• Title/Summary/Keyword: Degradation rate

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A Study on the Degradation Properties of MTBE in Solution using Ultrasound (초음파를 이용한 수용액 속의 MTBE 분해 특성 연구)

  • Kim, Heeseok;Yang, Inho;Oh, Jeill;Her, Nam Guk;Jeong, Sangjo
    • Journal of Korean Society on Water Environment
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    • v.25 no.4
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    • pp.522-529
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    • 2009
  • To supply safe drinking water to areas lacking in water supply and drainage system, such as rural area and military bases in proximity to Demilitarized Zone, effective method for treating organic contaminants such as MTBE is required. This study focuses on seeking optimal conditions for effective degradation of MTBE using a bath type ultrasound reactor. Effectiveness of MTBE degradation by ultrasound is dependent on the frequency, power, temperature, treatment volume, initial concentration, catalyst, etc. In this study the degradation rate of MTBE by ultrasound was proportional to power/unit volume ratio and removal is relatively more efficient for 0.1 mM than for 1 mM of MTBE solution. Efficiency of ultrasound treatment for 1 mM MTBE solution was enhanced under bath temperature of $30^{\circ}C$ compared to $4^{\circ}C$, but the temperature effect was negligible for 0.1 mM MTBE solution. Also for 0.1 mM MTBE solution, effect of catalyst such as $TiO_2$ and $Fe^0$ on treatment speed was negligible, and zeolite even increases the time taken for the degradation. Under these specific experimental conditions of this study, the most determinant factor for degradation rate of MTBE in solution was frequency and power of ultrasound. The results have shown that a continuous ultrasound reactor system can be used for small scale remediation of organically polluted groundwater, under optimal conditions.

Photocatalytic Degradation of Pheonol in UV/TiO2 Honeycomb Reactor (UV/TiO2 허니컴 반응기에서 페놀의 광산화 반응)

  • Han, Po-Keun;Park, Sang-Eun;Lee, Sang-Wha
    • Applied Chemistry for Engineering
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    • v.17 no.1
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    • pp.100-105
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    • 2006
  • The photocatalytic activity of phenol degradation was investigated with the variation of operating parameters in $UV/TiO_2$ honeycomb reactor. In the comparison of phenol degradation rates among various $TiO_2$, Ishihara (STS-02)-coated honeycomb exhibited a slightly higher photocatalytic activity than Degussa P25-coated honeycomb. On the other hand, honeycomb coated by alcohol-mixed $TiO_2$ (N Co.) did not exhibit any photocatalytic activity on phenol degradation. With the increase of Degussa P25 coating amounts, the honeycomb reactor exhibited the gradual increase of phenol degradation rates. The degradation rate of phenol over $UV/TiO_2$ (Degussa P25) honeycomb reactor was asymptotically increased up to 500 mL/min, subsequently followed by a slight decrease as the recirculation rate (100~700 mL/min) was increased. UV absorption at 269 nm was high due to partial degradation of phenol at initial reaction time because the honeycomb surface was pre-adsorbed by phenol prior to UV irradiation.

A Study on Disposal Diagnosis Algorithm of PV Modules Considering Performance Degradation Rate (태양광모듈의 성능저하율을 고려한 폐기진단 알고리즘에 관한 연구)

  • Park, Ji-Hyun;Lee, Hu-Dong;Tae, Dong-Hyun;Ferreira, Marito;Rho, Dae-Seok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.10
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    • pp.493-502
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    • 2019
  • Recently, the installation of renewable energy including PV systems in distribution systems has increased energetically to cope with climate change and energy shortages according to the government's policy of renewable energy 3020. On the other hand, the electrical performance and lifespan of PV modules installed outdoors can be decreased considerably due to a range of deterioration phenomena depending on the ambient environmental factors. To overcome these problems, replacement of degraded PV modules with new ones is increased before the lifespan guaranteed by the makers of PV modules. Therefore, this paper proposes a disposal diagnosis algorithm to evaluate the time interval of the optimal replacement for PV modules according to performance degradation rate of PV modules. In addition, this study modeled an economic evaluation, which is composed of the cost and benefit of PV systems. From the simulation results based on the proposed modeling and algorithm to consider the performance degradation rate specifically, the replacement approach was found to have the best B/C ratio in 10th year with a 3[%] degradation rate and the disposal diagnosis algorithm of PV modules are useful and practical tools for economic evaluations of the replacement of PV modules.

Photocatalytic Degradation of Trichloroethylene over Titanium Dioxides (이산화티탄에 의한 삼염화에틸렌의 광촉매 분해반응)

  • Lee, Yong-Doo;Ahn, Byung-Hyun;Lim, Kwon-Taek;Jung, Yeon-Tae;Lee, Gun-Dae;Hong, Seong-Soo
    • Applied Chemistry for Engineering
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    • v.10 no.7
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    • pp.1035-1040
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    • 1999
  • Photocatalytic degradation of trichloroethylene has been carried out with UV-illuminated $TiO_2$-coated pyrex reactor in gas phase. Three commercial $TiO_2$ oxides were used as catalysts. The effect of reaction conditions, initial concentration of trichloroethylene, concentration of oxidant and light intensity on the photocatalytic activity were examined. Anatase-type catalyst showed higher activity than rutile-type, but P-25 catalyst showed the highest activity. The degradation rate increased with the decrease of flow rate and initial trichloroethylene concentration. It was preferable to use air as an oxidant. In addition, reactants with the water vapor decreased the activity and the degradation rate increased with the increase of light intensity, but it was very low with solar light. Photocatalytic deactivation was not observed at low concentration of trichloroethylene.

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Study on the Microbial Degradation of Nicotine (1) -Isolation and Identification of Nicotinophiles (미생물에 의한 니코틴 분해 연구(1) -니코틴 분해세균의 분리 및 동정)

  • 강은희;윤경하
    • Journal of the Korean Society of Tobacco Science
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    • v.2 no.1
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    • pp.17-27
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    • 1980
  • From 143 sources of collected samples, the distribution of nicotinophiles were investigated and the biological characteristics as well as the rate of nicotine degradation were determined for the selected 34 strains which could grow successfully in the nicotine media, and one of the most effective strains was chosen and identified at the species level. Nicotinophils were distributed abundantly in the soils rich with organic materials, tobacco seed and root. The selected 34 strains were classified into 7 genus and identified with 4 strains of Arthrobacter, 11 strains of non-pigmented Pseudomonas, 2 strains of pigmented Pseudomonas, 6 strains of Alkaligenes, 5 strains Chromobacter 2 strains of Listeria and 4 strains of Achromobacter. Pseeudomonas and Alkaligenes were better than other genus in the rate of nicotine degradation and tobacco seed and root were also good sources for the isolation of effective nicotinophiles. Amnog 34 strains, strain NCT 27 which exhibited 97.l% of nicotine degradation rate was the best one for nicotine degradation and was indentified with Pseudomonas putida.

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DGA Gases related to the Aging of Power Transformers for Asset Management

  • Kweon, Dongjin;Kim, Yonghyun;Park, Taesik;Kwak, Nohong;Hur, Yongho
    • Journal of Electrical Engineering and Technology
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    • v.13 no.1
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    • pp.372-378
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    • 2018
  • Life management technology is required as the failure risk of aged power transformers increases. Asset management technology is developed to evaluate the remaining life, establish the replacement strategies, and decide the optimal investment based on the reliability and economy of power transformers. The remaining life assessment uses data such as installation, operation, maintenance, refurbishment, and failure of power transformers. The optimal investment also uses data such as maintenance, outage, and social costs. To develop the asset management system for power transformers, determining the degradation parameters related to the aging of power transformers and evaluating the condition of power transformers using these parameters are important. In this study, since 1983, 110,000 Dissolved Gas Analysis (DGA) data have been analyzed to determine the degradation parameters related to the aging of power transformers. The alarm rates of combustible gases ($H_2$, $C_2H_2$, $C_2H_4$, $CH_4$, and $C_2H_6$), TCG, CO, and $CO_2$ were analyzed. The end of life and failure rate (bathtub curve) of power transformers were also calculated based on the failure data from 1981 to 2014. The DGA gases related to discharge, overheating, and insulation degradation were determined based on alarm and failure rates. $C_2H_2$, $C_2H_6$, and $CO_2$ were discharge, oxidation, and insulation degradation parameters related to the aging of power transformers.

Multi-view Rate Control based on HEVC for 3D Video Services

  • Lim, Woong;Lee, Sooyoun
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.8
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    • pp.245-249
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    • 2013
  • In this paper, we propose two rate control algorithms for multi-view extension of HEVC with two rate control algorithms adopted in HEVC and analyze the multi-view rate control performance. The proposed multi-view rate controls are designed on HEVC-based multi-view video coding (MV-HEVC) platform with consideration of high-level syntax, inter-view prediction, etc. not only for the base view but also for the extended views using the rate control algorithms based on URQ (Unified Rate-Quantization) and R-lambda model adopted in HEVC. The proposed multi-view rate controls also contain view-wise target bit allocation for providing the compatibility to the base view. By allocating the target bitrates for each view, the proposed multi-view rate control based on URQ model achieved about 1.83% of average bitrate accuracy and 1.73dB of average PSNR degradation. In addition, about 2.97% of average bitrate accuracy and 0.31dB of average PSNR degradation are achieved with the proposed multi-view rate control based on R-lambda model.

Degradation of residual pharmaceuticals in water by UV/H2O2 advanced oxidation process (UV/H2O2 고도산화기술을 이용한 수중 잔류의약물질 제거)

  • Park, Chinyoung;Seo, Sangwon;Cho, Ikhwan;Jun, Yongsung;Ha, Hyunsup;Hwang, Tae-Mun
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.6
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    • pp.469-480
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    • 2019
  • This study was conducted to evaluate the degradation and mineralization of PPCPs (Pharmaceuticals and Personal Care Products) using a CBD(Collimated Beam Device) of UV/H2O2 advanced oxidation process. The decomposition rate of each substance was regarded as the first reaction rate to the ultraviolet irradiation dose. The decomposition rate constants for PPCPs were determined by the concentration of hydrogen peroxide and ultraviolet irradiation intensity. If the decomposition rate constant is large, the PPCPs concentration decreases rapidly. According to the decomposition rate constant, chlortetracycline and sulfamethoxazole are expected to be sufficiently removed by UV irradiation only without the addition of hydrogen peroxide. In the case of carbamazepine, however, very high UV dose was required in the absence of hydrogen peroxide. Other PPCPs required an appropriate concentration of hydrogen peroxide and ultraviolet irradiation intensity. The UV dose required to remove 90% of each PPCPs using the degradation rate constant can be calculated according to the concentration of hydrogen peroxide in each sample. Using this reaction rate, the optimum UV dose and hydrogen peroxide concentration for achieving the target removal rate can be obtained by the target PPCPs and water properties. It can be a necessary data to establish design and operating conditions such as UV lamp type, quantity and hydrogen peroxide concentration depending on the residence time for the most economical operation.

Pixel Circuit with High Immunity to the Degradation of TFTs and OLED for AMOLED Displays

  • Lin, Chih-Lung;Tu, Chun-Da
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.473-476
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    • 2008
  • A simple voltage compensation pixel circuit for AMOLED is produced using low temperature polycrystalline silicon (LTPS) technology. Its operation is verified by AIM-SPICE. Simulation results show that the pixel circuit has high immunity to variation of LTPS-TFT and reduces the drop in luminance due to the degradation of the OLED.

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In vitro 계에서의 Streptozotocin 분해 및 세포내 흡수

  • 박기숙;호지숙;정진호
    • Toxicological Research
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    • v.7 no.2
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    • pp.183-189
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    • 1991
  • Since streptozotocin has been known to be chemically stable only under acidic condition(pH 4), the spontaneous degradation and cellular uptake of streprozotocin in neutral incubation medium was determined by chemical assay. Streptozotocin levels in both phosphate buffered saline (pH 7.4) and Krebs-Henseleit buffer (pH 7.4) decreased with a half life of about 2 hours. The presence of erythrocytes or pepatocytes under the same buffers did not affect the streptozotocin degradation rate at all. However, streptozotocin levels in plasma isolated from rats decreased rapidly compared to those in neutral buffers.

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