• 제목/요약/키워드: Der-f

검색결과 234건 처리시간 0.021초

질소와 진공 분위기에서 에이징 영향에 따른 불화유기박막의 나노트라이볼러지 특성 평가 (Nanotribological Characterization of Annealed Fluorocarbon Thin Film in N2 and Vacuum)

  • 김태곤;김남균;박진구;신형재
    • 한국마이크로전자및패키징학회:학술대회논문집
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    • 한국마이크로전자및패키징학회 2002년도 춘계 기술심포지움 논문집
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    • pp.193-197
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    • 2002
  • The tribological properties and van der Waals attractive forces and the thermal stability of films are very important characteristics of highly hydrophobic fluorocarbon (FC) films for the long-term reliability of nano system. The effect of thermal annealing on films and van der Waals attractive forces and friction coefficient of films have been investigate d in this study. It was coated Al wafer which was treated O2 and Ar that ocatfluorocyclobutane ($C_4_{8}$) and Ar were supplied to the CVD chamber in the ratio of 2:3 for deposition of FC Films. Static contact angle and dynamic contact angle were used to characterize FC films. Thickness of films was measured by variable angle spectroscopy ellipsometer (VASE). Nanotribological data was got by atomic force microscopy (AFM) to measure roughness, lateral force microscopy (LFM) to measure friction force, and force vs. distance (FD) curve to evaluate adhesion force. FC films were cured in N2 and vacuum. The film showed the slight changes in its properties after 3 hr annealing. FTIR ATR studies showed the decrease of C-F peak intensity in the spectra as the annealing time increased. A significant decrease of film thickness has been observed. The friction force of Al surface was at least thirty times higher than ones with FC films. The adhesive force of bare Al was greater than 100 nN. After deposit FC films adhesive force was decreased to 40 nN. The adhesive force of films was decreased down to 10 nN after 24 hr annealing. During 24 hr annealing in $N_2$and vacuum at $100^{\circ}C$ film properties were not changed so much.

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콜레스테릴 펜타노에이트의 결정 및 분자구조 (The Crystal and Molecular Structure of Cholesteryl Pentanoate)

  • 안중태;박영자
    • 대한화학회지
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    • 제34권1호
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    • pp.1-9
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    • 1990
  • 콜레스테릴 펜타노에이트의 결정은 사방정계에 속하며 a = 21.930(3), b = 21.404(3), c = 6.419(5) $\AA$이며 단위세포안에 4개의 분자가 있다. 1.0 $\sigma$ (I)보다 큰 강도를 가진 1,520개의 회절 반점에 대한 최종 R값은 0.086이다. 직접법에 의하여 구조를 풀었으며 C-H 결합길이와 메틸기는 길이를 고정시켜 이상적인 기하학적 구조에 맞춰 cascade diagonal least-squares refinement에 의하여 정밀화하였다. 테트라시클로 고리는 정상적인 구조를 하고 있으나 에스텔과 곁사슬 부분은 열적효과에 의하여 정상적인 길이와 각도의 값에서 변화를 보이고 있으며 에스텔의 끝부분이 굽어져 치켜들고 있다. 분자는 비결합성 van der waals힘에 의하여 서로 쌓여져 있고 가장 짧은 분자간 거리는 3.529 $\AA$이다.

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The Crystal and Molecular Structure of Bromhexine$\cdot$HCl

  • Koo, Hung-Hoe;Jung, Yong-Je;Lee, Soon-Won
    • Archives of Pharmacal Research
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    • 제7권2호
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    • pp.115-120
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    • 1984
  • The crystals of bromhexine-HCl, $C_{14}$ H$_{21}$ N$_{2}$Br$_{2}$Cl, are orthohombic, space group Pca2 with a = 14.598(2)A, b=12.461(3)A, c =9 9.186(1) A and Z = 4. Intensity dat for 967 reflections (Fobs > 6.sigma.(F)) were collected on a Rigaku-Denki automatic four circle diffractometer. The structure was solved by the Patterson and Fourier methods. Refinements were carried out to the final R value of 0.082. The cyclohexane ring has a normal chair form and the benzene ring is planar. There are three independenet hydrogen bounds in the structure. One is an intermolecular hydrogen bond (N-H... Cl) and the others are intramolecular hydrogen bonds (N-H...Br, N$^{+}$-H...Cl$^{[-10]}$ ) Apart from the hydrogen bounding system the molecules are held together in the crystal by van der Waals force.e.

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캐티온화제 처리한 면섬유에 대한 반응성 염료의 염색성 (A Study on Dyeing Properties of Cafionicagent Treated Cotton Fibre with Reactive Dye)

  • Jung, Young Jin;Lee, Young Hee;Kim, Kyung Hwan
    • 한국염색가공학회지
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    • 제6권4호
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    • pp.46-53
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    • 1994
  • Polymer cationic agent was prepared by the initial polymerisation of epichlorohydrin followed by amination with diethylamine. Cotton fibre treated with the polymer (6~8% o.w.f.) is highly cationic and exhibit increased substantivity for reactive dyes under neutral to weakly acid conditions. The modified substrate could be dyed with reactive dyes without salt or a little salt from dye bath. The increased concentration of cationic agents resulted in an increase the colour yield. Futhermore, treated cotton has an electropositive surface charge. Adsorption of Reactive dye can be attributed to both van der waals force and electrostatic attraction.

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KOMPSAT European Cooperation

  • Schiller C.;Triebnig G.;Kim Y.;Ahn S.;Moll B.;Kamp A. van der;Maass H.;Schwarz J.;Kressler F.
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2004년도 Proceedings of ISRS 2004
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    • pp.154-157
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    • 2004
  • The KOMPSAT European Cooperation aims at enhancing existing and establishing new collaborations between KARI and various European institutions. The objective is to create mutual data and information exchange possibilities and to develop new data applications of available and future space based Earth Observation sensors. In this paper, the concept of a KOMPSAT regional application center, a joint development between KARI, ARCS and other European partners is presented. This includes the establishment of an additional KOMPSAT-2 downlink in Europe, and the developments of a state-of-the-art user service system for urban and environmental security monitoring.

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Numerical analysis of a new SMA-based seismic damper system and material characterization of two commercial NiTi-alloys

  • Olsen, J.S.;Van der Eijk, C.;Zhang, Z.L.
    • Smart Structures and Systems
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    • 제4권2호
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    • pp.137-152
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    • 2008
  • The work presented in this paper includes material characterisation and an investigation of suitability in seismic dampers for two commercially available NiTi-alloys, along with a numerical analysis of a new damper system employing composite NiTi-wires. Numerical simulations of the new damper system are conducted, using Brinson's one-dimensional constitutive model for shape memory alloys, with emphasis on the system's energy dissipation capabilities. The two alloys tested showed some unwanted residual strain at temperatures higher than $A_f$, possibly due to stress concentrations near inclusions in the material. These findings show that the alloys are not ideal, but may be employed in a seismic damper if precautions are made. The numerical investigations indicate that using composite NiTi-wires in a seismic damper enhances the energy dissipation capabilities for a wider working temperature range.

Magnetic Fields of the Youngest Protostellar System L1448 IRS 2 revealed by ALMA

  • 권우진;;;;;;김종수
    • 천문학회보
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    • 제43권1호
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    • pp.44.3-45
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    • 2018
  • Magnetic fields affect star formation in a broad range of scales from parsec to hundreds au. In particular, interferometric observations and ideal magneto-hydrodynamic (MHD) simulations have reported that formation of a rotation-supported disk at the earliest young stellar objects (YSOs) is largely suppressed by magnetic fields aligned to the rotational axis of YSOs: magnetic braking. Our recent ALMA observations toward L1448 IRS 2, which has a rotation detected and its magnetic fields aligned to the rotation axis (poloidal fields) in ~500 au scales, show that the fields switch to toroidal at the center in ~100 au scales. This result suggests that magnetic braking may not be so catastrophic for early disk formation even in YSOs with magnetic fields aligned to the rotational axis.

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캐티온화제 처리한 면섬유의 집접 염료의 염색성 (A Study on Dyeing Properties of Cationic Agent Treated Cotton Fibre with Direct Dye)

  • Jung, Young Jin;Lee, Young Hee;Lee, Myoung Hane;Lee, Eon Pil
    • 한국염색가공학회지
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    • 제7권2호
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    • pp.1-8
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    • 1995
  • Polymer cationic agent was prepared by the initial polymerization of epichlorohydrin followed by amination with diethyl-amine. Cotton fibre treated with the polymer (6∼8% o.w.f.) is highly cationic and exhibit increased substantivity for anionic dyes. The modified substrate could be dyed with direct dyes without salt or a little salt from dye bath. The increased concentration of cationic agents resulted in an increase the colour yield. Futhermore, treated cotton has an electropositive surface charge. Adsorption of direct dye can be attributed to both van der waals force and electrostatic attraction.

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투명 ZnO를 활성 채널층으로 하는 박막 트랜지스터 (Thin Film Transistor with Transparent ZnO as active channel layer)

  • 신백균
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제55권1호
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    • pp.26-29
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    • 2006
  • Transparent ZnO thin films were prepared by KrF pulsed laser deposition (PLD) technique and applied to a bottom-gate type thin film transistor device as an active channel layer. A high conductive crystalline Si substrate was used as an metal-like bottom gate and SiN insulating layer was then deposited by LPCVD(low pressure chemical vapour deposition). An aluminum layer was then vacuum evaporated and patterned to form a source/drain metal contact. Oxygen partial pressure and substrate temperature were varied during the ZnO PLD deposition process and their influence on the thin film properties were investigated by X-ray diffraction(XRD) and Hall-van der Pauw method. Optical transparency of the ZnO thin film was analyzed by UV-visible phometer. The resulting ZnO-TFT devices showed an on-off ration of $10^6$ and field effect mobility of 2.4-6.1 $cm^2/V{\cdot}s$.

Exploring Study Designs for Evaluation of Interventions Aimed to Reduce Occupational Diseases and Injuries

  • van der Molen, Henk F.;Stocks, Susan J.;Frings-Dresen, Monique H.W.
    • Safety and Health at Work
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    • 제7권1호
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    • pp.83-85
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    • 2016
  • Effective interventions to reduce work-related exposures are available for many types of work-related diseases or injuries. However, knowledge of the impact of these interventions on injury or disease outcomes is scarce due to practical and methodological reasons. Study designs are considered for the evaluation of occupational health interventions on occupational disease or injury. Latency and frequency of occurrence of the health outcomes are two important features when designing an evaluation study with occupational disease or occupational injury as an outcome measure. Controlled evaluation studies-giving strong indications for an intervention effect-seem more suitable for more frequently occurring injuries or diseases. Uncontrolled evaluation time or case series studies are an option for evaluating less frequently occurring injuries or diseases. Interrupted time series offer alternatives to experimental randomized controlled trials to give an insight into the effectiveness of preventive actions in the work setting to decision and policy makers.