• Title/Summary/Keyword: Diffusible hydrogen

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Study on EEC and SSC of the Electric Resistance Welded Linepipe Steel

  • Kim, Wan Keun;Koh, Seong Ung;Yang, Boo Young;Kim, Kyoo Young
    • Corrosion Science and Technology
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    • v.6 no.3
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    • pp.96-102
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    • 2007
  • The resistance of the linepipe steel to hydrogen-induced cracking (HIC) and sulfide stress cracking (SSC) is very important for steel to be used in sour oil/gas environments. Welding of steels is necessary to the construction of pipe-line transporting oil/gas. In this study, HIC and SSC resistance of an electric resistance welded (ERW) steel plate which belongs to API X70 grade was evaluated by using NACE TM0284-96A and NACE TM0177-96A methods. HIC and SSC fracturing behavior was investigated by observing fractured surfaces using optical microscopy (OM) and scanning electron microscopy (SEM). It was discussed in terms of metallurgical parameters such as the distribution of primary microstructure, second phases and inclusions. Results showed that the weld joint of ERW steel is more sensitive than base metal to HIC and SSC. This is due to difference in the contribution of metallurgical parameters to HIC and SSC nucleation and propagation.

Weldability of HY type High Strength-Toughness Steel (HY계 고강도 고인성강의 용접성)

  • ;;;Ahn, S. K.;Shim, I. O.
    • Journal of Welding and Joining
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    • v.13 no.3
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    • pp.65-76
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    • 1995
  • Weldability of DS100 and HY type high strength-toughness steel plates, tentatively produced as domestic production, was investigated. DS100 and DS130A had nearly same hardenability in HAZ in spite of its difference in Ceq. Based upon the y-groove test results, cold cracking susceptibility of DS130 was superior to that of DS100 because of its lower hydrogen level in weld metal. Solidification cracking tested by the Trans-Varestraint test was occured in all of the weld metals, and its susceptibility was high in the row of DS100, DS130A and DS130B. However, no liquation cracking and ductility-dip cracking tested by the Longi-Varestraint test with 6.0% augmented strain were detected in base metal and reheated weld metal. Toughness in the GMA welding joint was satisfied with the relative Mill Spec, even though welded joint of DS100 had relatively low impact energy especially at the weld metal.

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A Study on Tensile Restraint Crack Critical Stress Characteristcs of Gravity-Wet-Type Underwater Welded Joints (중력식 습식 수중용접부의 인강구속균열 임계응력 특성에 관한 연구)

  • O, Se-Gyu;Gang, Mun-Ho;Han, Sang-Deok
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.23 no.2
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    • pp.61-65
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    • 1987
  • In this study, the characteristics of TRC (tensile restraint crack) critical stress in the gravity type underwater wet welding process and in the in-air welding have been investigated for Y, y and 45$^{\circ}$r grooves using the KR Grade A-3 steel plates and the E4303 covered electrodes. The following results were obtained: (1) In the TRC tests, the initial critical stress of Y groove is higher than those of the 45$^{\circ}$r single bebel grooves in both in-air and underwater weldings, and the cold fracture sensitivity is higher in the underwater welding than in the in-air welding. (2) The hardness of underwater weld metal is the highest in heat affected zone is about Hk 365 in the in-air weld but Hk 670 in the underwater weld which is higher for cooling speed is more rapid, resulting in the lower critical stress by increase of fracture sensitivity. (3) The diffusible hydrogen quantity for 48 hours is about 18cc/100g-weld-metal in the in-air welding but 48cc/100g-weld-metal in the underwater welding. So that, in the case of underwater welding the diffusible hydrogen penetrates about 3 times more than that in the in-air welding.

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A Study on Tensile Restraint Crack Critical Stress Characteristcs of Gravity-Wet-Type Underwater Welded Joints (중력식 습식 수중용접부의 인강구속균열 임계응력 특성에 관한 연구)

  • Sae Kyoo Oh;Moon Ho Kang;Sang Deok Han
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.23 no.2
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    • pp.15-15
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    • 1987
  • In this study, the characteristics of TRC (tensile restraint crack) critical stress in the gravity type underwater wet welding process and in the in-air welding have been investigated for Y, y and 45°r grooves using the KR Grade A-3 steel plates and the E4303 covered electrodes. The following results were obtained: (1) In the TRC tests, the initial critical stress of Y groove is higher than those of the 45°r single bebel grooves in both in-air and underwater weldings, and the cold fracture sensitivity is higher in the underwater welding than in the in-air welding. (2) The hardness of underwater weld metal is the highest in heat affected zone is about Hk 365 in the in-air weld but Hk 670 in the underwater weld which is higher for cooling speed is more rapid, resulting in the lower critical stress by increase of fracture sensitivity. (3) The diffusible hydrogen quantity for 48 hours is about 18cc/100g-weld-metal in the in-air welding but 48cc/100g-weld-metal in the underwater welding. So that, in the case of underwater welding the diffusible hydrogen penetrates about 3 times more than that in the in-air welding.

DEVELOPMENT OF A PRACTICAL METHOD FOR THE ESTIMATION OF WELD INDUCED CRACK IN THICK PLATE WELDMENTS

  • Lee, Jae-Myung;Yoon, Dong-Ryul;Heo, Hee-Young;Jang, Tae-Won;Lee, Jae-Won
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.396-401
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    • 2002
  • A practical method for evaluating the possibility of the occurrence of cracking in actual thick-plate T-joint weldments is presented in this study. Systematic experiments based on the method of the design of experiment are conducted in order to investigate the crack tendency in relation to typical welding parameters such as diffusible hydrogen, restraint intensity, preheating temperature and so on. The elastic analysis using the [mite element techniques is employed to quantify the restraint intensities of the specimens. The defined restraint intensities are treated in numerical way for the sake of considering the most uncertain factor among some major factors that govern the cracking phenomena due to welding. The critical plane for judgment of the crack occurrence or crack density is presented as a function of typical welding parameters including determined restraint intensities. The results of numerical estimation by the proposed method for the experimental specimens show the usefulness as a practical tool in welding induced crack problem having extensive uncertainties.

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The Effects of Microstructure on Cold Crack in High-Strength Weld Metals (고강도 용착금속의 미세조직이 저온균열에 미치는 영향)

  • Lee, Myung-Jin;Kang, Nam-Hyun
    • Journal of Welding and Joining
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    • v.32 no.1
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    • pp.22-27
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    • 2014
  • In the past, cold crack was commonly observed in the HAZ(heat affected zone) of high-strength steels. Applying to TMCP(thermo-mechanical controlled process) and HSLA(high strength low alloy) steels, cold crack tends to increase the occurrence in the weld metal. It is generally understood that cold crack occurs when the following factors are present simultaneously : diffusible hydrogen in the weld metal, a susceptible microstructure and residual stress. In particular, many studies investigated the microstructural effect on the cold crack in HAZ and the cold crack in weld metals starts to receive the special attendance in modern times. The purpose of the study is to review the effect of weld microstructures (grain boundary ferrite, Widm$\ddot{a}$nstatten ferrite, acicular ferrite, bainite and martensite) on cold crack in the weld metals. Among various microstructures of weld metals, acicular ferrite produced the greatest resistance to the cold crack due to the fine interlocking nature and high-angle grain boundary of the microstructure.

A Simplified Method to Estimate Welding Induced Crack of Weldments with Initial Structural Restraints

  • Lee, J.M.;Paik, J.K.;Kim, M.H.;Kang, S.W.;Heo, H.Y.
    • International Journal of Korean Welding Society
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    • v.4 no.1
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    • pp.38-45
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    • 2004
  • A practical method for evaluating the possibility of the occurrence of cracking in actual thick-plate T-joint weldments is presented in this study. Systematic experitrients based on the method of the design of experiment are conducted in order to investigate the crack tendency in relation to typical welding parameters such as diffusible hydrogen, restraint intensity, preheating temperature and so on. The elastic analysis using the fmite element techniques is employed to quantify the restraint intensities of the specimens. The defined restraint intensities are treated in numerical way for the sake of considering the most uncertain factor among some major factors that govern the cracking phenomena due to welding. The critical plane for judgment of the crack occurrence or crack density is presented as a function of typical welding parameters including determined restraint intensities. The results of numerical estimation by the proposed method for the experimental specimens show the usefulness as a practical tool in welding induced crack problem having extensive uncertainties.

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Mutation in clpxoo4158 Reduces Virulence and Resistance to Oxidative Stress in Xanthomonas oryzae pv. oryzae KACC10859

  • Cho, Jung-Hee;Jeong, Kyu-Sik;Han, Jong-Woo;Kim, Woo-Jae;Cha, Jae-Soon
    • The Plant Pathology Journal
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    • v.27 no.1
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    • pp.89-92
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    • 2011
  • Cyclic AMP receptor-like protein (Clp), is known to be a global transcriptional regulator for the expression of virulence factors in Xanthomonas campestris pv. campestris (Xcc). Sequence analysis showed that Xanthomonas oryzae pv. oryzae (Xoo) contains a gene that is strongly homologous to the Xcc clp. In order to determine the role of the Clp homolog in Xoo, a marker exchange mutant of $clp_{xoo4158}$ was generated. Virulence and virulence factors, such as the production of cellulase, xylanase, and extracellular polysaccharides (EPS) and swarming motility were significantly decreased in the $clp_{xoo4158}$ mutant. Moreover, the mutation caused the strain to be more sensitive to hydrogen peroxide and to over-produce siderophores. Complementation of the mutant restored the mutation-related phenotypes. Expression of $clp_{xoo4158}$, assessed by reverse-transcription realtime PCR and clp promoter activity, was significantly reduced in the rpfB, rpfF, rpfC, and rpfG mutants. These results suggest that the clp homolog, $clp_{xoo4158}$, is involved in the control of virulence and resistance against oxidative stress, and that expression of the gene is controlled by RpfC and RpfG through a diffusible signal factor (DSF) signal in Xanthomonas oryzae pv. oryzae KACC10859.