• Title/Summary/Keyword: Degradation rate

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Anaerobic Lipid Degradation Through Acidification and Methanization

  • Kim,, I-Jung;Kim, Sang-Hyoun;Shin, Hang-Sik;Jung, Jin-Young
    • Journal of Microbiology and Biotechnology
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    • v.20 no.1
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    • pp.179-186
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    • 2010
  • In biological wastewater treatment, high lipid concentrations can inhibit the activity of microorganisms critical to the treatment process and cause undesirable biomass flotation. To reduce the inhibitory effects of high lipid concentrations, a two-phase anaerobic system, consisting of an anaerobic sequencing batch reactor (ASBR) and an upflow anaerobic sludge blanket (UASB) reactor in series, was applied to synthetic dairy wastewater treatment. During 153 days of operation, the two-phase system showed stable performance in lipid degradation. In the ASBR, a 13% lipid removal efficiency and 10% double-bond removal efficiency were maintained. In the UASB, the chemical oxygen demand (COD), lipid, and volatile fatty acid (VFA) removal efficiencies were greater than 80%, 70%, and 95%, respectively, up to an organic loading rate of 6.5 g COD/l/day. No serious operational problems, such as significant scum formation or sludge washout, were observed. Protein degradation was found to occur prior to degradation during acidogenesis.

Review of advanced oxidation processes (AOPs) for treatment of pharmaceutical wastewater

  • Verma, Manisha;Haritash, A.K.
    • Advances in environmental research
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    • v.9 no.1
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    • pp.1-17
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    • 2020
  • Pharmaceutically active compounds (PhACs) have become an environmental havoc in last few decades with reported cases of antibiotic resistant bacteria (ARB) and antibiotic resistant genes (ARGs), lethal effects over aquatic organisms, interference in natural decomposition of organic matter, reduced diversity of microbial communities in different environmental compartments, inhibition of growth of microbes resulting in reduced rate of nutrient cycling, hormonal imbalance in exposed organisms etc. Owing to their potential towards bioaccumulation and persistent nature, these compounds have longer residence time and activity in environment. The conventional technologies of wastewater treatment have got poor efficiency towards removal/degradation of PhACs and therefore, modern techniques with efficient, cost-effective and environment-friendly operation need to be explored. Advanced oxidation processes (AOPs) like Photocatalysis, Fenton oxidation, Ozonation etc. are some of the promising, viable and sustainable options for degradation of PhACs. Although energy/chemical or both are essentially required for AOPs, these methods target complete degradation/mineralization of persistent pollutants resulting in no residual toxicity. Considering the high efficiency towards degradation, non-toxic nature, universal viability and acceptability, AOPs have become a promising option for effective treatment of chemicals with persistent nature.

Photocatalytic Degradation of Methylene Blue using $TiO_2$ Supported on Activated Carbon (TiO$_2$가 담지된 활성탄을 이용한 Methylene Blue의 광분해)

  • Lee, Jong-Dae;Lee, Tae-Jun;Cho, Kyong-Tae
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.2
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    • pp.153-159
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    • 2006
  • The photocatalytic degradation of methylene blue(MB) was investigated using $TiO_2$ as photocatalyst and UV radiation. $TiO_2$ supported with activated carbon(AC) was prepared by SOL-GEL method and depended on several parameters such as the mass ratio of $TiO_2/AC$, pH and experimental time. The presence of the anatase and rutile crystal phase was determined by XRD analyses of the prepared $TiO_2$. The degradation of MB with $TiO_2/AC$ was about 20% higher than that of AC alone. A variation of photodegradation was negligible under UV radiation conditions ( ${\geq}$ 40W). It was experimentally showed that the photodegradation rate was increased with increasing the amount of photocatalyst. The optimal catalyst was prepared by impregmation of $5wt%-TiO_2$ with AC and was calcined at $300^{\circ}C$, and showed about 99% removal efficiency for 3hrs.

Classification of stator coil degradation of traction motor by PD signal distribution analysis (PD 분포 분석에 의한 견인전동기 고정자 코일의 열화도 분류에 관한 연구)

  • Park, Seong-Hee;Lim, Jong-Ho;Jang, Dong-Uk;Park, Hyun-June;Kang, Seong-Hwa;Lim, Kee-Joe
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1183-1186
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    • 2004
  • Degradation and insulation failure of traction motor depend on the continuous stress imposed on it. And knowing on insulation condition is important thing for safety operation of EMU(electric multiple unit). In this paper, PD(partial discharge) characteristics for degradation analysis of stator coil is studied. For PD data acquisition, two models are made; one is normal condition coil, the other is aged condition coil. And PD data for discrimination were acquired from PD detector. And these data making use of a computer-aided discharge analyser, statistical and other discharge parameters is calculated to discrimination between different discharge sources. And also these parameter is applied to classify PD sources by neural networks. Neural Networks has good recognition rate for degradation of stator coil.

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A COMPARATIVE STUDY OF THE PROTECTION OF DHAINCHA (Sesbania aculeata) SEED MEAL AND FISH MEAL FROM RUMEN DEGRADATION USING NYLON BAG TECHNIQUE

  • Hussain, M.;Chowdhury, B.;Siddiqua, A.;Routh, C.K.;Saadullah, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.6 no.2
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    • pp.197-203
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    • 1993
  • The protection of dry matter and nitrogen from rumen degradation of dhaincha seed (Sesbania aculeate) meal was studied using nylon bag technique. The dhaincha seed meal was subjected to various heat treatments that included oven drying, autoclaving and boiling. Similar experiment was conducted with fish meal as reference for comparison. The oven-dried dhaincha meal was found to retain more dry matter and nitrogen than was found boiled or autoclaved meal. While autoclaving appeared to improve nitrogen and dry matter retention to some extent, boiling seemed to cause more loss of dry matter from nylon bag. Heat treatment caused high retention of nitrogen by fish meal. The calculated effective protein degradation was 80.4% and 83.2% for the oven dried fish meal and dhaincha seed meal whereas same values were 74.2% and 86.7% for autoclaved fish and dhaincha seed meal respectively at the outflow rate of 4.4% per hour. The in vitro study revealed higher digestibility for heat treated samples by pepsin. The dry matter, nitrogen and ash content of dhaincha seed meal were 85.93%, 5.93% and 7.31% respectively.

Microstructure of Cured Urea-Formaldehyde Resins Modified by Rubber Latex Emulsion after Hydrolytic Degradation

  • Nuryawan, Arif;Park, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.5
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    • pp.605-614
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    • 2014
  • This study investigated microstructural changes of cured urea-formaldehyde (UF) resins mixed with aqueous rubber latex emulsion after intentional acid etching. Transmission electron microscopy (TEM) was used in order to better understand a hydrolytic degradation process of cured UF resins responsible for the formaldehyde emission from wood-based composite panels. A liquid UF resin with a formaldehyde to urea (F/U) molar ratio 1.0 was mixed with a rubber latex emulsion at three different mixing mass ratios (UF resin to latex = 30:70, 50:50, and 70:30). The rate of curing of the liquid modified UF resins decreased with an increase of the rubber latex proportion as determined by differential scanning calorimetry (DSC) measurement. Ultrathin sections of modified and cured UF resin films were exposed to hydrochloric acid etching in order to mimic a certain hydrolytic degradation. TEM observation showed spherical particles and various cavities in the cured UF resins after the acid etching, indicating that the acid etching had hydrolytically degraded some part of the cured UF resin by acid hydrolysis, also showing spherical particles of cured UF resin dispersed in the latex matrix. These results suggested that spherical structures of cured UF resin might play an important role in hindering the hydrolysis degradation of cured UF resin.

Photodegradation and Degradation Product of Piperophos (Piperophos의 광분해 및 분해생성물에 대한 연구)

  • 민경진
    • Journal of Food Hygiene and Safety
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    • v.19 no.2
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    • pp.97-103
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    • 2004
  • The present study was performed to investigate photodegradation rate constants and degradation products of piperophos by the USEPA method. The pesticide was very stable in 16 days exposure of sunlight from October 3 to 22, 2003 and humic acid had no sensitizing effect on the photolysis of each pesticide in sunlight. In the UV irradiation test, piperophos was rapidly degraded as increasing UV intensity. In case of UV irradiation with TiO$_2$ and with TiO$_2$ powder amount, degradation of piperophos was slower than UV irradiation. In order to identify photolysis product, the extracts of degradation product was analyzed by GC/MS. The mass spectrum of photolysis product of piperophos was at m/z 166. It was suggested that the photolysis products of piperophos was O, O-dipropyl phosphorodithioate.

Evaluation of Degradation Behavior of the Long-Term Serviced Boiler Header (장기 사용 보일러 헤더의 열화거동 평가에 관한 연구)

  • Gwon, Jae-Do;Bae, Yong-Tak;Choe, Seong-Jong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.7 s.178
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    • pp.1673-1680
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    • 2000
  • The degradation of a boiler header constructed by a material, 1Cr-0.5Mo steel in a fossil power plant is observed when the header is exposed for a long period to the high temperature and pressure. The present investigations are for evaluating the effect of the degradation on the material, such as its strength changes. Reheat-treated metal is used to compare the mechanical properties of the degraded and that of reheat-treated materials. Through the investigation, following results are obtained 1) the area ratio of ferrite in the reheat-treated material is larger than that of the degraded material, 2) the hardness and tensile strength of the degraded material are lower than that of the reheat-treated material, 3) the ductile-brittle transition temperature(DBTT) increased toward high temperature region, 4) the fatigue crack growth rate(FCGR) of the degraded material is higher than that of the reheat-treated material in the region of low ΔK value while FCGR of the both materials are similar in high ΔK region.

The Stockpile Reliability of Propelling Charge for Performance and Storage Safety using Stochastic Process (확률과정론을 이용한 추진장약의 성능과 저장안전성에 관한 저장신뢰성평가)

  • Park, Sung-Ho;Kim, Jae-Hoon
    • Journal of Korean Society for Quality Management
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    • v.41 no.1
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    • pp.135-148
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    • 2013
  • Purpose: This paper presents a method to evaluate the stockpile reliability of propelling charge for performance and storage safety with storage time. Methods: We consider a performance failure level is the amount of muzzle velocity drop which is the maximum allowed standard deviation multiplied by 6. The lifetime for performance is estimated by non-linear regression analysis. The state failure level is assumed that the content of stabilizer is below 0.2%. Because the degradation of stabilizer with storage time has both distribution of state and distribution of lifetime, it must be evaluated by stochastic process method such as gamma process. Results: It is estimated that the lifetime for performance is 59 years. The state distribution at each storage time can be shown from probability density function of degradation. It is estimated that the average lifetime as $B_{50}$ life is 33 years from cumulative failure distribution function curve. Conclusion: The lifetime for storage safety is shorter than for performance and we must consider both the lifetime for storage safety and the lifetime performance because of variation of degradation rate.

Degradation of Phenanthrene by Bacterial Strains Isolated from Soil in Oil Refinery Fields in Korea

  • KIM JEONG DONG;SHIM SU HYEUN;LEE CHOUL GYUN
    • Journal of Microbiology and Biotechnology
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    • v.15 no.2
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    • pp.337-345
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    • 2005
  • The degradation of phenanthrene, a model PAH compound, by microorganisms either in the mixed culture or individual strain, isolated from oil-contaminated soil in oil refmery vicinity sites, was examined. The effects of pH, temperature, initial concentration of phenanthrene, and the addition of carbon sources on biodegradation potential were also investigated. Results showed that soil samples collected from four oil refinery sites in Korea had different degrees of PAH contamination and different indigenous phenanthrene-degrading microorganisms. The optimal conditions for phenanthrene biodegradation were determined to be 30$^{circ}C$ and pH 7.0. A significantly positive relationship was observed between the microbial growth and the rate of phenanthrene degradation. However, the phenanthrene biodegradation capability of the mixed culture was not related to the degree of PAH contamination in soil. In low phenanthrene concentration, the growth and biodegradation rates of the mixed cultures did not increase over those of the individual strain, especially IC10. High concentration of phenanthrene inhibited the growth of microbial strains and biodegradation of phenanthrene, but was less inhibitory on the mixed culture. Finally, when non-ionic surfactants such as Brij 30 and Brij 35 were present at the level above critical micelle concentrations (CMCs), phenanthrene degradation was completely inhibited and delayed by the addition of Triton X100 and Triton N101.