• Title/Summary/Keyword: Dielectric dispersion

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Evaluation of Microwave Dielectric Properties in $(Pb_{0.5}Ca_{0.5})(Fe_{0.5}Ta_{0.5})O_3$ Ceramics by the Dielectric Mixing Rule (유전체 혼합 법칙을 이용한 $(Pb_{0.5}Ca_{0.5})(Fe_{0.5}Ta_{0.5})O_3$세라믹스의 마이크로파 유전특성 평가)

  • 박흥수;윤기현;김응수
    • Journal of the Korean Ceramic Society
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    • v.37 no.3
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    • pp.240-246
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    • 2000
  • The microwave dielectric properties of the complex perovskite (Pb0.5Ca0.5)(Fe0.5Ta0.5)O3 ceramics were investigated with the porosity and the dielectric mixing rule. Assuming that the specimens were mixtures of real dielectrics and pores, with 3-0 connectivity, the ionic polarizabilities modified by Maxwell's equation were more close to the theoretical values rather than those modified by Wiener's equation in porous specimens. The theoretical dielectirc loss were obtained with the infrared reflectivity spectra from 50 to 4000cm-1, which were calculated by Kramers-Kronig analysis and classical osciallator model. The relative tendency of dielectric loss calculated from the theoretical value and Maxwell's equation in the specimens with different porosities was in good agreement with the one by the post resonant method.

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Effect of Poling Electric Field and Temperature Change on the Dielectric Anomalies of Relaxor Ferroelectric Strontium-Barium-Niobate Single Crystals

  • Shabbir, Ghulam;Ko, Jae-Hyeon;Kojima, Seiji
    • Journal of the Korean Physical Society
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    • v.73 no.10
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    • pp.1561-1565
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    • 2018
  • The dielectric properties of the uniaxial relaxor ferroelectric $Sr_xBa_{1-x}Nb_2O_6$ with x = 0.75 were investigated along the polar [001] direction as a function of temperature. The capacitance maximum showed the frequency dispersion commonly observed in relaxors. Additional weak dielectric anomalies were observed in the paraelectric phase; they were only seen during the heating process and disappeared upon subsequent cooling. These were attributed to the existence of large polar clusters strongly pinned at defects and/or to random fields and their metastable characters. Aligning the ferroelectric domains along the polar axis at room temperature removed the high-temperature dielectric anomalies. The dependences of the capacitance and the dielectric maximum temperature on the magnitude of the poling field were investigated.

Scattering characteristics of metal and dielectric optical nano-antennas

  • Ee, Ho-Seok;Lee, Eun-Khwang;Song, Jung-Hwan;Kim, Jinhyung;Seo, Min-Kyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.76.1-76.1
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    • 2015
  • Optical resonances of metallic or dielectric nanoantennas enable to effectively convert free-propagating electromagnetic waves to localized electromagnetic fields and vice versa. Plasmonic resonances of metal nanoantennas extremely modify the local density of optical states beyond the optical diffraction limit and thus facilitate highly-efficient light-emitting, nonlinear signal conversion, photovoltaics, and optical trapping. The leaky-mode resonances, or termed Mie resonances, allow dielectric nanoantennas to have a compact size even less than the wavelength scale. The dielectric nanoantennas exhibiting low optical losses and supporting both electric and magnetic resonances provide an alternative to their metallic counterparts. To extend the utility of metal and dielectric nanoantennas in further applications, e.g. metasurfaces and metamaterials, it is required to understand and engineer their scattering characteristics. At first, we characterize resonant plasmonic antenna radiations of a single-crystalline Ag nanowire over a wide spectral range from visible to near infrared regions. Dark-field optical microscope and direct far-field scanning measurements successfully identify the FP resonances and mode matching conditions of the antenna radiation, and reveal the mutual relation between the SPP dispersion and the far-field antenna radiation. Secondly, we perform a systematical study on resonant scattering properties of high-refractive-index dielectric nanoantennas. In this research, we examined Si nanoblock and electron-beam induced deposition (EBID) carbonaceous nanorod structures. Scattering spectra of the transverse-electric (TE) and transverse-magnetic (TM) leaky-mode resonances are measured by dark-field microscope spectroscopy. The leaky-mode resonances result a large scattering cross section approaching the theoretical single-channel scattering limit, and their wide tuning ranges enable vivid structural color generation over the full visible spectrum range from blue to green, yellow, and red. In particular, the lowest-order TM01 mode overcomes the diffraction limit. The finite-difference time-domain method and modal dispersion model successfully reproduce the experimental results.

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Electrical Properties of $C_{22}$-Quinolium(TCNQ) Langmuir-Blodgett Films Depending on the Frequency ($C_{22}$-Quinolium(TCNQ) LB 막의 주파수에 따른 전기적 특성)

  • Lee, S.K.;You, D.S.;Kim, T.W.;Kim, Y.K.;Kwon, Y.S.;Kang, D.Y.
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1289-1291
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    • 1994
  • Dielectric properties of $C_{22}$-Quinolium(TCNQ) Langmuir-Blodgett (LB) films were studied as a function of frequency(10Hz-13MHz) and annealing temperature($20{\sim}240^{\circ}C$). A complex dielectric constant ${\epsilon}^*={\epsilon}'-i{\epsilon}"$, in general, shows the frequency dependence of orientational polarization in the measured frequency range. A dielectric permittivity ${\epsilon}'$ at 10Hz is around 8.2 and decreases very slowly as the frequency increases up to 1 MHz, and then suddenly drops above this frequency, while a dielectric loss factor ${\epsilon}"$ reaches a maximum near 1 MHz. Its annealing temperature dependence at 10Hz shows that ${\epsilon}'$ and ${\epsilon}"$ increase as the temperature increases upto $180^{\circ}C$, even though there is a little drop near $120{\sim}160^{\circ}C$. Both ${\epsilon}'$ and ${\epsilon}"$ drop quickly above $180^{\circ}C$. which may be thought of a destruction of the LB films. Another fact of the annealing temperature dependence of the dielectric constant is an occurrence of the new dielectric dispersion below 100Hz. This low frequency dispersion is getting clear above $80^{\circ}C$.

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Extremely Low Numerical Dispersion FDTD Method Based on H(2, 4) Scheme for Lossy Material

  • Oh, Il-Young;Hong, Yongjun;Yook, Jong-Gwan
    • Journal of electromagnetic engineering and science
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    • v.13 no.3
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    • pp.158-164
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    • 2013
  • This paper expands a previously proposed optimized higher order (2, 4) finite-difference time-domain scheme (H(2, 4) scheme) for use with lossy material. A low dispersion error is obtained by introducing a weighting factor and two scaling factors. The weighting factor creates isotropic dispersion, and the two scaling factors dramatically reduce the numerical dispersion error at an operating frequency. In addition, the results confirm that the proposed scheme performs better than the H(2, 4) scheme for wideband analysis. Lastly, the validity of the proposed scheme is verified by calculating a scattering problem of a lossy circular dielectric cylinder.

Angular Dispersion-type Nonscanning Fabry-Perot Interferometer Applied to Ethanol-water Mixture

  • Ko, Jae-Hyeon;Kojima, Seiji
    • Journal of the Optical Society of Korea
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    • v.13 no.2
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    • pp.261-266
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    • 2009
  • The angular dispersion-type non-scanning Fabry-Perot was applied to an ethanol-water mixture in order to investigate its acoustic properties such as the sound velocity and the absorption coefficient. The scattered light from the mixture was analyzed by using the charge-coupled-device area detector, which made the measurement time much shorter than that obtained by using the conventional scanning tandem multi-pass Fabry-Perot interferometer. The sound velocity showed a deviation from ultrasonic sound velocities at low temperatures accompanied by the increase in the absorption coefficient, indicating acoustic dispersion due to the coupling between the acoustic waves and some relaxation process. Based on a simplified viscoelastic theory, the temperature dependence of the relaxation time was obtained. The addition of water molecules to ethanol reduced the relaxation time, consistent with dielectric measurements. The present study showed that the angular dispersion-type Fabry-Perot interferometer combined with an area detector could be a very powerful tool in the real-time monitoring of the acoustic properties of condensed matter.

Study on the electrical properties WO$_3$-doped SrTiO$_3$ ceramics (WO$_3$를 첨가한 SrTiO$_3$ 세라믹스의 전기적 성질에 관한 연구)

  • 유인규;김효태;변재동;김윤호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.9-13
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    • 1995
  • The effect of WO$_3$ addition and sintering condition on the electrical properties of SrTiO$_3$ceramic have been investigated. Resistivity and capacitance of grains and grain boundaries were obtained by applying impedance spectroscopy. From the result it could be concluded that the temperature dependance of capacitance of WO$_3$doped specimens were influenced directly by the variation of grain boundary capacitance. It was also found that the dispersion frequency increased as the degree of reduction of the specimen increased. The dispersion frequency characteristics showed discernably that the resistivity of the specimen varied with WO$_3$ content. The dielectric properties were influenced directly by the reduction of the specimens. The dielectric constant of grain boundaries of BL capacitor could be obtained by Cole-Cole plot and was influeneced by the amount of WO$_3$ added.

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Preparation and Characterization of Polyimide/Carbon-Nanotube Composites

  • Kim, Bong-Sup;Bae, Sang-Hoon;Park, Young-Hwan;Kim, Ji-Heung
    • Macromolecular Research
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    • v.15 no.4
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    • pp.357-362
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    • 2007
  • Polyimide/carbon nanotube (CNT) composite films, for potential use in high performance microelectronics and aerospace applications, were prepared by mixing a polyisoimide (PII) solution and a CNT suspension in NMP, followed by casting, evaporation and thermal imidization. The CNTs were modified by a nitric acid treatment to improve the thermal and electrical properties, as well as to provide good dispersion of the CNTs in a polymer matrix. The formation of functional groups on the modified CNT was confirmed by Raman spectroscopy. Scanning electron microscopy revealed the modified CNTs to be well dispersed in the polyimide matrix, with a uniform diameter of ca. 50 nm. The thermal stability of the films containing the CNTs was improved due to the enhanced interfacial interaction and good dispersion between the polyimide matrix and modified CNTs. In addition, the thermal expansion coefficient of the composites films was slightly decreased, but the dielectric constants increased linearly with increasing CNT content.

Preparation of a PVDF (Polyvinylidene Fluoride) Thin Film Grown by Using the Method of Electric Field Application (전계인가법을 이용한 PVDF 박막의 제작과 특성에 대한 연구)

  • 장동훈;강성준;윤영섭
    • Proceedings of the IEEK Conference
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    • 2000.06b
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    • pp.76-79
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    • 2000
  • The 3$\mu\textrm{m}$-thick PVDF (Polyvinyiidene fluoride) thin film have been prepared using physical vapor deposition with electric field, and its FT-IR specrum, dielectric property and electric conduction phenomenon have been investigated. Since the characteristic peaks ate detected at 509.45 and 1273.6〔cm〕 in the FT-IR spectrum, we are confirmed that the ${\beta}$ -phase is dominant in the PVDF thin film. In the results of dielectric properties, the PVDF thin film shows anomalous dispersion, i.e. gradual decrease of dielectric constant with increase of frequency, and also that the dielectric absorption point changes from 200Hz to 7000Hz with increasing temperature of thin film, which is consistent with the Debye's theory. The activation energy (ΔH) obtained from temperature dependence of dielectric loss is 21.64 ㎉/㏖. We confirm that the electric conduction mechanism of PVDF thin film is dominated by ionic conduction by investigating the dependence of the leakage current of the thin film on the temperature and the electric field.

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Dielectric and Optical Study of Polymer Nematic Liquid Crystal Composite

  • Manohar, S.;Shukla, S.N.;Chandel, V.S.;Shukla, J.P.;Manohar, R.
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.3
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    • pp.111-115
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    • 2013
  • The dielectric anisotropy and dispersion of the real and imaginary part of the permittivity of commercially important nematic mixture E-24 and its polymer composite were investigated in the frequency range from 1 kHz to 10 MHz, and temperature range $14^{\circ}C$ to $55^{\circ}C$. The percentage optical transmittance and density have also been measured for both the systems. The results have been explained by assuming molecular rotation about the long molecular axis, under a hindering nematic potential. The dielectric anisotropy ${\Delta}{\varepsilon}$ is positive, and the mean dielectric permittivity falls with rising temperature. ${\Delta}{\varepsilon}$ is also used to determine the order parameter with varying temperature.