• Title/Summary/Keyword: Deposition flux

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A Study on Bulk Deposition Flux of Sulfate and Nitrate in Pusan, Korea (부산지역에서의 Sulfate와 Nitrate의 침적량에 관한 연구)

  • 김유근;박종길;문덕환;황용식
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.113-114
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    • 2001
  • 산업화ㆍ도시화에 따라 인구 증가, 교통량 증가 및 도시 구조물의 증가 등으로 인하여 도시의 대기오염과 열섬 현상 등이 날로 심각한 사회문제로 제기되고 있다. 일반적으로 대기 중에 부유하는 오염물질들은 광화학 반응을 통하여 2차 오염물질이 생성되기도 하고, 기상인자에 의하여 확산 또는 수송되어 대기오염도가 감소하거나, 중력에 의하여 지표 부근에 침적되어 제거된다. 특히, 건성 및 습성 침적되는 강하먼지는 단위 지역의 대기오염을 파악하거나, 타 지역과의 비교에 지표로 활용되고 있다. (중략)

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Kinetic Model on the Vacuum Deposition (眞空 蒸着에 관한 速度論的 모델)

  • Kim, Dae-Soo
    • Journal of the Korean institute of surface engineering
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    • v.19 no.2
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    • pp.51-58
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    • 1986
  • A theoretical model was proposed to predict the rate of particles impinging on the negatively biased substrate and the total kinetic energy per unit time. The model takes into an account of kinetic theory based on Maxwell statistics and elementary plasma theory, incorporated with Hertz-Knudsen's evaporation theory. It is found that as the bias potential increases the ion flux and kinetic energy increases to a value above which the effect of potential is insignificant.

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Chemical Characteristics and Deposition of Aerosols in the Cheju-Korea Straits (제주-대한해협 해역에서 에어로졸의 화학적 특성과 침적)

  • Suk Hyun, Kim;Hyunmi, Lee;Deok-Soo, Moon
    • Ocean and Polar Research
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    • v.44 no.4
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    • pp.297-310
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    • 2022
  • To understand the chemical composition of aerosols in the Cheju-Korea Straits and their contribution to the ocean by deposition, aerosol samples were collected on board R/V Eardo from November 1997 to May 1999. The average concentrations of Al, NO3-, non-sea-salt (nss)-SO42-, and NH4+ in aerosols were 2.19, 5.59, 6.16 and 2.08 ㎍ m-3, respectively. The Al concentration in the high yellow dust period was about 100 times higher than that in the non-yellow dust period. The concentration ratio of NO3-/nss-SO42- ranged between 0.47 and 1.5, indicating that the aerosols in the Cheju-Korea Straits are under the effects of NOx and SOx emitted from China, Korea and Japan. The equivalent concentration ratio of [NH4+]/[nss-SO42-+ NO3-] with the average of 0.58±0.29 indicates that nss-SO42- and NO3- are not neutralized by NH4+. A high activity concentration of 210Pb with 1.13-1.23 mBq m-3 was observed during the high yellow dust period, indicating that 210Pb is easily adsorbed in the yellow dust originating from the continent of Asia. The distribution of 7Be and NH4+ concentrations showed a strong negative linear correlation during the low yellow dust period, April 1998. The total mineral dust flux in the Cheju-Korea Straits was estimated to be 1.21×106 tons yr-1, accounting for about 12% of the annual sediment discharge via the Nakdong River. The combined annual deposition of NH4+ and NO3- was 0.103 mole N m-2 yr-1 was estimated to support 4% of the annual primary productivity in the East China Sea.

A Study on the Characterization of Size Distributions and Atmospheric Dry Deposition of Heavy Metals (대기중 중금속 입자의 입경분포 및 건식침적 특성에 관한 연구)

  • Yi, Seung-Muk;Lee, Eun-Young;Cheong, Jang-Pyo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.3
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    • pp.575-585
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    • 2000
  • Mass and elemental dry deposition fluxes and ambient particle size distributions were measured using dry deposition plates, a cascade impactor. and a CPS(Coarse Particle Sampler), from July to November 1998 in Seoul. Korea. Primarily anthropogenic elemental fluxes (Cu, Mn, Ni, Pb, Zn) were on average one to two orders of magnitude lower than primarily crustal elements (Al, Ca). Complete total and elemental particle size distributions showed trimodal size distributions due to the peak in particles larger than $10{\mu}m$ in diameter. A multi-step model and the Sehmel-Hodgson model were used to calculate total and cumulative deposition fluxes. The result indicated that dry deposition fluxes were extremely sensitive to the mass of particles larger than $10{\mu}m$ in diameter due to their high dry deposition velocities. The result showed that particles larger than $10{\mu}m$ in diameter dominated atmospheric dry deposition. The modeled fluxes calculated using the measured atmospheric particle size distributions and modeled deposition velocities were compared to measured ones. In general, the measured mass and elemental fluxes agreed well with the modeled ones.

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Numerical Simulation for Net-water Flux of the Cross-sectional area in the Nakdong River Estuary (낙동강 하구역내 사주간의 단면유량플럭스 수치모의)

  • Yoon, Han-Sam;Lee, In-Cheol;Ryu, Cheong-Ro
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.8 no.4
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    • pp.186-192
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    • 2005
  • We investigated the deposition characteristics and mass transport flux estimation of the Nakdong estuary, Korea. To understand the effects of the tidal current circulation that influences estuary terrain changes, we used a 2D numerical model to map seawater circulation under three different situations, with the level of river flow being set as none or flood. The net-water flux of the cross-sectional area between sandbars (known as dung) was estimated. From our review of previous research, we know that the development of local sandbars shifted from the west to the east side of the estuary after the construction of the Nakdong River dike. Current development is occurring mostly at the Bakhap-dung near Tadea. The seawater circulation pattern over this large-scale area of tidal na is brings changes related to the quantity of the outflow from the Nakdong River. Based on the calculated results for the net-water flux of the cross-sectional area, we see very strong accumulation in local waters around Jangjiado, Bakhapdung, and Tadae under flood river flow conditions, but accumulation in local waters around Jinudo under the other states of flow. Consequently, in the Nakdong estuary, the main sensitive regions that are affected by changes in the flow of river discharge are the local waters around Jangiado, Bakhapdung, Tadae, and Jinudo.

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Hydrogen Perm-Selectivity Property of the Palladium Hydrogen Separation Membranes on Porous Stainless Steel Support Manufactured by Metal Injection Molding (금속 사출성형 방식의 다공성 스테인리스 강 지지체에 형성된 팔라듐 수소 분리막의 투과 선택도 특성)

  • Kim, Se-Hong;Yang, Ji-Hye;Lim, Da-Sol;Kim, Dong-Won
    • Journal of the Korean institute of surface engineering
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    • v.50 no.2
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    • pp.98-107
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    • 2017
  • Pd-based membranes have been widely used in hydrogen purification and separation due to their high hydrogen diffusivity and infinite selectivity. However, it has been difficult to fabricate thin and dense Pd-based membranes on a porous stainless steel(PSS) support. In case of a conventional PSS support having the large size of surface pores, it was required to use complex surface treatment and thick Pd coating more than $6{\mu}m$ on the PSS was required in order to form pore free surface. In this study, we could fabricate thin and dense Pd membrane with only $3{\mu}m$ Pd layer on a new PSS support manufactured by metal injection molding(MIM). The PSS support had low surface roughness and mean pore size of $5{\mu}m$. Pd membrane were prepared by advanced Pd sputter deposition on the modified PSS support using fine polishing and YSZ vacuum filling surface treatment. At temperature $400^{\circ}C$ and transmembrane pressure difference of 1 bar, hydrogen flux and selectivity of $H_2/N_2$ were $11.22ml\;cm^{-2}min^{-1}$ and infinity, respectively. Comparing with $6{\mu}m$ Pd membrane, $3{\mu}m$ Pd membrane showed 2.5 times higher hydrogen flux which could be due to the decreased Pd layer thickness from $6{\mu}m$ to $3{\mu}m$ and an increased porosity. It was also found that pressure exponent was changed from 0.5 on $6{\mu}m$ Pd membrane to 0.8 on $3{\mu}m$ Pd membrane.

Fundamentals of Particle Fouling in Membrane Processes

  • Bhattacharjee Subir;Hong Seungkwan
    • Korean Membrane Journal
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    • v.7 no.1
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    • pp.1-18
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    • 2005
  • The permeate flux decline due to membrane fouling can be addressed using a variety of theoretical stand-points. Judicious selection of an appropriate theory is a key toward successful prediction of the permeate flux. The essential criterion f3r such a decision appears to be a detailed characterization of the feed solution and membrane properties. Modem theories are capable of accurately predicting several properties of colloidal systems that are important in membrane separation processes from fundamental information pertaining to the particle size, charge, and solution ionic strength. Based on such information, it is relatively straight-forward to determine the properties of the concentrated colloidal dispersion in a polarized layer or the cake layer properties. Incorporation of such information in the framework of the standard theories of membrane filtration, namely, the convective diffusion equation coupled with an appropriate permeate transport model, can lead to reasonably accurate prediction of the permeate flux due to colloidal fouling. The schematic of the essential approach has been delineated in Figure 5. The modern approaches based on appropriate cell models appear to predict the permeate flux behavior in crossflow membrane filtration processes quite accurately without invoking novel theoretical descriptions of particle back transport mechanisms or depending on adjust-able parameters. Such agreements have been observed for a wide range of particle size ranging from small proteins like BSA (diameter ${\~}$6 nm) to latex suspensions (diameter ${\~}1\;{\mu}m$). There we, however, several areas that need further exploration. Some of these include: 1) A clear mechanistic description of the cake formation mechanisms that clearly identifies the disorder to order transition point in different colloidal systems. 2) Determining the structure of a cake layer based on the interparticle and hydrodynamic interactions instead of assuming a fixed geometrical structure on the basis of cell models. 3) Performing well controlled experiments where the cake deposition mechanism can be observed for small colloidal particles (< $1\;{\mu}m$). 4) A clear mechanistic description of the critical operating conditions (for instance, critical pressure) which can minimize the propensity of colloidal membrane fluting. 5) Developing theoretical approaches to account for polydisperse systems that can render the models capable of handing realistic feed solutions typically encountered in diverse applications of membrane filtration.

Development of Welding Flux and Process for Prevention of Cold Cracking in SAW Weld Metal (잠호용접부 균열방지를 위한 용접 플락스 및 시공기법 개발)

  • Choi, Kee-Young;Kim, Chan;Kim, Young-Pil
    • Special Issue of the Society of Naval Architects of Korea
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    • 2007.09a
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    • pp.118-127
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    • 2007
  • SAW(Submerged Arc Welding) process is generally applied to a wide range of welding area in the fabrication of steel structure. This process has a good characteristic properties such as the high quality of welds and the high deposition rates, but in case of welding on a thick steel plate, it also has higher cold crack susceptibility than that of a thin steel plate. The purpose of this research is to find the main factor of crack generation and clarify the countermeasure for crack prevention, and then establish the optimum welding condition in a heavy thick steel plate. The results of this study are as follows, 1. The cause of crack generation is found the diffusible hydrogen penetrated into weld metal by decomposition of the remained moisture in SAW flux during welding. 2. For the removal of diffusible hydrogen, the raw materials of SAW flux are to be dehydrated at the high temperature in the initial manufacturing stage. 3. Mechanical properties of weld metal welded with the dehydrated SAW flux were evaluated very excellent, furthermore the weld metal has been proved to have low diffusible hydrogen content with 3.1ml /100g. 4. The weldability and quality welded with thick steel plates were improved by establishing the new optimum welding condition.

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A Characteristics and Distributions of Wet Deposition in Korea, 2005 (2005년 우리나라 습성강하물의 특성과 분포)

  • Han J.S.;Lee S.D.;Hong Y.D.;Kong B.J.;Shin S.A.;Jung I.R.
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.4
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    • pp.459-467
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    • 2006
  • This study was carried out to characteristics and distributions of acid deposition in Korea. Precipitation was collected by acid deposition monitoring networks and analyzed for pH, conductivity, and following major ionic components $SO_4^{2-}$, $CI^-$, $NO_3^-$, $NH_4^+$, $Na^+$, $K^+$, $Ca^{2+}$, $Mg{2+}$. During the investigation period, Volume weighted annual mean pH of precipitation in Korea is 4.8, showing slightly acidic level. The amount of rainfall in the range of pH 5.1$\sim$5.5 charged approximately 28% of annual precipitation,23.4% in pH 4.6$\sim$5.0, and contributed 16.2% under pH 4.5. Among seasons, alkaline precipitation has occurred more often in spring, meanwhile acidic precipitation in which pH is under 4.5 has frequently occurred in autumn. Volume weighted annual mean concentrations of $SO_4^{2-}$, $NO_3^-$, $CI^-$ are 2.558 mg/L, 1.590 mg/L, 1.286 mg/L respectively, and provided that $SO_4^{2-}$, is the major contributor, followed by $NO_3^-$, $CI^-$. In case of cation, annual mean concentration for $NH_4^+$, $Na^+$, $K^+$, $Ca^{2+}$, $Mg{2+}$, $H^+$ are 0.693 mg/L, 0.528 mg/L, 0.439 mg/L, 0.455 mg/L, 0.089 mg/L,0.015 mg/L, and $NH_4$ were decided as the main contributor, followed by $Na^+$, $K^+$, $Ca^{2+}$, $Mg{2+}$, $H^+$. Annual wet deposition rate for sulfate, nitrate and ammonia are $3.316gm^{-2}yr^{-1}$, $2.057gm^{-2}yr{-1}$, $0.894gm^{-2}yr{-1}$, respectively, and it was founded that the deposition flux in summer contributes about 38.42% to 67.62% to total deposition.

Characteristics of Ambient Metals: Size Segregated Ambient Concentrations and Dry Deposition Fluxes at Four Sites in Kunpo in 2000

  • Kim, Yong-Pyo;Yun, Hui-Jung;Yi, Seung-Muk
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E2
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    • pp.57-68
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    • 2002
  • Atmospheric dry deposition fluxes and size segregated concentrations of particulate metal elements were measured at four sites in Kunpo, a small city in the Seoul metropolitan area in Korea. At each site, aerosol samples were collected by dry deposition plates, a cascade impactor, and a coarse panicle rotary impactor during four sampling periods. At all sites, the average fluxes of metals measured during daytime were higher than nighttime fluxes due to higher wind speeds and higher ambient concentrations during daytime. The average fluxes of crustal elements (Al, Ca) were 1∼2 orders of magnitude higher than anthropogenic elements (As, Cd, Cu, Mn, Ni, Pb, and Zn). The daytime fluxes of Al and Ca were between 90 and 12000 $\mu\textrm{g}$ m$\^$-2/ day$\^$-1/, and the nighttime fluxes of Al and Ca were between 20 and 2200 $\mu\textrm{g}$ m$\^$-2/ day$\^$-1/. The daytime fluxes of Pb, a typical anthropogenic element, were between 20 and 160$\mu\textrm{g}$ m$\^$-2/ day$\^$-1/, and the nighttime fluxes of Pb were between ND and 100$\mu\textrm{g}$ m$\^$-2/ day$\^$-1/. Also the ambient metal concentrations during daytime were higher than nighttime. Based on a dust emission estimation study in Kunpo, it was found that dust emissions during daytime are higher than nighttime. The concentrations of crustal elements were higher than anthropogenic elements. The distributions of heavy metals were mainly in small particles (D$\_$p/ 9㎛). The fraction of crustal elements in the large particles (D$\_$p/> 9㎛) were higher than anthropogenic elements.