• Title/Summary/Keyword: Derived Air Concentration

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A Derivation of Aerosol Optical Depth Estimates from Direct Normal Irradiance Measurements

  • Yun Gon Lee;Chang Ki Kim
    • New & Renewable Energy
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    • v.20 no.1
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    • pp.79-87
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    • 2024
  • This study introduces a method for estimating Aerosol Optical Depth (AOD) using Broadband Aerosol Optical Depth (BAOD) derived from direct normal irradiance and meteorological factors observed between 2016 and 2017. Through correlation analyses between BAOD and atmospheric components such as Rayleigh scattering, water vapor, and tropospheric nitrogen dioxide, significant relationships were identified, enabling accurate AOD estimation. The methodology demonstrated high correlation coefficients and low Root Mean Square Errors (RMSE) compared to actual AOD500 measurements, indicating that the attenuation effects of water vapor and the direct impact of tropospheric nitrogen dioxide concentration are crucial for precise aerosol optical depth estimation. The application of BAOD for estimating AOD500 across various time scales-hourly, daily, and monthly-showed the approach's robustness in understanding aerosol distributions and their optical properties, with a high coefficient of determination (0.96) for monthly average AOD500 estimates. This study simplifies the aerosol monitoring process and enhances the accuracy and reliability of AOD estimations, offering valuable insights into aerosol research and its implications for climate modeling and air quality assessment. The findings underscore the viability of using BAOD as a surrogate for direct AOD500 measurements, presenting a promising avenue for more accessible and accurate aerosol monitoring practices, crucial for improving our understanding of aerosol dynamics and their environmental impacts.

Experimental Evaluation of an Analytical Method for Chlorofluorocarbons (CFSs) in Air and Water Using Gas Chromatography (가스 크로마토그래피를 이용한 대기와 물시료의 CFCs(chlorofluorocarbons) 분석법의 실험적 평가)

  • Koh, Dong-Chan;Choi, Beom-Kyu;Kim, Yong-Je
    • Economic and Environmental Geology
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    • v.40 no.1 s.182
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    • pp.129-140
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    • 2007
  • CFC(CFC-12, CFC-11 and CFC-113) analytical system for air and water was constructed using a customized purge and trap extraction device and a gas chromatograph with an electron capture detector. Sampling methods of air and water for CFCs were also established. The analytical system was experimentally optimized to result in reproducibilities of triplicates less than 2% for current air samples and less than 5% for groundwater samples with CFC-12 concentration of 160 to 180 pg/kg, and verified with respect to the CFC system in USGS, which showed analytical results were in agreement within 10%. CFCs in air were monitored at three sites over 19-month period in the central part of South Korea, and the result indicates no significant local sources of CFCs in those areas. For groundwater in Jeju Island, CFCs were measured over a year with a two-month interval. The time-series data showed seasonal fluctuations which could be interpreted by the effect of recharge pulse derived from large amount of rainfall during monsoon period with a few month delay, which indicates high permeability of basaltic rocks in Jeju Island.

Photocatalysis of Low Concentration of Gaseous-Phase Benzene Using Visible-Light Irradiated N-doped and S-doped Titanium Dioxide

  • Jo, Wan-Kuen;Kim, Jong-Tae
    • Environmental Engineering Research
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    • v.13 no.4
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    • pp.171-176
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    • 2008
  • Studies on visible-light-driven photocatalysis of air pollutants at indoor air quality (IAQ) levels have been limited. Current study investigated visible-light derived photocatalysis with N-doped and S-doped titanium dioxide ($TiO_2$) for the control of benzene at indoor levels. Two preparation processes were employed for each of the two types of photocatalyst: urea-Degussa P-25 $TiO_2$ and titania-colloid methods for the N-doped $TiO_2$; and titanium isopropoxid- and tetraisopropoxide-thiourea methods for the S-doped $TiO_2$. Furthermore, two coating methods (EDTA- and acetylacetone-dissolving methods) were tested for both the N-doped and S-doped $TiO_2$. The two coating methods exhibited different photocatalytic degradation efficiency for the N-doped photocatalysts, whereas they did not exhibit any difference for the S-doped photocatalysts. In addition, the two doping processes showed different photocatalytic degradation efficiency for both the S-doped and N-doped photocatalysts. For both the N-doped and S-doped $TiO_2$, the photocatalytic oxidation (PCO) efficiency increased as the hydraulic diameter (HD) decreased. The degradation efficiency determined via a PCO system with visible-light induced $TiO_2$ was lower than that with UV-light induced unmodified $TiO_2$, which was obtained from previous studies. Nevertheless, it is noteworthy that for the photocatalytic annular reactor with the HD of 0.5 cm, PCO efficiency increased up to 52% for the N-doped $TiO_2$ and 60% for the S-doped $TiO_2$. Consequently, when combined with the advantage of visible light use over UV light use, it is suggested that with appropriate HD conditions, the visible-light-assisted photocatalytic systems can also become an important tool for improving IAQ.

Energy and Air Quality Benefits of DCV with Wireless Sensor Network in Underground Parking Lots

  • Cho, Hong-Jae;Jeong, Jae-Weon
    • International Journal of High-Rise Buildings
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    • v.3 no.2
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    • pp.155-165
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    • 2014
  • This study measured and compared the variation of ventilation rate and fan energy consumption according to various control strategies after installing wireless sensor-based pilot ventilation system in order to verify the applicability of demand-controlled ventilation (DCV) strategy that was efficient ventilation control strategy for underground parking lot. The underground parking lot pilot ventilation system controlled the ventilation rate by directly or indirectly tracking the traffic load in real-time after sensing data, using vehicle detection sensors and carbon monoxide (CO) and carbon dioxide ($CO_2$) sensor. The ventilation system has operated for 9 hours per a day. It responded real-time data every 10 minutes, providing ventilation rate in conformance with the input traffic load or contaminant level at that time. A ventilation rate of pilot ventilation system can be controlled at 8 levels. The reason is that a ventilation unit consists of 8 high-speed nozzle jet fans. This study proposed vehicle detection sensor based demand-controlled ventilation (VDS-DCV) strategy that would accurately trace direct traffic load and CO sensor based demand-controlled ventilation (CO-DCV) strategy that would indirectly estimate traffic load through the concentration of contaminants. In order to apply DCV strategy based on real-time traffic load, the minimum required ventilation rate per a single vehicle was applied. It was derived through the design ventilation rate and total parking capacity in the underground parking lot. This is because current ventilation standard established per unit floor area or unit volume of the space made it difficult to apply DCV strategy according to the real-time variation of traffic load. According to the results in this study, two DCV strategies in the underground parking lot are considered to be a good alternative approach that satisfies both energy saving and healthy indoor environment in comparison with the conventional control strategies.

Desirable pH of Slurry in the Desulfurization Absorber for a 200 MW Anthracite Power Plant (200 MW급 무연탄 발전용 탈황 흡수탑에서 적정 슬러리pH)

  • Choi, Hyun-Ho;Yoo, Hoseon
    • Plant Journal
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    • v.16 no.1
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    • pp.38-43
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    • 2020
  • In this study, Seochon Thermal Power Plant No.1 for anthracite coal was tested to find the proper operation range of limestone slurry pH in the absorber tower which can be operated continuously in compliance with the Air Quality Preservation Act and Seocheon Thermal Power Division's internal regulation, sulfur dioxide average emission regulation. When operating the sulfur dioxide concentration [ppm] in the combustion gas flowing into the desulfurization absorption tower at 370, 400, 460 and 550 ppm while the main operating elements such as the flow rate of the combustion gas were fixed, the proper slurry pH Were 4.4, 4.5, 4.8 and 5.1, respectively. Therefore, it is recommended to operate with the correlation equation, RpH=0.004×Cin+2.93 derived using sulfur dioxide and the appropriate slurry pH.

The Aerosol Characteristics in Coexistence of Asian Dust and Haze during 15~17 March, 2009 in Seoul (짙은 황사와 연무가 공존한 대기의 에어러솔 특성 - 2009년 3월 15~17일 -)

  • Lee, Hae-Young;Kim, Seung-Bum;Kim, Su-Min;Song, Seung-Joo;Chun, Young-Sin
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.2
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    • pp.168-180
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    • 2011
  • The variation of the physicochemical properties of atmospheric aerosols in coexistence of the heavy Asian Dust and Haze observed from $15^{th}$ to $17^{th}$ March 2009 in Seoul was scrutinized through the mass and ion concentration observations and synoptic weather analysis. Although the ratio of PM1.0/PM10 was constant at 0.3 (which is typical during Asian Dust period in Korea) during the measurement period, both PM10 and PM1.0 mass concentrations were 3~6 times and 2~4 times higher than that of clear days, respectively. Water-soluble ion components accounted for 30~50% of PM10 and 50~70% of PM1.0 mass concentration. One of the secondary pollutants, $NO_3^-$ was found to be associated with $Ca^{2+}$ and $Na^+$ in coarse mode indicating that the aerosol derived from natural source was affected by anthropogenic pollutants. While the acidity of the aerosols increased in fine mode when the stagnation of weather patterns was the strongest (March $16^{th}$), the alkalinity increased in coarse mode when new air masses arrived with a southwestern wind after ending a period of stagnation (March $17^{th}$). In the selected case, SOR (Sulfur Oxidation Ratio, $nSO_4^{2-}/[nSO_4^{2-}+nSO_2]$) and NOR (Nitrogen Oxidation Ratio, $nNO_3^-/[nNO_3^-+nNO_2]$) values of ion components were higher than the general values during Asian Dust period. These results imply that dust aerosols could be mixed with pollutants transported from China even in heavy Asian Dust cases in Korea.

Application of Ventilation Corridor to Mitigate Particulate Matter for the Sejong-Si (미세먼지 저감대책으로서 바람길 적용 방안 : 세종시를 대상으로)

  • Nam, Seongwoo;Sung, Sunyong;Park, Jong-Soon
    • The Journal of the Korea Contents Association
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    • v.20 no.3
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    • pp.1-9
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    • 2020
  • The purpose of this study is to verify the effects of ventilation corridor and derive adequate policy alternatives to its application for the city of Sejong, which is located in an inland of Korean Peninsula. In order to introduce the ventilation corridor in the city, it is necessary both to understand change on fresh air flow affected by the construction of new cities and to show its effects which are able to circulate air flow of the city. The study identified ventilation effects using computational fluid dynamics models. In particular, it analyzed change on wind speed and direction after constructing of a new town and cool air flow along the lowlands generated after sunset. In addition, it identified those of reducing particulate matter when arranging buildings conforming to the ventilation corridor at block level. The policy implications derived from simulation can be summarized as follows. First, it is desirable to plan ventilation corridors so that fresh air from mountains, forests, and valleys can flow into cities and mitigate the concentration of particulate matter. Furthermore, public facilities covering parks, plazas, and playgrounds should be installed preferentially to attract safe outdoor activities near to areas with low levels of particulate matter. Finally, it is adequate to prepare for a number of alternative plans by analyzing ventilation corridors when setting out district unit plan.

Optimization study on roof break direction of gob-side entry retaining by roof break and filling in thick-layer soft rock layer

  • Yang, Dang-Wei;Ma, Zhan-Guo;Qi, Fu-Zhou;Gong, Peng;Liu, Dao-Ping;Zhao, Guo-Zhen;Zhang, Ray Ruichong
    • Geomechanics and Engineering
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    • v.13 no.2
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    • pp.195-215
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    • 2017
  • This paper proposes gob-side entry retaining by roof break and filling in thick-layer soft rock conditions based on the thick-layer soft rock roof strata migration law and the demand for non-pillar gob-side entry retaining projects. The functional expressions of main roof subsidence are derived for three break roof direction conditions: lateral deflection toward the roadway, lateral deflection toward the gob and vertically to the roof. These are derived according to the load-bearing boundary conditions of the main roadway roof stratum. It is concluded that the break roof angle is an important factor influencing the stability of gob-side entry retaining surrounding rock. This paper studies the stress distribution characteristics and plastic damage scope of gob-side entry retaining integrated coal seams, as well as the roof strata migration law and the supporting stability of caving structure filled on the break roof layer at the break roof angles of $-5^{\circ}$, $0^{\circ}$, $5^{\circ}$, $10^{\circ}$ and $15^{\circ}$ are studied. The simulation results of numerical analysis indicate that, the stress concentration and plastic damage scope to the sides of gob-side entry retaining integrated coal at the break roof angle of $5^{\circ}$ are reduced and shearing stress concentration of the caving filling body has been eliminated. The disturbance of coal mining to the roadway roof and loss of carrying capacity are mitigated. Field tests have been carried out on air-return roadway 5203 with the break roof angle of $5^{\circ}$. The monitoring indicates that the break roof filling section and compaction section are located at 0-45 m and 45-75 m behind the working face, respectively. The section from 75-100 m tends to be stable.

Health and Economic Burden Attributable to Particulate Matter in South Korea: Considering Spatial Variation in Relative Risk (지역간 상대위험도 변동을 고려한 미세먼지 기인 질병부담 및 사회경제적 비용 추정 연구)

  • Byun, Garam;Choi, Yongsoo;Gil, Junsu;Cha, Junil;Lee, Meehye;Lee, Jong-Tae
    • Journal of Environmental Health Sciences
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    • v.47 no.5
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    • pp.486-495
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    • 2021
  • Background: Particulate matter (PM) is one of the leading causes of premature death worldwide. Previous studies in South Korea have applied a relative risk calculated from Western populations when estimating the disease burden attributable to PM. However, the relative risk of PM on health outcomes may not be the same across different countries or regions. Objectives: This study aimed to estimate the premature deaths and socioeconomic costs attributable to long-term exposure to PM in South Korea. We considered not only the difference in PM concentration between regions, but also the difference in relative risk. Methods: National monitoring data of PM concentrations was obtained, and missing values were imputed using the AERMOD model and linear regression model. As a surrogate for relative risk, hazard ratios (HRs) of PM for cardiovascular and respiratory mortality were estimated using the National Health Insurance Service-National Sample Cohort. The nation was divided into five areas (metropolitan, central, southern, south-eastern, and Gangwon-do Province regions). The number of PM attributable deaths in 2018 was calculated at the district level. The socioeconomic cost was derived by multiplying the number of deaths and the statistical value of life. Results: The average PM10 concentration for 2014~2018 was 45.2 ㎍/m3. The association between long-term exposure to PM10 and mortality was heterogeneous between areas. When applying area-specific HRs, 23,811 premature deaths from cardiovascular and respiratory disease in 2018 were attributable to PM10 (reference level 20 ㎍/m3). The corresponding socioeconomic cost was about 31 trillion won. These estimated values were higher than that when applying nationwide HRs. Conclusions: This study is the first research to estimate the premature mortality caused by long-term exposure to PM using relative risks derived from the national population. This study will help precisely identify the national and regional health burden attributed to PM and establish the priorities of air quality policy.

Comparison of Atmospheric Carbon Dioxide Concentration Trend and Accuracy from GOSAT and AIRS data over the Korean Peninsula (한반도 지역에서의 이산화탄소 변화 경향과 AIRS, GOSAT 위성 자료의 정확도 비교)

  • Lee, Sanghee;Kim, Jhoon;Cho, Hi-Ku;Goo, Tae-Young;Ou, Mi-Lim;Lee, Jong-Ho;Yokota, Tatsuya
    • Korean Journal of Remote Sensing
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    • v.31 no.6
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    • pp.549-560
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    • 2015
  • With the global scale impact of atmospheric $CO_2$ in global warming and climate system, it is necessary to monitor the $CO_2$ concentration continuously on a global scale, where satellite remote sensing has played a significant role recently. In this study, global monthly $CO_2$ concentrations obtained by satellite remote sensing were compared with ground-based measurements at Anmyeon-do and Gosan Korean Global Atmosphere Watch Center. Atmospheric $CO_2$ concentration has increased from 371.87 ppm in January 1999 to 405.50 ppm in December 2013 at Anmyeon-do station (KMA, 2013). Comparison of the continuous measurements by flask air sampling at Anmyeon-do shows the same trend and seasonal variations with those of global monthly mean dataset. Nevertheless, the trends of $CO_2$ over Northeast Asia showed the higher than those of global and the trends also changes with different slope. $CO_2$ products derived from Greenhouse Gases Observing Satellite (GOSAT) and Atmospheric Infrared Sounder (AIRS) were compared with ground-based measurement at Anmyeon-do. The monthly mean values of GOSAT and AIRS data are systemically lower than those obtained at Anmyeon-do, however, the seasonal cycle of satellite products present the similar trend with values of global and Anmyeon-do. The accuracy of $CO_2$ products from GOSAT and AIRS were evaluated statistically for two years from January 2011 to December 2012. GOSAT showed good correlation with the correlation coefficient, RMSD and bias of 0.947, 5.610 and -5.280 to ground-based measurements respectively, while AIRS showed reasonable comparison with 0.737, 8.574 and -7.316 at Anmyeon-do station, respectively.