• Title/Summary/Keyword: Dicarboximide

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Incidence of Benzimidazole- and Dicarboximide Resistant Isolates of Monilinia fructicola from Overwintering Mummies and Peduncles on Peach trees (월동 복숭아 미이라 과일과 과병으로부터 분리한 Monilinia fructicola의 Benzimidazole과 Dicarboximide계 살균제에 대한 저항성 밀도)

  • 임태헌;장태현;차병진
    • Korean Journal Plant Pathology
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    • v.14 no.4
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    • pp.367-370
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    • 1998
  • Monilina fructicola, the brown rot fungus of stone fruits, was isolated from overwintering mummies and peduncles on peach trees from February to March, 1998. The resistant population of these isolates to benzimidazole (benomyl, carbendazim and thiophanate-methyl) and dicarboximide (iprodione, vinclozolin and procymidone) was examined. Among 417 isolates, the incidence of isolates resistant to benomyl, carbendazim, and thiophanate-methyl were 45 (10.8%), 47 (11.3%), and 46 (11.0%), respectively. Forty two (10.0%) isolates showed cross-resistance to benzimidazole fungicides. On the other hand, the resistant isolates against iprodione, vinclozolin and procymidone were 186 (44.6%), 1 (0.2%) and 150 (36.0%), respectively. Among the isolates, 116 (27.8%) showed cross-resistance to iprodione and procymidone. Moreover, 27 (6.5%) of 417 isolates showed double-resistance to both benzimidazole (benomyl) and dicarboximide (iprodione).

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Occurrence of Botrytis cinerea Resistant to Dicarboximide Fungicides on Strawberries in Greenhouses (시설재배(施設栽培) 딸기 포장(圃場)에서 Dicarboximide 계(系) 약제저항성(藥劑抵抗性) 잿빛곰팡이병균(病菌)의 발생(發生))

  • Yu, Seung Hun;Park, Jeong Hun
    • Korean Journal of Agricultural Science
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    • v.19 no.2
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    • pp.170-178
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    • 1992
  • Isolates of Botrytis cinerea resistant to dicarboximide fungicides were collected from strawberry fields in greenhouses in spring and early summer of 1990. Five out of 9 isolates of B. cinera were resistant, which showed mycerial growth on PDA containing dicarboximide fungicides(procymidone and vinclozolin) with concentrations of 100, 400 and $1,600{\mu}g/ml$. The minimal inhibitory concentration(MIC) values of the dicaboximide-resistant isolates was more than $6,400{\mu}g/ml$, while that of the sensitive isolates was less than $6.25{\mu}g/ml$. The germination ratio of conidia of the resistant isolates on PDA containing procymidone and vincolozolin was more than 95%, while that of the sensitive was less than 15%. The procymidone-resistant isolates were also resistant to vinclozolin, showing cross-resistant between the fungicides, but cross-resistant was not observed between the dicarboximides and dichlofluanid. Resistance to benomyl was also found in all the dicarboximide resistant isolates. Occurrence frequency of dicarboximide-resistant isolates out of 223 isolates was about 40%. The resistant isolates were widely distributed throughout Korea.

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Fitness of Dicarboximide-Resistant and Sensitive Monilinia fructicola Isolated from Peach in Korea

  • Lim, Tae-Heon;Yi, Jae-Choon;Chang, Tae-Hyun;Byeongjin Cha
    • The Plant Pathology Journal
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    • v.17 no.4
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    • pp.205-209
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    • 2001
  • Dicarboximide-resistant isolates of Monilinia fructicola grew readily on media amended with dicarbosimide fungicides, and showed cross-resistance to pentachlo-ronitrobenzene (PCNB). The fitness of resistant isolates was inferior to that of sensitive isolates. Mycelial growth on fungicide-free medium was not significantly different between the dicarboximide-resistant and sensitive isolates. The originally high $\textrm{EC}_{50}$ values of the resistant isolate decreased after storage for 16 weeks at $4^{\circ}$. After inoculation with the mixture of spore suspensions of resistant and sensitive isolates, the re-isolation rate of the resistant spores was significantly reduced regardless of the mixing ratio. From the results, it could be concluded that the competitive ability of the resistant isolates is inferior to the sensitive ones.

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Convolutive Cyclic Voltammetry Investigation of Dicarboximide Laser Dye at a Platinum Electrode in 1,2-Dichloroethane (1,2-Dichloroethane 내 백금 전극에서의 dicarboximide 레이저 염료에 대한 convolutive 순환 전압-전류법 연구)

  • Al-Bishri, Hassan M.;El-Mossalamy, E.H.;El-Hallag, Ibrahim;El-Daly, Samy
    • Journal of the Korean Chemical Society
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    • v.55 no.2
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    • pp.169-176
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    • 2011
  • The electrochemical investigation of N,N-bis (2,5-di-tert-butylphenyl)-3,4,9,10 perylenebis (dicarboximide) laser dye have been carried out using cyclic voltammetry and convolution - deconvolution voltammetry combined with digital simulation technique at a platinum electrode in 0.1 mol/L tetrabutyl ammonium perchlorate (TBAP) in solvent 1,2 dichloroethane ($CH_2Cl-CH_2Cl$). The investigated dye was reduced via consumption of two sequential electrons to form radical anion and dianion (EE mechanism). In switching the potential to positive scan, the compound was oxidized by loss of two electrons, which were followed by a fast aggregation process ($EC_1EC_2$ mechanism). The electrode reaction pathway and the chemical and electrochemical parameters of the investigated compound were determined using cyclic voltammetry and convolutive voltammetry. The extracted electrochemical parameters were verified and confirmed via digital simulation method.

Effect of N-Octyl bicycloheptene dicarboximide on the Toxicity of S-Bioallethrin in Rats (S-Bioallethrin의 독성에 미치는 N-Octyl bicycloheptene dicarboximide의 영향)

  • 홍사욱;장준식
    • Environmental Analysis Health and Toxicology
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    • v.8 no.1_2
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    • pp.37-58
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    • 1993
  • In order to investigate the toxicities of S-bioallethrin (5-biol) and its combination treatment with N-octyl bicycloheptene dicarboximide (MGK-264), the acute and subacute toxicity, and enzyme activity test were performed. $LD_{50}$ levels of S-biol and MGK-264 in rats are 640 mg/kg and 3, 280 mg/kg respectively. However, when rats were treated with the mixture of S-biol and MGK-264 (1 : 5 ratio), the $LD_{50}$ was decreased to 545 mg/kg. In serological analysis, ALT and LDH were increased in animals treated with the mixture. Also glucose level was significantly increased after 5 weeks in animals treated with both S-biol and the mixture. Other biochemical parameters such as cytochrome P-450 and NADPH-cytochrome c reductase in the liver and kidney were shown to be not significantly changed. Levels of total ATPase and $mg^{2+}$ ATPase were significantly decreased in the liver of animals treated with the mixture after 4-5 weeks. In addition, S-biol can alone decrease total ATPase activity. Total ATPase activity was also significantly decreased in the kidney after 5 week treatment with the mixture. Similarily, glucose-6-phosphatase activity was significantly decreased in animals treated with the mixture. When either S-biol or MGK-264 was administered, cholinesterase and carboxyesterase activities were slightly decreased but they were significantly decreased when the mixture was administered.

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Distribution of Monilinia fructicola Isolates Resistant to Dicarboximide or to both Procymidone and Carbendazim in Korea

  • Cha, Byeong-Jin;Lim, Tae-Heon
    • The Plant Pathology Journal
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    • v.19 no.1
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    • pp.46-50
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    • 2003
  • To evaluate the sensitivity of Monilinia fructicola to dicarboximides used in controlling brown rot of peach, the fungus was isolated from commercial peach orchards in Chochiwon (CH), Chongdo (CD), Gyeongsan (GY), and Youngduk (YO) in Korea. The population shift of dicarboximide-resistant isolates of M. fructicola was investigated for 3 years starting 1998. The frequency of procymidone-resistant isolates (PRI) was higher in CD and GY than in CH and YO. The frequency of PRI was higher in the mid season (July-August) than in the rest of the year. Cross-resistance rate of PRI to iprodione was over 87.8% during the investigation, and double-resistance to both procymidone and carbendazim was less than 10%. However, the rate of cross-resistant isolates to vinclozolin was low. In the orchards in GY and CH without any fungicide spray, the PRI population was persistent and did not vary for 3 years. The results suggest that dicarboximide resistance of M. fructicola could be a problem in controlling brown rot and blossom blight on peach trees because it may take a long time to recover the population with sensitive isolates even in the absence of these fungicides.

Synthesis and Characterization of Pentarylene Bisimide Derivative as NIR Colorant (NIR Colorant용 Pentarylene Bisimide의 합성 및 특성 연구)

  • Baek, Kwan;Jeong, Yeon-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.2
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    • pp.140-146
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    • 2012
  • A variety of dyes are commercially available today, there is an ongoing need for new chromophoric systems and low-band-gap materials. For example, near-infrared (NIR) emission has received increased attention for applications in bioassays and medicine while NIR absorption is demanded for laser-welding of plastics or efficient blocking of heat rays. Most of the commercially available NIR materials are not suitable for such purposes owing to their insufficient stability. We have developed a novel NIR-absorbing polyaromatic dye. By extending the system of perylenebis(dicarboximide)s along the molecular long axis, we have obtained the higher homologue pentarylenebis(dicarboximide). We have tried to introduce imide functional group to pentarylene in order to increase chemical and thermal stability.

Fungicide Resistance and Genetic Diversity of Botrytis cinerea of Citrus (감귤 잿빛곰팡이병균의 살균제에 대한 저항성 및 유전적 다양성)

  • 고영진;이재군;서정규;문두길;한해룡
    • Korean Journal Plant Pathology
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    • v.14 no.6
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    • pp.682-688
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    • 1998
  • Fungicide resistance of 48 isolates of Botrytis cinerea collected from citrus in Cheju was investigated and genetic diversity was analyzed with random amplified polymorphic DNA(RAPD). High levels of resistance to benzimidazole fungicides benomyl and thiophanate-methyl and N-phenylcarbamate fungicide diethofencarb were observed. Negative cross resistance was clear between benzimidazole and N-phenylcarbamate fungicides, and multiple resistance to the fungicides was also observed. There was cross resistance among the dicarboximide fungicides procymidione, vinclozolin and iprodione as it was observed between the benzimidazole fungicides benomyl and thiophanate-methyl. The lowest levels of resistance were to the dicarboximide fungicides, but no sensitive isolate to polyoxin B was observed. The isolates showed genetically diverse RAPD profiles according to the geographic origin collected, but there was no significant correaltion between RAPD profiles of genomic DNA and the levels of fungicide resistance of the isolates. The isolates showed genetically diverse RAPD profiles, indicating that genetic differentiation had already occurred in the populations of B. cinerea distributed in Cheju.

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