• Title/Summary/Keyword: Diffusion cell methods

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Boron Diffused Layer Formation Process and Characteristics for High Efficiency N-type Crystalline Silicon Solar Cell Applications (N-type 고효율 태양전지용 Boron Diffused Layer의 형성 방법 및 특성 분석)

  • Shim, Gyeongbae;Park, Cheolmin;Yi, Junsin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.3
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    • pp.139-143
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    • 2017
  • N-type crystalline silicon solar cells have high metal impurity tolerance and higher minority carrier lifetime that increases conversion efficiency. However, junction quality between the boron diffused layer and the n-type substrate is more important for increased efficiency. In this paper, the current status and prospects for boron diffused layers in N-type crystalline silicon solar cell applications are described. Boron diffused layer formation methods (thermal diffusion and co-diffusion using $a-SiO_X:B$), boron rich layer (BRL) and boron silicate glass (BSG) reactions, and analysis of the effects to improve junction characteristics are discussed. In-situ oxidation is performed to remove the boron rich layer. The oxidation process after diffusion shows a lower B-O peak than before the Oxidation process was changed into $SiO_2$ phase by FTIR and BRL. The $a-SiO_X:B$ layer is deposited by PECVD using $SiH_4$, $B_2H_6$, $H_2$, $CO_2$ gases in N-type wafer and annealed by thermal tube furnace for performing the P+ layer. MCLT (minority carrier lifetime) is improved by increasing $SiH_4$ and $B_2H_6$. When $a-SiO_X:B$ is removed, the Si-O peak decreases and the B-H peak declines a little, but MCLT is improved by hydrogen passivated inactive boron atoms. In this paper, we focused on the boron emitter for N-type crystalline solar cells.

Diffusion-weighted Magnetic Resonance Imaging for Predicting Response to Chemoradiation Therapy for Head and Neck Squamous Cell Carcinoma: A Systematic Review

  • Sae Rom Chung;Young Jun Choi;Chong Hyun Suh;Jeong Hyun Lee;Jung Hwan Baek
    • Korean Journal of Radiology
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    • v.20 no.4
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    • pp.649-661
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    • 2019
  • Objective: To systematically review the evaluation of the diagnostic accuracy of pre-treatment apparent diffusion coefficient (ADC) and change in ADC during the intra- or post-treatment period, for the prediction of locoregional failure in patients with head and neck squamous cell carcinoma (HNSCC). Materials and Methods: Ovid-MEDLINE and Embase databases were searched up to September 8, 2018, for studies on the use of diffusion-weighted magnetic resonance imaging for the prediction of locoregional treatment response in patients with HNSCC treated with chemoradiation or radiation therapy. Risk of bias was assessed by using the Quality Assessment Tool for Diagnostic Accuracy Studies-2. Results: Twelve studies were included in the systematic review, and diagnostic accuracy assessment was performed using seven studies. High pre-treatment ADC showed inconsistent results with the tendency for locoregional failure, whereas all studies evaluating changes in ADC showed consistent results of a lower rise in ADC in patients with locoregional failure compared to those with locoregional control. The sensitivities and specificities of pre-treatment ADC and change in ADC for predicting locoregional failure were relatively high (range: 50-100% and 79-96%, 75-100% and 69-95%, respectively). Meta-analytic pooling was not performed due to the apparent heterogeneity in these values. Conclusion: High pre-treatment ADC and low rise in early intra-treatment or post-treatment ADC with chemoradiation, could be indicators of locoregional failure in patients with HNSCC. However, as the studies are few, heterogeneous, and at high risk for bias, the sensitivity and specificity of these parameters for predicting the treatment response are yet to be determined.

Experimental Analysis of GDL Degradation in PEM Fuel Cell (고분자전해질형 연료전지 가스확산층의 내구 성능 저하에 관한 실험적 분석)

  • Ha, Tae-Hun;Park, Jae-Man;Cho, Jun-Hyun;Min, Kyoung-Doug;Lee, Eun-Suk;Jung, Ji-Young;Kim, Do-Hun;Jin, Yong-Won;Lee, Dae-Han
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.132-132
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    • 2009
  • To achieve the commercialization of PEM fuel cell, the durability problem must be solved. Recently, many researchers have focused on this durability problem and degradation studies about membrane and electrode have been reported. But durability characteristics of gas diffusion layer is not much reported yet. Durability of GDL is very important to maintain the performance of PEM fuel cell because the main function of GDL is a path of fuel and water and the GDL degradation causes the loss of the GDL function. In this study, the degradation of GDL, especially, the mechanical degradation process was investigated with the leaching test. The effect of water dissolution was observed through the test and the amount of GDL degradation was measured with various measurement methods such as weight measurement, static contact angle measurement, scanning electron microscope. After 2,000 hours test, the GDL showed structural damage and loss of hydrophobicity.

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Permeation Characteristics of Hazardous Substances in Tattoo Dye using Franz Diffusion Cells (Franz Diffusion Cell을 이용한 문신용 염료 내 유해물질의 피부 투과특성 연구)

  • Park, Kyo-Hyun;Jung, Se-Hoon;Shin, Ho-Sang;Kim, Bae-Hwan
    • Journal of Environmental Health Sciences
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    • v.42 no.1
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    • pp.61-70
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    • 2016
  • Objectives: The purpose of this study is to determine the exposure risk to tattoo components by analyzing skin absorption using the in vitro method. Tattoos are commonly used for cosmetic purposes, and the skin of not only the operator but of the people who are undergoing the cosmetic procedure is continuously exposed to hazardous chemicals. Methods: Skin permeation risk determination was conducted by the in vitro Franz diffusion cell method according to the ingredient types of tattoo dyes, such as volatile organic compounds (VOCs), non-volatile organic compounds and heavy metals, using hairless mouse full skin and human cadaver epidermis. Results: The major components with good skin penetration for each type of tattoo dye ingredient were clarified. Among the tatto dye ingredients, 1,2-Dichlorobenzene, Zn, Al, Pb and Ti showed good skin penetration. Most of the skin transmission rates were higher in hairless mouse full skin than in human cadaver epidermis. Conclusion: A possible exposure risk to hazardous substances in tattoo dyes was confirmed from this study. These results are expected to provide a positive contribution to the establishment of management regulations for tattoo dyes.

Real time Image Processor for Reproduction of Gray Levels in Dark Areas on Plasma Display Panel (PDP) (플라즈마 디스플레이 패널의 어두운 영역에서의 계조 재현을 위한 실시간 영상처리기)

  • Lee, Chang-Hun;Park, Seung-Ho;Gang, Jin-Gu;Kim, Chun-U
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.1
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    • pp.46-54
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    • 2002
  • Plasma Display Panel (PDP) is required to be both the determination of white point of each gray level and the inverse gamma correction since no-balanced RGB cell and linear property of PDP, respectively. However, these two methods cause degradation of grey level representation and undesirable false contour in the dark areas on PDP. In this paper, we implemented real time image processor of the proposed error diffusion algorithm and unsharp masking operation to protect the blurring image caused by the error diffusion. Experimental results showed drastic improvements of gray level representation and reduction of undesirable false contour.

A Study of the Electrode Catalyst Migration and Aging Mechanism of PEMFC (고분자연료전지 내 촉매 이동 및 노화메커니즘에 관한 연구)

  • Lee, Yoon-Hee;Lee, Ki-Suk;Yun, Jong-Jin;Byun, Jung-Yeon
    • Journal of Hydrogen and New Energy
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    • v.23 no.3
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    • pp.256-263
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    • 2012
  • We studied the degradation phenomenon of Pt catalyst in PEMFC. We used the electron microscope analysis technique including the ultra-microtome pretreatment method, FEG-SEM and TEM analysis methods for analysis of Pt nanoparticles. The Pt catalyst degradation is observed not only in electrode site but also in membrane site. We investigated these various degradation phenomena. The cathode electrode layer thickness is reduced. The size of the catalyst is increased much larger than initial size in membrane site. The catalyst moved from electrode layer to the electrolyte membrane. The rounded shape of catalyst was changed to the polygon. As a result, we found that the catalyst degradation processes of migration and coarsening occurred by the followings mechanisms; (1) dissolution of Pt ; (2) diffusion of Pt ion ; (3) Pt ion chemical reduction in membrane; (4) Coarsening of Pt particles (Ostwald ripening) ; (5) polygon shape change of Pt by {111} plane growth.

Study on the Skin Absorption of the Organic Solvents (유기용제의 피부흡수 연구)

  • Kim, Hyeon-Yeong;Chung, Yeong-Hyen;Jeong, Jae-Hwang;Sur, Gil-Soo;Moon, Young-Han
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.7 no.2
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    • pp.279-288
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    • 1997
  • The penetrating speeds of organic solvents into the nude mouse skin were measured by in vitro methods(diffusion cell methods) and in vivo methods(measuring internal residues of the organic solvents). The results were as follows: 1. The penetrating speeds of toluene, m-xylene, MEK, MIBK, ethanol, IPA and 2-bromopropane into the skin were $0.4832mg/cm^2/h$, $0.1738mg/cm^2/h$, $1.124mg/cm^2/h$, $0.6627mg/cm^2/h$, $1.747mg/cm^2/h$, $1.359mg/cm^2/h$, and 2-bromopropane $4.165mg/cm^2/h$ respectively. 2. The penetrating speeds of the mixtures of two, toluene and m-xylene, the mixture of three, IPA, ethyl acetate, and MIBK, the mixture of five, toluene, m-xylene, IPA, ethyl acetate, and MIBK were $0.172mg/cm^2/h$, $1.431mg/cm^2/h$, and $2.983mg/cm^2/h$ respectively. 3. The absorption speeds of 2-bromopropane and styrene which were measured by in vivo processes were $3.12mg/cm^2/h$ and $1.44mg/cm^2/h$ respectively. The absorption speed of 2-bromopropane mesured in vivo was 74.9% of that measured by in vitro methods, $4.165mg/cm^2/h$.

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Computer Models on Oxygenation Process in the Pulmonary Circulation by Gas Diffusion

  • Chang, Keun-Shik;Bae, Hwang
    • International Journal of Vascular Biomedical Engineering
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    • v.4 no.1
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    • pp.9-16
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    • 2006
  • In this article we introduce computer models that have been developed in the past to determine the concentration of metabolic gases, the oxygen and carbon dioxide, along the pulmonary circulation. The terminal concentration of these gases in the arterial blood is related with the total change of the partial pressure of the same gases in the alveoli for the time beginning with inspiration and ending with expiration. It is affected not only by the ventilation-perfusion ratio and the gas diffusion capacity of the lung membrane but also by the pulmonary defect such as shunt, dead space, diffusion impairment and ventilation-perfusion mismatch. Some pathological pulmonary symptoms such as ARDS and CDPD can be understood through the mathematical models of these pulmonary dysfunctions. Quantitative study on the blood oxygenation process using various computer models is therefore of foremost importance in order to monitor not only the pulmonary health but also the cardiac output and cell metabolism. Reviewed in this paper include the basic and advanced methods that enable numerical study on the gas exchange and on the arterial oxygenation process, which might depend on the various heart and lung physiological conditions listed above.

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Absorption of d-Limonene in Orange Juice into a Laminated Food Package Studied with a Solid Phase Micro-extraction Method

  • Lee, Hahn-Bit;Yang, Hee-Jae;Min, Sea-C.
    • Food Engineering Progress
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    • v.14 no.4
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    • pp.354-358
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    • 2010
  • The methods for determining the diffusion parameters for the diffusion of d-limonene, a major volatile compound of orange juice, through a multi-layered food packaging material and predicting its absorption into the packaging material have been investigated. The packaging material used was the 1.5-mm thick multi-layered packaging material composed of high impact polystyrene (HIPS), polyvinylidene chloride (PVDC), and low density polyethylene (LDPE). Orange juice was placed in a cell where volatiles were absorbed in the sample package and kept at $23{\pm}2^{\circ}C$ for 72 hr. The d-limonene absorbed in a 1.5-mm thick multi-layered food packaging material was analyzed by a solid phase micro-extraction (SPME). The absorption parameters for the absorption of d-limonene in the packaging material were determined and absorption of d-limonene into the packaging material was predicted using absorption storage data. The SPME desorption at $60^{\circ}C$ for 1 hr resulted in the most sensitive and reproducible results. The diffusion coefficients of d-limonene in the packaging material and the partition coefficient at $23{\pm}2^{\circ}C$ were approximately $1-2{\times}10^{12}m^2$/s and 0.03, respectively. The absorption profile no earlier than 30 hr was fit well by a model derived from the Fick's law.

Fabrication and Characteristics of $P^+N$ and $P^+NN^+$ Junction Silicon Solar Cell ($P^+N, P^+NN^+$ 접합형 실리콘 태양전지의 제작 및 특성)

  • Lee, Dae-U;Lee, Jong-Deok;Kim, Gi-Won
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.20 no.1
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    • pp.22-26
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    • 1983
  • P+N and P+NN+ solar cells with the area of 3.36 $\textrm{cm}^2$ were fabricated by thermal diffusion. Under the light intensity of 100 mW/$\textrm{cm}^2$, total area(active area) conversion efficiency was 13.4%(14.7%) for P+N cell fabricated by 15 min boron predeposition at 94$0^{\circ}C$ and 20 min annealing at 80$0^{\circ}C$, and 14.3%(15.6%) for P+NN+ cell processed by 15 min boron predeposition at 94$0^{\circ}C$ and 50 min annealing at 80$0^{\circ}C$ after 20 min back phosphorus diffusion at 1,05$0^{\circ}C$. The minority carrier lifetime in bulk of P+NN+ cells was increased about 2~3 times comparing with P+N cells because of guttering and BSF effect due to back phosphorus doping. The methods used for efficiency improvement were AR coating, Ag electroplating, back doping and fine grid pattern as well as the control of front doping profile.

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