• Title/Summary/Keyword: Diamondoid topology

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Synthesis, Crystal Structures and Properties of Two 3D CdII and ZnII Complexes with a 3-Fold Interpenetrating Feature

  • Lin, Hongyan;Sui, Fangfang;Liu, Peng;Wang, Xiuli;Liu, Guocheng
    • Bulletin of the Korean Chemical Society
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    • v.34 no.7
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    • pp.2138-2142
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    • 2013
  • Two new 3D coordination complexes [Cd(3-bpcd)(pht)] (1) and [Zn(3-bpcd)(pht)] (2) [3-bpcd = N,N'-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide, $H_2pht$ = phthalic acid] have been hydrothermally synthesized. X-ray diffraction analysis reveals that the complexes 1 and 2 represent a 4-connected diamondoid topology with a 3-fold interpenetrating feature. Moreover, the fluorescent properties of complexes 1 and 2 are studied.