• 제목/요약/키워드: Degradation model

검색결과 1,590건 처리시간 0.025초

절연층 폴리머의 전하 전송 및 EL 특성 (Charge Transport and Electroluminescence in Insulating Polymers)

  • 최용성;안성수;김병철;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 춘계학술대회 논문집 센서 박막재료연구회 및 광주 전남지부
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    • pp.91-97
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    • 2008
  • Polymers submitted to thermo/electrical stress suffer from ageing that can drastically affect their functional behaviour. Understanding the physico/chemical processes at play during ageing and defining transport regimes in which these mechanisms start to be critical is therefore a prime goal to prevent degradation and to develop new formulation or new materials with improved properties. It is thought that a way to define these critical regimes is to investigate under which conditions (in terms of stress parameters) light is generated in the material by electroluminescence (EL). This can happen through impact excitation/ionization involving hot carriers or upon bi-polar charge recombination (a definition that excludes light from partial discharges, which would sign an advanced stage in the degradation process). After a brief review of the EL phenomenology under DC, we introduce a numerical model of charge transport postulating a recombination controlled electroluminescence. The model output is critically evaluated with special emphasize on the comparison between simulated and experimental light emission. Finally, we comment some open questions and perspectives.

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Degradation of oxytetracycline by nano zero valent iron under UV-A irradiation: Chemical mechanism and kinetic

  • Hassanzadeh, Parisa;Ganjidoust, Hossein;Ayati, Bita
    • Advances in environmental research
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    • 제3권1호
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    • pp.29-43
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    • 2014
  • Pharmaceutical wastewater effluents are well known for their difficult elimination by traditional biotreatment methods and their important contribution to environmental pollution due to its fluctuating and recalcitrant nature. OTC is one of the nonbiodegradable antibiotics that makes antibiotic-resistant, so it can make be high risk for environment. NZVI can be a good choice for removal of OTC in aqueous solution. Response surface methodology (RSM) was used to optimize the amounts of NZVI and OTC to be used at pH 3 and under 200 W, UV-A irradiation. The responses were removal percent of absorption at 290 and 348 nm, TOC and COD of OTC. In the optimum condition, Linear model was performed 155 ppm of OTC were removed by 1000 ppm NZVI after 6.5 hours and the removal efficiency of absorption at 290 and 348 nm, TOC and COD were 87, 95, 85 and 89 percent, respectively. In the similar process, there is no organic compound after 14 hours. The parameters ORP, DO and pH were investigated for 6:30 hours to study the type of NZVI reaction in process. In the beginning of reaction, oxidation was the dominant reaction after 3 hours, photocatalytic reaction was remarkable. The mechanism of OTC degradation is proposed by HPLC/ESI-MS and four by products were found. Also the rate constants (first order kinetic chain reaction model) were 0.0099, 0.0021, 0.0010, 0.0049 and $0.0074min^{-1}$, respectively.

Textile dye wastewater treatment using coriolus versicolor

  • Sathian, S.;Radha, G.;Priya, V. Shanmuga;Rajasimman, M.;Karthikeyan, C.
    • Advances in environmental research
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    • 제1권2호
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    • pp.153-166
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    • 2012
  • Decolourization potential of white rot fungal organism, coriolus versicolor, was investigated in a batch reactor, for textile dye industry wastewater. The influence of process parameters like pH, temperature, agitation speed and dye wastewater concentration on the decolourization of textile dye wastewater was examined by using Response surface methodology (RSM). The maximum decolourization was attained at: pH- 6.8, temperature - $27.9^{\circ}C$, agitation speed - 160 rpm and dye wastewater concentration - 1:2. From the analysis of variance (ANOVA) results it was found that, the linear effect of agitation speed and dye wastewater concentration were significant for the decolourization of textile dye wastewater. At these optimized condition, the maximum decolourization and chemical oxygen demand (COD) reduction was found to be 64.4% and 79.8% respectively. Various external carbon sources were tried to enhance the decolourization of textile dye wastewater. It was observed that the addition of carbon source enhances the decolourization of textile dye wastewater. Kinetics of textile dye degradation process was studied by first order and diffusional model. From the results it was found that the degradation follows first order model with $R^2$ value of 0.9430.

변형률 적합성을 고려한 토목섬유 보강재의 장기허용강도 결정 모델 (Model to Determine Long-term Allowable Strength of Geosynthetics Reinforcements Considering Strain Compatibility)

  • 전한용;유증조;목문성
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2005년도 춘계 학술발표회 논문집
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    • pp.1580-1587
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    • 2005
  • To calculate the long-term allowable strength of geosynthetic reinforcement, replacement method was recommended. The isochronous creep curve by S. Turner was used to define the relation between creep strain and allowable strength. In isochronous curve at given time, one can read the allowable strength at allowable creep strain. The allowable strain gets from specification by directors or manufacturers according to the allowable displacement of reinforced structures. The allowable strength can be determined in relation to the allowable horizontal displacement each structures case by case. The effect of install damage on isochronous behaviors of geosynthetic reinforcement was little. In previous study, install damage increase the creep strain slightly. And the degradation was not identified. But it is supposed that degradation increase the creep strain. In conclusion, The recommended model to determine long-term allowable strength of geosynthetic reinforcements considering tensile deformation of reinforcement and soil is fit for proper, correct and economic design for reinforced earth walls.

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게이트바이어스에서 감마방사선의 IGBT 전기적 특성 (Electrical Characteristics of IGBT for Gate Bias under $\gamma$ Irradiation)

  • 노영환
    • 전자공학회논문지SC
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    • 제46권2호
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    • pp.1-6
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    • 2009
  • 금속 산화막 반도체 전계효과 트랜지스터(MOSFET)와 트랜지스터(Transistor)와 접합형으로 구성된 절연 게이트 양극성 트랜지스터(IGBT)의 게이트바이어스 상태에서 감마방사선을 조사하면 전기적특성에서 문턱전압과 전류이득의 감소가 발생한다. 저선량과 고선량에서 문턱전압의 이동은 전류의 증감에 따라 변화한다. 본 논문에서 콜렉터전류는 게이트와 에미터간의 전압으로 구동되는데 게이트 바이어스 전압과 조사량에 따라 실험하고 전기적 특성을 분석한다. 그리고 IGBT를 설계하는데 필요한 모델파라미터를 구하고 연구하는데 있다.

G-Networks Based Two Layer Stochastic Modeling of Gene Regulatory Networks with Post-Translational Processes

  • Kim, Ha-Seong;Gelenbe, Erol
    • Interdisciplinary Bio Central
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    • 제3권2호
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    • pp.8.1-8.6
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    • 2011
  • Background: Thanks to the development of the mathematical/statistical reverse engineering and the high-throughput measuring biotechnology, lots of biologically meaningful genegene interaction networks have been revealed. Steady-state analysis of these systems provides an important clue to understand and to predict the systematic behaviours of the biological system. However, modeling such a complex and large-scale system is one of the challenging difficulties in systems biology. Results: We introduce a new stochastic modeling approach that can describe gene regulatory mechanisms by dividing two (DNA and protein) layers. Simple queuing system is employed to explain the DNA layer and the protein layer is modeled using G-networks which enable us to account for the post-translational protein interactions. Our method is applied to a transcription repression system and an active protein degradation system. The steady-state results suggest that the active protein degradation system is more sensitive but the transcription repression system might be more reliable than the transcription repression system. Conclusions: Our two layer stochastic model successfully describes the long-run behaviour of gene regulatory networks which consist of various mRNA/protein processes. The analytic solution of the G-networks enables us to extend our model to a large-scale system. A more reliable modeling approach could be achieved by cooperating with a real experimental study in synthetic biology.

Super-Resolution Iris Image Restoration using Single Image for Iris Recognition

  • Shin, Kwang-Yong;Kang, Byung-Jun;Park, Kang-Ryoung
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제4권2호
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    • pp.117-137
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    • 2010
  • Iris recognition is a biometric technique which uses unique iris patterns between the pupil and sclera. The advantage of iris recognition lies in high recognition accuracy; however, for good performance, it requires the diameter of the iris to be greater than 200 pixels in an input image. So, a conventional iris system uses a camera with a costly and bulky zoom lens. To overcome this problem, we propose a new method to restore a low resolution iris image into a high resolution image using a single image. This study has three novelties compared to previous works: (i) To obtain a high resolution iris image, we only use a single iris image. This can solve the problems of conventional restoration methods with multiple images, which need considerable processing time for image capturing and registration. (ii) By using bilinear interpolation and a constrained least squares (CLS) filter based on the degradation model, we obtain a high resolution iris image with high recognition performance at fast speed. (iii) We select the optimized parameters of the CLS filter and degradation model according to the zoom factor of the image in terms of recognition accuracy. Experimental results showed that the accuracy of iris recognition was enhanced using the proposed method.

다공성 매질에서의 착화하는 방사성핵종의 이동에 대한 이론적 접근 (A Theoretical Approach on the Migration of a Chelating Radionuclide in Porous Medium)

  • 백민훈;이건재
    • Journal of Radiation Protection and Research
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    • 제17권2호
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    • pp.49-59
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    • 1992
  • 이온 또는 착화된 상태의 방사성핵종의 이동에 대한 착화제의 영향을 조사하기 위하여 새로운 모델이 제시되었다. 착화된 방사성핵종의 이동거동은 착화제와 착화된 방사성핵종의 열화를 포함하는 대류-확산 이동방정식에 의해 해석되었다. 이 수학적 모델은 해석적인 방법 에 의해 구해졌으며 지연요소를 조사함으로써 분석되었다. 계산결과들은 감소된 지연요소에 의해 착화된 방사성핵종의 이동속도가 이온형태의 방사성핵종보다 매우 빠름을 보여주었다. 따라서 원자력발전소로부터의 착화제의 발생과 환경으로의 유출을 감소시킬 수 있는 새로운 구제책이 필요하다고 하겠다.

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결함 핵연료 피폭관 내부에서의 수소 침투에 관한 개론적 고찰 (Internal Hydriding of Defected Zircaloy Cladding Fuel Rods : A Review)

  • Kim, Yongsoo;Donald R. Olander;Wonmok Jae
    • Nuclear Engineering and Technology
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    • 제25권4호
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    • pp.570-587
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    • 1993
  • 최근 전 세계적으로 내부2차수소 침투에 의한 것으로 보이는 핵연료의 심각한 파손이 잇달아 보고되었다. 본 논문에서는 결함 핵연료에서의 내부 수소 침투 현상이 개괄적으로 고찰된다. 먼저 핵연료의 피복관으로 사용되는 질코늄 합금의 개발사와 그 질코늄 합금이 사용되는 원자로 내의 운전조건이 소개되고 산화 질코늄 막에서의 수소의 투과성, 질코늄과 질코늄 합금에서의 수소의 최종 용해도와 침전도등 질코늄의 수소 침투에 관련된 기본 사항과 수소 침투가 기계적 강도에 미치는 악 영향등이 고찰된다. 결함 핵연료봉 내부에서 발생되는 수소의 대량 내부 침투의 메카니즘이 관찰된 제 현상을 중심으로 정성적으로 설명되고 이러한 수소의 대량 침투에 의한 핵연료치 파손심화를 줄이기 위한 노력의 일환으로 제시된 정량적 모델이 간단히 언급되고 이러한 정량적인 모델의 심도있는 개발을 위해 필요한 자료와 추후의 연구 내용이 설명된다.

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고온시의 경화된 시멘트 페이스트의 공극률 예측모델 (A Prediction Model on Porosity of Hardened Cement Paste under High Temperatures)

  • 이재승;정성진;정영한;김흥열;김형준
    • 한국화재소방학회논문지
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    • 제23권3호
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    • pp.103-109
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    • 2009
  • 콘크리트의 온도에 의한 재료적 특성에 대한 저감은 두 가지 메커니즘에 기인한다. 첫 번째 메커니즘은 온도범위에 따른 구성성분의 상변화이다. 초기 구성성분들은 온도 증가로 인해 다른 성분들로 상변화를 일으킨다. 두 번째 메커니즘은 온도에 의한 각 구성성분의 역학적 특성 변화이다. 따라서 고온에 노출된 콘크리트의 재료적 특성에 관한 모델 역시 이 두 가지 메커니즘을 함께 고려하여 제시되어야 한다. 본 연구는 위에서 언급한 두 가지 메커니즘을 고려한 고온에 노출된 콘크리트의 재료적 특성 모델을 제안하기 위한 기반연구로서, 온도범위에 따른 상변화를 고려한 경화된 시멘트 페이스트의 공극률에 대한 이론적 모델을 제시한다.