• Title/Summary/Keyword: Degradation rate

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Degradation Monitoring of Visible Channel Detectors on COMS MI Using Moon Observation Images (달 관측 영상을 이용한 천리안위성 기상탑재체 가시채널 검출기의 성능감쇄 분석)

  • Seo, Seok-Bae;Jin, Kyoung-Wook
    • Korean Journal of Remote Sensing
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    • v.29 no.1
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    • pp.115-121
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    • 2013
  • The first geostationary satellite in Korea, COMS (Communication, Ocean, and Meteorological Satellite), has been operating properly since its successful completion of the IOT (In Orbit Test). COMS MI (Meteorological Imager) acquires Earth observation images from visible and infrared channels. This paper describes a method to compute the degradation of the COMS visible detectors and the result of the degradation during the two years of the operation. The visible channel detectors' performance was determined based on the comparison between the instrument-based measurements and ROLO model-based values. The degradation rate of the visible channel detectors of COMS MI showed a normal condition.

Degradation and Stabilization of Methionine Enkephalin and $[D-Ala^2]-methionine$ Enkephalinamide in the Corneal Extracts of Rabbits (토끼의 각막 추출액 중 메치오닌엔케팔린 및 [D-알라$^2$-메치오닌엔케팔린아미드의 분해 및 안정화)

  • Lee, Chi-Ho;Lee, Kyoung-Jin;Chun, In-Koo;Sung, Young-Gi;Shin, Young-Hee
    • Journal of Pharmaceutical Investigation
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    • v.24 no.1
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    • pp.1-9
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    • 1994
  • In order to study systemic peptide delivery through the ocular route, the stabilities of methionine enkephalin (Met-Enk) and $[D-ala^2]-methionine$ enkephalinamide (YAGFM) in the corneal extracts of rabbits were investigated using reversed phase HPLC. Met-Enk was found to be hydrolyzed most rapidly in the corneal epithelium, but YAGFM was relatively stable. Aminopeptidases appeared to contribute over 60% to the degradation of Met-Enk and the degradation rate of Met-Enk followed the first order kinetics. The half-lives of Met-Enk in the extracts of the corneal epithelium and endothelium were 36 and 673 min, respectively. From the effects of enzyme inhibitors, it was found that the application of the mixture of amastatin, thimerosal and EDTA was very useful for the inhibition of peptide degradation.

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Isolation and Characterization of Nonylphenol-degrading Bacteria

  • Yu, Dae-Ung;Kim, Dong-Myung;Chung, Yong-Hyun;Lee, Yang-Bong;Kim, Young-Mog
    • Fisheries and Aquatic Sciences
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    • v.15 no.2
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    • pp.91-97
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    • 2012
  • To isolate a nonylphenol (NP)-degrading bacterium, we isolated a single colony from the NP-degrading microbial consortium SW-3, which was previously isolated from an aqueous environment. Ten colonies that exhibited different cell morphologies were isolated and the strains were named SW-3-A, -B, -C, -D, -E, -F1, -F2, -G, -H, and -I. The ability of isolates to degrade NP was evaluated by kinetic analysis by the constant of NP degradation rate ($k_1$) and the half-life time of NP degradation ($t_{1/2}$). SW-3-F1, -F2, -G, and -I strains were superior at degrading NP. The $k_1$ and $t_{1/2}$ values of the four strains were sixfold higher and one-sixth lower, respectively, than those of the consortium strain. Additionally, SW-3-F1, -G, and -I strains were tested for their ability to degrade NP during coculture. NP degradation by coculture with a combination of all three strains was inferior to that of culture conducted with single isolates, suggesting that the three strains are antagonistic toward each other during NP degradation.

Preparation of Fe-AC/$TiO_2$ composites and pH dependence of their Photocatalytic activity for methylene blue

  • Meng, Ze-Da;Zhang, Kan;Oh, Won-Chun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.5
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    • pp.268-276
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    • 2009
  • In this study, activated carbon (AC) was treated with ferric ion by a sol-gel method. The compound (Fe-AC) was employed for the preparation of Fe-activated carbon/$TiO_2$, (Fe-AC/$TiO_2$) composites. The prepared Fe-AC/$TiO_2$ composites were characterized with surface properties, structural crystallinity, elemental identification and photocatalytic activity. The SEM results showed that ferric compounds and titanium dioxide were fixed onto the AC surfaces. The XRD results showed that Fe-AC/$TiO_2$ composites mostly contained anatase phase. EDX showed the presence of C, O, and Ti with Fe peaks in all samples. Its photocatalytic degradation effect was evaluated with the degradation behavior of the methylene blue (MB) solution. MB degradation could be attributed to the synergetic effects of adsorption, photo-degradation of $TiO_2$ and photo-Fenton of Fe component. The degradation rate for this photocatalysis was evaluated as a function of the concentration of the dye, the amount of $TiO_2$ and the pH. Photocataytic activity is good at activity pH.

Degradation of Thermal Creep by Hydrides of Zr-2/5Nb Pressure Tube (Zr-2.5Nb 압력관의 수소화물에 의한 고온 크리프의 열화거동)

  • Oh, Dong-Joon;Ma, Young-Wha;Yoon, Kee-Bong;Kim, Young-Suk
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.12 s.255
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    • pp.1526-1533
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    • 2006
  • The aim of this research was to confirm the existence of the thermal creep degradation by hydrides of Zr-2.5Nb pressure tube materials. Small punch creep tests were performed to obtain the relationship between a creep displacement and a loading period at $300^{\circ}C$. A creep stress and a creep strain rate were also converted from the previous results. The creep material constants and the creep stress exponents at the different hydride contents were compared. Finally the hydrides of the axial and circumferential section were observed using OM, SEM and TEM. The following conclusions were made: 1) The degradation of the thermal creep by hydrides was existed and it strongly depended on the hydride contents. 2) As the hydride contents were increased, the creep stress exponents (m) were also increased. 3) Even though the hydride was not precipitated in 50 ppm materials at $300^{\circ}C$, the degradation of thermal creep was found. Therefore, it was believed that this phenomenon strongly related to the hydride precipitation at room temperature.

Degradation of Chlorophenols and Phenol Mixtures by Cooperative Activities of Chlorophenol-degrading Strains

  • Bae, Hee-Sung;Cho, Young-Gyun;Lee, Sung-Taik
    • Journal of Microbiology and Biotechnology
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    • v.7 no.1
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    • pp.43-48
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    • 1997
  • Three strains capable of degrading a chlorophenol were isolated by selective enrichment from soils contaminated with industrial wastewater. A Pseudomonas solanacearum TCP114 could use 2,4,6-trichlorophenol (TCP) as sole carbon and energy source, while two strains of Pseudomonas testosteroni CPW301 and Arthrobacter ureafaciens CPR706 could use 4-CP. All isolates also grew well on phenol. The degradation of one component by a pure strain was strongly affected by the presence of other compounds in the medium, CPW301 and CPR706 entirely lost the ability to degrade 4-CP and phenol in the presence of TCP. TCP114 also lost the ability to degrade phenol when 4-CP was added to the culture medium. These restrictions on the degradability could be overcome by employing defined mixed cultures (TCP114 and one strain of 4-CP degrading strains). All three components were successfully degraded by defined mixed cultures through their cooperative activities. It was also demonstrated that defined mixed cultures could be immobilized by using calcium alginate for the semi-continuous degradation of the three component mixture. Immobilization could not only accelerate the degradation rate, but also allowed the reuse of the cell mass several times without loss of the cells' degrading capabilities.

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Degradation of Polymer Electrolyte Membrane under Low Current/Low Humidity Conditions (저전류/저가습 조건에서 고분자전해질 막 열화)

  • Kim, Tae-Hee;Lee, Jung-Hun;Lee, Ho;Lim, Tae-Won;Park, Kwon-Pil
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.2
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    • pp.157-163
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    • 2007
  • During PEMFC operation, low current and low humidity conditions accelerate the degradation of perfluorosulfonic acid membrane. But, there have been no studies that clearly explain why these conditions accelerate the membrane degradation. In this study, the hydrogen permeability through the membrane, I-V polarization of MEA, fluoride emission rate(FER) in effluent water were measured during cell operation under low current densities and low relative humidity(RH). The experimental results were evaluated with oxygen radical mechanism the most commonly known for membrane degradation. It seems that low RH of anode is a good condition for $H{\cdot}$ radical formation on the Pt catalyst and the low current condition accelerates the $H{\cdot}$ to form $HO_2{\cdot}$ radical attacking the polymer membrane.

Effect of Power Intensity on the Phenol and Chlorinated Compounds Mixture Solutions by Ultrasound (초음파로 페놀 분해 시 염소계화합물의 첨가와 음향 강도의 영향)

  • Lim, Myunghee;Son, Younggyu;Yang, Jaekeun;Khim, Jeehyeong
    • Journal of Korean Society on Water Environment
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    • v.24 no.1
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    • pp.118-122
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    • 2008
  • Degradations of phenol and chlorinated compounds mixtures were studied with ultrasound of 20 kHz and 0.57, 1.14 W/mL. In presence of carbon tetrachloride (CT), degradation rate of phenol is faster than chloroform (CF), dichloromethane (DCM) and phenol solution. It is due to that CT generates of free chlorine (HOCl and $OCl^-$) from the sonochemical degradation and plays a role of hydrogen atom scavenger. CF and DCM are react with free chlorine, so amount of free chlorine is smaller than CT solution. The degradation rates of chlorinated compounds decreased with co-presence of phenol in the solution due to the distribution ultrasonic energy to both compounds. The measured chloride ion was lower than the theoretical concentration assuming complete degradation. This means not all the contaminants destructed went through complete degradation.

Photocatalytic degradation of textile dye CI Basic Yellow 28 wastewater by Degussa P25 based TiO2

  • Konecoglu, Gulhan;Safak, Toygun;Kalpakli, Yasemen;Akgun, Mesut
    • Advances in environmental research
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    • v.4 no.1
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    • pp.25-38
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    • 2015
  • Wastewaters of textile industry cause high volume colour and harmful substance pollutions. Photocatalytic degradation is a method which gives opportunity of reduction of organic pollutants such as dye containing wastewaters. In this study, photocatalytic degradation of C.I. Basic Yellow 28 (BY28) as a model dye contaminant was carried out using Degussa P25 in a photocatalytic reactor. The experiments were followed out at three different azo dye concentrations in a reactor equipped UV-A lamp (365 nm) as a light source. Azo dye removal efficiencies were examined with total organic carbon and UV-vis measurements. As a result of experiments, maximum degradation efficiency was obtained as 100% at BY28 concentration of $50mgL^{-1}$ for the reaction time of 2.5 h. The photodegradation of BY28 was described by a pseudo-first-order kinetic model modified with the langmuir-Hinshelwood mechanism. The adsorption equilibrium constant and the rate constant of the surface reaction were calculated as $K_{dye}=6.689{\cdot}10^{-2}L\;mg^{-1}$ and $k_c=0.599mg\;L^{-1}min^{-1}$, respectively.

Degradation of PDP Phosphors Under VUV Excitation (PDP 형광체의 진공 자외선 조사에 따른 열화 특성)

  • Lee, R.Y.;Lee, S.H.;KIm, Y.H.
    • Korean Journal of Materials Research
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    • v.12 no.9
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    • pp.735-739
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    • 2002
  • $(Y,Gd)BO_3$: Eu, $Zn_2$$SiO_4$ : Mn and $BaMgAl_{10}$ $O_{17}$ : Eu phosphors used in PDP were continuously irradiated by vacuum ultra violet generated from the penning gas (96%Ar+4%Xe) discharge and then the change of emitting intensity with time was investigated. The brightness of these phosphors decreased exponentially with VUV excitation time. The experimental data showed that the degradation rate increased in the order of $Zn_2$$SiO_4$ : Mn>(Y,Gd)$BO_3$: Eu>$BaMgAl_{10}$ $O_{17}$ : Eu phosphor. This different degradation property of phosphors was interpreted in terms of brightness saturation and stability against VUV irradiation. It was found that the degradation property of $(Y,Gd)BO_3$ : Eu red phosphor synthesized by ultrasonic thermal spray was superior to commercial phosphor.