of the tube, on the other hand, the growth rate was low due to high temperature and saturation vapor concentration. The effects of Brownian diffusion and thermophoresis were not high enough to transport the coating material vapor quickly from the tube center to the wall. The 1D model based on perfect radial mixing could not take into account this phenomenon, resulting in a much higher growth rate than what the 2D model predicted. The result of this study indicates that contrary to a previous report for a thermodenuder, 2D heat and mass transports must be taken into account to model accurately the condensational particle growth in a coater.

Mechanism on the Synthesis of Titanium Carbide by SHS (Self-Propagating High-Temperature Synthesis) Method (자체반응열 고온합성법에 의한 탄화티타늄 합성에 관한 메카니즘)

  • Ha, Ho;Hwang, Gyu-Min;Han, Hee-Dong
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1249-1258
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    • 1994
  • Titanium carbide was synthesized by reacting the prepared titanium powder and carbon black using SHS method sustains the reaction spontaneously, utilizing heat generated by the exothermic reaction itself. In this process, the effect of the particle size of titanium powder on combustion temperature and combustion wave velocity was investigated. By controlling combustion temperature and combustion wave velocity via mixing Ti and C powder with TiC, the reaction kinetics of TiC formation by SHS method was considered. Without reference to the change of combustion temperature and combustion wave velocity, TiC was easily synthesized by combustion reaction. As the particle size of titanium powder was bigger, or, as the amount of added diluent(TiC) increased, combustion temperature and combustion wave velocity were found to be decreased. The formation of TiC by combustion reaction in the Ti-C system seems to occur via two different mechanisms. At the beginning of the reaction, when the combustion temperatures were higher than 2551 K, the reaction was considered to be controlled by the rate of dissolution of carbon into a titanium melt with an apparent activation energy of 148 kJ/mol. For combustion temperatures less than 2551 K, it was considered to be controlled by the atomic diffusion rate of carbon through a TiC layer with an apparent activation energy of 355 kJ/mol. The average particle size of the synthesized titanium carbide was smaller than that of the starting material(Ti).

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The Role of Slits and Swirl Vanes on the Turbulent Flow Fields in Gun-Type Gas Burner with a Cone-Type Baffle Plate (콘형 배플판을 갖는 Gun식 가스버너의 난류유동장에 대한 슬릿과 스월베인의 역할)

  • Kim, Jang-Kweon;Jeong, Kyu-Jo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.4
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    • pp.466-475
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    • 2003
  • The gun-type gas burner adopted in this study is generally composed of eight slits and swirl vanes. Thus, this paper is studied to investigate the effect of slits and swirl vanes on the turbulent flow fields in the horizontal plane of gas swirl burner with a cone type baffle plate measured by using X-probe from hot-wire anemometer system. This experiment is carried out at flow rate 450 $\ell$/min in the test section of subsonic wind tunnel. The axial mean velocity component in the case of burner model with only swirl vanes shows the characteristic that spreads more remarkably toward the radial direction than axial one, it does, however, directly opposite tendency in the case of burner model with only slits. Consequently. both slits and swirl vanes composing of gun-type gas burner play an important role in decrease of the speed near slits and increase of the flow speed in the central part of a burner because the biggest speed spurted from slits encircles rotational flow by swirl vanes and it drives main flow toward the axial direction. Moreover, the turbulent intensities and turbulent kinetic energy of gun-type gas burner are distributed with a fairly bigger size within X/R<0.6410 than burner models which have only slits or swirl vanes because the rotational flow by swirl vanes and the fast jet flow by slits increase flow mixing, diffusion, and mean velocity gradient effectively.