• 제목/요약/키워드: Deposition flux

검색결과 248건 처리시간 0.028초

광촉매 반응과 침지형 정밀여과를 이용한 자연산 유기물의 제거 (Use of a Combined Photocatalysis/Microfiltration System for Natural Organic Matter Removal)

  • 추광호;박경원;김문현
    • 멤브레인
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    • 제14권2호
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    • pp.149-156
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    • 2004
  • 본 연구에서는 광촉매 반응과 막분리 기술을 접목시킨 혼성 고도 정수처리 공정에서 소독 부산물의 전구체로 알려진 자연산 유기물을 효과적으로 제거하고자 하였고 다양한 운전 조건에서 시스템의 성능을 비교 평가하였다. 자연산 유기물은 흡입여과 방식의 분리막과 TiO$_2$ 광촉매를 이용하여 광분해하였을 때 광촉매 투입량의 증가에 따라 반응속도가 증가하였지만 과량의 촉매 주입시에는 반응 속도 향상에 오히려 부정적으로 작용하였다. 자연산 유기물을 보다 효과적으로 제거하기 위해 산화철 주입, TiO$_2$ 표면처리, 분리막 표면코팅을 시도하여 제거특성 및 운전에 따른 막여과 특성을 평가하였다. 산화철 주입은 초기에 흡착작용으로 인해 제거율 증가를 보였으나 반응이 진행됨에 따라 산화철 입자에 의한 광산란으로 광분해 효율이 오히려 감소되었다. 산화철 입자에 의한 광산란을 제어하고자 TiO$_2$ 표면을 광처리와 열처리 방법을 이용해 철을 직접 부착시킨 경우 긍정적인 효과를 얻지 못했다. 그러나 산화철로 막표면을 코팅하여 광산란 효과를 배제시킨 경우에는 향상된 결과를 보였다 막투과 플럭스 15 L/$m^2$-h에서 정밀여과를 수행하였을 때 TiO$_2$나 산화철에 의한 막오염은 거의 일어나지 않았고 안정된 막투과도를 나타내었다.

3차원 위빙 대용착 지능 용접캐리지 개발 및 적용 (The Development and Application of Intelligent Welding Carriage with High Deposition Rate by 3-D Weaving)

  • 김영주;조방현;아미트;이상범;이원구;김진용;허만주
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2010년도 춘계학술발표대회 초록집
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    • pp.65-65
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    • 2010
  • In shipbuilding industry, welding position are usually flat and vertical position at the erection stage. Application of SAW and EGW for these positions makes it possible to achieve enhanced productivity and high quality. But owing to their large size and weight it is difficult to apply these techniques in short and narrow regions. To overcome this problem, our company developed light weight and compact size 4-axis welding carriage which perform 3D weaving. The purpose of this study is to explain the development and application of intelligent welding carriage using 3D weaving pattern that can fill a large amount of welds and thereby making it possible to achieve high quality of welding. This study shows 3D weaving pattern, development of weaving database, and skill of adaptive control response for the variable gap. Also, it shows the results of procedure qualification test for the AH-grade steel when applied to the intelligent welding carriage.

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Development Treatment Planning System Based on Monte-Carlo Simulation for Boron Neutron Capture Therapy

  • Kim, Moo-Sub;Kubo, Kazuki;Monzen, Hajime;Yoon, Do-Kun;Shin, Han-Back;Kim, Sunmi;Suh, Tae Suk
    • 한국의학물리학회지:의학물리
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    • 제27권4호
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    • pp.232-235
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    • 2016
  • The purpose of this study is to develop the treatment planning system (TPS) based on Monte-Carlo simulation for BNCT. In this paper, we will propose a method for dose estimation by Monte-Carlo simulation using the CT image, and will evaluate the accuracy of dose estimation of this TPS. The complicated geometry like a human body allows defining using the lattice function in MCNPX. The results of simulation such as flux or energy deposition averaged over a cell, can be obtained using the features of the tally provided by MCNPX. To assess the dose distribution and therapeutic effect, dose distribution was displayed on the CT image, and dose volume histogram (DVH) was employed in our developed system. The therapeutic effect can be efficiently evaluated by these evaluation tool. Our developed TPS could be effectively performed creating the voxel model from CT image, the estimation of each dose component, and evaluation of the BNCT plan.

개질된 표면을 이용한 풀비등 임계열유속 증진에 관련한 실험적 연구 (Experimental Investigation of CHF Enhancement on the Modified Surface Under Pool Boiling)

  • 강순호;안호선;조항진;김무환;김형모;김준원
    • 대한기계학회논문집B
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    • 제33권11호
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    • pp.840-848
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    • 2009
  • In the boiling heat transfer mechanism, CHF(critical heat flux) is the significantly important parameter of the system. So, many researchers have been struggling to enhance the CHF of the system in enormous methods. Recently, there were lots of researches about enormous CHF enhancement with the nanofluids. In that, the pool boiling CHF in nanofluids has the significantly increased value compared to that in pure water because of the deposition of the nanoparticle on the heater surface in the nanofluids. The aim of this study is the comparison of the effect of the nanoparticle deposited surface and the modified surface which has the similar morphology and made by MEMS fabrication. The nanoparticle deposited surface has the complex structures in nano-micro scale. Therefore, we fabricated the surfaces which has the similar wettability and coated with the micro size post and nano structure. The experiment is performed in 3 cases : the bare surface with 0.002% water-ZnO nanofluids, the nanoparticle deposited surface with pure water and the new fabricated surface with pure water. The contact angle, a representative parameter of the wettability, of the all 3 cases has the similar value about 0 and the SEM(scanning electron microscope) images of the surfaces show the complex nano-micro structure. From the pool boiling experiment of the each case, the nanoparticle deposited surface with pure water and the fabricated surface with pure water has the almost same CHF value. In other words, the CHF enhancement of the nanoparticle deposited surface is the surface effect. It also shows that the new fabricated surface follows the nanoparticle deposited surface well.

팔라듐 합금 수소 분리막의 전처리에 관한 연구 (A Study on the Surface Pre-treatment of Palladium Alloy Hydrogen Membrane)

  • 박동건;김형주;김효진;김동원
    • 한국표면공학회지
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    • 제45권6호
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    • pp.248-256
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    • 2012
  • A Pd-based hydrogen membranes for hydrogen purification and separation need high hydrogen perm-selectivity. The surface roughness of the support is important to coat the pinholes free and thin-film membrane over it. Also, The pinholes drastically decreased the hydrogen perm-selectivity of the Pd-based composite membrane. In order to remove the pinholes, we introduced various surface pre-treatment such as alumina powder packing, nickel electro-plating and micro-polishing pre-treatment. Especially, the micro-polishing pretreatment was very effective in roughness leveling off the surface of the porous nickel support, and it almost completely plugged the pores. Fine Ni particles filled surface pinholes with could form open structure at the interface of Pd alloy coating and Ni support by their diffusion to the membrane and resintering. In this study, a $4{\mu}m$ surface pore-free Pd-Cu-Ni ternary alloy membrane on a porous nickel substrate was successfully prepared by micro-polishing, high temperature sputtering and Cu-reflow process. And $H_2$ permeation and $N_2$ leak tests showed that the Pd-Cu-Ni ternary alloy hydrogen membrane achieved both high permeability of $13.2ml{\cdot}cm^{-2}{\cdot}min^{-1}{\cdot}atm^{-1}$ permation flux and infinite selectivity.

마산만의 Tributyltin 거동 및 물질수지 산정 (Estimation of Transport and Mass balance of Tributyltin in Masan Bay)

  • 김동명
    • 한국해양환경ㆍ에너지학회지
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    • 제5권4호
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    • pp.48-56
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    • 2002
  • 마산만에 대하여 stella 프로그램을 이용한 Tributyltin모델을 구축하였으며, 민감도 분석 및 물질수지를 산정하여 수질관리의 기초자료로 제공하였다. 민감도 분석결과 수층과 유기 입자내 Tributyltin의 경우는 침강속도와 분배계수에 가장 큰 영향을 받는 것으로 나타났으며, 식물플랑크톤 체내의 Tributyltin의 경우는 식물플랑크톤의 생물농축계수가 가장 큰 영향을 미치는 인자로 나타났다. 따라서 추후의 Tributyltin에 대한 모델 적용 시에는 이들 계수에 대한 정밀한 고찰이 필요할 것으로 사료된다. 대상해역의 Tributyltin 현존량은 수층의 Tributyltin량이 3.29×10⁴g, 플랑크톤 체내의 Tributyltin량이 1.16×10²g, 입자상 유기물내의 Tributyltin량이 3.17×10³g로 나타났다 상간의 전환경로는 입자상 유기물로 분배되는 경로가 1.64×10³g/day로 가장 크게 나타났으며, 다음이 저질로의 침전으로 1.52×10³/g/4ay이었으며 외해로의 유출이 1.32×10³g/4ay로 나타났다.

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The use of HRSEM to characterize new and aged membranes in drinking water production

  • Wyart, Y.;Nitsche, S.;Chaudanson, D.;Glucina, K.;Moulin, P.
    • Membrane and Water Treatment
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    • 제2권4호
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    • pp.251-266
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    • 2011
  • This work deals with the use of High Resolution Scanning Electron Microscopy (HRSEM) to verify ultrafiltration membrane selectivity at the end of the production line as well as membrane ageing. The first part of this work is focused on new membranes. It is shown that it is better to use sputtering metallization than vacuum deposition, as this latter technique entails thermal damage to the skin layer. Moreover, the impact of the metallization layer on the determination of the membrane pore size is studied and it is observed that no impact of the metallization step can be clearly defined for a metallization layer ranging from 3 to 12 nm. For example, an average pore size of 16.9 nm and a recovery rate of 6.5 % are observed for a 150 kDa cellulose acetate membrane. These results are in agreement with those given by the manufacturer: pore size ranging from 10 to 15 nm and recovery rate ranging from 5 to 10 %. The second part of this work focuses on the study of membrane ageing. A PVDF hollow fibre membrane is studied. It is shown that a 65 % decrease in the permeate flux can be linked to a decrease in the number of pores at the surface of the membrane and a decrease in the recovery rate. In conclusion, a mapping of the pores is performed for several new hollow fibre membranes used to produce drinking water, made of different materials, with different geometries and molecular weight cut-off. These results provide reference data that will help better understand the phenomena of membrane fouling and membrane ageing.

해안사구에서의 유효풍속과 지형변화 (The Effective Wind Velocity and the Patterns of Morphological Change in the Coastal Dune Area)

  • 서종철
    • 한국지역지리학회지
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    • 제10권3호
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    • pp.667-681
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    • 2004
  • 이 연구의 목적은 태안반도 신두해안사구의 유효풍속과 지형변화의 관계를 밝히는 것이다. 퇴적물의 유동은 8개의 횡단면에서 침식핀을 이용하여 1999년 7월부터 2000년 7월까지 고도변화를 측정한 후 계산되었다. 연구결과가 시사하는 바는 다음과 같다. 첫째, 사구지역에서의 지형변화와 유효풍속에 근거하여 퇴적기와 침식기가 구분되었다. 퇴적기는 11월부터 4월까지로 모래의 집적이 주로 전사구에서 일어났으며 순차적으로 사구평지로 이어졌다. 침식기는 5월부터 10일까지로 전사구의 말단부에서 소규모 침식과 퇴적이 반복되는 패턴을 보였다. 둘째. 조사기간 동안 조사지역에서의 전체 퇴적물수지는 $10.2\;m^3$/m/yr로 잉여로 나타났으나 지역적인 차이가 나타났다. 이차사구에서는 결핍되는 곳도 나타났다. 사구지역의 북단에서는 모래의 공급이 활발하게 이루어지고 있는 반면 중앙부와 남부지역에서는 모래의 공급이 빈약했다.

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Structural and Optical Properties of GaN Nanowires Formed on Si(111)

  • Han, Sangmoon;Choi, Ilgyu;Song, Jihoon;Lee, Cheul-Ro;Cho, Il-Wook;Ryu, Mee-Yi;Kim, Jin Soo
    • Applied Science and Convergence Technology
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    • 제27권5호
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    • pp.95-99
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    • 2018
  • We discuss the structural and optical characteristics of GaN nanowires (NWs) grown on Si(111) substrates by a plasma-assisted molecular-beam epitaxy. The GaN NWs with high crystal quality were formed by adopting a new growth approach, so called Ga pre-deposition (GaPD) method. In the GaPD, only Ga was supplied without nitrogen flux on a SiN/Si surface, resulting in the formation of Ga droplets. The Ga droplets were used as initial nucleation sites for the growth of GaN NWs. The GaN NWs with the average heights of 60.10 to 214.62 nm obtained by increasing growth time. The hexagonal-shaped top surfaces and facets were observed from the field-emission electron microscope images of GaN NWs, indicating that the NWs have the wurtzite (WZ) crystal structure. Strong peaks of GaN (0002) corresponding to WZ structures were also observed from double crystal x-ray diffraction rocking curves of the NW samples. At room temperature, free-exciton emissions were observed from GaN NWs with narrow linewidth broadenings, indicating to the formation of high-quality NWs.

The Effect of Plasma Gas Composition on the Nanostructures and Optical Properties of TiO2 Films Prepared by Helicon-PECVD

  • Li, D.;Dai, S.;Goullet, A.;Granier, A.
    • Nano
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    • 제13권10호
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    • pp.1850124.1-1850124.12
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    • 2018
  • $TiO_2$ films were deposited from oxygen/titanium tetraisopropoxide (TTIP) plasmas at low temperature by Helicon-PECVD at floating potential ($V_f$) or substrate self-bias of -50 V. The influence of titanium precursor partial pressure on the morphology, nanostructure and optical properties was investigated. Low titanium partial pressure ([TTIP] < 0.013 Pa) was applied by controlling the TTIP flow rate which is introduced by its own vapor pressure, whereas higher titanium partial pressure was formed through increasing the flow rate by using a carrier gas (CG). Then the precursor partial pressures [TTIP+CG] = 0:027 Pa and 0.093 Pa were obtained. At $V_f$, all the films exhibit a columnar structure, but the degree of inhomogeneity is decreased with the precursor partial pressure. Phase transformation from anatase ([TTIP] < 0.013 Pa) to amorphous ([TTIP+CG] = 0:093 Pa) has been evidenced since the $O^+_2$ ion to neutral flux ratio in the plasma was decreased and more carbon contained in the film. However, in the case of -50 V, the related growth rate for different precursor partial pressures is slightly (~15%) decreased. The columnar morphology at [TTIP] < 0.013 Pa has been changed into a granular structure, but still homogeneous columns are observed for [TTIP+CG] = 0:027 Pa and 0.093 Pa. Rutile phase has been generated at [TTIP] < 0:013 Pa. Ellipsometry measurements were performed on the films deposited at -50 V; results show that the precursor addition from low to high levels leads to a decrease in refractive index.