• 제목/요약/키워드: Decreasing current density

검색결과 115건 처리시간 0.024초

우선배향과 두절경조직 (Preferred Orientation and Microstructure of Zinc Electrodeposit in acid Chloride Solution)

  • 예길촌;박계생;손경옥
    • 한국표면공학회지
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    • 제16권4호
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    • pp.173-187
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    • 1983
  • Zinc was electrodeposited at temperature from 20$^{\circ}C$ to 60$^{\circ}C$ over the ranges of the current density from 2 to 20 A/dm2 in acid chloride bath. The cathode overpotentials increased with increasing current density and decreasing tem-perature. The (10$.$3)-(10$.$2) preferred orientation developed at cathode overpotentials below about 450mV, the (10$.$3)(10$.$2)-(10$.$1) texture developed at overpotentials between 500mV and 950mV, and the (00$.$1) (10$.$3) texture developed at cathode overpotentials about 1000mV. The (00$.$1) (10$.$3) preferred orientation was also formed at the lower potentials between 400mV and 850mV at temperatures above 40$^{\circ}C$. The preferred orientations of the zinc deposits was discussed was discussed with both cathode overpo-tential and surface energy of deposit lattice planes. The pyramid type of structure with macrostep developed at low cathode overpotentials and the truncated pyramidal type developed at higher overpotenial.

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비정질실리콘 pin태양전지에서 입사광 세기에 따른 전류 저압특성 (Incident Light Intensity Dependences of Current Voltage Characteristics for Amorphous Silicon pin Solar Cells)

  • 장진;박민
    • 대한전자공학회논문지
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    • 제23권2호
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    • pp.236-242
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    • 1986
  • The dependence of the current-voltage characteristics of hydrogenated amorphous silicon pin solar cells on the illumimination light intensity has been investigated. The open circuit voltage increases linearly with increasing the logarithm of light intensity up to AM 1, and nearly saturates above AM 1, indicating the open circuit voltage approaching the built-in potential of the pin solar cell above AM 1. The short circuit current density increase with light intensity in proportion to I**0.85 before and I**0.97 after light exposure. Since the series resistance devreses and shunt resistance increases with light intensily, the fill factor increases with light illumination. To increase the fill factor at high illumination in large area solar cells, t6he grid pattern on the ITO substrates should be made. Long light exposure on the solar cells gives rise to the increase of bulk resistance and defect states, resulting in the decrease of the fil factor and short circuit current density. The potential drop in the bulk of the a-Si:H pin solar cells at short circuit condition increases with decreasing temperature, and increases after long light exposure.

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Effects of Sulfuric Acid Concentration and Alloying Elements on the Corrosion Resistance of Cu-bearing low Alloy Steels

  • Kim, Ki Tae;Kim, Young Sik
    • Corrosion Science and Technology
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    • 제17권4호
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    • pp.154-165
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    • 2018
  • During the process of sulfur dioxide removal, flue gas desulfurization equipment provides a serious internal corrosion environment in creating sulfuric acid dew point corrosion. Therefore, the utilities must use the excellent corrosion resistance of steel desulfurization facilities in the atmosphere. Until now, the trend in developing anti-sulfuric acid steels was essentially the addition of Cu, in order to improve the corrosion resistance. The experimental alloy used in this study is Fe-0.03C-1.0Mn-0.3Si-0.15Ni-0.31Cu alloys to which Ru, Zn and Ta were added. In order to investigate the effect of $H_2SO_4$ concentration and the alloying elements, chemical and electrochemical corrosion tests were performed. In a low concentration of $H_2SO_4$ solution, the major factor affecting the corrosion rate of low alloy steels was the exchange current density for $H^+/H_2$ reaction, while in a high concentration of $H_2SO_4$ solution, the major factors were the thin and dense passive film and resulting passivation behavior. The alloying elements reducing the exchange current density in low concentration of $H_2SO_4$, and the alloying elements decreasing the passive current density in high concentration of $H_2SO_4$, together play an important role in determining the corrosion rate of Cu-bearing low alloy steels in a wide range of $H_2SO_4$ solution.

AF궤도회로에서 에너지 밀도가 정보신호 검출시간에 미치는 영향 (The Influence of Energy Density upon Detection Time of Information Signal in AF Track Circuit)

  • 김민석;황인광;이종우
    • 전기학회논문지
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    • 제60권6호
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    • pp.1146-1151
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    • 2011
  • There are two methods for train control in information transmission by using track circuit system and installing wayside transmitter. Information signal is transmitted to the on-board antenna by using rails. Continuous information about train intervals, speed and route is received by on-board antenna in AF track circuit system. The information signal is included with carrier wave and received by magnetic coupling in the on-board antenna. Therefore, it is important to define standard current level in the AF track circuit system. When current flowed to rails is low, magnetic sensors are not operated by decreasing magnetic field intensity. Hence, SNR is decreased because electric field intensity is decreased. When the SNR is decreased, there is the serious influence of noise upon demodulation. So, the frequency of information signal is not extracted in frequency response. Thus, it is possible to happen to train accident and delay as the information signal is not analyzed in the on-board antenna. In this paper, standard energy density is calculated by using Parseval's theory in UM71c track circuit. Hence, detection time of information signal is presented.

직류전기를 이용한 하수슬러지 함수율 변화특성에 관한 연구 (A Study on Characteristics of Water Content Changes of Wastewater Sludge Using Direct Current Electricity)

  • 안정모;송지윤;주재영;배윤선;박철휘
    • 상하수도학회지
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    • 제24권5호
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    • pp.609-615
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    • 2010
  • This study examined the change of water content in sludge using direct current electric equipment for decreasing the amount of sludge. The experiment showed that the average density of solids in the sludge treated by direct current before the centrifugal dewatering process was increased by 47.8%, when compared to those not treated by direct current. From the result of measuring the granularity of the sludge by the direct current treatment, that the average particle size of the sludge that was not exposed to the electric current was 52.36 ${\mu}m$, and more than 90% of the sludge was <94.29 ${\mu}m$ in size. On the other hand, the average particle size of the sludge passed through the direct current was 28.67 ${\mu}m$, and more than 90% of the sludge was 52.46 ${\mu}m$. This means that the average particle size of the sludge treated by the direct current was 45.2% smaller, and the standard deviation of granularity was improved. Because of water that separated from sludge moves to the (+) pole, larger particles become smaller and fine particles combine together, resulting in the equalization of the particle size. On the sludge after the centrifugal dehydrator, the change of the water content by the direct current was measured. The results showed that the average density of the solids was increased by 44.2% compared.

석탄 물성에 따른 직접탄소 연료전지의 전기화학 반응 특성 연구 (A Study on the Effect of Coal Properties on the Electrochemical Reactions in the Direct Carbon Fuel Cell System)

  • 안성율;엄성용;이영훈;문철언;성연모;최경민;김덕줄
    • 대한기계학회논문집B
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    • 제36권10호
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    • pp.1033-1041
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    • 2012
  • 본 논문에서는 석탄의 물리적 화학적 구조에 의한 직접탄소 연료전지 내부의 전기화학 반응 특성의 변화에 대하여 연구하였다. 석탄의 구조, 표면적 및 기공체적, 작용기의 분포 등을 분석하기 위하여 다양한 분석 기법(TGA, XRD, BET, XPS)을 사용하였다. 석탄 내부에 존재하는 탄소의 강력한 결정구조는 연료의 비표면적 및 기공크기를 축소시켜 고 전류밀도 영역에서 급격한 포텐셜의 감소를 초래한다. 표면에 분포하는 작용기는 저전류 밀도 영역에서의 전기화학 반응에 영향을 미치며, 제한 전류밀도 및 최대 전력밀도는 전체 탄소의 양과 밀접한 상관관계를 가지고 있다는 것을 확인할 수 있었다. 전해질의 물질전달 향상 및 작동온도에 의한 영향도 논하였다.

전하 트랩 및 주입 문제를 해결하기 위한 비정질 셀레늄 필름의 계면 특성 (Interfacial Properties of a-Se Thick Films to Solve Charge Trap and Injection Problems)

  • 조진욱;최장용;박창희;김재형;이형원;남상희;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.497-500
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    • 2001
  • Due to their better photosensitivity in X-ray, the amorphous selenium based photoreceptor is widely used on the X-ray conversion materials. It was possible to control the charge carrier transport of amorphous selenium by suitably alloying a-Se with other elements(e,g. As, Cl). The charge transport properties of amorphous Selenium is decided on hole which is induced from metal to selenium in metal-selenium junction and which is transferred in a-Se bulk. This phenomenon is resulted of changing electric field owing to increasing of space charge by deep trap of a-Se bulk. In this paper, We dopped the chlorine to compensate deep hole trap and deposited blocking layer using dielectric material to prevent from increasing space charge for injection charge between metal electrode and a-Se layer. We compared space charge and the decreasing of trap density through measuring dark and photo current.

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Fe-Al-Cr계 합금의 부식거동에 미치는 Al 및 Cr 합금원소의 영향 (Effects of Al and Cr Alloying Elements on the Corrosion Behavior of Fe-Al-Cr Alloy System)

  • 최한철
    • 한국표면공학회지
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    • 제38권6호
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    • pp.241-247
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    • 2005
  • Effects of Al and Cr alloying elements on the corrosion behavior of Fe-Al-Cr alloy system was investigated using potentiodynamic and cyclic potentiodynamic polarization tests(CPPT) in the $H_2SO_4$ and HCI solutions. The corrosion morphologies in Fe-Al-Cr alloy were analysed by utilizing scanning electron microscopy(SEM) and EDX. It was found that the corrosion potential of Fe-20Cr-20Al was highest whereas the critical anodic current density and passive current density were lower than that of the other alloys in 0.1 M $H_2SO_4$ solution. The second anodic peak at 1000 mV disappeared in the case of alloys containing high Al and low Cr contents. Pitting potential increased with increasing Cr content and repassivation potential decreased with decreasing Al content in 0.1 M HCI solution. Fe-Al-Cr alloy containing high Al and Cr contents showed remarkably improved pitting resistance against $Cl^-$ attack from pit morphologies.

지구단위계획(地區單位計劃)에서 건축(建築) 규모설정(規模設定)에 관한 연구(硏究) (A study on the suitable of building size in district units plan)

  • 이원근;이재국;도규환
    • 한국디지털건축인테리어학회논문집
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    • 제3권1호
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    • pp.39-49
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    • 2003
  • The height provisions, by the urban planning, describe the hightest height per width division, also define oblique line limitation by road without mentioning the highest per width division. Therefore this study will be a basic model for the standard of measuring the highest height per width division analysizing the propriety of current standard of oblique limitation. This technique is prepared to prevent the confusion and to complements the existing planning method. Therefore, it takes more time to establish this new method and to apply it to the existing condition. This study reviewed density control in District Units Plan, based on the guidelines of density, which included height, ratio of total floor to ground area, and land distribution. This study aims to provide efficient analysis by using current oblique limitation provisions Thus, proving the area rations of general residential areas are decreasing. Since the purpose of the District Units Plan is to avoid confusion and help ease the existing problematic conditions which have risen from the two above-mentioned conventional systems, further observation and research on these areas are necessary.

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황산철 도금액 중 Si 입자의 공석 특성 (Co-deposition of Si Particles During Electrodeposition of Fe in Sulfate Solution)

  • 문성모;이상열;이규환;장도연
    • 한국표면공학회지
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    • 제37권6호
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    • pp.319-325
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    • 2004
  • Fe thin films containing Si particles were prepared on metallic substrates by electrodeposition method in sulfate solutions and the content of codeposited Si particles in the films was investigated as a function of applied current density, the content of Si particels in the solution, solution pH, solution temperature and concentration of $FeSO_4$$7H_2$O in the solution. The amount of Si codeposited in the film was not dependent on the applied current density, solution pH and solution temperature, while it was dependent on the content of Si particles in the solution and the concentration of $FeSO_4$$7H_2$O in the solution. The amount of Si codeposited in the film increased with increasing content of Si particles in the solution but reached a maximum value of about 6 wt% when the content of Si particles in the solution exceeds 100 g/l. On the other hand, the content of Si codeposited in the film increased up to about 17 wt% with decreasing concentration of $FeSO_4$$7H_2$O in the solution. These results would be applied to the fabrication of very thin Fe-6.5 wt% Si sheets for electrical applications.