• 제목/요약/키워드: Diffusion Distance

검색결과 247건 처리시간 0.025초

BaCO3-TiO2계의 고상반응에 관한 연구 (A Study on Solid Reaction of BaCO3-TiO2 System)

  • 이응상;황성연;임대영
    • 한국세라믹학회지
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    • 제24권5호
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    • pp.484-490
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    • 1987
  • Diffusion coupling experiment was done to study expansion of body and soild reaction in BaCO3-TiO2 system. Specimen of BaCO3 and TiO2 was formed with Pt-mark's method. Each specimen was fired at interval of 25℃ from 900℃ to 1000℃ for 2hrs. After that, specimen was fixed with resin and polished. Product layers of specimen were observed with SEM and EDS. The result were following; 1. Diffusion component is Ba2+, which diffuse toward TiO2. 2. Large crack between layer of BaCO3 and Ba2TiO4 was generated because of difference of thermal expansion coefficient. 3. Ba2TiO4 is formed to TiO2 body by the reaction of BaTiO3 and BaO and its structure is very porous. 4. BaTiO3 changes immediately to Ba2TiO4 by the reaction of BaO. But BaTiO3 which formed by the reaction of TiO2 and Ba2TiO4 exsists as layer because the diffusion distance of Ba2+ is far.

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A Molecular Dynamics Study on the Gas Permeation of Glassy Polymer

  • Goo, Hyung Seo;Kim, In Ho;Ha, SeongYong;Cho, Dae Myeong;Rhim, Ji Won;Nam, SangYong
    • Korean Membrane Journal
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    • 제6권1호
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    • pp.30-36
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    • 2004
  • The gas permeation performance of commercially available polyetherimide (Ultem$\^$/) is simulated by means of molecular dynamics methods. By the observation of trajectory, long distance hopping of gas molecules is needed to transverse from top to bottom of membrane. Two possibilities mechanism of diffusion phenomena through glassy polymers can be issued. Diffusion coefficients were calculated by Einstein relation equation. In solubility simulation, the value of the constants C'$\_$H/ and b for O$_2$ at 300 K were calculated. The diffusion and solubility coefficient of He for PEI were simulated in this simulation work. the permeability coefficient is 9.88 Barrer. This value is closed to experimental value of 9.4 Barrer.

벽면 충돌 층류 확산화염의 특성 (The characteristics of laminar diffusion flame impinging on the wall)

  • 박용열;김호영
    • 대한기계학회논문집B
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    • 제20권3호
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    • pp.979-987
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    • 1996
  • A theoretical study for the laminar round jet diffusion flame impinging on the wall was carried out to predict the characteristics and structure of impinging jet flame and heat transfer to the wall. Finite chemistry via Arrhenius equation was adopted as the combustion model. All the transport properties were considered as the variable depending on the temperature and composition. For the parametric study, the distance from nozzle to perpendicular wall and Reynolds number at nozzle exit were chosen as the major parameters. As the results of the present study, the characteristics of flow field and the distributions of temperature, density and each chemical species were obtained. The heat transfer rate from flame to the wall and the effective heating area were calculated to investigate the influence of the major parameters on the heat transfer characteristics.

Solvent Effect on Stress Relaxation of PET Filament Fibers and Self Diffusion of Crystallites

  • Nam Jeong Kim;Eung Ryul Kim;Sang Joon Hahn
    • Bulletin of the Korean Chemical Society
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    • 제12권5호
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    • pp.468-473
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    • 1991
  • Viscoelastic properties of PET filament fibers on stress relaxation were investigated in the solvents of $H_2$O, 0.05% NaOH and 50% DMF using an Instron (UTM4-100 Tensilon) with solvent chamber. The theoretical stress relaxation equation derived by applying the Ree-Eyring's hyperbolic sine law to dashpot of three element non-Newtonian model was applied to the experimental stress relaxation curves, and the model parameters $G_1,G_2$, ${\alpha}$ and ${\beta}$ were obtained. By analyzing temperature dependency of the relaxation time, the values of activation entropy, activation enthalpy and activation free energy for flow in PET filament fiber were evaluated, the activation free energy being about 25.7 kcal/mol. The self diffusion coefficient and hole distance were obtained from parameters ${\alpha}$, ${\beta}$ and crystallite size in order to study the self diffusion and the orientation of crystallites in amorphous region and the effect of solvent.

용융 폴리우레탄의 완화 스펙트럼에 의한 자체확산분포 결정 (Determination of Self Diffusion Distributions of Molten Polyurethanes by Relaxation Spectra)

  • 김남정
    • 대한화학회지
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    • 제50권3호
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    • pp.196-202
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    • 2006
  • 점탄성 용융 폴리우레탄의 자체확산분포가 완화스펙트럼과 자체확산분포 관계식으로부터 얻어졌다. ester, PCL PCL dyed 형의 용융 폴리우레탄의 완화스펙트럼은 실험적인 응력완화 곡선을 Ree-Eyring and Maxwell non-Newtonian model(REM 모델)이론식에 적용시켜서 얻는다. 용융폴리우레탄의 응력완화 실험은 온도조절 장치가 있는 physica 레오메타를 이용하여 여러 온도에서 수행되었다. 이론적인 완화스펙트럼은 REM model로부터 유도한 이론적인 완화스펙트럼식을 프로그램화한 컴퓨터 계산에서 구하였다. 폴리우레탄 시료의 자체확산과 비결정 영역의 홀거리가 응력완화 실험에 의해서 연구 조사되었다. 비결정 영역에서의 유동단위의 확산을 연구하기 위해서 확산계수와 홀부피가 유변학적인 파라메타와 결정크기로부터 계산되었다. 폴리우레탄 시료의 완화스펙트럼과 자체확산은 유동 단위의 분자량분포, 점도, 홀부피, 활성화에너지와 밀접한 관계가 있는 것을 알 수 있다.

Faraday cup array 개발을 위한 Particle Beam Mass Spectrometer 시스템 내에서의 입자 확산 연구 (A Study on Particle Diffusion to Develop Faraday Cup Array of Particle Beam Mass Spectrometer System)

  • 문지훈;신용현;김태성;강상우
    • 한국입자에어로졸학회지
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    • 제8권1호
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    • pp.29-35
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    • 2012
  • The Faraday cup electrode of different size has been developed and evaluated to investigate the diffusion effect of particles by Brownian motion in a particle beam mass spectrometer(PBMS). Particles which focused and accelerated by aerodynamic lens are charged to saturation in an electron beam, and then deflected electrostatically into a Faraday cup detector for measurement of the particle current. The concentration of particles is converted from currents detected by Faraday cup. Measurements of particle current as a function of deflection voltage are combined with measured relationships between particle velocity and diameter, charge and diameter, and mass and diameter, to determine the particle size distribution. The particle currents were measured using 5, 10, 20, 40 mm sized Faraday cup that can be move to one direction by motion shaft. The current difference for each sizes as a function of position was compared to figure out diffusion effect during transport. Polystyrene latex(PSL) 100, 200 nm sized standard particles were used for evaluation. The measurement using 5 mm sized Faraday cup has the highest resolution in a diffusion distance and the smaller particles had widely diffused.

버너의 벽면온도와 연소실내 주위공기온도에 따른 매연입자의 열영동 부착 특성에 관한 수치적 연구 (Numerical Study on the Thermophoretic Deposition Characteristics of Soot Particles for Wall Temperature of Burner and Surrounding Air Temperature in Combustion Duct)

  • 최재혁;한원희;윤두호;윤석훈;정석호
    • Journal of Advanced Marine Engineering and Technology
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    • 제32권1호
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    • pp.57-65
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    • 2008
  • The characteristics of soot deposition on the cold wall in laminar diffusion flames have been numerically analyzed with a two-dimension with the FDS (Fire Dynamics Simulator). In particular, the effects of surrounding air temperature and wall temperature have been discussed. The fuel for the flame is an ethylene ($C_2H_4$). The surrounding oxygen concentration is 35%. Surrounding air temperatures are 300K, 600K, 900K and 1200K. Wall temperatures are 300K, 600K and 1200K. The soot deposition length defined as the relative approach distance to the wall per a given axial distance is newly introduced as a parameter to evaluate the soot deposition tendency on the wall. The result shows that soot deposition length is increased with increasing the surrounding air temperatures and with decreasing the wall temperature. And the numerical results led to the conclusion that it is essential to consider the thermophoretic effect for understanding the soot deposition on the cold wall properly.

Histology and Morphometries of the Epidermis of the Fins and Sucking Disc of the Mudskipper, Periophthalmus modestus (Pisces, Gobiidae)

  • Park, Jong-Young;Kim, Ik-Soo;Lee, Yong-Joo;Kim, So-Young
    • Animal cells and systems
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    • 제8권2호
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    • pp.111-115
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    • 2004
  • The epidermis of the mudskipper, Periophthalmus modestus, consists of three layers- the outermost layer, middle layer and stratum germinativum. Extensive fine blood capillaries are present near the superficial layer of epidermis and outermost layer in five fins and a sucking disc. The diffusion distance between the vascular capillaries and the surface of epidermis ranged from 3.6 to 10.9${\mu}$m: 3.6 ${\mu}$m in the sucking disc, 10.9 ${\mu}$m in the anal fin and 4.6 to 5.0 ${\mu}$m in the two dorsal fins. Rate of the surface area of respiratory epithelium, the surface area of the fine blood capillaries occupied per surface area of epidermis in 0.1mm, is 3.7 to 4.4% in two dorsal fins and 1.1% in the anal fin. The middle layer is simpler in structure consisting of small or voluminous cells swollen by epidermal cells, and this layer appeared web-like. Well-developed lymphatic spaces containing lymphocytes existed in the stratum germinativum. The five fins and sucking disc had no epidermal glands.

Measurements of $^{224}Ra\;and\;^{223}Ra$ in the Nakdong River estuary and the South Sea of Korea

  • Hwang, Dong-Woon;Kim, Gue-Buem;Yang, Han-Soeb
    • Journal of the korean society of oceanography
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    • 제38권2호
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    • pp.80-86
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    • 2003
  • The horizontal distributions of $^{224}Ra$ (half life=3.4 days) and $^{223}Ra$ (half life=11.3 days) were measured in surface seawaters of the Nakdong River estuary and the South Sea of Korea in April and October 2002. In order to determine these short-lived Ra isotopes, we used a delayed coincidence counter which is much more rapid and accurate than traditional methods. In an estuarine mixing zone (salinity, ~l6 ppt), the activities of $^{224}Ra\;and\;^{223}Ra$ were much greater than what would be expected from a mixture of freshwater and seawater in the Nakdong River estuary. This excess Ra may be a result of Ra desorption from fresh sediments originating from the river upstream. However, in the more open areas of the Nakdong River estuary (salinity>30 ppt) and the South Sea of Korea, $^{224}Ra\;and\;^{^{223}Ra$ activities decreased exponentially as a function of distance offshore. Using the decrease of $^{223}Ra$ with distance offshore in the South Sea of Korea, we estimated the apparent horizontal eddy diffusivities. The apparent eddy diffusion coefficients in South Sea of Korea are calculated to be approximately $3500-8000\;\textrm{m}^2/sec$.

블록 기반의 영상 분할과 수계 경계의 확장을 이용한 수계 검출 (Water body extraction using block-based image partitioning and extension of water body boundaries)

  • 예철수
    • 대한원격탐사학회지
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    • 제32권5호
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    • pp.471-482
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    • 2016
  • 본 논문에서는 수계 영역의 감독 분류 성능을 향상시키기 위하여 블록 기반의 영상 분할과 수계 경계의 확장을 이용하는 수계 검출 방법을 제안한다. 초기 수계 영역을 추출하기 위하여 수계 훈련 지역의 Normalized Difference Water Index (NDWI) 및 Near Infrared (NIR) 밴드 영상의 분광 정보를 이용하여 Mahalanobis 거리 영상을 생성한다. Mahalanobis 거리 영상에 포함된 잡음 성분의 영향을 감소시키기 위해서 인접한 화소의 연결 강도에 의해 확산 계수가 제어되는 평균 곡률 확산을 적용한 후에 초기 수계 영역을 추출한다. 추출된 수계 영상을 같은 크기의 블록으로 분할한 후에 수계 경계에 속하는 수계 영역의 정보를 이용하여 수계 영역을 갱신한다. 수계 경계에 속하는 수계 영역과 수계 훈련 지역 사이의 통계적인 거리가 임계값 이하이면, 수계 영역 갱신을 반복적으로 수행한다. 제안한 알고리즘을 KOMPSAT-2 영상에 적용한 결과 블록 크기가 $11{\times}11$에서 $19{\times}19$사이인 경우에 overall accuracy는 99.47%에서 99.53%, Kappa coefficient는 95.07%에서 95.80%의 분류 정확도를 보였다.