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Control of electrical types in the P-doped ZnO thin film by Ar/$O_2$ gas flow ratio

  • Kim, Young-Yi;Han, Won-Suk;Kong, Bo-Hyun;Cho, Hyung-Koun;Kim, Jun-Ho;Lee, Ho-Seoung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.11-11
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    • 2008
  • ZnO has a very large exciton binding energy (60 meV) as well as thermal and chemical stability, which are expected to allow efficient excitonic emission, even at room temperature. ZnO based electronic devices have attracted increasing interest as the backplanes for applications in the next-generation displays, such as active-matrix liquid crystal displays (AMLCDs) and active-matrix organic light emitting diodes (AMOLEDs), and in solid state lighting systems as a substitution for GaN based light emitting diodes (LEDs). Most of these electronic devices employ the electrical behavior of n-type semiconducting active oxides due to the difficulty in obtaining a p-type film with long-term stability and high performance. p-type ZnO films can be produced by substituting group V elements (N, P, and As) for the O sites or group I elements (Li, Na, and K) for Zn sites. However, the achievement of p-type ZnO is a difficult task due to self-compensation induced from intrinsic donor defects, such as O vacancies (Vo) and Zn interstitials ($Zn_i$), or an unintentional extrinsic donor such as H. Phosphorus (P) doped ZnO thin films were grown on c-sapphire substrates by radio frequency magnetron sputtering with various Ar/ $O_2$ gas ratios. Control of the electrical types in the P-doped ZnO films was achieved by varying the gas ratio with out post-annealing. The P-doped ZnO films grown at a Ar/ $O_2$ ratio of 3/1 showed p-type conductivity with a hole concentration and hole mobility of $10^{-17}cm^{-3}$ and $2.5cm^2/V{\cdot}s$, respectively. X-ray diffraction showed that the ZnO (0002) peak shifted to lower angle due to the positioning of $p^{3-}$ ions with a smaller ionic radius in the $O^{2-}$ sites. This indicates that a p-type mechanism was due to the substitutional Po. The low-temperature photoluminescence of the p-type ZnO films showed p-type related neutral acceptor-bound exciton emission. The p-ZnO/n-Si heterojunction LEO showed typical rectification behavior, which confirmed the p-type characteristics of the ZnO films in the as-deposited status, despite the deep-level related electroluminescence emission.

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Numerical investigation of space effects of serial spur dikes on flow and bed changes by using Nays2D (수치모형을 이용한 수제 간격에 따른 흐름 및 하도변화 연구)

  • Lee, Kyung Su;Jang, Chang-Lae
    • Journal of Korea Water Resources Association
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    • v.49 no.3
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    • pp.241-252
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    • 2016
  • In this study, the characteristics of flow and bed changes with variation of space and length of serial spur dikes were investigated with 2 dimensional numerical simulation. Upstream spur dike was affected by flow and made a role as a single spur dike. As time increased, local scouring was developed around outside of spur dike, and migrated upstream. The aggradation of the bed at the back of spur-dike was made at the initial stage of experiment and numerical modelling. However, the aggradation of the bed was increased in the downstream area. The scour whole around a spur dike upstream was not deep as the Dimensionless spur-dike interval (b) of the dike increased. The depth of scour hole was nearly constant at the dynamic equilibrium state. The dimensionless scour depth ($y_s/H$) increased with L/b. The spur dike downstream had the characteristics of single spur dike as the L/b was larger than 10. However, the spur dike downstream was affected by the dike upstream as the L/b was less than 4, and the bed of the upstream in the spur dike was aggradated and the effects of the serial spur dikes on the bed decreased.

Heat Transfer Modeling by the Contact Condition and the Hole Distance for A-KRS Vertical Disposal (A-KRS 수직 처분공 접촉 조건 및 처분공 간의 거리에 따른 열전달 해석)

  • Kim, Dae-Young;Kim, Seung-Hyun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.17 no.3
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    • pp.313-319
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    • 2019
  • The A-KRS (Advanced Korean Reference Disposal System) is the disposal concept for pyroprocessed waste, which has been developed by the Korea Atomic Energy Research Institute. In this disposal concept, the amount of high-level radioactive waste is minimized using pyrochemical process, called pyroprocessing. The produced pyroprocessed waste is then solidified in the form of monazite ceramic. The final product of ceramic wastes will be disposed of in a deep geological repository. By the way, the decay heat is generated due to the radioactive decay of fission products and raises the temperature of buffer materials in the near field of radioactive waste repository. However, the buffer temperature must be kept below $100^{\circ}C$ according to the safety regulation. Usually, the temperature can be controlled by variation of the canister interdistance. However, KAERI has modelled thermal analysis under the boundary condition, where the waste canisters are in direct contact with each other. Therefore, a reliable temperature analysis in the disposal system may fail because of unknown thermal resistence values caused by the spatial gap between waste canisters. In the present work, we have performed thermal analyses considering the gap between heating elements and canisters at the beginning of canister loading into the radioactive waste repository. All thermal analyses were performed using the COMSOL software package.

Stability Analysis for the Pohang Deep Geothermal Borehole (포항 심부 지열 시추공의 안정성 분석 연구)

  • Lee, Min-Jung;Chang, Chan-Dong;Lee, Jun-Bok;Lee, Tae-Jong;Hwang, Se-Ho
    • Geophysics and Geophysical Exploration
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    • v.11 no.3
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    • pp.204-213
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    • 2008
  • This paper presents the analysis about the stability of the Pohang deep geothermal borehole drilled in 2006. Severe wellhole instability problems such as collapse and tight hole occurred in weak rocks while drilling. Optimal mud pressure (mud window) required to prevent instability problems during drilling is obtained from analysis on in-situ stress and rock strength. The window is bounded by vertical stress in its upper limit and by either collapse pressure or pore pressure in its lower limit. Mud window varies with different types of rocks. In the top-most semi-consolidated mudstone formation, no mud window can secure borehole stability. In some weak rock types (basic dyke and crystal tuff), the borehole pressure needs to be higher by $50{\sim}60%$ than hydrostatic pressure. That means a mud density of 1.5 g/$cm^3$ or higher should be applied during drilling in order to prevent excessive collapse around the borehole.

Growth and characterization of GaAs and AlGaAs with MBE growth temperature (MBE 성장온도에 따른 GaAs 및 AlGaAs의 전기광학적 특성)

  • Seung Woong Lee;Hoon Young Cho;Eun Kyu Kim;Suk-Ki Min;Jung Ho Park
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.4 no.1
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    • pp.11-20
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    • 1994
  • GaAs and AlGaAs epi-layers were grown on semi-insulating (100) GaAs substrate by molecular beam epitaxy (MBE) and their electrical and optical properties have been investigated by several measurements. In undoped GaAs, the p-type GaAs layers with the good surface morphology were obtained under the growth conditions of the substrate temperatures ranging from 570 to $585^{\circ}C$ and the $As_4$/Ga ratios from 17 to 22. In the samples with the growth rates of the ranges of $0.9~1.1 {\mu}m/h$, the impurity concentrations were in the ranges of $1.5{\times}10^{14}~5.6{\times}10^{14}cm^{-3}$ with the Hall mobilities of $590~410cm^2/V-s$. In the Si-doped GaAs, the n-type GaAs layers with low electro trap, only two hole deep levels were observed with uniform doping profiles (<1%). AlGaAs layers with good surface morphology and crystallinity were grown under an optimum condition of the substrate temperature, $600^{\circ}C $. 8 deep level defects were observed between 0.17~0.85eV in undoped AlGaAs layers.

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Efficiency of Geothermal Energy Generation Assessed from Measurements of Deep Depth Geothermal Conductivity (고심도 지중열전도도에 의한 지열 응용의 효율성)

  • Cho, Heuy-Nam;Lee, Dal-Heui;Jeong, Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.22 no.2
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    • pp.233-241
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    • 2012
  • The objectives of this study were to test geothermal conductivity (k), water velocity, water quantity, and pipe pressure from a ground heat exchanger in the field, and then to analyze these data in relation to the effectiveness and economical efficiency for application of geothermal energy. After installation of the apparatus required for field tests, geothermal conductivity values were obtained from three different cases (second, third, and fourth). The k values of the second case (506 m depth) and third case (151 m depth) are approximately 2.9 and 2.8, respectively. The k value of the fourth case (506 m depth, double pipe) is 2.5, which is similar to the second and third cases. This result indicates that hole depth is a critical factor for geothermal applications. Analysis of the field data (k, water velocity, water quantity, and pipe pressure) reveals that a single geothermal system at 506 m depth is more economically efficient than three geothermal systems at depths intervals of 151 m. Although it is more expensive to install a geothermal system at 506 m depth than at 151 m depth, test results showed that the geothermal system of the fourth case (506 m, double pipe) is more economically efficient than the system at 151 m depth. Considering the optional cost of maintenance, which is a non-operational expense, the geothermal system of the fourth case is economically efficient. Large cities and areas with high land prices should make greater use of geothermal energy.

Soil Mineral Nutrients and Microbes Are Responsible for Large Patch Disease Caused by Rhizoctonia solani AG2-2 in Zoysiagrass Turf (골프장 한국잔디의 Rhizoctonia solani AG2-2에 의한 Large Patch 발생 토양에서 근권 미생물과 무기영양 평가)

  • Chang, Tae-Hyun;Ru, Yeon-Ju;Lee, Yong-Se
    • Asian Journal of Turfgrass Science
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    • v.21 no.2
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    • pp.113-126
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    • 2007
  • Mineral nutrients and population dynamics of soil microbes in the root zones of zoysiagrass infected by Rhizoctonia solani AG2-2 and that of healthy plants were sampled from ten golf courses using a cup cutter(diameter $10\;cm\;{\times}\;8\;cm$ deep). Analysis of variance(ANOVA) showed significant differences in content of $NO_3$-N(P = 0.05), $NH_4$-N(P = 0.1), and K(P = 0.1) between infected and healthy samples. The content of $NO_3$-N in the soils of large patch was 9.49 mg/kg and that in soil of healthγ plants was 7.02 mg/kg. However, the content of $NH_4$-N in the soil of large patch was 12.02 mg/kg whereas 14.40 mg/kg for the soil under the healthy plants. The content of K in the soil of large patch was lower than that of soil of healthy plants. There was few numbers of Pseudomonas colonies In the soils of large patch compared to that of healthy plants. These results indicated that the content of $NO_3$-N, NH4-N, and K and the microbial population dynamics in root zones correlated to occurrence of large patch.

A methodology for assessing fatigue life of a countersunk riveted lap joint

  • Li, Gang;Renaud, Guillaume;Liao, Min;Okada, Takao;Machida, Shigeru
    • Advances in aircraft and spacecraft science
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    • v.4 no.1
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    • pp.1-19
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    • 2017
  • Fatigue life prediction of a multi-row countersunk riveted lap joint was performed numerically. The stress and strain conditions in a highly stressed substructure of the joint were analysed using a global/local finite element (FE) model coupling approach. After validation of the FE models using experimental strain measurements, the stress/strain condition in the local three-dimensional (3D) FE model was simulated under a fatigue loading condition. This local model involved multiple load cases with nonlinearity in material properties, geometric deformation, and contact boundary conditions. The resulting stresses and strains were used in the Smith-Watson-Topper (SWT) strain life equation to assess the fatigue "initiation life", defined as the life to a 0.5 mm deep crack. Effects of the rivet-hole clearance and rivet head deformation on the predicted fatigue life were identified, and good agreement in the fatigue life was obtained between the experimental and the numerical results. Further crack growth from a 0.5 mm crack to the first linkup of two adjacent cracks was evaluated using the NRC in-house tool, CanGROW. Good correlation in the fatigue life was also obtained between the experimental result and the crack growth analysis. The study shows that the selected methodology is promising for assessing the fatigue life for the lap joint, which is expected to improve research efficiency by reducing test quantity and cost.

A Pressure Applied Low-Level Laser Probe to Enhance Laser Photon Density in Soft Tissue (생체조직내 레이저 광 밀도 향상을 위한 압력 인가형 저출력 레이저 프로브)

  • Yeo, Chang-Min;Park, Jung-Hwan;Son, Tae-Yoon;Lee, Yong-Heum;Jung, Byung-Jo
    • Journal of Biomedical Engineering Research
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    • v.30 no.1
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    • pp.18-22
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    • 2009
  • Laser has been widely used in various fields of medicine. Recently, noninvasive low-level laser therapeutic medical devices have been introduced in market. However, low-level laser cannot deliver enough photon density to expect positive therapeutic results in deep tissue layer due to the light scattering property in tissue. In order to overcome the limitation, this study was aimed to develop a negative pressure applied low-level laser probe to optimize laser transmission pattern and therefore, to improve photon density in soft tissue. In order to evaluate the possibility of clinical application of the developed laser probe, ex-vivo experiments were performed with porcine skin samples and laser transmissions were quantitatively measured as a function of tissue compression. The laser probe has an air suction hole to apply negative pressure to skin, a transparent plastic body to observe variations of tissue, and a small metallic optical fiber guide to support the optical fiber when negative pressure was applied. By applying negative pressure to the laser probe, the porcine skin under the metallic optical fiber guide is compressed down and, at the same time, low-level laser is emitted into the skin. Finally, the diffusion images of laser in the sample were acquired by a CCD camera and analyzed. Compared to the peak intensity without the compression, the peak intensity of laser increased about $2{\sim}2.5$ times and FWHM decreased about $1.67{\sim}2.85$ times. In addition, the laser peak intensity was positively and linearly increased as a function of compression. In conclusion, we verified that the developed low-level laser probe can control the photon density in tissue by applying compression, and therefore, its potential for clinical applications.

Influence of Wet Chemistry Damage on the Electrical and Structural Properties in the Wet Chemistry-Assisted Nanopatterned Ohmic Electrode (Wet chemistry damage가 Nanopatterned p-ohmic electrode의 전기적/구조적 특성에 미치는 영향)

  • Lee, Young-Min;Nam, Hyo-Duk;Jang, Ja-Soon;Kim, Sang-Mook;Baek, Jong-Hyub
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.150-150
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    • 2008
  • 본 연구에서는 Wet chemistry damage가 Nanopatterned p-ohmic electrode에 미치는 영향을 연구하였다. Nanopattern은 Metal clustering을 이용하여, P-GaN와 Ohmic형성에 유리한 Pd을 50$\AA$ 적층한 후 Rapid Thermal Annealing방법으로 $850^{\circ}C$, $N_2$분위기에서 3min열처리를 하여 Pd Clustering mask 를 제작하였다. Wet etching은 $85^{\circ}C$, $H_3PO_4$조건에서 시간에 따라 Sample을 Dipping하는 방법으로 시행하였다 Ohmic test를 위해서 Circular - Transmission line Model 방법을 이용하였으며, Atomic Force Microscopy과 Parameter Analyzer로 Nanopatterned GaN surface위에 형성된 Ni/ Au Contact에서의 전기적 분석과, 표면구조분석을 시행하였다. AFM결과 Wet처리시간에 따라서 Etching형상 및 Etch rate이 영향을 받는 것이 확인되었고, Ohmic test에서 Wet chemistry처리에 의한 Tunneling parameter와 Schottky Barrier Height가 크게 증/감함을 관찰하였다. 이러한 결과들은 Wet처리에 의해서 발생된 Defect가 GaN의 표면과 하부에서 발생되며, Deep acceptor trap 및 transfer거동과 밀접한 관련이 있음을 확인 할 수 있었다. 보다 자세한 Transport 및 Wet chemical처리영향에 관한 형성 Mechanism은 후에 I-V-T, I-V, C-V, AFM결과 들을 활용하여 발표할 예정이다.

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