• Title/Summary/Keyword: Diffusion mixing

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An Experimental Study on the Estimation of Chloride Diffusion Coefficient of LNG Storage Tanks (LNG 저장탱크 염해 확산 계수 산출을 위한 실험적 고찰)

  • Lee, Seung-Rim;Hwang, Seung-Hyun
    • Journal of Energy Engineering
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    • v.21 no.2
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    • pp.119-123
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    • 2012
  • Although LNG storage tanks are very delicate with chloride attack owing to its operating inshore location, specific integrity management system for chloride attack has not been studied so far. As the design warranty life time, about 25 years, has come, to prevent paying huge amount of construction cost and required resources for new alternative storage tanks and manage the life time of operating storage tanks, the basic data of chloride attack is necessary. This study intended to build up basic data for following detailed study to develop technologies for life time management of LNG storage tanks, NT Build 492 method in North Europe was used to test chloride diffusion coefficient for the newly-constructing concrete outer tank. Results of these tests lead us to the conclusion that 90 days diffusion coefficients show 46% of 28 days' due to a large quantity of fly ash mixing and much similar to estimation from concrete process table. It seems resonable to conclude that 90 days specimens are recommended estimating the chloride diffusion coefficient for LNG storage tanks to enhance the reliabilities.

Flame Hole Dynamics Model of a Diffusion Flame in Mixing Layer (혼합층에서의 확산화염에 대한 flame hole dynamics 모델)

  • Kim, Jun-Hong;Chung, S.H.;Kim, J.S.
    • 한국연소학회:학술대회논문집
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    • 2003.05a
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    • pp.223-227
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    • 2003
  • The method of flame hole dynamics is demonstrated as a mean to simulate turbulent flame extinction. The core of the flame hole dynamics involves derivation of a random walk mapping for the flame holes, created by local quenching, between the burning and quenched states provided that the dynamic characteristics of flame edges is known. Then, the random walk mapping is projected to a background turbulent field. The numerical simulations are carried out with the further simplifications of flame string and unconditioned scalar dissipation rate. The simulation results show how the chance of partial quenching is influenced by the crossover scalar dissipation rate. Finally, a list of improvements, necessary to achieve more realistic turbulent flame quenching simulation, are discussed.

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A Study on the Amorphization Reaction of the Co-Zr Multilayered Thin Film (Co-Zr 다층 박막의 저온 비정질화에 관한 연구)

  • 안지수;이병일;주승기
    • Journal of the Korean Magnetics Society
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    • v.6 no.3
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    • pp.170-173
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    • 1996
  • Co-Zr multilayered thin films were prepared by three-gun magnetron sputtering system and low temperature arrorphization was attempted. According to thin film X-ray and cross-sectional TEM analysis, it has been found that zirconium layer is arrorphized by diffusion of cobalt and the amorphization rate at the upper interface is two or three times faster than that at the lower interface of the zirconium layers. This new phenomenon is explained in terms of atomic mixing during sputtering.

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Selective Carbonization and Nitridation of Titanium in (ZrTi)O2 Powders Synthesized by Copreciptation Method

  • Shin Soon-Gi
    • Korean Journal of Materials Research
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    • v.15 no.10
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    • pp.662-666
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    • 2005
  • Solid solutions of $(Zr/Ti)O_2$ were prepared in powder form by the coprecipitation technique. After mixing with carbon or exposing to nitrogen gas at elevated temperature, titanium cations selectively diffused out from the oxide compound to form titanium carbide (TiC) or titanium nitride (TiN), respectively. TiN formed strong interfacial contacts between the oxide grains. In contrast, TiC formed as small crystallites on oxide grains but did not bind the matrix grains together. TiN therefore played a role in strengthening the interparticle bonding, but TiC weakened the bonding between grains. Partial diffusion of titanium cations also led to nanolayered structure being formed between the oxide grains, which provided weak interfacial layers that fractured in a step-wise fashion.

A Study on Combustion Characteristics of Gasoline and Diesel Fuels in a Compression Ignition Engine (압축착화 엔진에서 가솔린과 디젤연료의 연소 특성에 관한 연구)

  • Kim, Kihyun
    • Journal of Power System Engineering
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    • v.21 no.1
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    • pp.63-69
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    • 2017
  • The combustion characteristics of gasoline and diesel were tested in a compression ignition engine. Both fuels were used with same common rail injection system. Combustion experiment showed that low load condition of 0.45 MPa IMEP (indicated mean effective pressure) was tested in metal and optical engines. The gasoline combustion showed higher hydrocarbon and carbon monoxide emissions but lower soot emission compared with diesel combustion. NOx emissions were very high at late injection timing but significantly decreased at early injection timing due to the lean combustion resulted from vigorous mixing process. Direct combustion visualization showed that the diesel combustion was dominated by diffusion combustion exhibiting soot incandescence and the gasoline combustion was mostly consisted of premixed combustion showing blue chemiluminescence.

Numerical simulation of unsteady flow field behind bluff body (Bluffbody 비정상 유동장에 대한 수치해석)

  • Ryu, Myeong-Seok;Gang, Seong-Mo;Kim, Yong-Mo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.3
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    • pp.350-357
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    • 1997
  • The transient incompressible flow behind the axisymmetric bluff body is numerically simulated using the random vortex method(RVM). Based on the vorticity formulation of the unsteady Navier-Stokes equations, the Lagrangian approach with a stochastic simulation of diffusion using random walk technique is employed to account for the transport processes of the vortex elements. The numerical solutions for 2-dimensional recirculating flow behind a backward-facing step in the laminar range of Reynolds number are compared with experimental data. The present simulation focuses on the transitional flow regime where the recirculation zone behind the bluff body becomes highly unsteady and large-scale vortex eddies are shed from the bluff body wake due to intrinsic shear layer instabilities. The unsteady vertical flow structures and the mixing characteristics behind the bluff body are discussed in detail.

A Study on the Chloride ion Penetration Characteristic of Concrete containing Ground Granulated Blast Furnace Slag (고로슬래그미분말 치환 콘크리트의 염화물 침투특성에 관한 연구)

  • 김현수;지남용
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.997-1002
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    • 2001
  • There are two types of chloride in concrete; one is added as concrete materials' chloride when concrete's mixing, and .the other is penetrated from the air and sea water in the sea-shore area. These chlorides penetrate into concrete, and they are accumulated inside the concrete with aging. This study aimed to evaluate the chloride ion penetration resistance of concrete containing GGBFS in the sea-shore area. Therefore, the specimens made with the replacement ratios(0, 0.30, 0.45, 0.60) of GGBFS were put into 3% NaCl solution according to the chloride accelerating test of JCI-SC3, and then investigated the weight changes, compressive strength, chloride ion with the depths of the specimens by aging. The result is that the diffusion coefficient of chloride ion is decreased with the increase of replacement ratios when compared to OPC

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Numerical Analysis of the Chemical Injection Characteristics Using a Low Reynolds Number Turbulence Model

  • Chang, Byong-Hoon;Chang Kyu;Park, Han-Rim
    • Journal of Energy Engineering
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    • v.8 no.1
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    • pp.110-118
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    • 1999
  • In order to protect the nuclear reactor coolant system from corrosion, lithium is injected into the coolant from the chemical injection tank. The present study investigates the chemical injection characteristics of the injection tank using a low Reynolds number turbulence model. Laminar flow analysis showed very little diffusion of the jet and gave incorrect flow and concentration fields. A disk located near the inlet of the injection tank was effective in mixing the chemical additives in the top portion of the tank, and significant reduction in injection time was obtained.

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Experimental Study on Combustion Characteristics of Porous Ceramic Liquid Fuel Combustor (다공 세라믹 액체 연료 연소기의 연소 특성에 관한 실험적 연구)

  • Chung, K.H.;Lim, I.G.
    • Journal of the Korean Society of Combustion
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    • v.4 no.1
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    • pp.85-93
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    • 1999
  • Experimental study on a porous ceramic liquid fuel combustor is performed. Compact burner with low pollutant emission and high combustion efficiency is realized through the use of porous ceramic materials of high porosities. The use of porous ceramic materials in burner material results in rapid vaporization of liquid fuel and enhancement in mixing process, and thus nearly premixed combustion of liquid fuel is achieved instead of diffusion and partially premixed combustion method, which is often used and apt to produce high pollutant emissions such as CO, NOx and soot. With this enhanced vaporization and premixing method of liquid fuel vapor and air, it is found that enhanced combustion process with intense radiation output and better emission characteristics in NOx, CO and soot emission, compared to other conventional liquid fuel burning method, are possible.

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Thermal Insulation Properties of Epoxy/Mesoporous Carbon Composites

  • Heo, Gun-Young;Seo, Min-Kang;Oh, Sang-Yeob;Choi, Kyeong-Eun;Park, Soo-Jin
    • Carbon letters
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    • v.12 no.1
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    • pp.53-56
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    • 2011
  • This study aimed to investigate the influence of mesoporous carbons on the thermal insulation properties of epoxy/mesoporous carbon composites. The mesoporous carbon (CMK-3) was prepared by conventional templating method using SBA-15. The epoxy/mesoporous carbon composites were prepared by mixing the synthesized CMK-3 with diglycidylether of bisphenol A (DGEBA). As experimental results, the curing reactivities of the DGEBA/CMK-3 composites were found to decrease with the addition of the CMK-3. Also, the thermal conductivities of DGEBA/CMK-3 composites were found to decrease with increasing CMK-3 content. This could be interpreted in terms of the slow thermal diffusion rate resulting in pore volume existing in the gaps in the interfaces between the mesoporous carbon and the DGEBA matrix.