• Title/Summary/Keyword: Degradation time

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Degradation of the Pd catalytic layer electrolyte in dye sensitized solar cells (염료감응태양전지에서 Pd 촉매층의 전해질과의 반응에 따른 특성 저하)

  • Noh, Yunyoung;Song, Ohsung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.4
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    • pp.2037-2042
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    • 2013
  • A TCO-less palladium (Pd) catalytic layer on the glass substrate was assessed as the counter electrode (CE) in a dye sensitized solar cell (DSSC) to confirm the stability of Pd with the $I^-/I_3{^-}$electrolyte on the DSSC performance. A 90nm-thick Pd film was deposited by a thermal evaporator. Finally, DSSC devices of $0.45cm^2$ with glass/FTO/blocking layer/$TiO_2$/dye/electrolyte(10 mM LiI + 1 mM $I_2$ + 0.1 M $LiClO_4$ in acetonitrile solution)/Pd/glass structure was prepared. We investigated the microstructure and photovoltaic property at 1 and 12 hours after the sample preparation. The optical microscopy, field emission scanning electron microscopy (FESEM), cyclic voltammetry measurement (C-V), and current voltage (I-V) were employed to measure the microstructure and photovoltaic property evolution. Microstructure analysis showed that the corrosion by reaction between the Pd layer and the electrolyte occurred as time went by, which led the decrease of the catalytic activity and the efficiency. I-V result revealed that the energy conversion efficiency after 1 and 12 hours was 0.34% and 0.15%, respectively. Our results implied that we might employ the other non-$I^-/I_3{^-}$electrolyte or the other catalytic metal layers to guarantee the long term stability of the DSSC devices.

A Policy of Page Management Using Double Cache for NAND Flash Memory File System (NAND 플래시 메모리 파일 시스템을 위한 더블 캐시를 활용한 페이지 관리 정책)

  • Park, Myung-Kyu;Kim, Sung-Jo
    • Journal of KIISE:Computer Systems and Theory
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    • v.36 no.5
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    • pp.412-421
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    • 2009
  • Due to the physical characteristics of NAND flash memory, overwrite operations are not permitted at the same location, and therefore erase operations are required prior to rewriting. These extra operations cause performance degradation of NAND flash memory file system. Since it also has an upper limit to the number of erase operations for a specific location, frequent erases should reduce the lifetime of NAND flash memory. These problems can be resolved by delaying write operations in order to improve I/O performance: however, it will lower the cache hit ratio. This paper proposes a policy of page management using double cache for NAND flash memory file system. Double cache consists of Real cache and Ghost cache to analyze page reference patterns. This policy attempts to delay write operations in Ghost cache to maintain the hit ratio in Real cache. It can also improve write performance by reducing the search time for dirty pages, since Ghost cache consists of Dirty and Clean list. We find that the hit ratio and I/O performance of our policy are improved by 20.57% and 20.59% in average, respectively, when comparing them with the existing policies. The number of write operations is also reduced by 30.75% in average, compared with of the existing policies.

Preservation Values and Effects on Cleaning and Adhesive Agents for Plastic Artifacts (플라스틱 작품의 보존 가치 및 세척제와 접착제의 효능 평가)

  • Chung, Yong Jae;Yu, Ji A;Kang, Dai Ill
    • Journal of Conservation Science
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    • v.29 no.2
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    • pp.127-138
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    • 2013
  • Plastic, widely used as a material for contemporary art, get damaged as directly exposed to temperature, humidity, ultra violet, etc. And it is very quickly damaged in early time, once damaged, it can't recover into original state. But like this characteristics, there is a few advanced research in Korea. So this study deal with a rising value of plastic artifacts in other country, United Kingdom and France, current conservation state, identification and cleaning method. Also 5 types of cleaners(distilled water, ethanol, acetone, eraser) and adhesives(cyanoacrylate, epoxy, acrylic, chloroprene rubber) were evaluated by produced plastics(PVC, PE, PP, PS, PU). As a result of experiment, ethanol and acetone that were previous evaluated in other research performed in other country are the best cleaner. Result of degradation after adhesive, cyanoacrylate and epoxy resin showed better performance and stability. As a basic research, this study is expected that can be used in future researches.

Anaerobic Digestion of Fish Offal(II) : Evaluation of Biodegradability Using Biochemical Methane Potential (생선 폐기물의 혐기성 소화 처리(II) : Biochemical Methane Potential을 이용한 생분해도 평가)

  • Jeong Byung-Gon
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.9 no.3
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    • pp.154-159
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    • 2006
  • It is essential to understand the decomposition characteristics for developing the optimum anaerobic digestion system of organic wastes. In this study, BMP (Biochemical Methane Potential) test using serum bottle was conducted to evaluate the anaerobic degradability of fish offal. 3 different groups of fish offal including waste from mackerel and hairtail handling except viscera and fish viscera were chosen for the substrates. Grinded fish offal was transferred anaerobically to serum bottle in amounts of 50 ml, 100 ml and 150 ml, respectively. BMP test was carried out in triplicate. Cumulative methane production and methane production rate depending on incubation time were evaluated. These results varied depending on substrate characteristics. The average values of ultimate methane yield ranged between $420ml{\cdot}CH_4/g{\cdot}VS$ and $490ml{\cdot}CH_4/g{\cdot}VS$, and the methane production and degradation rate of viscera were higher than those of other parts of fish offal. According to the analysis of elemental composition, average C/N ratio of fish offal used in this study was 5.2. Theoretical ultimate methane yield calculated from elemental composition was $522ml{\cdot}CH_4/g{\cdot}VS$. Biodegradability was calculated as 0.847.

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Decomposition Characteristics and Seedling Growth of Common Reed (Phragmites australis) by Salt Concentration in Saemangeum Reclaimed Land (새만금 간척지에서 염농도에 따른 갈대(Phragmites australis) 유묘 생장 및 분해 특성)

  • Oh, Yang-Yeol;Kim, Sun;Ryu, Jin-Hee;Lee, Su-Hwan;Lee, Jung-Tae;Bae, Hui-Su;Kim, Young-Joo;Kim, Kil-Young
    • Journal of Environmental Science International
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    • v.28 no.12
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    • pp.1061-1069
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    • 2019
  • Common reed (Phragmites australis) is widespread in reclaimed land and wetland habitats. Every year, the common reed produces extensive colonies by means of underground rhizomes and ground-surface stolons. From an agricultural point of view, the common reed's large biomass is a good material for supplying organic matter. However, it has not yet been studied in terms of seedling production, transplanting conditions, and decomposition characteristics in reclaimed land. Seeds were harvested from the native common reed in Saemangeum, South Korea, the previous year and stored on an open field. The seeds were sowed in the greenhouse at the beginning of April. Common reed decomposition was studied from June to September, with the use of coarse mesh (5 mm) stem litterbags, on three samping dates and with five replicate packs per sample. These packs were dug in five soil condition (low-salinity topsoil, subsoil, high-salinity topsoil, subsoil, paddy topsoil) to 0.2 m and 0.4 m depth. The highest germination rate of common reed seeds was observed in non-salt solution, but the exhibited germination rate was 70% at 9.38 dS m-1. The plant height of young reed decreased steadily with increasing salinity, but leaf number did not decrease by 9.38 dS m-1. The survival rate of the two-year-old reed was 83.3%, which was 35% higher than that of the one-year reed. The transplant success rate was 0% in the no vinyl mulching in the soil, but the first year and second year seedlings survived rates were 63% and 83.3%, respectively, in vinyl mulching. Common reed decomposition rates were faster low salinity than high salinity. All nutrient contents were found to fluctuate significantly with time by soil conditions. We also need to study the growth rate of reed transplanting seedlings by soil moisture contents and the comparison of degradation in common reed tissues.

Change in Chemical Composition of Acer mono Saps Collected in Different Region and Time Depending on Storing Period (저장기간에 따른 채취 지역 및 시기별 고로쇠 수액의 성분분석)

  • Kim, Ho-Yong;Kim, Seon-Hong;Gwak, Ki-Seob;Park, Mi-Jin;Choi, Won-Sil;Kang, Ha-Young;Choi, In-Gyu
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.1
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    • pp.75-84
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    • 2010
  • This study was performed to investigate change in chemical composition of Acer mono saps collected in Hamyang, Inje, Namyangju and Yeongwol depending on storing period. pH of A. mono sap was in the range of 4.43~5.68, and it was decreased rapidly with the increase of storing period. A. mono sap collected in Yeongwol in Feb. 22 contained 2.06% sucrose. Degradation of sucrose was occurred when storing period was extended, and it caused production of organic acid like pyruvic acid, lactic acid, acetic acid and ethanol. Detected minerals in A. mono sap were K, Ca, Na, Mg, P, Si, Al, Mn, Fe, Cu and Zn, however, K and Ca content reached 93%. A. mono sap collected in Inje in Mar. 03 contained 131.72 mg/${\ell}$, which was especially high K content among the A. mono sap. 1.55~3.50 mg/${\ell}$ of Ascorbic acid was found in the A. mono sap. Sap collected in early date was less degraded.

Study on Lean-Premixed Combustion Characteristics of Dual-Stage Burner (이중 연료 분사구조를 갖는 희박-예혼합 버너의 연소특성 연구)

  • Jang, Jae Hwan;Cho, Ju Hyeong;Kim, Han Seok;Lee, Sang Min;Kim, Min Kuk;Ahn, Kook Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.1
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    • pp.51-57
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    • 2013
  • This study aims to experimentally investigate the combustion characteristics of a lean premixed swirl-stabilized burner with dual-stage fuel injection arrays. The results show that a variation in the fuel distribution to fuel stages 1 (upstream) and 2 (downstream) produces a noticeable change in the NOx and CO emissions. Reducing the confined ratio, defined as the ratio of the nozzle exit diameter to the liner diameter, may reduce NOx and CO emissions owing to reduced combustion loading and longer residence time, respectively. A nozzle exit velocity of 30 m/s shows the optimum characteristics in terms of NOx and CO emissions and flame stability: increasing or decreasing the nozzle exit velocity leads to a degradation in emissions or flame stability, respectively.

Supergene Alteration of High-Ca Limestone from the Pungchon Formation (풍촌층 고품위 석회석의 표성변질)

  • Oh Sung Jin;Kim Kyong Jin;Noh Jin Hwan
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.2
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    • pp.135-144
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    • 2005
  • In the high-Ca limestone zone of the Pungchon Formation of the Lower Chosun Supergroup, cryptocrystalline alterations with reddish brown color occur as fissure-fillings or coatings, which was originated from the upper formation, i. e., the Hwajeol Formation. The precipitates result in degradation and contamination of the high-Ca limestone ore in grade and quality, showing characteristic occurrence and mineral composition typical of suggesting a supergene origin. Chalcedonic quartz, kaolinite, illite, goethite and hematite are constituting a characteristic authigenic mineral assemblage and, in places, smectite is less commonly included in the weathering product. In addition to these authigenic phases, some detrital minerals such as mica and orthoclase constituting relatively coarser grains are also rarely present in the supergene alterations. A rather complex clay facies consisting of kaolinite, illite and smectite in the alterations seems to correspond to the typical clay composition of the reported residual pedogenic soils by limestone weathering. The cryptocrystalline weathering product is partly altered to stilbite, a characteristic hydrothermal zeolite, in places, by the hydrothermal contact of late stage. The time of formation and infiltration of the supergene alterations seems to correspond to the stage just after the epithermal alteration of the Pungchon Limestone, i. e., an early Jurassic age. The supergene alteration, which may imply the stage of uplifting, weathering and erosion of the Chosun Supergroup, appears to have undergone at an oxygen-rich environment in descending water of meteoric origin by means of a chemical leaching and diffusion.

Study on Aging Characteristics Depending on the Utilized Mordants of Dyed Restoration Paper for Paper Conservation (지류보존처리를 위한 염색보수지의 매염제에 따른 열화특성 연구)

  • Jee, Joo-Yeon;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.29 no.1
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    • pp.47-54
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    • 2013
  • The following study tests for the effects of mordants on the production of restoration papers during the conservation process of damaged paper artifacts. For this, four different types of synthetic mordants that are being marketed currently ($K_2CO_3$, $AlK(SO_4)_2{\cdot}12H_2O$, $Cu_2SO_4{\cdot}5H_2O$, $FeSO_4$) were selected to produce samples for measuring variable properties through artificial degradation. The research conducts tests for changes in color, tensile index, and pH level (degree of acidity). The results for changes in color have shown that the value of ${\Delta}E^*ab$ of $K_2CO_3$ mordant sample was the highest, and the tests for tensile index have shown that the strength of dyeing sample was decreased in accordance with the aging time, but Changes according to the mordant was not evident. Finally, the findings for pH level have shown that samples with $Cu_2SO_4{\cdot}5H_2O$ and $FeSO_4$ have pH levels drop below 6. As a result, the research have concluded that mordants used for dyeing restoration paper were identified to have an affect in the dyeing and aging characteristics of the paper.

Dissolution Profile Analysis of Hydroxypropyl Methylcellulose-based Vitamin C Tablets (Hydroxypropyl methylcellulose를 활용한 비타민 C 지속성 정제의 용출 특성 분석)

  • Cha, Ja-Hyun;Hong, Jun-Kee;Lee, Sung-Wan;Cha, Jae-Uk;Ko, Won-Hwa;Baek, Hyon-Ho;Park, Hyun-Jin
    • Korean Journal of Food Science and Technology
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    • v.44 no.3
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    • pp.274-279
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    • 2012
  • The objective of this study was to develop oral matrix tablets for the sustained release of vitamin C. In this study hydroxypropyl methylcellulose (HPMC) has been utilized as an excipient, as it is one of the most widely used polymers, for use during long periods of time in formations. The vitamin C tablet formulation depends on the molecular weight and concentration of sustained-delivery in HPMC. Anti-oxidants have been added as a dissolution medium in order to prevent vitamin C degradation in water. The dissolution test was carried out in a distilled water medium, and the release model equation was applied to analyze the vitamin C release pattern. The results demonstrated that the release and lasting power of vitamin C tablets, containing HPMC, lasted for more than 12 h.