• Title/Summary/Keyword: Decomposition Products

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Decomposition-Based Simplification of Machined Part in Solid Model (볼륨분해를 이용한 절삭가공부품 솔리드 모델의 단순화)

  • Woo, Yonn-Hwan
    • Korean Journal of Computational Design and Engineering
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    • v.12 no.2
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    • pp.101-108
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    • 2007
  • As 3D solid modeling has been widely used in designing products, solid models of the products are directly used in various applications such as engineering analysis and process planing. However, the fully-detailed solid models may not be necessary in some application. For example, it is often more efficient to use simplified model of part of engineering analysis. Generation of mesh for the complex original model requires a quite amount of time, and the consequence of finite element analysis may not be desirable due to small and detailed geometry in the model. In this paper, a method to simplify solid models of machined part is presented. This method decomposes the delta volume of machined part, and uses the decomposed volumes to simplify the solid model. Since this method directly recognizes the features to be removed from the final model, it is independent of not only design features of specific CAD system, but also designer's design practice of design sequences.

Thermoeconomic Analysis of Power Plants with Integrated Exergy Stream (통합적 엑서지에 의한 발전 플랜트의 열경제학적 해석)

  • Kim, D.;Lee, H.;Kwak, H.
    • Proceedings of the KSME Conference
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    • 2000.04b
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    • pp.871-878
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    • 2000
  • Exergetic and thermoeconomic analysis were performed for a 500-MW combined cycle plant and a 137-MW steam power plant without decomposition of exergy stream of matter into thermal and mechanical exergies. The calculated costs of electricity are almost same within 0.5% as those obtained by the thermoeconomic method with decomposition of exergy into thermal and mechanical exergies of the combined cycle plant. However for the gas-turbine cogeneration plant having different kinds of products. the difference in the unit costs of products, obtained from the two methodologies is about 2%. Such outcome indicates that the level at which the cost balances are formulated does not affect the result of thermoeconomic analysis, that is somewhat contradictory to that concluded previously.

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Hydrogen production by catalytic decomposition of propane over carbon black catalyst in a fluidized bed (유동층 반응기에서 카본블랙 촉매를 이용한 프로판의 촉매 분해에 의한 수소생산 연구)

  • Nam, Woo-Seok;Jung, Jae-Uk;Yoon, Ki-June;Lee, Dong-Hyun;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.388-391
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    • 2006
  • A fluidized bed reactor made of quartz with 0.055m I.D. and 1.0m in height was employed for the thermocatalytic decomposition of propane to produce $CO_2-free$ hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor The propane decomposition rate used carbon black DCC-N330, Hi-900L as a catalyst. The propane decomposition reaction was carried out at the temperature range of $600-800^{\circ}C$, propane gas velocity of $1.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature on the reaction rates was investigated. Resulting production in our experiment were not only hydrogen but also several by products such as methane, ethylene, ethane, and propylene.

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The Recovery of Carbon Fiber from Carbon Fiber Reinforced Epoxy Composites for Train Body (철도차량용 폐 복합소재에서의 탄소섬유 회수)

  • Lee, Suk-Ho;Lee, Cheul-Kyu;Kim, Yong-Ki;Kim, Jung-Seok;Ju, Chang-Sik
    • Proceedings of the KSR Conference
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    • 2008.11b
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    • pp.406-415
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    • 2008
  • Recently, the amount of thermosetting plastic wastes have increased with the production of reinforced plastic composites and causes serious environmental problems. The epoxy composites, one of the versatile thermosetting plastics with excellent properties, cannot be melted down and remolded as what is done in the thermoplastic industry. In this research, a series of experiments that recovers carbon fibers from carbon fiber reinforced epoxy composites for train body was performed. We experimentally examined various decomposition processes and compared their decomposition efficiencies and mechanical property of recovered carbon fibers. For the prevention of tangle of recovered carbon fibers, each composites specimen was fixed with a Teflon supporter and no mechanical mixing was applied. Decomposition products were analyzed by scanning electron microscope (SEM), gas chromatography mass spectrometer (GC-MS), and universal testing machine (UTM). Carbon fibers could be completely recovered from decomposition process using nitric acid aqueous solution, liquid-phase thermal cracking and pyrolysis. The tensile strength losses of the recovered carbon fibers were less than 4%.

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Study on Recovery of Polymeric Raw Materials from WastePolystyrene in Motor Oil using Microwave Thermal Decomposition (마이크로웨이브 열분해(熱分解)를 이용(利用)한 폐(廢) 폴리스티렌과 모터 오일 혼합물(混合物)로부터 고분자(高分子) 원료(原料) 물질(物質) 회수(回收)에 관한 연구(硏究))

  • Kang, Tae-Won
    • Resources Recycling
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    • v.15 no.5 s.73
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    • pp.11-16
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    • 2006
  • A novel microwave-induced pyrolysis was used for the recovery of valuable products from waste polystyrene in motor oil. Quartz tube was introduced as microwave reactor and silicon carbide was used as the microwave absorbent. In the experiments, different pyrolysis conditions were applied, such as time range from 30 minutes to 1 hour and microwave input power range from 180 to 250W. The distillate products from pyrolysis were analyzed with GC/MS. Styrene, 1-methyl styrene, toluene, ethyl benzene were the four main products. Styrene recovery rate from polystyrene was around 50%. Temperature for the complete pyrolysis using microwave was around $300^{\circ}C$ which is much lower than that of conventional thermal pyrolysis.

Study of Oil Palm Biomass Resources (Part 1) - Characteristics of Thermal Decomposition of Oil Palm Biomass - (오일팜 바이오매스의 자원화 연구 I - 오일팜 바이오매스의 열분해 특성 -)

  • Sung, Yong Joo;Kim, Chul-Hwan;Cho, Hu-Seung;Sim, Sung-Woong;Lee, Gyeong-Sun;Cho, In-Jun;Kim, Se-Bin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.1
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    • pp.13-20
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    • 2013
  • In this study, oil palm biomass such as empty fruit bunch (EFP) and palm kernel shell (PKS) was used as raw materials for making pellets. EFB and PKS are valuable lignocellulosic biomass that can be used for various purposes. If EFB and PKS are used as alternative raw materials for making pellets instead of wood, wood could be saved for making pulps or other value-added products. In order to explore their combustion characteristics, EFB and PKS were analyzed using thermal gravimetric analyzer (TGA) with ultimate and proximate analyses. From the TGA results, thermal decomposition of EFB and PKS occurred in the range of 280 to $400^{\circ}C$ through devolatilization and combustion of fixed carbon. After $400^{\circ}C$, their combustion were stabilized with combustion of residual lignin and char. PKS contained more fixed carbons and less ash contents than EFB, which indicated that PKS could be more active in combustion than EFB.

Bioconversion and growth performance of Hermetia illucens in single fruit by-products

  • Bonwoo Koo;Ji Yeong Park;Eunsun Kim;Yongsoon Kim;Kwanho Park
    • International Journal of Industrial Entomology and Biomaterials
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    • v.46 no.2
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    • pp.34-40
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    • 2023
  • As agricultural production increases due to population growth, agricultural by-products that are generated at all production stages increase commensurately. Black soldier fly (BSF) (Hermetia illucens) treatment has potential as an environmentally friendly process to combat the environmental pollution caused by agricultural by-products. This study examined the utilization of BSF larvae in the decomposition of the by-products of apples and mandarins, fruits commonly produced in South Korea. The BSF test larvae were fed apple pomace or mandarin waste, and the control larvae were fed calf feed. Larval weight and size were measured at 4-day intervals until larvae reached the pre-pupal stage. Larval development time, survival rate, and BSF fecundity rate were calculated for all three substrates. Waste reduction and bioconversion ratios were also calculated. The developmental time of larvae fed with apple pomace and mandarin waste was greater than that of the control larvae. The average weight of larvae fed with the fruit by-products was less than that of the control. There was no significant difference in the survival rate of BSF larvae or the fecundity rate of BSF between the substrates used in this study. BSF larvae decomposed 48.0% and 61.5% of apple pomace and mandarin waste, respectively. The bioconversion efficiency rates of BSF larvae fed with apple pomace and mandarin waste were 9.1% and 12.1%, respectively. These results indicated that decomposition of single fruit by-products by BSF larvae is an environmentally friendly and effective bioconversion process.

Water Vapor Adsorption and Hydrogen Peroxide Decomposition on Date Pit Carbonization Products

  • Youssef, A.M.;El-Nabarawy, Th.;Ahmed, S.A. Sayed;Rashwan, W.E.
    • Carbon letters
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    • v.6 no.4
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    • pp.227-233
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    • 2005
  • Carbonization products C1, C2, C3, C4 and C5 were prepared by the carbonization of date pit in limited air, at 500, 600, 700, 800 and $1000^{\circ}C$, respectively. C1-V-600, C3-V-600, C1-V-1000 and C3-V-1000 were prepared by thermal treatment of C1 and C3 under vacuum at 600 and $1000^{\circ}C$. The textural properties were determined from nitrogen adsorption at 77 K and from carbon dioxide adsorption at 298 K. The surface pH, the FTIR spectra and the acid and base neutralization capacities of some carbons were investigated. The amounts of surface oxygen were determined by out-gassing the carbon-oxygen groups on the surface as $CO_2$ and CO. The adsorption of water vapor at 308 K on C1, C2, C3 and C4 was measured and the decomposition of $H_2O_2$ at 308 K was also investigated on C1, C2, C3, C4 and C5. The surface area and the total pore volume decreased with the rise of the carbonization temperature from 500 to $1000^{\circ}C$. The adsorption of water vapor is independent on the textural properties, while it is related to the amount of acidic carbon-oxygen groups on the surface. The catalytic activity of $H_2O_2$ decomposition does not depend on the textural properties, but directly related to the amount of basic carbon-oxygen complexes out-gassed as CO, at high temperatures.

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Exposure Assessment for Volatile Organic Compounds Generated through Extruding Work with Nylon 66 Resin (Nylon 66 수지의 압출 작업시 발생하는 휘발성유기화합물에 대한 노출평가)

  • Park, Seung-Hyun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.3
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    • pp.256-262
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    • 2014
  • Objectives: The purpose of this study was to identify the major volatile organic compounds generated during extrusion work with nylon 66 resin and evaluate causes of discomfort among extrusion workers. Methods: A thermal decomposition experiment using nylon 66 resin collected at a worksite was conducted in the laboratory. Based on hazards identified through the thermal decomposition experiment, the exposure levels of the workers were evaluated. Results: The major decomposition products were formaldehyde, acetaldehyde, aniline, cyclopentanone and diphenyl amine. These materials were identical to those sampled in the extrusion booth. The sources of the annoying smells, about which the workers had complained, were formaldehyde, aniline, diphenyl amine, and other hazards in the vapor and fine particles produced by the extrusion work. Formaldehyde, acetaldehyde, and aniline were detected from air samples among workers involved in extrusion work. However, the concentration levels were much lower than Korean occupational exposure limits. The average concentration levels of formaldehyde, acetaldehyde, and aniline were 0.0120 ppm, 0.0036 ppm and 0.0006 ppm, respectively. Conclusions: The extrusion process at around $300^{\circ}C$ thermally decomposes the nylon 66 resin, emitting formaldehyde, aniline, and other hazards, which might have made workers uncomfortable due to their smells. The workers exposure levels to volatile organic compounds were far lower than Korean occupational exposure limits. However, since formaldehyde is a human carcinogen and acetaldehyde and aniline are also confirmed animal carcinogens, it is recommended that exposure levels should be maintained at a minimum level.