• Title/Summary/Keyword: Degree of oxidation

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Nano-Soot Particle Formation in Inverse Diffusion Flames (인버스 확산화염에서의 나노 수트 입자 생성)

  • Lee, Eui-Ju;Shin, Hyun-Joon;Oh, Kwang-Chul;Shin, Hyun-Dong
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.19-26
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    • 2003
  • Experimental measurements of flame structure and soot characteristics were performed for ethene inverse diffusion flames (IDF). IDF has been considered as the excellent flow field to study the incipient soot because soot particle do not experience the oxidation process. In this study, LIF image clarified the reaction zone of IDF with OH signal and PAH distribution. laser light scattering technique also identified the being of soot particle. To address the degree of soot maturing, C/H ratio and morphology of soot sample were investigated. From these measurements, the effect of flow residence time and temperature on soot inception could be suggested, and more details on soot characteristic in the IDF was determined according to fuel dilution and flame condition. The fuel dilution results in a decrease of temperature and enhancement of residence time, but the critical dilution mole fraction is existed for temperature not to effect on soot growth. Also, the soot inception evolved on the specific temperature and its morphology are independent of the fuel dilution ratio of fuel.

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A Characteristic Analysis on Clay Pigments of Mural Paintings in Sri Lanka

  • Yoo, Seon-Young;Seneviratne, Buddakoralelage Janani Namal;Kim, Gyu-Ho
    • Journal of Conservation Science
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    • v.38 no.4
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    • pp.327-333
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    • 2022
  • Sri Lanka has four types of mural painting styles; Classic, Late Classic, Kandyan, and Southern styles, but there is little research on scientific analysis for mural paintings. In this study, we analyze white, yellow, and red clay pigments which were collected from ancient producing sites. Analyzing pigment samples shows that samples are containing aluminum oxide(Al2O3) and silicon dioxide(SiO2) which are connected to the soil. And a degree of iron oxidation determines yellow or red colors. To understand the characteristics of clay pigment samples, we go over previous pigment analyses of mural paintings in Sri Lanka. Kaolin is identified after the 17th century, yellow and red ochre are applied in early periods, Classic and Late Classic styles. The change in raw materials of pigments occurred in the 17th century.

Automatic Measuring Apparatus for Salt and Dust Contamination (염진해 오손도 자동측정장치)

  • 최남호;구경완;이명섭;한상옥;정재기;조성배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.187-190
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    • 1999
  • To reduce the maintenance expence, and the possibility of electric outage and accident, accurate measurement should be carried. But the classical method has some problems in the aspect of man power, reliability, and expence. In this paper, we propose a new type apparatus, which could detect the degree of contamination on insulators on outdoor insulation system, such as transmission and distribution line insulator and bushing. The new type apparatus consists of Pelltier module, electrode system, and measuring part. At first leakage current detecting method was considered, then with the fault(oxidation of electrode) of that method we should propose a another method. We carried various test to prove the possiblity and reliability of the propoused apparatus. And we get some useful result with laboratory test.

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Studies on the Effect of Korean Ginseng Components on Acetic acid Fermentation. [II] (인삼성분이 초산발효에 미치는 영향에 관한 연구(제2보))

  • 남성희;유태종
    • Journal of Ginseng Research
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    • v.4 no.2
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    • pp.133-145
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    • 1980
  • In order to find out the inhibitors of acetic acid fermentation in Korean ginseng (Panax Sin son C. A. Meyer), total aglycone, panaxadiol, panaxadiol, oleanolic acid and ${\beta}$ -sitosterol were added to the basal medium, respectively, and a surface culture was carried out at 30$^{\circ}C$. The results were as follows: 1 . Saponins lost their activity to inhibit the acetic acid fermentation by hydrolysis. 2 Panaxadiol inhibited slightly, and the degree of inhibition was about 1/300 of that of free saponins. 3. Panaxadiol and oleanolic acid inhibited silighly similar to total aglycone. 4. Acetic acid fermentation was stimulated at the early stage when ${\beta}$-sitosterol was added to the media below the level of 0.000815%. But the fermentation was inhibited when media contained it more than that media 5. An over-oxidation of acetic acid was observed when the media contained total aglycone. panaxadiol, panaxatriol, oleanolic acid and ${\beta}$-sitosterol, respectively, while the media which contained sucrose, ginseng extracts ginseng saponins was shown not to be over-oxidized.

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Development of Hydrophobically Modified Casein Derivative-Based Delivery System for Docosahexaenoic Acids by an Acid-Induced Gelation

  • Ho-Kyung Ha;Dan-Bi Woo;Mee-Ryung Lee;Won-Jae Lee
    • Food Science of Animal Resources
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    • v.43 no.2
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    • pp.220-231
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    • 2023
  • Although omega-3 fatty acids including docosahexaenoic acid (DHA) contain various health-promoting effects, their poor aqueous solubility and stability make them difficult to be induced in dairy foods. The aims of this research were to manufacture casein derivative-based delivery system using acid-induced gelation method with glucono-σ-lactone and to investigate the effects of production variables, such as pH and charged amount of linoleic acid, on the physicochemical properties of delivery systems and oxidative stability of DHA during storage in model milk. Covalent modification with linoleic acid resulted in the production of casein derivatives with varying degrees of modification. As pH was reduced from 5.0 to 4.8 and the charged amount of linoleic acid was increased from 0% to 30%, an increase in particle size of casein derivative-based delivery systems was observed. The encapsulation efficiency of DHA was increased with decreased pH and increased charged amount of linoleic acid. The use of delivery system for DHA resulted in a decrease in the development of primary and secondary oxidation products. An increase in the degree of modification of casein derivatives with linoleic acid resulted in a decrease in the formation of primary and secondary oxidation products than of free DHA indicating that delivery systems could enhance the oxidative stability of DHA during storage in model milk. In conclusions, casein derivatives can be an effective delivery system for DHA and charged amount of linoleic acid played a key role determining the physicochemical characteristics of delivery system and oxidative stability of DHA.

Improved Kerosene Quality with the Use of a Gamma Alumina Nanoparticles Supported Zinc Oxide Catalyst in a Digital Batch Baffled Reactor: Experiments and Process Modelling

  • Jasim I. Humadi;Ghassan Hassan Abdul Razzaq;Ghassan Hassan Abdul Razzaq;Mustafa A. Ahmed;Liqaa I. Saeed
    • Korean Chemical Engineering Research
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    • v.61 no.2
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    • pp.226-233
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    • 2023
  • To create an environmentally sustainable fuel with a low sulfur concentration, requires alternative sulfur removal methods. During the course of this study, a high surface gamma alumina-supported ZnO nanocatalyst with a ZnO/-Al2O3 ratio of 12% was developed and tested for its ability to improve the activity of the oxidative desulfurization (ODS) process for the desulfurization of kerosene fuel. Scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) were used to characterize the produced nanocatalyst. In a digital batch baffled reactor (20~80 min), the effectiveness of the synthesized nanocatalyst was tested at different initial concentrations of dibenzothiophene (DBT) of 300~600 ppm, oxidation temperatures (25~70 ℃), and oxidation periods (0.5, 1, and 2 hours). The baffles included in the digital baffled batch reactor resist the swirling of the reaction mixture, thus facilitating mixing. The ODS procedure yielded the maximum DBT conversion (95.5%) at 70 ℃ with an 80-minute reaction time and an initial DBT level of 600 ppm. The most precise values of kinetic variables were subsequently determined using a mathematical modelling procedure for the ODS procedure. The average absolute error of the simulation findings was less than 5%, demonstrating a good degree of agreement with the experimental results acquired from all runs. The optimization of the operating conditions revealed that 99.1% of the DBT can be removed in 140 minutes.

A Study for Conservation for the Wooden Coffin - Artificial Deterioration Using Fenton's Reagent - (녹나무목관 보존처리에 관한 연구 - Fenton 산화를 이용한 생재의 인공열화 연구 -)

  • Yang, Suk-Ja;Yang, Seok-Jin;Jeong, Ah-Reum
    • 보존과학연구
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    • s.30
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    • pp.203-215
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    • 2009
  • In the conservation treatment of wood remains, polymers, treatment methods, and treatment period can be varied, depending on the percentage of moisture content and species of trees. Thus, in order to apply the appropriate conservation treatment, a lot of information from the wood remains are required. Despite the information from the wood remains, testing a part of the wood remains is necessary to get information about the polymers. When the wooden coffin made of camphor trees was excavated, it was cracked in the section of radiation, and there were hairlines cracks. Therefore, without any conservation treatment, it is impossible to restore it. This experiment is for the conservation treatment of the wooden coffin excavated from Songhyun-dong tombs No 7, Changnyeong. For this experiment, I used camphor trees from Jejudo. The purpose of this experiment is to asses the possibility of preliminary testing materials before the conservation treatment on the wooden coffin. After the camphor trees from Jejudo are artificially aged by Fenton's reagent, they are As a result of oxidation by Fenton, the degree of oxidation is high in proportion to the amount of peroxide and iron sulfate. Among several samples, the sample 'na' made the most similar result to the wooden coffin from Songhyun-dong. If I use this condition to make the sample in polymer tests, it is very helpful to find the most suitable polymer for the conservation treatment of wooden coffin. After the same species of trees are oxidized by Fenton and they become the similar condition, we are able to find suitable methods of conservation treatment. The suitable methods reduce the demage of the remains and make us to get more information. Thus, we are able to carry out conservation treatment more exactly.

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Changes in the Concentration of Tocopherol and Carotenoid in Pinenut Oil during Autoxidation (잣 지방질의 자동산화에 따른 토코페롤 및 카로티노이드의 변화)

  • Kim, Myung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.22 no.1
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    • pp.96-100
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    • 1993
  • The changes in the concentration of toropherol and carotenoid in pinenut oil at various stage of refining are studied during autoxidation. The oxidative stability of pinenut oil decreased with the refining degree increased. The tocopheol content of total crude oil was 55.51mg/100g oil and $\alpha$, ${\gamma}$and $\beta$-tocopherol in the crude oil were 25.48mg, 23.94mg and 6.99mg in order, respectively. The amount of $\delta$-tocopherol was trace. The concentrations of $\alpha$, ${\gamma}$ and $\beta$-tocopherol in pinenut oil after degumming or alkaline refining were 23. 85mg, 19.79mg and 6.12mg or 24.08mg, 24.04mg and 5.33mg, respectively. The content of f-carotene was 0.63% of total unsaponifiable materials and that of lycopene was trace. The concentrations of carotenoids and toropherols in pinenut oil decreased while autoxidation progressed. Degrees of destruction of carotenoids and toropherols. were significant at first stage of oxidation. Decrease in $\alpha$-toropherol was found to be faster than that in $\alpha$, ${\gamma}$-tocopherol during oxidation.

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Electrochemical Behavior of Plasma Electrolytic Oxidized Films Formed in Solution Containing Mn, Mg and Si Ions

  • Lim, Sang-Gyu;Choe, Han Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.80-80
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    • 2017
  • Titanium and its alloys that have a good biocompatibility, corrosion resistance, and mechanical properties such as hardness and wear resistance are widely used in dental and orthopedic implant applications. However, they do not form a chemical bond with bone tissue. Plasma electrolytic oxidation (PEO) that combines the high voltage spark and electro-chemical oxidation is a novel method to form ceramic coatings on light metals such as tita-nium and its alloys. This is an excellent re-producibility and economical, because the size and shape control of the nano-structure is relatively easy. Silicon (Si), manganese (Mn), and magne-sium (Mg) have a useful to bone. Particularly, Si has been found to be essential for normal bone, cartilage growth, and development. Mn influences regulation of bone remodeling be-cause its low content in body is connected with the rise of the concentration of calcium, phosphates and phosphatase out of cells. Pre-studies have shown that Mg plays very im-portant roles in essential for normal growth and metabolism of skeletal tissue in verte-brates and can be detected as minor constitu-ents in teeth and bone. In this study, Electrochemical behavior of plasma electrolytic oxidized films formed in solution containing Mn, Mg and Si ions were researched using various experimental in-struments. A series of Si-Mn-Mg coatings are produced on Ti dental implant using PEO, with the substitution degree, respectively, at 5 and 10%. The potentiodynamic polarization and AC impedance tests for corrosion behav-iors were carried out in 0.9% NaCl solution at similar body temperature using a potentiostat with a scan rate of 1.67mV/s and potential range from -1500mV to + 2000mV. Also, AC impedance was performed at frequencies anging from 10MHz to 100kHz for corrosion resistance.

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Effects of Gaseous Ozone Exposure on Bacterial Counts and Oxidative Properties in Chicken and Duck Breast Meat

  • Muhlisin, Muhlisin;Utama, Dicky Tri;Lee, Jae Ho;Choi, Ji Hye;Lee, Sung Ki
    • Food Science of Animal Resources
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    • v.36 no.3
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    • pp.405-411
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    • 2016
  • The effects of gaseous ozone exposure on the bacterial counts and oxidative properties were evaluated in duck and chicken breast fillets, which were stored under a continuous flux of gaseous ozone (10×10−6 kg O3/m3/h) at 4±1℃ for 4 d. The ozone generator was set to on for 15 min and off for 105 min, and this cyclic timer was set during storage. Ozone effectively reduced the growth of coliform, aerobic and anaerobic bacteria in both chicken and duck breast. However, lipid oxidation occurred faster in duck breast than chicken breast with higher degree of discoloration, TBARS value, and antioxidant enzyme (glutathione peroxidase and catalase) activity decline rates. It is concluded that ozone effectively controlled the growth of bacteria in both chicken and duck breast with less effects on oxidative deterioration in chicken breast.