• Title/Summary/Keyword: Degradation Curve

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Degradation Mechanisms of Organic Light-emitting Devices with a Glass Cap (유리 덮개로 보호된 OLED소자의 발광특성 저하 연구)

  • Yang Yong Suk;Chu Hye Yong;Lee Jeong-Ik;Park Sang-He;Hwang Chi Sun;Chung Sung Mook;Do Lee-Mi;Kim Gi Heon
    • Journal of the Korean Vacuum Society
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    • v.15 no.1
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    • pp.64-72
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    • 2006
  • We demonstrated organic light-emitting devices (OLEDs) based on the organic thin-film materials such as tris-(8-hydroxyquinoline) aluminum $(Alq_3)$. The structure of OLEDs was vacuum deposited upon transparent and thin glass substrates pre-coated with a transparent, conducting indium tin oxide thin film. The luminance characteristics, current, capacitance, and dispersion factor for degraded OLEDs, which were made by various bias currents $(0.5mA\;{\leq}\;I_{Bias}\;{\leq}9mA)$, are studied. The current dependences of lifetime were divided at approximately 2mA, and they represented nearly linear behaviors but had different slopes in a logarithmic plot of lifetime versus bias current. With lighting OLEDs, the anomaly of capacitance, as shown in the CV curve, occurred because of two factors, polarization in the bulk of organic materials and the interface between the metal and organic layers. In decayed OLEDs that had lower bias currents of less than 2mA, it was found that the degradation of luminance was related to both the decrease of polarization and to the lowering of the injection barrier.

Long-term corrosion-resistance of an uncoated weathering steel and its on-line and in-situ measurements (무도장 내후성강의 장기 내식성 및 그 현장즉시측정법)

  • Park, Jeong Real;Kim, Kyoo Young
    • Journal of Korean Society of Steel Construction
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    • v.16 no.4 s.71
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    • pp.415-423
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    • 2004
  • To investigate the long-term corrosion resistance of an uncoated weathering steel, an important outdoor constructional steel material, skyward surfaces of the weathering steel and a control steel initially exposed to rural and industrial atmospheres for 9 years were electrochemically tested in neutral artificial rain in terms of electrochemical potentials, impedances, and anodic potentiodynamic polarization curves. Their results were then discussed. A quite passive and stable rust layer to the artificial rain was well formed on the skyward surface of the weathering steel exposed to the industrial and rural atmospheres, and its corrosion rate in the artificial rain was measured to be about a low $3{{\mu}m}/y$. Continuous immersion of all the weathered surfaces in the artificial rain revealed the gradual degradation of the weathered corrosion layers on the steel, resulting in a cathodically controlled corrosion of the substrate steel by the electrochemical measurements. Alloy components of the weathering steel were found to retard the degradation of the weathered corrosion layers on the steel in the artificial rain. For better corrosion evaluation of the weathering steel, more electrochemical measurements of surfaces that have been exposed for more than 9 years to more closely simulated atmospheric waters are needed. These measurements are almost non-destructive and can provide online and in situ information on the corrosion rate, the development of corrosion and the conditions of rust layers on any interested surface and at any exposure time of the steel, so they can be effectively applicable to the corrosion evaluation of steel structures such as bridges, towers, and architectures by forming an electrochemical cell on an interested structural surface and by using a portable electrochemical instrument.

Decrease of PEMFC Performance by Toluene in Air (공기 중 톨루엔에 의한 고분자전해질연료전지의 성능감소)

  • Lee, Ho;Song, Jin-Hoon;Kim, Ki-Joong;Kim, Sae-Hoon;Ahn, Byung-Ki;Lim, Tae-Won;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.49 no.1
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    • pp.15-20
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    • 2011
  • The contamination effect of toluene in the airstream on PEM fuel cell performance was studied with various toluene concentration under different operation conditions. And the recovery of the cell performance by applying clean air and the removal of toluene in the air by adsorption of active carbon were investigated. The toluene concentration range used in the experiments was from 0.1 ppm to 5.0 ppm. The performance degradation and recovery were measured by constant-current discharging and electrochemical impedance spectroscopy(EIS). Toluene adsorption capacity of KOH impregnated active carbon was obtained from the adsorption isotherm curve. The severity of the contamination increased with increasing toluene concentration, current density and air stoichiometry, but decrease with increasing relative humidity. The cell performance was recovered by toluene oxidation with oxygen and water in humidified neat air. EIS showed that the increase of charge transfer resistance due to toluene adsorption on Pt surface mainly reduced the performance of PEMFC. Toluene adsorption capacity of active carbon decreased as KOH weight increased in KOH impregnated active carbon.

A Study on Pseudo-Range Correction Modeling in order to Improve DGNSS Accuracy (DGNSS 위치정확도 향상을 위한 PRC 보정정보 모델링에 관한 연구)

  • Sohn, Dong Hyo;Park, Kwan Dong
    • Journal of Korean Society for Geospatial Information Science
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    • v.23 no.4
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    • pp.43-48
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    • 2015
  • We studied on pseudo-range correction(PRC) modeling in order to improve differential GNSS(DGNSS) accuracy. The PRC is the range correction information that provides improved location accuracy using DGNSS technique. The digital correction signal is typically broadcast over ground-based transmitters. Sometimes the degradation of the positioning accuracy caused by the loss of PRC signals, radio interference, etc. To prevent the degradation, in this paper, we have designed a PRC model through polynomial curve fitting and evaluated this model. We compared two quantities, estimations of PRC using model parameters and observations from the reference station. In the case of GPS, the average is 0.1m and RMSE is 1.3m. Most of GPS satellites have a bias error of less than ${\pm}1.0m$ and a RMSE within 3.0m. In the case of GLONASS, the average and the RMSE are 0.2m and 2.6m, respectively. Most of satellites have less than ${\pm}2.0m$ for a bias error and less than 3.0m for RMSE. These results show that the estimated value calculated by the model can be used effectively to maintain the accuracy of the user's location. However;it is needed for further work relating to the big difference between the two values at low elevation.

The reliability physics of SiGe hetero-junction bipolar transistors (실리콘-게르마늄 이종접합 바이폴라 트랜지스터의 신뢰성 현상)

  • 이승윤;박찬우;김상훈;이상흥;강진영;조경익
    • Journal of the Korean Vacuum Society
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    • v.12 no.4
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    • pp.239-250
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    • 2003
  • The reliability degradation phenomena in the SiGe hetero-junction bipolar transistor (HBT) are investigated in this review. In the case of the SiGe HBT the decrease of the current gain, the degradation of the AC characteristics, and the offset voltage are frequently observed, which are attributed to the emitter-base reverse bias voltage stress, the transient enhanced diffusion, and the deterioration of the base-collector junction due to the fluctuation in fabrication process, respectively. The reverse-bias stress on the emitter-base junction causes the recombination current to rise, increasing the base current and degrading the current gain, because hot carriers formed by the high electric field at the junction periphery generate charged traps at the silicon-oxide interface and within the oxide region. Because of the enhanced diffusion of the dopants in the intrinsic base induced by the extrinsic base implantation, the shorter distance between the emitter-base junction and the extrinsic base than a critical measure leads to the reduction of the cut-off frequency ($f_t$) of the device. If the energy of the extrinsic base implantation is insufficient, the turn-on voltage of the collector-base junction becomes low, in the result, the offset voltage appears on the current-voltage curve.

A Study on Characteristics of Lincomycin Degradation by Optimized TiO2/HAP/Ge Composite using Mixture Analysis (혼합물분석을 통해 최적화된 TiO2/HAP/Ge 촉매를 이용한 Lincomycin 제거특성 연구)

  • Kim, Dongwoo;Chang, Soonwoong
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.1
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    • pp.63-68
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    • 2014
  • In this study, it was found that determined the photocatalytic degradation of antibiotics (lincomycin, LM) with various catalyst composite of titanium dioxide ($TiO_2$), hydroxyapatite (HAP) and germanium (Ge) under UV-A irradiation. At first, various type of complex catalysts were investigated to compare the enhanced photocatalytic potential. It was observed that in order to obtain the removal efficiencies were $TiO_2/HAP/Ge$ > $TiO_2/Ge$ > $TiO_2/HAP$. The composition of $TiO_2/HAP/Ge$ using a statistical approach based on mixture analysis design, one of response surface method was investigated. The independent variables of $TiO_2$ ($X_1$), HAP ($X_2$) and Ge ($X_3$) which consisted of 6 condition in each variables was set up to determine the effects on LM ($Y_1$) and TOC ($Y_2$) degradation. Regression analysis on analysis of variance (ANOVA) showed significant p-value (p < 0.05) and high coefficients for determination value ($R^2$ of $Y_1=99.28%$ and $R^2$ of $Y_2=98.91%$). Contour plot and response curve showed that the effects of $TiO_2/HAP/Ge$ composition for LM degradation under UV-A irradiation. And the estimated optimal composition for TOC removal ($Y_2$) were $X_1=0.6913$, $X_2=0.2313$ and $X_3=0.0756$ by coded value. By comparison with actual applications, the experimental results were found to be in good agreement with the model's predictions, with mean results for LM and TOC removal of 99.2% and 49.3%, respectively.

Proposed Reduction Factor of Cyclic p-y Curves for Drilled Shafts in Weathered Soil (풍화토 지반에 근입된 현장타설말뚝의 Cyclic p-y 곡선의 감소계수 제안)

  • Kim, Byung-Chul;Jeong, Sang-Seom;Ko, Jun-Young
    • Journal of the Korean Geotechnical Society
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    • v.31 no.2
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    • pp.47-63
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    • 2015
  • A fundamental study of drilled shafts subjected to lateral cyclic loading in weathered soil was carried out based on field tests and numerical analysis. The emphasis was given on quantifying the cyclic p-y curve function from lateral cyclic loading tests and three-dimensional finite element analysis. Lateral cyclic loading tests and three-dimensional finite element analysis were carried out to investigate the behavior of drilled shafts according to the direction of cyclic loading. Based on the field tests and numerical analysis, a modified lateral load transfer relationship and design chart with degradation factors were proposed by considering the characteristics of cyclic loading. It was found that the prediction by the proposed p-y curve function is in good agreement with the general trends observed by in-situ measurements, and it represents a practical improvement in the prediction of lateral displacement and bending moment distribution of drilled shafts subjected to cyclic loading.

Plasma D-dimer Can Effectively Predict the Prospective Occurrence of Ascites in Advanced Schistosomiasis Japonica Patients

  • Wu, Xiaoying;Ren, Jianwei;Gao, Zulu;Xu, Yun;Xie, Huiqun;Li, Tingfang;Cheng, Yanhua;Hu, Fei;Liu, Hongyun;Gong, Zhihong;Liang, Jinyi;Shen, Jia;Liu, Zhen;Wu, Feng;Sun, Xi;Niu, Zhongzheng;Ning, An
    • Parasites, Hosts and Diseases
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    • v.55 no.2
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    • pp.167-174
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    • 2017
  • China still has more than 30,000 patients of advanced schistosomiasis while new cases being reported consistently. D-dimer is a fibrin degradation product. As ascites being the dominating symptom in advanced schistosomiasis, the present study aimed to explore a prediction model of ascites with D-dimer and other clinical easy-achievable indicators. A case-control study nested in a prospective cohort was conducted in schistosomiasis-endemic area of southern China. A total of 291 patients of advanced schistosomiasis were first investigated in 2013 and further followed in 2014. Information on clinical history, physical examination, and abdominal ultrasonography, including the symptom of ascites was repeatedly collected. Result showed 44 patients having ascites. Most of the patients' ascites were confined in the kidney area with median area of $20mm^2$. The level of plasma D-dimer and pertinent liver function indicators were measured at the initial investigation in 2013. Compared with those without ascites, cases with ascites had significantly higher levels of D-dimer ($0.71{\pm}2.44{\mu}g/L$ vs $0.48{\pm}2.12{\mu}g/L$, P=0.005), as well ALB (44.5 vs 46.2, g/L) and Type IV collagen (50.04 vs $44.50{\mu}g/L$). Receiver operating characteristic curve analyses indicated a moderate predictive value of D-dimer by its own area under curve (AUC) of 0.64 (95% CI: 0.54-0.73) and the cutoff value as $0.81{\mu}g/L$. Dichotomized by the cutoff level, D-dimer along with other categorical variables generated a prediction model with AUC of 0.76 (95% CI: 0.68-0.89). Risks of patients with specific characteristics in the prediction model were summarized. Our study suggests that the plasma D-dimer level is a reliable predictor for incident ascites in advanced schistosomiasis japonica patients.

Impact Properties and Fractography of Structural Materials for LNG Tank at Cryogenic Temperatures (LNG 저장탱크용 재료의 극저온 충격특성과 파면해석)

  • Shin Hyung-Seop;Lee Hae-Moo;Shin Ju-Yeong;Park Jong-Seo
    • Journal of the Korean Institute of Gas
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    • v.2 no.1
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    • pp.99-106
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    • 1998
  • In order to investigate the impact properties of structural materials for LNG tank, instrumented Charpy impact tests were carried out at cryogenic temperatures. $9\%$ Ni steel showed a superior fracture resistance because of less degradation in toughness until 77 K. From the load-deflection curve obtained by an instrumented methods it was found that with the decrease of temperature from 173 K to 77 K, the peak load in the curve increased, but the total absorbed energy decreased. In addition, the energy absorbed during the crack growth was larger than one absorbed in the process of crack initiation. In SUS304L material, the energy absorbed in the process of the crack initiation was relatively large, but the energy absorbed in the process of crack growth was small, the behavior of absorbed energy was well agreed with the observations of the fracture surface which showed a relatively smooth fracture surface. The absorbed Charpy impact energy in the case of A5083 alloy was lower as compared with other steels, and some cracks were observed along the crack propagation direction at the fracture surface of 77 K.

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Methodology to Predict Service Lives of Pavement Marking Materials (도로 차선 재료의 공용수명 예측방법)

  • Oh, Heung-Un;Lee, Hyun-Seock;Jang, Jung-Hwa;Kang, Jai-Soo
    • International Journal of Highway Engineering
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    • v.10 no.4
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    • pp.151-159
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    • 2008
  • Performances of retroreflectivity vary place to place, according to traffic volumes and time lengths after striping, depending on pavement marking materials and colors. The present paper uses the nation wide data of retroreflectivity, which has been collected from freeways and then tries to develop the regression curve setting traffic volume and service life as independent variables and retroreflectivities as dependent variables. The DB system includes two year's measurement in $2005{\sim}2006$ over Korean freeway pavement marking at an interval of three months for the period. The mobile measurement system, a laserlux, was employed for the purpose. The DB has provided a lot of information about materials and performance of the specific pavement marking such as geometric features, traffic volumes, material characteristics and the installation date. This study provides the comparison of pavement marking performances under diversified conditions. Based on accumulated pavement marking performances, this study provides performance curves based on the diversified factors. The goal of the retroreflectivity modeling is to develop equations that can be used to estimate an average retroreflectivity of pavement markings as a function time since application and traffic volume. After representing the variation of retroreflectivities and estimating regression curves by linear, exponential, logarithmic and power function, the regression curve which had the highest coefficient of determination and the value similar to the last field measurement was regarded as the retroreflectivity decay model. As a result of verification, the decay model showed the signification within the 90% confidence level and especially showed the clear relation with field data according to increase of cumulative vehicle exposure. Accordingly, these models can be used to determine service lives, retroreflectivity degradation rates, and retroreflectivity of new markings.

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