• Steel and Composite Structures
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• 제45권3호
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• pp.369-388
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• 2022

Composite effect between steel and recycled aggregate concrete (RAC) in steel reinforced-RAC (SRRAC) structures can effectively improve RAC's adverse mechanical properties due to the natural defects of recycled coarse aggregate (RCA). However, the performance of SRRAC after thermal exposure will have a great impact on the safety of the structure. In this paper, firstly, the mechanical properties of SRRAC structures after high temperatures exposure were tested, including 24 SRRAC columns and 32 SRRAC beams. Then, the change rules of beams and columns performance with the maximum temperature and replacement percentage were compared. Finally, the formulas to evaluate the residual bearing capacity of SRRAC beams and columns after exposure to high temperatures were established. The experimental results show that the maximum exposure temperature can be judged by the apparent phenomenon and mass loss ratio of RAC. After high temperatures exposure, the mechanical properties of SRRAC beams and columns change significantly, where the degradation of bearing capacity and stiffness is the most obvious. Moreover, it is found that the degradation degree of compression member is more serious than that of flexural member. The formulas of residual bearing capacity established by introducing influence coefficient of material strength agree well with the experimental results.

• 산업기술연구
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• 제17권
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• pp.297-303
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• 1997

This study investigates the characteristics of humic acid before and after ozonation. The results were comapred in such terms as CODCr, CODMn, TOC(total organic carbon) and molecular size distribution. As a result of ozonation (with the dose of 3mgO3/mgHumic Acid), UV NIS absorbance, CODCr, CODMn and TOC were decreased with similar tendency. The mole fraction of high molecular size was rapidly decreased and the fraction ratio of low molecular size was increased through ozone treatment. This fact can be correlated with the change in the difference and the ratio of CODCr and CODMn (the value of CODCr-CODMn and CODMn/CODCr). From this result, it can be inferred that the molecular size and the degree of chemical oxidative degradation of humic acid after ozonation were changed.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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• pp.230-231
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• 2006

We synthesized sol according to kinds(particle size/stabilized ion) of colloidal silica(CS), content ratio of alkoxysilane versus CS and reaction degree in sol solution and studied the surface property of coated gel materials. The contact angle of the thin films prepared from LHSA/N1030 CS/tetramethoxysilane(TMOS)/methyltrimethoxysilane(MTMS) sol-gel reaction system showed a little good relationship with content ratio of TMOS/MTMS silanes. The surface roughness of LHSA CS/TMOS/MTMS reaction system showed flatter than that of LHSA/N1030 CS. The thermal degradation of LHSA CS/TMOS/MTMS coating flim occurred at $550^{\circ}C$.

• 멤브레인
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• 제18권2호
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• pp.124-131
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• 2008

조직공학용 생체 물질로 사용하고자 가교제 1,3-butadiene diepoxide (BD)를 사용하여 락타이드와 가교시킨 히아루론산 막을 제조하였다. 막의 락타이드 및 BD 반응도는 핵자기 공명 분광볍으로 결정하였다. BD 농도가 높을 경우 6%이하의 성장저해 현상이 나타났으나 그 값은 세포 성장에 문제되지 않을 정도로 충분히 낮았다. 가교온도가 낮을수록 탄성 율은 증가하고 팽윤도는 감소하였다. 막의 생분해속도는 가교온도가 낮을수록 감소하였다. 약물방출 실험 결과 가교 온도가 낮을수록 막을 통한 약물 투과는 감소하였다.

• Archives of Pharmacal Research
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• 제9권2호
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• pp.87-91
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• 1986

In attempt to develop a drug delivery system using serum albumin microspheres, bovine serum albumin microspheres containing antitumar agent. Cytarabine, were prepared. The shape, surface characteristics, size distribution, behavior of in vivo distribution, drug release behavior, and degradation of albumin microsphers in animal liver issue homogenate and proteolytic enzyme were investigated. The shape of albumin microspheres was spherical and the surface was smooth and compact. The size distribution of the albumin microspheres was effected by dispertion forces during emulsification and albumin concentration. Distribution of albumin microspheres after imtravenous administration in rabbit was achieved immediately. In vitro, albumin microsphere matrix was so hard that it retained most of cytarabine except initial burst during the first 10 minutes, and the level of drug release during the initial burst was affected by heating temperature, drug/albumin microsphere matrix was so hard that it retained most of cytarabine except initial burst during the first 10 minutes, and the level of drug release during the initial burst was affected by heating temperature, drug/albumin concentration ratio and size distribution. After drug release test, the morphology of albumin microspheres was not changed. Albumin microsphere matrix was degraded by the animal liver issue homogenate and proteolytic enzyme. The degree of degradation was affected by heating temperature.

• KSBB Journal
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• 제8권3호
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• pp.237-242
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• 1993

Chitin 섬유는 인장강도가 기대치 보다 약하며 생 체조직 내에서 흡수도가 너무 빨라 수술 후 2주일 정도의 강도 유지밖에 못하는 단점 등이 었으므로, chitin과 그 구조가 비슷한 cellulose와 혼합하여 인 장력과 유연성이 크게 증대된 Chitulose 섬유를 개 발하였다. 우선 chitin과 cellulose가 잘 용해되어 혼 합펼 수 있는 용매로서 DMAc/LiCl을 탐색하였으며 이 용애계에 용해시킨 Chitulose 용액을 가지고 습 식방사하여 얻은 Chitulose 섬유 중, 용매에 대한 chitin cellulose 함량비가 1.5: 0.2얼 때, Instron 시험결과 강도와 유연성이 가장 좋았으며, 멸균시 autoclave해도 변화되지 않아 열에 매우 안정한 것 으로 나타났다. 이 섬유를 가지고 400-500g되는 백서의 피하조직에 매몰시킨 후, 생체 내 분해흡수 도를 관찰한 결과, 매볼 후 14일부터 분해되기 시작 하여 40일 후에는 완전히 분해흡수되였다.

• Archives of Pharmacal Research
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• 제8권3호
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• pp.159-168
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• 1985

In attempt to develop a drug delivery system using serum albumin microspheres, bovine serum albumin microspheres containing antitumor agent, cytarabine, were prepared. The shape, surface characteristics, size distribution, behavior of in vitro distribution, drug release behaior, and degradation of albumin microspheres in animal liver tissue homogenate and proteolytic enzyme were investigated. The shape of albumin microspheres was spherical and the surface was smooth and compact. The size distribution of the albumin microspheres was affected by dispersion forces during emulsification and albumin concentration. Distribution of albumin mirospheres after intravenous administration in rabbit was achieved immediately. In vitro, albumin microsphere matrix was so hard that it retained most of cytarabine except initial burst during the first 10 minutes, and the level of drug release during the initial burst was affected by heating temperature, drug/albumin concentration ratio and size distribution. After drug release test, the morphology of albumin micropheres was not changed. Albumin microsphere matrix was degraded by the rabbit liver tissue homogenate and proteolytic enzyme. The degree of degradation was affected by heating temperature.

• 한국환경복원기술학회지
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• 제19권6호
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• pp.101-110
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• 2016

Development activities in forest areas are analysed based on degree of slope, altitude, land cover, and prefectures in order to improve the capacity of existing regulations of 'feasibility of forest land conversion' and 'assessment of forest land characteristics' in this research. 959 land based developments between year 2007 and 2013 have been analysed. A development site includes over 50% of forest is categorized as a forest type, degree of slope is steeper than $8.5^{\circ}$ as mountain type, and a development included in the both categories as combined type. Distribution characteristics of the above three types are analysed by development categories and regions adopting Relative Mountain Development Index(RMDI). In results, 44.94% of total development activities have been carried out in Gyeongsang Do in order of urban development, industrial complex, sports facilities, and soil and stone collection quarrying. Developments less than $0.3km^2$ which are exempt from the feasibility of forest land conversion regulation consist 86 cases of forest type, 78 cases in mountain type, and 78 cases in combined type. SAI by slope range showed the highest value of 1.55 in less than $5^{\circ}$ and the lowest value of 0.69 between $20^{\circ}-25^{\circ}$. RMDI value in Gyeongsang Do where mountain ratio is 67.05% appeared 1.17, which is 5 times more than Gangwon Do where mountain area ratio is 81.30%, and 2 times more than Chungchung Do where mountain area ratio is 51.24%. Development activities in forestland in Korea showed unequal distributions and 26% of those developments were not subjected to the feasibility of forest land conversion regulation.

• Corrosion Science and Technology
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• 제19권1호
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• pp.37-42
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• 2020

Even though 304 low-carbon (304L) stainless steel was developed to enhance the resistance to intergranular corrosion and stress corrosion cracking, it is occasionally subject to degradation in harsh environments. The degree of sensitization (DOS) of 304L stainless steel was studied as a function of sensitization using a double-loop electrochemical potentiokinetic reactivation (DL-EPR) method. Sensitizing heat treatment was performed in an Ar atmosphere at 500℃, 600℃, and 700℃, with heat treatment times varying from 0 to 96 h. DOS was measured by the ratio of the peak current density value of the forward scan to that of the reverse scan. After the EPR experiment, the specimen surface was observed by scanning electron microscopy and energy dispersive spectroscopy. The DOS of the specimens heat-treated at 600℃ increased with heat treatment times up to 48 h and then decreased due to a self healing effect. The DOS was higher in specimens heat-treated at 600℃ than those at 500℃ or 700℃. Corrosion of the sensitized specimens occurred mainly at the δ-γ phase boundary. The corrosion morphology at the δ-γ phase boundary changed with sensitizing heat-treatment conditions due to differences in chromium activity in γ austenite and δ ferrite.

• Korean Chemical Engineering Research
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• 제49권6호
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• pp.775-780
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• 2011

50 $cm^2$의 활성면적을 가진 셀을 이용하여 5-셀 DMFC 스택을 제작하고 4 A의 부하로 4,000 시간 운전한 후 성능감소 및 성능 감소 원인을 분석하였다. 4,000 시간 운전 후 10 A에서 스택의 전력 밀도가 28.7% 감소하였으며 다섯개의 셀 중 두 개는 거의 성능저하가 일어나지 않았고 두 개는 약 40%의 성능 저하, 한 개는 약 60%의 성능 저하를 보였으며 각 셀별 성능저하의 정도의 차이는 스택 내에서의 위치와 상관관계가 없었다. 스택 내의 다섯 셀 중 가장 성능감소가 심하였던 셀의 경우 연료극 촉매층의 Pt 입자 크기가 증가하였으며 연료가 들어가는 쪽의 Pt 입자의 크기 증가가 더 심하였다. 그러나 4,000 시간 장기운전 후 공기극 촉매층에서는 Pt 입자 크기의 변화는 거의 없었다. 스택 내의 모든 셀에서 4,000 시간 운전 후 연료극 촉매에서 공기극 촉매로의 루테늄의 크로스오버가 SEM-EDX로 관찰되었으며 특히 성능감소가 심하였던 셀의 경우 공기극 촉매층에서 Ru/Pt의 비율이 가장 컸다.