• Journal of Environmental Health Sciences
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• v.22 no.4
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• pp.25-32
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• 1996

The Bioconcentration factor(BCF) is used as an important criterion in the risk assessment of environmental contaminants. Also it can be used as indicator of biomagnification of environmentally hazardous chemicals through food-chain as well as a tool for ranking the bioconcentration potential of the chemicals in the environment. This paper reports the measured BCF value on carbofuran in Carassius auratus(goldfish), under steady state, and examined corelation between the BCF value and the depuration rate constant. Carassius auratus(goldfish) was chosen as test organism and test periods were 1-day, 3-day and 5-day. Experimental concentrations were 0.05, 0.10 and 0.50 ppm. Carbofuran in fish tissue and in test water was extracted with n-hexane and acetonitril. GC-ECD was used to detect and quantitate carbofuran. The depuration rate of carbofuran from the whole body of goldfish is determined over the 24-h period after treatment. The obtained results were as follows: 1. It was possible to determine short term BCFs of carbofuran through relatively simple procedure in environmental concentrations. 2. $BCF_1$ of carbofuran in concentration of 0.05, 0.10 and 0.50 ppm were 1.66, 1.64 0.61, $BCF_3$ were 2.08, 2.14, 0.66 and $BCF_5$ were 2.21, 2.57, 0.86, respectively. 3. Carbofuran concentration in fish extract was increased as increasing test concentration and prolonging test period, but $BCF_s$ in concentration of 0.50 ppm was greately decreased. 4. Determined deputation rate constants of carbofuran in concentration of 0.05, 0.10, 0.50 ppm were 0.076, 0.082 and 0.089, respectively. 5. It is considered that great decrease of $BCF_s$ in concentration of 0.50 ppm is due to high water solubility and stability of carbofuran in testwater. 6. It is suggested that low BCF of carbofuran is due to its relatively high water solubility and depuration rate, compared to BPMC, carbaryl and chlorothalonil.

• The Korean Journal of Physiology and Pharmacology
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• v.16 no.3
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• pp.205-209
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• 2012

The objective of the present study was to establish the method of measurement of hydrogen peroxide and to estimate the anti-oxidative effect of genistein in the skin. UVB induced skin oxidation and anti-oxidative effect of genistein formulations were evaluated by determining levels of hydrogen peroxide. The mechanism involved in the determination of hydrogen peroxide is based on a color reaction between ferric ion ($Fe^{3+}$) and xylenol orange, often called FOX assay and subsequent monitoring of absorbance values of the reactant at 540 nm. The reaction was to some extent pH-dependent and detection sensitivity was greatest at pH 1.75. Genistein liposomal gel demonstrated better anti-oxidative effect with regard to lowering hydrogen peroxide levels elevated by UVB irradiation compared to genistein-suspended gel. A linear relationship has been observed between anti-oxidative effect of genistein and drug deposition in the skin tissue. Genistein liposomal gel resulting in the localization of the drug in the deeper skin led to improved anti-oxidative effect compared to genistein gel. The suggested method for evaluation of oxidation of the skin can be used as a tool to screen effective anti-oxidative agents and their delivery systems acting on the skin.

• Journal of The Korean Society of Agricultural Engineers
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• v.52 no.1
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• pp.1-11
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• 2010

Generation and transportation of runoff and pollutant loads within watershed generated eutrophication at Daecheong reservoir. To improve water quality at Daecheong reservoir, the best management practices should be developed and applied at upper watersheds for water quality improvement at downstream areas. In this study, two small watersheds of upper Daecheong reservoir were selected. The Long-Term Hydrologic Impact Assessment (L-THIA) model has been widely used for the estimation of the direct runoff worldwide. To apply the L-THIA ArcView GIS model was evaluated for direct runoff and water quality estimation at small watershed. And the Web-based Hydrograph Analysis Tool (WHAT) was used for direct runoff separating from total flow. As a result, the $R^2$ (Coefficient of determination) value and Nash-Sutcliffe coefficient value for direct runoff comparison at An-nae watershed were 0.81 and 0.71, respectively. And the $R^2$ value and Nash-Sutcliffe coefficient value at Wol-oe were 0.95 and 0.93. The $R^2$ value of BOD, TOC, T-N and T-P at An-nae watershed were BOD 0.94, TOC 0.81, T-N 0.94 and T-P 0.89. And the $R^2$ value of BOD, TOC, T-N and T-P at Wol-oe watershed were BOD 0.80, TOC 0.93, T-N 0.86 and T-P 0.65. The result that estimated pollutant loadings using the L-THIA ArcView GIS model reflected well the measured pollutant loadings except for T-P in Wol-oe watershed. With L-THIA ArcView GIS model, the direct runoff and non-point pollutant (NPS) loadings in the watershed could be analyzed through simple input data such as daily rainfall, land uses, and hydrologic soil group.

• Journal of The Korean Society of Agricultural Engineers
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• v.59 no.6
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• pp.9-18
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• 2017

The objective of this study was to estimate the climate change impact on inflow to Namgang Dam using SWAT (Soil and Water Assessment Tool) model. The SWAT model was calibrated and validated using observed flow data from 2003 to 2014 for the study watershed. The $R^2$ (Determination Coefficient), RMSE (Root Mean Square Error), NSE (Nash-Sutcliffe efficiency coefficient), and RMAE (Relative Mean Absolute Error) were used to evaluate the model performance. Calibration results showed that the annual mean inflow were within ${\pm}5%$ error compared to the observed. $R^2$ were ranged 0.61~0.87, RMSE were 1.37~7.00 mm/day, NSE were 0.47~0.83, and RMAE were 0.25~0.73 mm/day for daily runoff, respectively. Climate change scenarios were obtained from the HadGEM3-RA. The quantile mapping method was adopted to correct bias that is inherent in the climate change scenarios. Based on the climate change scenarios, calibrated SWAT model simulates the future inflow and evapotranspiration for the study watershed. The expected future inflow to Namgang dam using RCP 4.5 is increasing by 4.8 % and RCP 8.5 is increasing by 19.0 %, respectively. The expected future evapotranspiration for Namgang dam watershed using RCP 4.5 is decreasing by 6.7 % and RCP 8.5 is decreasing by 0.7 %, respectively.

• Proceedings of the Korean Magnetic Resonance Society Conference
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• 2002.08a
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• pp.70-71
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• 2002

Exchange-coupled cluster of transition-metal ions are relevant to many different scientific areas, ranging from chemistry to solid-state physics, biology, material science and has been the subject of much research in recent years(1,2). Single crystal EPR spectroscopy works as a very effective tool for the measurement of J values for small exchange interactions. This makes EPR technique very suitable for detection of weak exchange coupling transmitted over long distances via extended atomic and melecular bridges. Large polyoxometallates (3) may provide ideal structural environments for the study of interactions between paramagnetic ions. The detailed nature of magnetic interaction (positive sign and magnitude of J~0.006 $cm^{-1}$ /) was clearly determined for di-copper(II) system by single crystal EPR spectroscopy (4). The single-triplet (S-T) transitions are forbidden by different symmetries of the wave functions. However, when the singlet ground state is mixed into triplet states, the S-T transitions can be allowed and observed as weak lines. These weak S-T lines are positioned symmetrically with respect to the main transitions in the distance equals to 2J from the center of the spectrum. This lines allow one to determine the J-value with very high accuracy when │J│ ＜ hv 0.32 $cm^{-1}$ /. Unfortunately, the S-T transitions in the single crystal were detected by EPR method only in a few complexes until now. We have measured single-triplet transition lines for several magnetically coupled cluster systems and determined their J values accurately. The temperature dependency of J was studied by monitoring the changes in S-T.

• Nutrition Research and Practice
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• v.14 no.1
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• pp.70-75
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• 2020

BACKGROUND/OBJECTIVES: The aim of this study was to determine the relationship among emotional eating behavior, tendency to eat palatable foods, and several risk factors. SUBJECTS/METHODS: This study was carried out on 2,434 persons (1,736 women and 698 men) aged between 19 and 64 years. A questionnaire form was used as a data collection tool, which consisted of items for the socio-demographic characteristics, anthropometric measurements, Emotional Appetite Questionnaire (EMAQ), and the Palatable Eating Motives Scale (PEMS). RESULTS: A positive significant correlation was observed between the BMI groups and the negative emotions, negative situations, and negative total scores of EMAQ (P < 0.01). The regression results on negative subscales showed that a one unit increase in BMI resulted in a 0.293 unit increase in negative situations scores, a 0.626 unit increase in negative emotions scores, and a 0.919 unit increase in negative total EMAQ scores. When the BMI groups and PEMS subscale scores were examined, a significant relationship was found in the social motives, rewarding, and conformity subscales (P < 0.01). A one unit increase in BMI increased the coping motives scores by 0.077 units. CONCLUSION: The emotional states have a significant effect on the eating behavior. On the other hand, an increase in eating attacks was observed, particularly in people who were under the effect of a negative emotion or situation. Nevertheless, there were some limitations of the study in terms of quantitative determination of the effects of this eating behavior depending on the BMI.

• Journal of the Korean Association of Geographic Information Studies
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• v.12 no.4
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• pp.182-190
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• 2009

To solve the problems of traffic congestion, air pollution and energy derived from increased car consumption, people are in recognition of the importance of green mode, bicycle. Bicycle use rate in Busan is lower due to the terrain and limited public transportation accessibility. Therefore, geographical conditions and use activation should be initially considered in the bicycle route planning. We calculated a weight using AHP(Analytic Hierarchy Process), make a database using GIS tool and deduced the routes applying calculated weight in this study. The result of this study, We could get reliable data as inspecting consistency of the research. Routes are deducted in the place where using demand is higher than arbitrarily chosen routes. Therefore, the route planning through AHP is expected to be utilized in area-specialty-reflected route planning or bicycle road alternatives testing.

• Proceedings of the Korea Water Resources Association Conference
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• 2019.05a
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• pp.155-155
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• 2019

The Agricultural Policy/Environmental eXtender (APEX) models have been developed for assessing agricultural management efforts and their effects on soil and water at the field scale as well as more complex multi-subarea landscapes, whole farms, and watersheds. National Academy of Agricultural Sciences, Wanju, Korea, has modified a key component of APEX application, named APEX-Paddy for simulating water quality with considering appropriate paddy management practices, such as puddling and flood irrigation management. Calibration and validation are an anticipated step before any model application. Simple techniques are essential to assess whether or not a parameter should be adjusted for calibration. However, very few study has been done to evaluate the ability of APEX-Paddy to simulate the impact of multiple management scenarios on nutrients loss. In this study, the observation data from experimental fields at Iksan in South Kora was used in calibration and evaluation process during 2013-2015. The APEX auto- calibration tool (APEX-CUTE) was used for model calibration and sensitivity analysis. Four quantitative statistics, the coefficient of determination ($R^2$),Nash-Sutcliffe(NSE),percentbias(PBIAS)androotmeansquareerror(RMSE)were used in model evaluation. In this study, the hydrological process of the modified model, APEX-Paddy, is being calibrated and tested in predicting runoff discharge rate and nutrient yield. Field-scale calibration and validation processes are described with an emphasis on essential calibration parameters and direction regarding logical sequences of calibration steps. This study helps to understand the calibration and validation way is further provided for applications of APEX-Paddy at the field scales.

• Proceedings of the Korea Water Resources Association Conference
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• 2019.05a
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• pp.35-35
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• 2019

본 연구에서는 분포형 수문 모형 Drying Stream Assessment Tool and Water Flow Tracking (DrySAT-WTF)을 활용해 우리나라의 1976년부터 2015년까지의 유출량을 산정하고, 이를 다층퍼셉트론(Multi Layer Perceptron) 인경신경망 모형(Artificial Neural Network Model)에 적용해 미래 유출을 예측하였다. DrySAT-WFT은 전국 표준 유역을 대상으로 하천 건천화 원인 추적 및 평가를 위해 개발된 모형으로 유출모의를 위한 기상자료 외에 건천화 영향 요소를 고려하기 위한 산림 높이, 도로망, 지하수 이용량, 토지이용, 토심 변화에 대한 DB를 적용 가능한 것이 특징이다. DrySAT-WFT를 위한 기상자료로 모의 기간에 대한 일별 강우량, 상대습도, 평균풍속, 평균 및 최고, 최저 기온, 일조시간을 구축하였으며, 연대별 건천화 영향 요소 DB를 구축하여 적용하였다. 전국 다목적 댐 보 12지점의 유량을 활용해 모형의 보정(2005-2010) 및 검증(2011-2015)을 실시한 결과, 평균 결정계수(Coefficient of determination, $R^2$)는 0.76, 모형효율성계수(Nash-Sutcliffe efficiency, NSE)는 0.62, 평균제곱근오차(average root mean square error, RMSE)는 3.09로 신뢰성 있는 유출 모의 결과를 나타내었다. 미래 유출량 예측을 위한 MLP-ANN은 1976년부터 2015년까지의 유출 모의 결과를 Training Set으로 훈련하여 $R^2$가 0.5 이상이 되어 신뢰성을 확보하였고, 2016년부터 2018년까지의 기간을 1개월 단위로 실제 유출량과 예측 유출량을 비교하며 적용성을 검증 및 향상시켰다.

• Proceedings of the Korea Water Resources Association Conference
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• 2019.05a
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• pp.407-407
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• 2019

According to Asian Development Bank report Pakistan is among water scarce countries. Climate scenario on the basis IPCC fifth assessment report (AR5) revealed that annual mean temperature of Pakistan from year 2010-2019 was $17C^o$ which will rise up to $21C^o$ at the end of this century, similarly almost 10% decrease of annual rainfall is expected at the end of the century. It is a changing task in underdeveloped countries like Pakistan to meet the water demands of rapidly increasing population in a changing climate. While many studies have tackled scarcity and stream flow forecasting of the Upper Indus Basin (UIB) Pakistan, very few of them are related to socio-economic and climate change impact on sustainable water management of UIB. This study investigates the pattern of current and future surface water availability for various demand sites (e.g. domestic, agriculture and industrial) under different socio-economic and climate change scenarios in Upper Indus Basin (UIB) Pakistan for a period of 2010 to 2050. A state-of-the-art planning tool Water Evaluation and Planning (WEAP) is used to analyze the dynamics of current and future water demand. The stream flow data of five sub catchment (Astore, Gilgit, Hunza, Shigar and Shoyke) and entire UIB were calibrated and validated for the year of 2006 to 2011 using WEAP. The Nash Sutcliffe coefficient and coefficient of determination is achieved ranging from 0.63 to 0.92. The results indicate that unmet water demand is likely to increase severe threshold and the external driving forces e.g. socio-economic and climate change will create a gap between supply and demand of water.