• Title/Summary/Keyword: Degradation product

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Fermentation Characteristics, Tannin Contents and In vitro Ruminal Degradation of Green Tea and Black Tea By-products Ensiled at Different Temperatures

  • Kondo, Makoto;Hirano, Yoshiaki;Kita, Kazumi;Jayanegara, Anuraga;Yokota, Hiro-Omi
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.7
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    • pp.937-945
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    • 2014
  • Green and black tea by-products, obtained from ready-made tea industry, were ensiled at $10^{\circ}C$, $20^{\circ}C$, and $30^{\circ}C$. Green tea by-product silage (GTS) and black tea by-product silage (BTS) were opened at 5, 10, 45 days after ensiling. Fermentation characteristics and nutrient composition, including tannins, were monitored and the silages on day 45 were subjected to in vitro ruminal fermentation to assess anti-nutritive effects of tannins using polyethylene glycol (PEG) as a tannin-binding agent. Results showed that the GTS and BTS silages were stable and fermented slightly when ensiled at $10^{\circ}C$. The GTS stored at $20^{\circ}C$ and $30^{\circ}C$ showed rapid pH decline and high acetic acid concentration. The BTS was fermented gradually with moderate change of pH and acid concentration. Acetic acid was the main acid product of fermentation in both GTS and BTS. The contents of total extractable phenolics and total extractable tannins in both silages were unaffected by storage temperatures, but condensed tannins in GTS were less when stored at high temperature. The GTS showed no PEG response on in vitro gas production, and revealed only a small increase by PEG on $NH_3$-N concentration. Storage temperature of GTS did not affect the extent of PEG response to both gas production and $NH_3$-N concentration. On the other hand, addition of PEG on BTS markedly increased both the gas production and $NH_3$-N concentration at any ensiled temperature. It can be concluded that tannins in both GTS and BTS suppressed rumen fermentation, and tannins in GTS did more weakly than that in BTS. Ensiling temperature for both tea by-products did not affect the tannin's activity in the rumen.

Effect of Nutrient Nitrogen on the Degradation of Pentachlorophenol by White Rot Fungus, Phanerochaete chrysosporium

  • Chung, Nam-Hyun;Kang, Gu-Young;Kim, Gyu-Hyeok;Lee, Il-Seok;Bang, Won-Gi
    • Journal of Microbiology and Biotechnology
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    • v.11 no.4
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    • pp.704-708
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    • 2001
  • The effect of nutrient nitrogen on the degradation of pentachlorophenol (PCP) by Phanerochaete chrysosporium in a liquid culture was investigated. PCP disappeared at almost the same rate in both nutrient nitrogen-sufficient (NS) and -limited (NL) sttionary cultures. However, more pentachloroanisole (PCA) was accumulated in the NS culture than in the NL culture. The effect of nitrogen on the degradation of PCA was also tested in both cultures. PCA disappeared faster in the NL culture than in the NS culture, indicating that the lower accumulation of PCA during the degradation of PCP in the NL culture was due to the faster degradation of PCA in the NL culture than in the NS culture. In another experiment, PCA was added to shaking cultures rather than stationary cultures to search for any other metabolite(s). While no other metabolite but PCA was found in the NS stationary culture, 2,4,5,6-tetrachloro-2,5-cyclohexadiene-1,4-dione(TCHD) was found as the only indentifiable product in the NL shaking culture. Thus, PCP would appear to be metabolized to TCHD via PCa or directly oxidized to TCHD by lignin peroxidase. Since all the above results indicate that no innocuous metabolite was formed during the degradation of PCP by the fungus, it is quite feasible to use the fungus in the biotreatment of PCP.

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Analysis of the Degradation Products of Turmeric using GC-MS (GC-MS법을 이용한 울금의 퇴화물 분석)

  • Ahn, Cheun-Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.31 no.6 s.165
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    • pp.859-868
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    • 2007
  • Degradation products of the dye extracted from turmeric and the turmeric dyed textiles were examined by using GC-MS after 100 oven (OV) and $H_2O_2/UV/O_2$(PER) treatments for up to 28 days. Throughout the OV degradation times, 2-propenoic acid, 3-(2-hydroxyphenyl)- was found consistently, while isovanillin, and vanillic acid were newly detected. In 28 day PER degradation sample, feruloylmethane, 2-propenoic acid, 3-(2-hydroxyphenyl)-, benzoic acid, and vanillic acid were detected as well as isovanillin. Feruloylrnethane, and 2-propenoic acid, 3-(2-hydroxyphenyl)- were detected from the degraded fabric samples. With the absence of curcuminoids in the GC-MS result, the decreasing pattern of 2-propenoic acid, 3-(2-hydrokyphenyl)- reflect the degradation of curcuminoids in turmeric extraction with the progression of OV degradation times. It is suggested that isovanillin, feruloylmethane, 2-propenoic acid,3-(2-hydroxyphenyl)-, and vanillic acid are the probable fingerprint products for determining the turmeric dye from the badly faded archaeological textiles.

The Electrical De연세대학교 전기전자공학과gradation Rate of a Bi-2223 wires by the Various Transferred Current (수송전류에 따른 Bi-2223 선재의 전기적 열화)

  • Bae, Duck-Kweon;Lee, Sang-Jin;Bae, Joon-Han;Ko, Tae-Kuk;Park, Kyong-Yop
    • Proceedings of the KIEE Conference
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    • 2002.07b
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    • pp.831-834
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    • 2002
  • Several companies in the world are marketing superconducting wires, films and bulks. High-Tc superconducting systems using these superconductors are begun to commercialize. For the successful realization or commercialization of superconducting system used Bi-2223 wires, the database on the degradation of critical current is essentially needed. In this paper, the electrical degradation of a Bi-2223 wires is measured. The electrical degradation rate was measured after the certain time of continuous current transportation. Specimens have the length of 190cm and double-pancakes coil have the length of 10m were tested. Tested Bi-2223 wires are commercialized product has 115A of Ic. When the transportation current was 95% of Ie, the degradation of Ic was appeared after 5 hours of transportation time. When the transferred current is enough larger than Ic, Bi-2223 double pancake is damaged seriously.

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Degradation of the Herbicide, Alachlor, by Soil Microorganisms -Part I. Degradation in the flooded paddy soils- (제초제 Alachlor의 토양미생물에 의한 분해 -제일보(第一報). 담수답토양에서의 분해-)

  • Lee, Jae-Koo
    • Applied Biological Chemistry
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    • v.27 no.2
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    • pp.64-72
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    • 1984
  • Alachlor, 2-chloro-2, '6'-diethyl-N-(methoxymethyl) acetanilide, which had been incubated in the flooded paddy soils yielded 1-formyl-2,3-dihydro-7-ethylindole, 2,6-diethylaniline, 2,6-diethylacetanilide, 2,6-diethyl-N-(methoxymethyl) acetanilide, 2-hydroxy-2, '6'-diethyl-N-(methoxymethyl) acetanilide, and three unidentifiable compounds as its degradation products. The water-soluble products of Alachlor in soil suspensions increased with incubation periods and similar results were obtained from the incubation of Rhizoctonia solani, as verified by use of the ring $-^{14}C-$labeled Alachlor. Streptomyces lavendulae Ru 3340-8 produced 2-hydroxy-2, '6'-diethyl-N-(methoxymethyl) acetanilide as the major degradation product as much as 25%, whereas Bacillus brevis IFO 3331, Bacillus cruciviae, and Pseudomonas putida did not produce it.

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Calculation of The Core Damage & FP Release Behavior for The PHEBUS FPT0 Similar to Cold Leg Break Accident Using MELCOR

  • Park, Jong-Hwa;Cho, Song-Won;Kim, Hee-Dong
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05b
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    • pp.637-642
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    • 1996
  • This paper presents the analysis results for the core degradation processes and the fission product release of the PHEBUS FPT0 experiment using MELCOR1.8.3. The objective of this study is to assess models associated with the core damage and fission product behavior in MELCOR. The calculation results were much improved through sensitivity studies. Thermal/hydraulic behavior in the core and the circuit was well predicted under the intact core geometry. In non-eutectic model case. the UO$_2$ dissolution model in the MELCOR always showed such a tendency that the resulting dissolved UO$_2$ mass was small at the highly oxidized condition due to the model logic. Total H$_2$ generation mass was underpredicted because the stiffner was not modeled and the liner in the shroud was not allowed to be oxidized in MELCOR. Some difficulties were found in modeling the activation product were solved by manipulating the RN input associated with the initial fission product inventory. These problem were occurred because there are no control rod model in MELCOR. Generally the fission product release ratio showed a similar trend compared with the measured data except the activation product. which have no model to simulate in MELCOR.

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Production of Fuels from an Agricultural by-Product Biomass (농부산물 바이오매스를 이용한 연료물질의 생성)

  • Lee, Jong-Jib
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.1
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    • pp.85-94
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    • 2007
  • Rice straw, produced as an agricultural by-product, is usable biomass as fuels if depolymerized to monomer unit, because the chemical structure are similar to high octane materials found in gasoline. In this study, parameters of thermochemical degradation by solvolysis reaction of rice straw such as the effect of reaction temperature, reaction time and type of solvent on conversion yield and degradation products were investigated. It was found that the effectiveness of the solvent on the solvolysis reaction was as follows; acetone>cresol>butanol. When acetone was used as a solvent, the highest rice straw conversion was observed to be 91.5% at $500^{\circ}C$, 40 min. Combustion heating value of liquid products from thermochemical conversion processes was in the range of 7,380 cal/g. The energy yield and mass yield in acetone-solvolysis of rice straw was as high as 69.0% and 38.2 g-oil/100g-raw material after 40 min of reaction at $350^{\circ}C$. Various aliphatic and aromatic compounds were detected in the rice straw solvolysis products. The major components of the solvolysis products, that could be used as fuel, were 4-methyl-2-pentanone, 3,5,5-trimethyl-2-cyclopentan-1-one as ketones.

Numerical analysis of concrete degradation due to chloride-induced steel corrosion

  • Ayinde, Olawale O.;Zuo, Xiao-Bao;Yin, Guang-Ji
    • Advances in concrete construction
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    • v.7 no.4
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    • pp.203-210
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    • 2019
  • Concrete structures in marine environment are susceptible to chloride attack, where chloride diffusion results in the corrosion of steel bar and further lead to the cracking of concrete cover. This process causes structural deterioration and affects the response of concrete structures to different forms of loading. This paper presents the use of ABAQUS Finite Element Software in simulating the processes involved in concrete's structural degradation from chloride diffusion to steel corrosion and concrete cover cracking. Fick's law was used for the chloride diffusion, while the mass loss from steel corrosion was obtained using Faraday's law. Pressure generated by steel corrosion product at the concrete-steel interface was modeled by applying uniform radial displacements, while concrete smeared cracking alongside the Extended Finite Element Method (XFEM) was used for concrete cover cracking simulation. Results show that, chloride concentration decreases with penetration depth, but increases with exposure time at the concrete-steel interface. Cracks initiate and propagate in the concrete cover as pressure caused by the steel corrosion product increases. Furthermore, the crack width increases with the exposure time on the surface of the concrete.

Arthrobacter sp. Strain KU001 Isolated from a Thai Soil Degrades Atrazine in the Presence of Inorganic Nitrogen Sources

  • Sajjaphan, Kannika;Heepngoen, Pimpak;Sadowsky, Michael J.;Boonkerd, Nantakorn
    • Journal of Microbiology and Biotechnology
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    • v.20 no.3
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    • pp.602-608
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    • 2010
  • An atrazine-degrading bacterium, strain KU001, was obtained from a sugarcane field at the Cane and Sugar Research and Development Center at the Kasetsart University, Kamphaeng Saen Campus, Thailand. Strain KU001 had a rod-to-coccus morphological cycle during growth. Biolog carbon source analysis indicated that the isolated bacterium was Arthrobacter histidinolovorans. Sequence analysis of the PCR product indicated that the 16S rRNA gene in strain KU001 was 99% identical to the same region in Arthrobacter sp. The atrazine degradation pathway in strain KU001 consisted of the catabolic genes trzN, atzB, and atzC. Strain KU001 was able to use atrazine as a sole nitrogen source for growth, and surprisingly, atrazine degradation was not inhibited in cells grown on ammonium, nitrate, or urea, as compared with cells cultivated on growth-limiting nitrogen sources. During the atrazine degradation process, the supplementation of nitrate completely inhibited atrazine degradation activity in strain KU001, whereas ammonium and urea had no effect on atrazine degradation activity. The addition of strain KU001 to sterile or nonsterile soils resulted in the disappearance of atrazine at a rate that was 4- to 5-fold more than that achieved by the indigenous microbial community. The addition of citrate to soils resulted in enhanced atrazine degradation, where 80% of atrazine disappeared within one day following nutrient supplementation.

Degradation of the herbicide dicamba under sunlight and in soil (제초제 Dicamba의 자연광 및 토양 중 분해)

  • Oh, Kyeong-Seok;Oh, Byung-Youl;Park, Seung-Soon;Ihm, Yang-Bin;Kyung, Kee-Sung;Lee, Jae-Koo
    • The Korean Journal of Pesticide Science
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    • v.4 no.3
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    • pp.1-6
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    • 2000
  • In order to elucidate the degradation of the herbicide dicamba, the degradabilities of dicamba under sunlight and in soils were investigated. The photodegradation rate of the authentic dicamba under sunlight condition was only 3.3% after 9 weeks. 4-Hydroxy dicamba turned out to be the major product, and 5-hydroxy dicamba was also identified. Dicamba was degraded to 3,6-dichlorosalicylic acid by demethylation in the viable soil, which resulted in 14.7 to 23.2% degradation of the applied amount during 8 weeks of incubation. Meanwhile, the degradation was quite slow in the sterilize soil, which revealed that the soil microbes played a major role in dicamba degradation.

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