• Title/Summary/Keyword: Diesel removal

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TPH Removal of Oil-Contaminated Soil by Hot Air Sparging Process (고온 공기분사공정에 의한 유류오염대수층의 TPH 제거)

  • Lee, Jun-Ho;Park, Kap-Song
    • Journal of Korean Society on Water Environment
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    • v.23 no.5
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    • pp.665-675
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    • 2007
  • In-situ Air Sparging (IAS, AS) is a remediation technique in which organic contaminants are volatilized from saturated zone to unsaturated layer. This study focuses on the removal and interaction of Volatile Organic Compounds (VOCs) and $CO_2$, and Total Petroleum Hydrocarbon (TPH) in saturated and unsaturated, and air space zone on the unsaturated soil surface. Soil sparging temperature of hot air has risen to $34.9{\pm}2.7^{\circ}C$ from $23.0{\pm}1.9^{\circ}C$ for 36 days. At the diffusing point, fluid TPH concentrations were reduced to 78.7% of the initial concentration in saturated zone when hot air was sparged. The TPH concentrations were decreased to 66.1% for room temperature air sparging. The amount of VOCs for hot air sparging system, in air space, was approximately 26% larger than constant air sparging system. The amount of $CO_2$ was 4,555 mg (in unsaturated zone) and 4,419 mg (in air space) when hot air was sparged was 3,015 mg (in unsaturated zone) and 3,634 mg (in air space) for room air temperature in the $CO_2$ amount. The removals of VOCs and biodegradable $CO_2$ through the hot air sparging system (modified SVE) were more effective than the room temperature air sparging. The regression equation were $Y=976.4e^{-0.015{\cdot}X}$, $R^2=0.98$ (hot air sparging) and $Y=1055e^{-0.028{\cdot}X}$, $R^2=0.90$ (room temperaure air sparging). Estimated remediation time was approximately 500 days, if final saturated soil TPH concentration was set to 1.2 mg/L application of tail effect.

A Study on DeNOx Characteristics of Corona/Catalyst Hybrid System (코로나/촉매 일체형 시스템의 탈질특성에 관한 연구)

  • Chang, Hong-Ki;Choi, Chang-Sik;Shin, Jung-Uk;Ji, Young-Yeon;Hong, Min-Sun;Chung, Yoon-Jin
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.6
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    • pp.699-707
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    • 2007
  • This study was carried out to investigate the reaction characteristics of corona/catalyst hybrid $DeNO_x$ process. The experiments were performed by using the multi-staged pin-to-hole type corona reactor which is enable to control the pin-to-hole gap and to insert the catalyst. Also, used for this study, were catalysts which commercially used Pt, Pd and $TiO_2$, and oxygen and hydrocarbon ($C_2H_4$) as reagents. In the syn-gas test, at high temperatures in the range of $100{\sim}200^{\circ}C$, the corona-only $DeNO_x$ process did not reduce the $NO_x$ concentration effectively. However in the presence of ethylene and oxygen as reagents, the $NO_x$ removal efficiency was better at these high temperatures than corona-only $DeNO_x$ process. In addition, coronal catalyst hybrid process with $TiO_2$ showed more efficiency of $NO_x$ removal than Pt and Pd catalyst, because the $TiO_2$ catalyst was more active than Pt and Pd catalyst to converse the $NO_2$ to $HNO_3$. Furthermore, at the condition of real diesel exhaust gas, the $DeNO_x$ efficiency of corona/catalyst hybrid process was not good at higher reaction temperature and plasma density.

Development of Lower Noise Excavator (굴삭기 저소음화 기술개발)

  • Ko, Kyung-Eun;Kim, Young-Hyun;Joo, Won-Ho;Kim, Dong-Hae;Bae, Jong-Gug;Shim, Tae-Koo;Kang, Jeong-Weon;Son, Deuk-Kyun;Kim, Choon-O
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.16 no.12 s.117
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    • pp.1185-1191
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    • 2006
  • The radiated noise of the excavator is composed of the various noise sources such as the diesel engine, cooling fan and hydraulic system, so the noise reduction for each noise source is required. In this study, the source contribution analysis for these principal noise sources is performed by using the noise source removal method. And to reduce the noise due to each one, the various experiments and analyses are studied. On the basis of these results, the proper noise reduction countermeasures are derived to develop the excavator satisfied the $2^{nd}$ noise regulation of EU.

A Comparative Study on Mitigation Alternatives in Response to an Extended SBO for APR1400 Using Systems Engineering (확장된 소내전원 상실 사고시의 대체대응활동 완화를 위한 비교 연구: 시스템 엔지니어링 관점으로)

  • Elaswakh, Islam Sabry;Oh, SJ;Lim, Hak-Kyu
    • Journal of the Korean Society of Systems Engineering
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    • v.12 no.2
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    • pp.91-99
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    • 2016
  • The safety of nuclear power plants has received much attention; this safety largely depends on the continuous availability of electrical energy source during all modes of nuclear power plant operation. A station blackout (SBO) describes the loss of the off-site electric power, the failure of the emergency diesel generators, and the unavailability of the alternate AC (AAC) power. Consequently, all systems that are AC powered such as the safety injection, shutdown cooling, component cooling water, and essential service water systems are unavailable. The aim of this study is to investigate the deficiencies of the existing alternatives for coping with an extended SBO for APR1400 design. The method is analyzing the existing deficiencies and proposing an optimal solution for the NPP design during the extended SBO. This study, established a new passive system, called passive decay heat removal system (PDHRS), using systems engineering approach.

Functionalized magnetite / silica nanocomposite for oily wastewater treatment

  • Hakimabadi, Seyfollah Gilak;Ahmadpour, Ali;Mosavian, Mohammad T. Hamed;Bastami, Tahereh Rohani
    • Advances in environmental research
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    • v.4 no.2
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    • pp.69-81
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    • 2015
  • A new magnetite-silica core/shell nanocomposite ($Fe_3O4@nSiO_2@mSiO_2$) was synthesized and functionalized with trimethylchlorosilane (TMCS). The prepared nanocomposite was used for the removal of diesel oil from aqueous media. The characterization of magnetite-silica nanocomposite was studied by X-ray diffraction (XRD), Fourier transform infrared (FTIR), transmission electron microscopy (TEM), surface area measurement, and vibrating sample magnetization (VSM). Results have shown that the desired structure was obtained and surface modification was successfully carried out. FTIR analysis has confirmed the presence of TMCS on the surface of magnetite silica nanocomposites. The low- angle XRD pattern of nanocomposites indicated the mesoscopic structure of silica shell. Furthermore, TEM results have shown the core/shell structure with porous silica shell. Adsorption kinetic studies indicated that the nanocomposite was able to remove 80% of the oil contaminant during 2 h and fit well with the pseudo-second order model. Equilibrium studies at room temperature showed that the experimental data fitted well with Freundlich isotherm. The magnetic property of nanocomposite facilitated the separation of solid phase from aqueous solution.

Modeling Study on Dispersion and Scavenging of Traffic Pollutants at the Location Near a Busy Road

  • Ma, Chang-Jin
    • Asian Journal of Atmospheric Environment
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    • v.9 no.4
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    • pp.272-279
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    • 2015
  • The information about the dispersion and scavenging of traffic-related pollutants at the locations near busy expressways is very helpful to highway planners for developing better plans to reduce exposures to air pollution for people living as well as children attending schools and child care centers near roadways. The objective of the current study was to give information in the dispersion and scavenging of vehicle-derived pollutants at the region near a busy urban expressway by a combination of two different model calculations. The modified Gaussian dispersion model and the Lagrange type below-cloud scavenging model were applied to evaluate $NO_x$ dispersion and DEP (Diesel exhaust particles) wet removal, respectively. The highest $NO_x$ was marked 53.17 ppb within 20-30 meters from the target urban expressway during the heaviest traffic hours (08:00AM-09:00AM) and it was 2.8 times higher than that of really measured at a nearby ambient measuring station. The calculated DEP concentration in size-resolved raindrops showed a continuous decreasing with increasing raindrop size. Especially, a noticeable decrease was found between 0.2 mm and 1.0 mm raindrop diameter.

Monitoring of petroleum hydrocarbon degradative potential of indigenous microorganisms in ozonated soil

  • ;;Rameshwar;Tatavarty
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.152-157
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    • 2003
  • Diesel-contaminated soils were ozonated for different times (0 - 900 min) and incubated for 9 wk to monitor petroleum hydrocarbons (PH)-degradative potential of indigenous microorganisms in the soils. Increased ozonation time decreased not only concentration of PH but also number of microorganisms in the soils. Microorganisms in the ozonated soils increased during 9-wk incubation as monitored by culture- and nonculture-based methods. Higher (1-2 orders of magnitude) cell number was observed by quantitative analysis of soil DNA using probes detecting genes encoding 165 rRNA(rrn), naphthalene dioxygenase (nahA), toluene dioxygenase (todC), and alkane hydroxylase (alkB) than microbial abundance estimated by culture-based methods. Such PH-degraders were relatively a few or under detection limit in 900-min ozonated soil. Further PH-removal observed during the incubation period supported the presence of PH-degraders in ozonated soils. Highest reduction (25.4%) of total PH (TPH) was observed in 180-min ozonated soil white negligible reduction was shown in 900-min ozonated soil during the period, resulting in lowest TPH-concentration in 180-min ozonated soil among the ozonated soils. Microbial community composition in 9-wk incubated soils revealed slight difference between 900-min ozonated and unozonated soils as analyzed by whole cell hybridization using group-specific rRNA-targeted oligonucleotides. Results of this study suggest that appropriate ozonation and subsequent biodegradation by indigenous microorganisms may be a cost-effective and successful remediation strategy for PH-contaminated soils.

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Effect of NO on Catalytic Soot Oxidation in Tight Contact with $Pt/CeO_2$ Using a Flow Reactor System ($Pt/CeO_2$ 촉매와 Tight Contact 한 상태의 Model Soot 산화에 NO가 미치는 영향에 관한 실험적 연구)

  • Lee, Dong-Il;Song, Chang-Hoon;Song, Soon-Ho;Chun, Kwang-Min
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.3
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    • pp.52-56
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    • 2011
  • Active regeneration in CDPF requires $O_2$ which regenerates soot at high temperature. However, small amount of NO can interrupt $O_2$ regeneration in CDPF. To verify this phenomena, soot oxidation experiments using a flow reactor with a $Pr/CeO_2$ catalyst are carried out to simulate Catalyzed Diesel Particulate Filter (CDPF) phenomena. Catalytic soot oxidation with and without small amount of NO is conducted under tight contact condition. As the heating rate rises, the temperature gap of maximum reaction rate is increased between with and without 50ppm NO. To accelerate the $NO_2$ de-coupling effect, CTO process is performed to eliminate interfacial contact for that time. As CTO process is extended, temperature which indicates peak reaction rate increases. From this result, it is found that small amount of NO can affect tight contact soot oxidation by removal of interfacial contact between soot and catalyst.

A study on the removal of the water from the anthracite slurry by Oil Agglomeration Prosess(partI) (Oil Agglomeration Process에 의한 무연탄 슬러리의 탈수에 관한 연구(제1보))

  • 권이동;신강호;조동성
    • Resources Recycling
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    • v.2 no.2
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    • pp.39-44
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    • 1993
  • This study was carried out to remove the water from low grade anthracite slurry produced at Eoryong coal mine by the oil agglomeration process. 80% of Anthracite as a coal oil mixture (COM) was separated from water by the difference of specific gravity. Then, the amount of kerosene, diesel oil, and heavy oil forming COM was 10% of the amount of sample, respectively. The recovery rate of combustibles and ash content of agglomerated anthracite were affected largely by the amount of added oil, pulp density, particle size, mixing time, and impeller speed. The recovery rate of combustibles was increased to 95% and ash content was decrea-sed from 30% to 13.5% under the optimum conditions.

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Computational Study on the Soot Blowing Method for Enhancing the Performance of the SCR System (SCR 시스템의 효율적인 운영을 위한 Soot Blowing 방법에 대한 해석적 연구)

  • Seo, MoonHyeok;Chang, HyukSang
    • Particle and aerosol research
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    • v.8 no.3
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    • pp.99-110
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    • 2012
  • In the SCR (selective catalytic reduction) system which is used for controlling the NOx emission from the Diesel engines, the soot deposited on the catalysis causes degradation of the system performance. Numerical study was done to evaluate the performance of soot blower which is proposed as a method for removing the soot on the catalysis. The spray conditions and the effect of the compressed air from the AIG (air inlet gun) were analyzed numerically to evaluate the overall effective method of the soot blowing. The characteristics of the final velocity distribution and velocity waves across the inlet section of the catalysis were evaluated with respect to the geometries of the AIG outlets and pressure conditions. An experimental model was used to validate the results of the numerical calculation that is used for finding the effective removal blowing momentum transfer quantities of soot the inlet section of the catalysis, and it is proposed that the required minimum blowing momentum transfer quantities are over than 0.499 $kg/m{\bullet}t_{eff}$ in the current study.