• Title/Summary/Keyword: Denitrofication

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The Improvement of Denitrofication by Using Sodium Salts in the SNCR Process (SNCR 공정에서 Sodium Salts 첨가제를 이용한 탈질반응 개선에 관한 연구)

  • Lee, Seung Moon;Park, Kwinam;Kwak, Tae-Heon;Park, Jin-Won;Makin, Sanjeev;Kim, Byung-Hwan
    • Korean Chemical Engineering Research
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    • v.43 no.2
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    • pp.324-329
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    • 2005
  • The efficiency of reducing nitric oxide using urea combined with alkali salt additives is reported in this study. The inlet concentration of NO is 500 ppm with air flow rates of 3 and 5 L/min. Reduction of NO was studied from 650 to $1,050^{\circ}C$ with urea concentrations of 0.3 to 1 mol/L. The efficiency for the reduction of NO increased by 44% when urea is added alone. A further increase in efficiency was observed in the presence of NaOH as additive in fact, the efficiency was increased by more than 25% and 75% when 0.5 mol/L and 1 mol/L NaOH were added with the urea. The efficiency for the reduction of NO increased with all additives, but descended in the order NaOH, $Na_2CO_3$, $NaNO_3$, HCOONa, and CHCOONa. The maximum efficiency of NaOH and $Na_2NO_3$ are 74% and 73%, respectively. All these additives did not alter the comparatively wide operating temperature window for reducing NO. However, sodium compounds do not shift the maximum NO concentration towards lower temperatures when the NO removal activity enhances.