• Title/Summary/Keyword: Degradation product

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A Method for Evaluating Product Degradation Status Using Product Usage Data (제품 사용데이터를 활용한 제품 열화상태 평가 방안에 대한 연구)

  • Shin, Jongho;Jun, Hongbae;Cattaneo, Cedric;Kiritsis, Dimitris;Xirouchakis, Paul
    • Korean Journal of Computational Design and Engineering
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    • v.18 no.1
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    • pp.36-48
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    • 2013
  • In general, the product is used under several circumstances including environmental and usage conditions. According to the circumstances, the product has various performance degradation processes. In order to optimize the lifecycle of product usage, it is important to observe the degradation process and make suitable decisions on product operations. However, there are not much research works in evaluating the degree of product degradation based on product usage data. Recently, due to emerging ICT (Information and Communication Technology) technologies, it becomes possible to get the product usage data. Based on the gathered data, it is possible to analyze the degree of product degradation. The analysis of product usage data can improve product use and product design with advanced decisions. To this end, this study addresses one approach based on FMEA/FMECA method, called PDMCA (Performance, Degradation Modes and Criticality Analysis) for evaluating product degradation status and making suitable decisions.

Application of Accelerated Degradation Testing for VFD (Vacuum Fluorescent Display) (VFD(Vacuum Fluorescent Display) 가속열화시험 응용사례)

  • Bae, Suk-Joo
    • Journal of Applied Reliability
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    • v.5 no.4
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    • pp.413-425
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    • 2005
  • As an alternative to traditional life testing, degradation tests can be effective in assessing product reliability when measurements of degradation leading to failure can be observed. This article presents an accelerated degradation testing for vacuum fluorescent displays (VFDs). The accelerated degradation model is based on Arrhenius-lifetime relationship for cathode temperatures. We compare the results between accelerated degradation test and test at normal use condition. Accelerated degradation test for display devices is observed as an efficient method to warrantee product reliability to customers, as well as a tool to save time and costs.

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A Study of Upgrading of Pyrolysis Wax Oil Obtained from Pyrolysis of Mixed Plastic Waste (혼합폐플라스틱 열분해 왁스오일의 고급화 연구)

  • Lee, Kyong-Hwan;Nam, Ki-Yun;Song, Kwang-Sup;Kim, Geug-Tae;Choi, Jeong-Gil
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.321-324
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    • 2009
  • Upgrading of pyrolysis wax oil has been conducted in a continuous fixed bed reactor at $450^{\circ}C$, 1hour, LHSV 3.5/h. The catalytic degradation using HZSM-5 catalyst are compared with the thermal degradation and also was studied with a function of experimental variables. The raw pyrolysis wax oil shows relatively high boiling point distribution ranging from around $300^{\circ}C$ to $550^{\circ}C$, which has considerably higher boiling point distribution than that of commercial diesel. The product characteristic from thermal degradation shows a similar trend with that of raw pyrolysis wax oil. This means the thermal degradation of pyrolysis wax oil at high degradation temperature is not sufficiently occurred. On the other hand, the catalytic degradation using HZSM-5 catalyst relative to the thermal degradation shows the high conversion of pyrolysis wax oil to light hydrocarbons. This liquid product shows high gasoline range fraction as around 90% fraction and considerably high aromatic fraction in liquid product. Also, in the catalytic degradation the experimental variable such as catalyst amount and reaction temperature was studied.

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A Comparison of the Experiment Results and the Radical Degradation Pathways in PCE through Atomic Charge Calculation

  • Lee, Byung-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.3
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    • pp.492-497
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    • 2016
  • The intermediate product resulting from the radical degradation experiment of PCE and the atomic charge gained through Gaussian03W were compared against each other. The result was that the ratio of PCE radical degradation was almost 98% or higher after the 9 hr point in reaction time. The reaction speed constant was $0.16hr^{-1}$ and it followed the first reaction. We could see that at each location of the PCE molecule, dechlorination happened at a point where the negative atomic charge was the greatest. Moreover, the intermediate product of PCE radical degradation that was confirmed in the experiment and literature coincided exactly with the intermediate product in the atomic charge calculation. Therefore, when the atomic charge is calculated, the radical degradation pathway of the organic chlorine compound could be forecast.

Analysis of Degradation Data Using Robust Experimental Design (강건 실험계획법을 이용한 열화자료의 분석)

  • 서순근;하천수
    • Journal of Korean Society for Quality Management
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    • v.32 no.1
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    • pp.113-129
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    • 2004
  • The reliability of the product can be improved by making the product less sensitive to noises. Especially, it Is important to make products robust against various noise factors encountered in production and field environments. In this paper, the phenomenon of degradation assumes a simple random coefficient degradation model to present analysis procedures of degradation data for robust experimental design. To alleviate weak points of previous studies, such as Taguchi's, Wasserman's, and pseudo failure time methods, novel techniques for analysis of degradation data using the cross array that regards amount of degradation as a dynamic characteristic for time are proposed. Analysis approach for degradation data using robust experimental design are classified by assumptions on parametric or nonparametric degradation rate(or slope). Also, a simulation study demonstrates the superiority of proposed methods over some previous works.

Reaction Conditions for Laccase Catalyzed Degradation of Bisphenol A

  • Kim, Young-Jin
    • Journal of Environmental Health Sciences
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    • v.30 no.2
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    • pp.79-83
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    • 2004
  • The oxidative degradation of BPA with laccase from Trametes versiclor was conducted in a closed, temperature controlled system containing acetate buffer for pH control. The effects of medium pH, buffer concentration, temperature and mediator on degradation of BPA were investigated. The inactivation of the enzyme by temperature and reaction product was also studied. The optimal pH for BPA degradation showed about 5. Buffer concentration did not affect BPA degradation. On the other hand, the enzyme stability was higher at low concentration buffer(25 mM). Temperature rise increased the degradation rate of BPA up to 45$^{\circ}C$. The valuable mediator of laccase for BPA was ABTS. Elevated temperature and reaction product irreversibly inactivated the enzyme.

Photodegradation and Degradation Product of Piperophos (Piperophos의 광분해 및 분해생성물에 대한 연구)

  • 민경진
    • Journal of Food Hygiene and Safety
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    • v.19 no.2
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    • pp.97-103
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    • 2004
  • The present study was performed to investigate photodegradation rate constants and degradation products of piperophos by the USEPA method. The pesticide was very stable in 16 days exposure of sunlight from October 3 to 22, 2003 and humic acid had no sensitizing effect on the photolysis of each pesticide in sunlight. In the UV irradiation test, piperophos was rapidly degraded as increasing UV intensity. In case of UV irradiation with TiO$_2$ and with TiO$_2$ powder amount, degradation of piperophos was slower than UV irradiation. In order to identify photolysis product, the extracts of degradation product was analyzed by GC/MS. The mass spectrum of photolysis product of piperophos was at m/z 166. It was suggested that the photolysis products of piperophos was O, O-dipropyl phosphorodithioate.

Degradation Rate and Velocity under Different Acidic and Alkaline Degradation Agents for Liquid Fertilizer of Rendering By-product (가축사체 랜더링 부산물의 액비화를 위한 산 및 알칼리 분해제별 분해율과 분해속도 평가)

  • Seo, Young-Jin;Seo, Dong-Cheol;Choi, Ik-Won;Kang, Se-Won;Lee, Sang-Gyu;Sung, Hwan-Hoo;Kim, Tae-Seung;Kim, Hyun-Goo;Park, Sun-Hwa;Kang, Seog-Jin;Cho, Ju-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.5
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    • pp.810-816
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    • 2012
  • In order to develop liquid fertilizer using rendering by-product, rates and velocities of degradation from rendering by-product using pig cadaver investigated under different amount of injection and time with degradation agents (KOH, NaOH, $HNO_3$ and $H_2SO_4$). The amount of residue by degradation agent of $HNO_3$ treatment method was higher than that in KOH, NaOH and $H_2SO_4$ treatment methods. The degradation velocities (K; $hr^{-1}$) of rendering by-product in KOH treatment method were higher in the order of 25% ($0.0309hr^{-1}$) > 30% ($0.0268hr^{-1}$) > 20% ($0.0142hr^{-1}$) > 15% ($0.0111hr^{-1}$) > 10% ($0.0102hr^{-1}$) of weight of rendering by-product. In all conditions, the degradation velocity of rendering by-product using $H_2SO_4$ 30% of weight of rendering by-product was rapid than that for KOH, NaOH and $HNO_3$ treatment methods. Degradation rates of rendering by-product using NaOH were similar to that of KOH and $H_2SO_4$ except for $HNO_3$ under injecting 25% and 30% of rendering by-product weight.

A Study on Reliability Prediction of System with Degrading Performance Parameter (열화되는 성능 파라메터를 가지는 시스템의 신뢰성 예측에 관한 연구)

  • Kim, Yon Soo;Chung, Young-Bae
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.38 no.4
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    • pp.142-148
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    • 2015
  • Due to advancements in technology and manufacturing capability, it is not uncommon that life tests yield no or few failures at low stress levels. In these situations it is difficult to analyse lifetime data and make meaningful inferences about product or system reliability. For some products or systems whose performance characteristics degrade over time, a failure is said to have occurred when a performance characteristic crosses a critical threshold. The measurements of the degradation characteristic contain much useful and credible information about product or system reliability. Degradation measurements of the performance characteristics of an unfailed unit at different times can directly relate reliability measures to physical characteristics. Reliability prediction based on physical performance measures can be an efficient and alternative method to estimate for some highly reliable parts or systems. If the degradation process and the distance between the last measurement and a specified threshold can be established, the remaining useful life is predicted in advance. In turn, this prediction leads to just in time maintenance decision to protect systems. In this paper, we describe techniques for mapping product or system which has degrading performance parameter to the associated classical reliability measures in the performance domain. This paper described a general modeling and analysis procedure for reliability prediction based on one dominant degradation performance characteristic considering pseudo degradation performance life trend model. This pseudo degradation trend model is based on probability modeling of a failure mechanism degradation trend and comparison of a projected distribution to pre-defined critical soft failure point in time or cycle.

Effect of Reaction Temperature Program on Thermal Degradation of Low-quality Pyrolytic Oil for Bench-scale Continuous Reaction System (벤치 규모 연속반응시스템에서 저급 열분해유 분해반응에 대한 반응온도 프로그램의 영향)

  • Lee, Kyong-Hwan;Nam, Ki-Yun
    • Clean Technology
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    • v.15 no.3
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    • pp.186-193
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    • 2009
  • The characteristics of product materials obtained from thermal degradation of low-qualify pyrolytic oil were investigated in this study. The reactants were produced by pyrolysis of mixed plastic waste with film type in a commercial rotary kiln reaction system. The properties of reactants were measured by elemental analysis, calorimetry analysis and SIMDIST analyst. The result of degradation experiments with different reaction temperature programs was discussed through product yields, cumulative yields and production rates of oil products. The multi-step reaction temperature program resulted in higher yields of product oils and lower yields of residues than one-step reaction temperature program. The product characteristics such as production yield and the rate of oil products etc. were influenced by reaction temperature program in the continuous thermal degradation.