• Title/Summary/Keyword: Degradation product

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Analysis of Field Reliability Data with Supplementary Information on Degradation Data and Covariates (열화자료와 설명변수 정보를 고려한 사용현장 신뢰성 자료의 분석)

  • 서순근;하천수
    • Journal of Applied Reliability
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    • v.2 no.2
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    • pp.63-83
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    • 2002
  • Degradation data can provide more reliability information than traditional failure-time data, especially products with few or no failures. This paper is concerned with a method of estimating lifetime distribution from field data with supplementary information on degradation data and covariates. When a distribution of degradation rate obtained by follow-up study for a portion of products that survive after-warranty follows a reciprocal-Weibull or lognormal distribution. A time-to-failure distribution of the product follows Weibull or lognormal distribution, respectively. A method of estimating lifetime parameters for this kind of data and their asymptotic properties are studied. Effects of after-warranty report probability, follow-up rate, and proportion of degradation data on pseudo maximum likelihood estimators of these parameters are investigated.

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TREATMENT OF ANIMAL MANURE AND WASTES FOR ULTIMATE DISPOSAL - Review -

  • Winter, J.;Hilpert, R.;Schmitz, H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.5 no.2
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    • pp.199-215
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    • 1992
  • Sources of organic waste materials for aerobic and/or anaerobic degradation, or for composting of solid wastes in Germany were estimated. The basic microbiology and the energetics of these processes were compared with special emphasis on anaerobic degradation, for which a general degradation scheme of carbohydrates is presented. Advantages of anaerobic over aerobic treatment processes are pointed out and conditions for maintaining a highly stable anaerobic process as well as producing a sanitized, hygienic product are discussed. Reactor systems suitable for efficient treatment of wastes with a high or low proportion of suspended solids are principally compared and results of laboratory studies on the degradation of several wastes and animal manures summarized. Finally, a piggery slurry treatment factory for an ultimate slurry processing to obtain a dry fertilizer and a harmless, disposable liquid, as it is in operation in Helmond/Holland, is presented and preliminary process data are presented.

Isolation of Cholesterol Utilizing Bacteria and Their Degradation Pattern (콜레스테롤 이용 박테리아의 분리 및 분해 특성)

  • 최민호;조도현;박연희
    • Microbiology and Biotechnology Letters
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    • v.22 no.4
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    • pp.340-346
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    • 1994
  • Six bacterial strains capable to grow on medium containing cholesterol as sole carbon source were isolated from soil, pork fat and cheese. Three of them were tentatively identified as Rhodococcus species, Rhodococcus sp. CD-1, R. sp. CD-2, and R. sp. CD-3. All the isolates showed a varying amount of cholest-4-en-3-one as the degradation product, and three strains of Rhodococcus spp. showed rapid degradation of cholesterol. Radioisotopic studies revealed that cholesterol was degraded to non-sterol hydrophilic compounds via cholest-4-en-3-one, and presumably to C0$_{2}$- These strains showed two distinct patterns in further degradation of cholest-4-en-3-one. By one group, R. sp. CD-1 and R. sp. CD-3, cholest-4-en-3-one was rapidly converted to non-sterol inter- mediates without significant accumulation of sterol derivatives in the culture broth. In contrast, by another group, R. sp. CD-2, the substantial amount of cholest-4-en-3-one was accumulated indica- ting a lower conversion of the compound to the next metabolites.

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Degradation of Benzothiophene by Potassium Ferrate(VI) (Potassium Ferrate(VI)를 이용한 Benzothiophene 분해특성 연구)

  • Lee, Kwon-Chul;Kim, Il-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.5
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    • pp.643-649
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    • 2011
  • Degradation of benzothiophene(BT) in the aqueous phase by potassium ferrate(VI) was investigated. Potassium ferrate(VI) was prepared by the wet oxidation method. The degradation efficiency of BT was measured at various values of pH, ferrate(VI) dosage and initial concentration of BT. BT was degraded rapidly within 30 seconds by ferrate(VI). While the highest degradation efficiency was achieved at pH 5, the lowest degradation efficiency was achieved at pH 9. Also, the initial rate constant of BT increased with decreasing of the BT initial concentration. In addition, the intermediate analysis for the reaction of BT and ferrate(VI) has been conducted using GC-MS. Benzene, styrene, benzaldehyde, formaldehyde, benzoic acid, formic acid, and acetic acid were identified as reaction intermediates, and ${SO_4}^{2-}$ was identified as an end product.

Development of Reliability Acceptance Sampling Plan for the Case where the Degradation Quantity of the Performance Characteristic follows Weibull Distribution based on the Accelerated Degradation Test (성능특성치의 열화가 와이블 분포를 따를 때 가속열화시험을 활용한 신뢰성 샘플링검사계획의 개발)

  • Lim, Heonsang;Park, Jaehun;Sung, Si-Il
    • Journal of Applied Reliability
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    • v.18 no.2
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    • pp.122-129
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    • 2018
  • Purpose: This article develops an optimal reliability acceptance sampling plan for the case where the degradation quantity of the performance characteristic follows Weibull distribution. Method: For developing reliability acceptance sampling plans, the sample size and the acceptance constant are determined based on the accelerated characteristic of the test condition and the product. Results: The sample size and the acceptance constant are provided such that the constraints of the producer and the consumer risks are satisfied. Conclusion: Reliability acceptance sampling plans based on the accelerated degradation test method can be used for the quality control within a resonable amount of cost and time. In this article. an optimal reliability sampling plans are newly developed for this purpose.

Degradation of the Herbicide, Butachlor, in Soil (제초제(除草劑) Butachlor의 토양중(土壤中) 분해(分解))

  • Lee, Jae-Koo
    • Applied Biological Chemistry
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    • v.26 no.1
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    • pp.53-57
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    • 1983
  • Butachlor incubated for certain periods of time under the simulated, rather aerobic, rice-paddy conditions of two different soils exhibited two major degradation products. 2,6-diethyl-N-(butoxymethyl) acetanilide and a new product C in all cases, and a relativly small amount of another new product D named tentatively as 8-ethyl-2-hydroxy-N-(butoxymethyl)-3,4-dihydroquinoline in some cases. The supposedly microbial degradation seemed to proceed with incubation periods to some extent. An anaerobic incubation in the previous investigation showed 2,6-diethyl-N-(butoxymethyl) acetanilide as the major product, whereas the new product C with m/z 291 turned out to be the major one in the present condition. Structural elucidation of the products was done based on the fragmentation patterns of the given mass spectra and a possible pathway for their formation was postulated.

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A New Intermediate in the Degradation of Carbofuran by Sphingomonas sp. Strain SB5

  • Park Myung-Ryeol;Lee Sun-Woo;Han Tae-Ho;Oh Byung-Tack;Shim Jae-Han;Kim In-Seon
    • Journal of Microbiology and Biotechnology
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    • v.16 no.8
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    • pp.1306-1310
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    • 2006
  • Sphingomonas sp. strain SB5 could degrade carbofuran and carbofuran-7-phenol to a hydrolytic product, 2-hydroxy-3-(3-methlypropan-2-o1)phenol, and several red metabolites. However, the chemical structures of the red metabolites have largely remained unidentified. In this study, we identified the structure of one of the red metabolites as 5-(2-hydroxy-2-methyl-propyl)-2,2-dimethyl- 2,3-dihydro-naphtho[2,3-6]furan-4,6,7,9-tetrone by using mass spectrometric and NMR ($^1$H, $^{13}$C) analyses. It is suggested that the red metabolite resulted from condensation of some metabolites in the degradation of 2-hydroxy-3-(3-methlypropan-2-o1)phenol, a hydrolytic product derived from carbofuran. To our knowledge, this is the first paper to report a red metabolite in bacterial degradation of the insecticide carbofuran.

Microbial Degradation of $^{14}C-2$, 6-Diethylaniline in Soil and in Pure Culture ($^{14}C-2$, 6-Diethylaniline의 토양미생물에 의한 분해)

  • Lee, Jae-Koo;Ryu, In-Soo
    • Applied Biological Chemistry
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    • v.25 no.3
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    • pp.126-134
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    • 1982
  • When $^{14}C-2$, 6-Diethylaniline (2, 6-DEA) was incubated aerobically in soil, $^{14}CO_2$ evolved from non-sterile soil A and B was 6.5 and 10.1%, respectively, in the 21st week. Methanol could extract 3.1 and 13.5% of the radioactivity from soil A and B, respectively, 2, 6-Diethylacetanilide was detected as a degradation product in soil. Chaetomium globosum produced 2, 6-diethyl-p-benzoquinone as a degradation product in pure culture. A possible pathway was proposed to include p-hydroxylation of 2, 6-DEA, formation of quinoneimine, and the subsequent hydrolysis with the release of ammonia.

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Role of FT-IR in Assessing Lubricant Degradation - A Study on Palm Oil Methyl Ester Blended Lubricant

  • Maleque, M.A.;Masjuki, H.H.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.351-352
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    • 2002
  • In this paper, studies were made on the palm oil methyl ester (POME) added lubricants using FT-IR for monitoring oil degradation. In order to assess the degradation characteristics of POME added lubricant by FT-IR, static oxidation test was conducted using three different blended lubricants (viz, zero percent POME, five percent POME and ten percent POME with mineral-based oil) for 280 hrs. The oxidation temperature was set at $140^{\circ}C$. FT-IR quantitative data indicate an increased in oxidation products which was formed from 10% POME added lubricants after 280 hrs of oxidation test. The 5% POME added lubricant and mineral-based lubricant (without POME) showed less oxidation product after the test. From the FT-IR spectrum analysis of the oxidized oils it could be concluded that 5% POME can improve the performance of mineral-based oil by forming protective films.

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Basic Study of Degradation Test for Magnetic Contactors and Reliability Centered Maintenance

  • Ryu, Haeng-Soo;Han, Gyu-Hwan;Yoon, Nam-Sik
    • Journal of Electrical Engineering and Technology
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    • v.2 no.4
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    • pp.441-444
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    • 2007
  • The mechanical endurance is the critical characteristic of Magnetic contactors (MCs), which are widely used in such industrial equipments as elevators, cranes, and factory control rooms in order to close and open the control circuit. Testing time, however, is so long in most cases that some method of reducing the testing period is required. Therefore, the degradation test by the detected vibration of MCs is developed to reduce the testing time in this work. The degradation test data are analyzed and the prediction model is provided. Also, the possibility of this technology for Reliability Centered Maintenance (RCM) will be shown. This will reduce the period of the product development and raise the reliability of the equipment in power distribution.