• Title/Summary/Keyword: Degree of ionization

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Adsorption of chlorhexidine digluconate on acid modified fly ash: Kinetics, isotherms and influencing factors

  • Singh, Astha;Sonal, Sonalika;Kumar, Rohit;Mishra, Brijesh Kumar
    • Environmental Engineering Research
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    • v.25 no.2
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    • pp.205-211
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    • 2020
  • Chlorhexidine digluconate (CHD) in the aquatic environment causes irreversible change to microbes, making them resistant to biodegradation, which needs remediation other than biological process. Adsorption study was performed for the removal of CHD on fly ash (FA) as a function of pH and ionic strength. Experimental result has been validated by characterization using Scanning electron microscopy, Fourier Transform-Infrared Spectroscopy and Brunauer-Emmett-Teller. CHD adsorption with FA showed an increasing trend with an increase in pH. Variation in pH proved to be an influential parameter for the surface charge of adsorbent and the degree of ionization of the CHD molecules. The adsorption capacity of CHD decreased from 23.60 mg g-1 to 1.13 mg g-1, when ionic strength increased from to M. The adsorption isotherms were simulated well by the Freundlich isotherm model having R2 = 0.98. The Lagergren's model was incorporated to predict the system kinetics, while the mechanistic study was better explained by pseudo-second order for FA. On the basis of operational conditions and cost-effectiveness FA was found to be more economical as an adsorbent for the adsorption of CHD.

Electrochemical Properties of Pulp Fiber with LbL Multilayering by Polyelectrolyte at the Different pH and Salt Concentration (고분자전해질의 LbL multilayering 시 pH와 염 농도 조건에 따른 섬유의 전기화학적 특성)

  • Ryu, Jae-Ho;Lee, Sung-Rin;Chin, Seong-Min;Youn, Hye-Jung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.4
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    • pp.59-65
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    • 2008
  • Electrochemical properties of pulp fiber could be modified by LbL(Layer-by-Layer) multilayering. Salt concentration and pH affect the conformation and ionization degree of polyelectrolyte. In this study, therefore, we intended to evaluate the effect of pH and salt concentration in polyelectrolyte multilayering on the electrochemical properties of pulp fiber. The pH of the stock was varied to 4, 7, and 10. Salt concentration was controlled at 0.001, 0.003, and 0.005 M of NaCl. Higher zeta potential was obtained when pulp fibers were multilayered at the condition of higher pH and higher salt concentration. The final zeta potential of pulp fiber after multilayering was dependent on the adsorption ratio of polyelectrolyte and the initial zeta potential of fibers.

Study of the Hydrophilic Properties of Toughened Glass (강화유리 표면의 친수성 특성 조사에 관한 연구)

  • Park, Sung Jin;Seo, Jin Woo;Lee, Seung Kyu
    • Korean Journal of Optics and Photonics
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    • v.24 no.1
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    • pp.39-44
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    • 2013
  • In this study, we assessed the hydrophilic characteristics of the surface of toughened glass used in smartphones by investigating the optical properties and contact angle characteristics of the plasma device. In this study, the characteristics were different depending on the partial pressure of the gas, input voltage, and degree of ionization of argon gas. In this study, the surface of the toughened glass became more hydrophilic, as indicated by contact angle and light spectrum, after plasma treatment than before the treatment.

A QUALITY CHECK OF THE AKARI MID-INFRARED ALL-SKY DIFFUSE MAP TOWARD THE MASSIVE STAR-FORMING REGIONS NGC 6334 AND NGC 6357

  • Sano, Hidetoshi;Amatsutsu, Tomoya;Kondo, Toru;Nakamichi, Keichiro;Yamagishi, Mitsuyoshi;Ishihara, Daisuke;Oyabu, Shinki;Kaneda, Hidehiro;Tachihara, Kengo;Fukui, Yasuo
    • Publications of The Korean Astronomical Society
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    • v.32 no.1
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    • pp.21-23
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    • 2017
  • We present a comparative study of CO and polycyclic aromatic hydrocarbon (PAH) emission toward a region including the massive star-forming regions of NGC 6334 and NGC 6357. We use the NANTEN $^{12}CO(J=1-0)$ data and the AKARI $9{\mu}m$ All-Sky diffuse map in order to evaluate the calibration accuracy of the AKARI data. We confirm that the overall CO distribution shows a good spatial correspondence with the PAH emission, and their intensities exhibit a good power-law correlation with a spatial resolution down to 4' over the region of $10^{\circ}{\times}10^{\circ}$. We also reveal poorer correlation for small scale structures between the two quantities toward NGC 6357, due to strong UV radiation from local sources. Larger scatter in the correlation toward NGC 6357 indicates higher ionization degree and/or PAH excitation than that of NGC 6334.

A Study on Scattering Distribution in Metal of Ir-192 Gamma-Ray (Ir-192 $\gamma$선(線)의 금속(金屬)에 대(對)한 산란분포(散亂分布)에 관(關)한 연구(硏究))

  • Joo, Gwang-Tae
    • Journal of radiological science and technology
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    • v.4 no.1
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    • pp.63-71
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    • 1981
  • The metal-plates(Aluminium. Copper, Lead) of change the variation thickness have been penetrated by the collimated beam($450mm{\times}4mm{\phi}$) of Gamma-ray from $^{192}Ir$. Then, the scattered $\gamma$-ray dose in variable angle and the directly transmitted $\gamma$-ray dose were measured using the electrometer of ionization chamber. The results were summarized as follows: 1. Obtained the mass attenuation coefficients of $Al;0.0937cm^2g^{-1},\;Cu;0.0937cm^2g^{-1},\;pb;0.244cm^2g^{-1}$. 2. Total intensity of front scattered $\gamma$-ray follow the order of Al>Cu>pb. 3. The scattered $\gamma$-ray intensity with the lager angle of scattering was saturated after increase rapidly, and the scattering angle of the more larger was decreased. 4. The scattered $\gamma$-ray intensity through plates of aluminium or copper was saturated after increase with thicker scatterer, and the intensity was decreased at the more thicker. But the variation of scattered $\gamma$-ray dose in the lead plate made the fewest than Al and Cu. 5. The ratio of the scattered $\gamma$-ray dose and the directly transmitted $\gamma$-ray dose was saturated after increase with the thicker scatterer, and the scatterer of the more thicker was decreased. Degree of total intensity in these ratios was followed the order of Cu>Al>Pb.

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Light Scattering Studies on the Second CMC of the Aqueous Solution of Dodecyl Pyridinium Chloride and Tetradecyl Pyridinium Chloride (光散亂에 依한 Dodecyl Pyridinium Chloride 및 Tetradecyl Pyridinium Chloride 水溶液의 第二 CMC에 關한 硏究)

  • Moo Ill Chung;In Ja Tak;Kun Moo Lee
    • Journal of the Korean Chemical Society
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    • v.19 no.6
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    • pp.398-402
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    • 1975
  • The light scattering studies of the aqueous solution of dodecyl pyridinium chloride (DPC) and tetradecyl pyridinium chloride (TPC) over the concentration range of 0~70 mM revealed that there exists a so-called 2nd critical micelle concentration (cmc) at about 43 mM and 8 mM respectively in addition to their 1st cmc at 17 mM and 3.5 mM. The 2nd cmc was greatly influenced by additives KCl, which lowered the 2nd cmc. The micelle molecular weight of DPC and TPC solutions at 1st cmc were 20800 and 15600 and the degree of ionization of their micelles at 1st cmc were 0.092 and 0.226 respectively.

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A Study on the Characteristics of Sputter ion Plating by ion Energy Analysis (이온 에너지 분석에 의한 Sputter Ion Plating의 동작 특성 연구)

  • Sung, Y.M.;Lee, C.Y.;Cho, J.S.;Park, C.H.
    • Proceedings of the KIEE Conference
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    • 1994.11a
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    • pp.228-230
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    • 1994
  • A Spotter ion Plating(SIP) system with a r. f. coil electrode and the Facing Target Sputter(FTS) source was designed for high-quality thin film formation. The rf discharge was combined with DC facing target sputtering in order to enhance ionization degree of a sputtered atoms. The discharge voltage-discharge characteristics curves of a FTS source could be characterized by the fern of $I{\propto}V^n$ with n in the range of $8{\sim}12$. The energy of ions incident on the substrate depended on the sheath potential of DC biased substrate. The mean impact ion energy increased with negative bias voltage and rf power. The adhesive force of the TiN film formed was in the range of $30{\sim}50N$, and markedly influenced by substrate bias voltage.

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Electrical Resistivity Monitoring of Gas Hydrate Formation (가스하이드레이트 형성 과정의 비저항 모니터링)

  • Lee, J.Y.;Lee, J.H.;Lee, D.S.;Lee, W.S.;Kim, S.J.;Huh, D.G.;Kim, H.T.
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.186-187
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    • 2008
  • Electrical resistivity in hydrate-bearing sediments is sensitive to porosity, gas hydrate saturation, gas content, pore fluid composition, and temperature, so electrical measurements such as well logs and electromagnetic surveys have been used to explore gas hydrate-bearing formation. The high pressure tomography cell is designed considering the effect of electrode configuration and electrical shielding on tomography measurements and the safety. The evolution of electrical conductivity during $CO_2$ hydrate formation and dissociation reflects the combined effects of concurrent changes that include ionization of dissolved $CO_2$, temperature-dependent ionic mobility, changes in the degree of saturation, ion exclusion, surface conduction, and porosity changes. Measurements during hydrate formation and dissociation require careful analysis to properly interpret signatures, in particular when out-of plane conductivity anomalies prevail.

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A Study on a Classification Technique of Natural Mineral Waters by Its Constitution and Physico-Chemical Properties (鑛泉水 理化學的 水質評價 技法 에 관한 연구)

  • Nam, Sang-Ho
    • Journal of Environmental Health Sciences
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    • v.14 no.1
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    • pp.33-38
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    • 1988
  • Natural mineral water is generally quite different from ordinary drinking water due to its original nature and various properties. The complexity of natural mineral water requires, therefore, not only to identify its nature and proper characteristics, but also to classify them by a reasonable scientific basis of comparison. The study was concentrated on a possible classification technique to natural mineral waters by their constitutions and physico-ehemical properties. The classification was carried out by the computation of such numerical parameters as ionic equivalent percentage, electrolytic conductance or mobility, ionic molecular weight, molecular concentration, equivalent conductivity and degree of ionization in consideration of the determinative criteria as follows -particular single element or molecule -major components of natural waters as bicarbonate, sulphate, chloride,caloride, calcium, magnesium, and sodium -moleculat concentration related to blood osmotic pressure -water temperature at emergence from spring -contents of free carbon dioxide (CO2) -pH value of water -total dissolved solids or salts (NaCl) The results obtained proved out to be clearly distinguhhable from ordinary drinking water as far as concern natural mineral water as an example on the subject -simple water -bicarbonate-predominating water -cold spring -carbonated-non gaseous water -weak alkaline water -non saline water Putting these various results together, the sample turned out to be a kind of natural mineral water that can be used as a drinking water if microbiologically safe.

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Conductivity and Surface Tension Behavior for Binary Mixtures over a Various Concentration of TTAB

  • Ahn, Beom-Shu
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.2
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    • pp.160-168
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    • 2006
  • The conductances of trimethyltetradecylammonium bromide (TTAB) plus triphenyltetradecyl phosphonium bromide (TTPB) and TTAB plus trimethylhexadecylammonium bromide (HTAB) over the entire mole fraction range of TTAB were measured in water and in cyclodextrin plus water mixtures at fixed 4 and 8 mM of cyclodextrin at $30^{\circ}C$. The conductivity plot for both binary mixtures shows a single break from which the mixed critical micelle concentration and degree of micelle ionization were computed. From the slope of the conductivity curve, the equivalent ionic conductivities of the monomeric, associated, and the micelle states were calculated and discussed with respect to the surfactant-cyclodextrin complexation in the whole mole fraction range of both surfactant binary mixtures. The association constant K between the respective monomeric surfactant and cyclodextrin cavity of fixed 4 mM cyclodextrin was computed by considering 1:1 association from the surface tension measurement. A comparison among the K values for HTAB-cyclodetrin, TTAB-cyclodextrin, and TTPB-cyclodextrin shows that the former complexation is significantly stronger in comparison to the other ones due to the longer hydrophobic tail.