• Title/Summary/Keyword: Degradation temperature

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A Study on Stress Corrosion Cracking Evaluation with Material Degradation of High Temperature Components (고온부재의 재질열화에 따른 응력부식균열 평가에 관한 연구)

  • Park, Jong-Jin;Yu, Ho-Seon;Jeong, Se-Hui
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.20 no.4
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    • pp.1123-1132
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    • 1996
  • It has been reported that high temperature structural components represent the phenomenon of material degradation according to a long term service under high temperature and pressure. Especially, fossile power plant components using the fossil fuel and heavy oil are affected by dewpoint corrosion of $H_2SO_4$produced during a combustion. Therefore, the service materials subjected to high temperature and pressure may occur the stress corrosion cracking. The object of this paper is to investigate SCC susceptibility according to the material degradation of the high temperature structural materials in dewpoint corrosive environment-$H_2SO_4$.The obtained results are summarized as follows : 1) In case of secondary superheater tube, the fractograph of dimple is observed at the concentration of $H_2SO_4$-5%. When the concentration of $H_2SO_4$ is above 10%, the fracture mode is shifted from a transgranular fracture to an quasi-intergranular fracture according to the increment of concentration. 2) In the relationship between [$\Delta$DBTT]$_sp$ and SCC susceptibility, it is confirmed that the greater material degradation degree is, the higher SCC susceptibility is. In addition, it can be known that SP test is useful test method to evaluate SCC susceptibility for high temperature structural components. 3) When [$\Delta$DBTT]$_sp$ is above 17$17^{\circ}C$ the SCC fracture behavior is definitely observed with SCC susceptibility of above 0.4.

The research about the physical properties and flexural strength changed by Low Temperature Degradation of TZP monolithic all-ceramic crown block to make bio-prosthetic dentistry (치과용 생체보철물 제작을 위한 TZP 단일구조 전부도재관 블럭의 물성과 저온열화 후 굴곡강도에 관한 연구)

  • Lee, Jong-Hwa;Park, Chun-Man;Song, Jae-Sang;Lim, Si-Duk;Kim, Jae-Do;Kim, Byung-Sik;Hwang, In-Whan;Lee, Sung-Kuk
    • Journal of Technologic Dentistry
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    • v.34 no.2
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    • pp.83-93
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    • 2012
  • Purpose: The objective of this study is to find out physical properties and the flexural strength changed by the low temperature degradation of the block which is needed to make bio-prosthetic dentistry which is better than feldspar affiliated ceramic made by building up ceramic powder and also to apply this to the clinical use of zirconia monolithic all-ceramic crown. Methods: Flexural strength of each sample was evaluated before and after the Low Temperature Degradation, and physical properties of the Tetra Zirconia Block containing 3mol % was evaluated as well. The average and standard deviation of each experimental group were came out of the evaluation. Statistical package for social science 18.0 was used for statistics. Results: The average density of the monolithic all-ceramic crown was $6.0280{\pm}0.0147g/cm$, the relative density was 99.01 %. When the sample was sintered at $1480^{\circ}C$ the diameter of average particle was $396.62{\pm}33.71nm$. All the samples had no monolithic peak after XRD evaluation but only had tetragonal peak. There were statistically significant differences in the result of flexural strength of the samples evaluated after and before the low temperature degradation, the flexural strength before the low temperature degradation was $1747.40{\ss}{\acute{A}}$, at the temperature of $130^{\circ}C$ the flexural strength after the low temperature degradation was 1063.99MPa (p<0.001). There was statistically significant difference in the result of strength of 1020.07MPa after the low temperature degradation at the temperature of $200^{\circ}C$ (p<0.001). Conclusion: The block which was made for this evaluation possesses such an excellent strength among dental restorative materials that it is thought to have no problems to use for tetragonal zirconia polycrystal.

Evaluation of the Ductile-Brittle Transition Behavior of fracture Toughness by Material Degradation (열화에 따른 파괴인성치의 연성-취성 천이거동 평가)

  • 석창성;김형익;김상필
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.5
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    • pp.140-147
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    • 2003
  • As the huge energy transfer systems like as nuclear power plant and steam power plant are operated for a long time at a high temperature, mechanical properties are changed and ductile-brittle transition temperature is raised by degradation. So it is required to estimate degradation in order to assess the safety, remaining life and further operation parameters. The sub-sized specimen test method using surveillance specimen was developed for evaluating the integrity of metallic components. In this study, we would like to present the evaluation technique of the ductile-brittle transition temperature by the sub-sized specimen test. The four classes of the thermally aged 1Cr-1Mo-0.25V specimens were prepared using an artificially accelerated aging method. The tensile test and fracture toughness test were performed. The results of the fracture toughness tests using the sub-sized specimens were compared with the evaluation technique of the ductile-brittle transition temperature.

A Study on Dye Variation Extracted from Dyed Textile with Gardenia degraded at HIgh temperature after X-ray Irradiation (X-선 조사 후 고온 열화된 치자 염직물에서 추출한 색소 변이 연구)

  • Da Young Youn;Hae Jin Park;Se Eun Park;Seon Hong Heo;Su Bin Lim;Yong Jae Chung
    • Journal of Radiation Industry
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    • v.18 no.1
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    • pp.53-61
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    • 2024
  • This study explores the effects of X-ray irradiation for biological control and high-temperature degradation on dye stability in dyed textiles with Gardenia. To evaluate this study, optimal extraction solvents for these textiles were identified by comparing them with a crocin standard solution. Extraction using pyridine closely matched crocin. The study then assessed the stability of X-ray irradiation and high-temperature degradation on these textiles. Transparent yellow dyes were observed in all samples. Color differences were found to increase at higher irradiation doses and longer degradation periods. While UV spectroscopy spectra showed broadening and lowering trends with higher irradiation doses and longer degradation periods, suggesting a reduction in colorant transition, mass spectrometry revealed minimal chemical changes. In conclusion, both X-ray irradiation and high-temperature degradation induced spectral changes without complete dye decomposition. Major colorants were consistently detected.

Low Temperature Degradation Behavior of $^{18}O$-Containing Y-TZP ($^{18}O$을 함유하는 X-TZP의 저온열화거동)

  • 김병국
    • Journal of the Korean Ceramic Society
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    • v.34 no.2
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    • pp.171-174
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    • 1997
  • It was experimentally identified, for the first time, that oxygen phonons play an important role in the low temperature degradation(tetragonallongrightarrowmonoclinic phase transformation) of yttria stabilized tetragonal zir-conia polycrystals (Y-TZP). The degradation accompanied by immersing the samples in the boiling water were markedly reduced by substituting of 18O for 16O in Y-TZP. This was attributed to the heavier mass of 18O which leads to the smaller probability to find oxygen atoms beyond certain critical displacements.

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Bio Sparging Column Experiment for Remediation of Diesel Contaminated Groundwater (디젤오염 지하수 정화를 위한 공기주입정화법 칼럼 실험)

  • Chang Soon-Woong;Lee Si-Jin;Song Jung-Hoon;Kwon Soo-Youl
    • Journal of Environmental Science International
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    • v.13 no.12
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    • pp.1059-1065
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    • 2004
  • Bio sparging experiments were conducted in a laboratory column to investigate the potential removal of diesel contaminated groundwater. The objectives in this study were (a) to determine the extent of diesel degradation in laboratory columns under supplement of nutrient; (b) to determine the effect of variation of air flow in the removal of diesel and (c) to evaluate the potential enhancement of diesel degradation as a function of temperature. Our results showed that the nutrient supplement and higher air flow greatly enhanced diesel degradation. However, the variation of water temperature examined slightly increased degradation rate of diesel fuel.

Temperature Distribution of Tracking Degradation Using IRR-Camera (적외선방사카메라를 이용한 트래킹열화 온도분포)

  • Jeong, Seung-Chun;Lim, Jang-Seob;Chen, Jong-Cheol;Jung, Woo-Seong;Lee, Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05a
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    • pp.59-63
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    • 2000
  • The conventional tracking testing as IEC-60587 is widely used in surface aging measurement of outside insulator because those testing can carry out very short time in Lab testing. Also IEC-60587 testing is able to offer the standard judgement of relative degradation level of outside HV machine. Therefore it is very useful method compare to previous conventional tracking testing method and effective Lab testing method. But surface discharges(SD) have very complex characteristics of discharge pattern so it is required estimation research to development of precise analysis method. In recent, the study of IIR-camera is carrying out discover of temperature of power equipment through condition diagnosis and system development of degradation diagnosis. In this study, SD occurred from IEC-60587 is measured with partial temperature distribution in real time, the degradation grade of SD is analyzed through produced patterns in IEC-60587 according to applied time.

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Effect of Water Impingement Conditions on the Degradation of Epoxy Coatings in Tap Water

  • Kim, D.H.;Yoo, Y.R.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.21 no.5
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    • pp.327-339
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    • 2022
  • The water-jet technique started by Bridgman can cut metal and alloys without harmful gas and fume. However, while this technique is convenient to cut metals and alloys, in the case of coated pipe, water jet induces the degradation of coatings on the pipes, and may facilitate structural failure, leakage, and loss of products. While there are many reports on the effect of water jet on cut metals and the damage of metallic materials, research on the effect of water impingement on the epoxy coatings has been little studied. In this work, we therefore control the velocity of water jet, distance between nozzle and specimen, and water temperature, and discuss the effect of water impingement on the epoxy coatings. Increasing water velocity and water temperature and reducing nozzle distance increased the degradation rates of three epoxy coatings were increased. Among three test parameters - water velocity, nozzle distance and water temperature, water temperature was relatively effective to increase the degradation rate of epoxy coatings.

Effect of Temperature on Electrochemical Degradation of Membrane in PEMFC (PEMFC 고분자 막의 전기화학적 열화에 미치는 온도의 영향)

  • Lee, Ho;Kim, Taehee;Son, Ik Jae;Lee, Jong Hyun;Lim, Tae Won;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.47 no.4
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    • pp.441-445
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    • 2009
  • Effect of temperature on membrane degradation in PEMFCs was studied. After cell operation at different temperatures($60{\sim}90^{\circ}C$) under accelerating degradation conditions(OCV, anode dry, cathode RH 65%) for 144 h, cell performance decreased from 12 to 35%. The results of FER in effluent water showed that this decrease in cell performance was caused by membrane degradation by the attack of $H_2O_2$ or oxygen radicals(${\cdot}OH$, $HO_2{\cdot}$) and that resulted in increase in gas crossover for radical formation. Radical formation on the electrode was confirmed by ESR. Activation energy of 66.2 kJ/mol was obtained by Arrhenius plot used to analyze the effect of temperature on membrane degradation. Increase of cell temperature enhanced gas crossover rate, radical formation rate and membrane degradation rate.

Impact of Plasma Induced Degradation on Low Temperature Poly-Si CMOS TFTs during Etching Process

  • Chang, Jiun-Jye;Chen, Chih-Chiang;Chuang, Ching-Sang;Yeh, Yung-Hui
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.519-522
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    • 2002
  • In this paper, we analyze the impact of plasma etching process induced device degradation on low temperature poly-Si TFTs. The results indicate the relationship between device degradation and PPID effect during plasma fabrication. The dual-gate structure, which is used to suppress leakage current, is also discussed in this research.

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